U.S. patent application number 15/717897 was filed with the patent office on 2018-09-27 for alternating between deposition and treatment of diamond-like carbon.
The applicant listed for this patent is Applied Materials, Inc.. Invention is credited to Lucy Chen, Kenneth S. Collins, Yue Guo, Steven Lane, Gonzalo Antonio Monroy, Kartik Ramaswamy, Eswaranand Venkatasubramanian, Yang Yang.
Application Number | 20180274100 15/717897 |
Document ID | / |
Family ID | 63582216 |
Filed Date | 2018-09-27 |
United States Patent
Application |
20180274100 |
Kind Code |
A1 |
Yang; Yang ; et al. |
September 27, 2018 |
ALTERNATING BETWEEN DEPOSITION AND TREATMENT OF DIAMOND-LIKE
CARBON
Abstract
A method of forming a layer of diamond-like carbon on a
workpiece includes supporting the workpiece in a chamber with the
workpiece facing an upper electrode, and forming a plurality of
successive sublayers to form the layer of layer of diamond-like
carbon by alternating between depositing a sublayer of diamond-like
carbon on the workpiece in the chamber and treating the sublayer
with a plasma of the inert gas or an electron beam from the upper
electrode.
Inventors: |
Yang; Yang; (Los Gatos,
CA) ; Ramaswamy; Kartik; (San Jose, CA) ;
Venkatasubramanian; Eswaranand; (Sunnyvale, CA) ;
Collins; Kenneth S.; (San Jose, CA) ; Lane;
Steven; (Porterville, CA) ; Monroy; Gonzalo
Antonio; (San Francisco, CA) ; Chen; Lucy;
(Santa Clara, CA) ; Guo; Yue; (Menlo Park,
CA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Applied Materials, Inc. |
Santa Clara |
CA |
US |
|
|
Family ID: |
63582216 |
Appl. No.: |
15/717897 |
Filed: |
September 27, 2017 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
62476186 |
Mar 24, 2017 |
|
|
|
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C23C 16/505 20130101;
H01J 37/317 20130101; C23C 16/272 20130101; H01L 21/0234 20130101;
H01L 21/02274 20130101; C23C 16/487 20130101; H01L 21/022 20130101;
C23C 16/26 20130101; H01J 37/32568 20130101; H01J 37/32715
20130101; H01L 21/02271 20130101; H01L 21/02351 20130101; H01J
2237/3321 20130101; H01J 37/302 20130101; H01L 21/02115 20130101;
H01J 2237/332 20130101; C23C 16/56 20130101; C23C 16/4412 20130101;
C23C 16/52 20130101; H01J 37/32449 20130101; H01J 37/3233 20130101;
H01J 37/32082 20130101 |
International
Class: |
C23C 16/48 20060101
C23C016/48; C23C 16/27 20060101 C23C016/27; C23C 16/52 20060101
C23C016/52; C23C 16/56 20060101 C23C016/56; C23C 16/44 20060101
C23C016/44; H01L 21/02 20060101 H01L021/02; H01J 37/32 20060101
H01J037/32; H01J 37/302 20060101 H01J037/302; H01J 37/317 20060101
H01J037/317 |
Claims
1. An electron beam plasma reactor comprising: a plasma chamber
having a side wall; an upper electrode; a first RF source power
generator coupled to said upper electrode; a first gas supply to
provide a hydrocarbon gas; a second gas supply to provide an inert
gas; a gas distributor to deliver the hydrocarbon gas and the inert
gas to the chamber; a vacuum pump coupled to the chamber to
evacuate the chamber; a workpiece support pedestal to hold a
workpiece facing the upper electrode; and a controller configured
to operate the upper electrode, gas distributor and vacuum pump to
alternate between depositing a layer of diamond-like carbon on the
workpiece and treating the workpiece with an electron beam from the
upper electrode.
2. The reactor of claim 1, wherein the controller is configured to
cause the gas distributor to deliver the hydrocarbon gas from the
first gas supply into the chamber, and cause the first RF power
source to apply first RF power at a first frequency to the upper
electrode to generate a plasma in the chamber and produce
deposition of the layer of diamond-like carbon on the
workpiece.
3. The reactor of claim 2, comprising a lower electrode and a
second RF source power generator coupled to the lower electrode and
configured to apply second RF power at a second frequency to the
upper electrode.
4. The reactor of claim 2, wherein the controller is configured to
cause the vacuum pump to remove the hydrocarbon gas from the
chamber after deposition of the layer of diamond-like carbon on the
workpiece.
5. The reactor of claim 4, wherein the controller is configured to
after the hydrocarbon gas is removed, cause the gas distributor to
deliver the inert gas from the second gas supply into the chamber,
and cause the first RF power source to apply third RF power at a
third frequency to the upper electrode to generate a plasma of the
inert gas in the chamber and generate an electron beam from the
upper electrode toward the workpiece, the electron beam impinging
the layer of diamond-like carbon to treat the workpiece.
6. A method of forming a layer of diamond-like carbon on a
workpiece, comprising: supporting the workpiece in a chamber with
the workpiece facing an upper electrode; and forming a plurality of
successive sublayers to form the layer of layer of diamond-like
carbon by alternating between depositing a sublayer of diamond-like
carbon on the workpiece in the chamber and treating the sublayer
with a plasma of the inert gas or an electron beam from the upper
electrode.
7. The method of claim 6, wherein depositing a sublayer of
diamond-like carbon on the workpiece comprises introducing a
hydrocarbon gas into the chamber and applying first RF power at a
first frequency to the upper electrode that generates a plasma in
the chamber and produces a deposition of the sublayer of
diamond-like carbon on the workpiece.
8. The method of claim 7, wherein applying the first RF power
generates an electron beam from the upper electrode toward the
workpiece to enhance ionization of the hydrocarbon gas.
9. The method of claim 6, wherein treating the sublayer comprises
introducing an inert gas into the chamber and applying first RF
power at a second frequency to the upper electrode that generates a
plasma of the inert gas in the chamber.
10. The method of claim 9, wherein applying the second RF power
generates an electron beam from the upper electrode that impinges
the sublayer of diamond-like carbon on the workpiece.
11. A method of treating or depositing a layer of diamond-like
carbon on a workpiece in a chamber, comprising: supporting the
workpiece on a pedestal in the chamber, the workpiece facing an
upper electrode suspended from a ceiling of the chamber;
introducing an inert gas and/or hydrocarbon gas into the chamber;
applying first RF power at a first frequency to the upper electrode
that generates a plasma of the inert an inert gas and/or
hydrocarbon gas in the chamber to anneal a layer of diamond-like
carbon on the substrate or produce a deposition of diamond-like
carbon on the workpiece; and applying second RF power at a
plurality of discrete frequencies simultaneously to a lower
electrode in the pedestal, the plurality of frequencies including
second frequency and a third frequency that is higher than the
first frequency.
12. The method of claim 11, wherein the first frequency is less
than the third frequency.
13. The method of claim 12, wherein the first frequency is equal to
or less than the second frequency.
14. The method of claim 11, wherein the second frequency is less
than 2 MHz.
15. The method of claim 14, wherein the third frequency is greater
than 2 MHz.
16. An electron beam plasma reactor comprising: a plasma chamber
having a side wall; an upper electrode; a first RF source power
generator coupled to said upper electrode, the first RF source
power generator configured to apply first RF power at a first
frequency to the upper electrode; a first gas supply to provide a
hydrocarbon gas; a second gas supply to provide an inert gas; a gas
distributor to deliver the hydrocarbon gas and the inert gas to the
chamber; a vacuum pump coupled to the chamber to evacuate the
chamber; a workpiece support pedestal to hold a workpiece facing
the upper electrode; a lower electrode; a second RF source power
generator coupled to the lower electrode, the second RF RF source
power generator configured to apply second RF power at a plurality
of frequencies simultaneously to the lower electrode, the plurality
of frequencies including second frequency and a third frequency
that is higher than the first frequency; and a controller
configured to operate the upper electrode, lower electrode, gas
distributor and vacuum pump to deposit or anneal a layer of
diamond-like carbon on the workpiece.
17. The plasma reactor of claim 16, wherein the lower electrode is
supported by the workpiece support pedestal.
18. The plasma reactor of claim 17, wherein the first frequency is
less than the third frequency.
19. The plasma reactor of claim 18, wherein the first frequency is
equal to or less than the second frequency.
20. The plasma reactor of claim 16, wherein the second frequency is
less than 2 MHz.
21. The plasma reactor of claim 16, wherein the third frequency is
greater than 2 MHz.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to U.S. Application Ser.
No. 62/476,186, filed on Mar. 24, 2017, the disclosure of which is
incorporated by reference.
BACKGROUND
Technical Field
[0002] The disclosure concerns deposition or treatment in a plasma
reactor of diamond-like carbon on a workpiece such as a
semiconductor wafer.
Background Discussion
[0003] Diamond-like carbon (DLC) has been used as a coating in
various applications such as industrial tools, medical instruments,
at the like. Carbon layers with some portion of diamond-like carbon
have been used as an etchant mask for some semiconductor
fabrication processes. Diamond-like carbon has been deposited by
plasma
SUMMARY
[0004] In one aspect, a method of performing deposition of
diamond-like carbon on a workpiece in a chamber includes supporting
the workpiece in the chamber facing an upper electrode suspended
from a ceiling of the chamber, introducing a hydrocarbon gas into
the chamber, and applying first RF power at a first frequency to
the upper electrode that generates a plasma in the chamber and
produces a deposition of diamond-like carbon on the workpiece.
Applying the RF power generates an electron beam from the upper
electrode toward the workpiece to enhance ionization of the
hydrocarbon gas.
[0005] Implementations may include one or more of the following
features.
[0006] The first frequency may be between 100 kHz and 27 MHz. The
first frequency may be less than 12 MHz, e.g., the first frequency
may be about 2 Mhz. Second RF power may be applied at a second
frequency to a lower electrode in a pedestal that supports the
workpiece while the first RF power is applied to the upper
electrode. The first frequency may be equal to or less than the
second frequency.
[0007] An inert gas may be introduced into the chamber such the
plasma is a plasma of both the hydrocarbon gas and the inert
gas.
[0008] After deposition of a layer of diamond-like carbon on the
workpiece, the hydrocarbon gas may be removed from the chamber.
After removing the hydrocarbon gas, an inert gas may be introduced
into the chamber, and third RF power may be applied at a third
frequency to the upper electrode that generates a plasma of the
inert gas in the chamber and generates an electron beam from the
upper electrode toward the workpiece, the electron beam impinging
the layer of diamond-like carbon. Impinging the layer of
diamond-like carbon with the electron beam may reduce internal
stress in the layer. Fourth RF power may be applied at a fourth
frequency to a lower electrode in a pedestal that supports the
workpiece while the third RF power is applied to the upper
electrode.
[0009] In another aspect, a method of treating a layer of
diamond-like carbon on a workpiece includes supporting the
workpiece in a chamber with the layer of diamond-like carbon facing
an upper electrode, introducing an inert gas into the chamber, and
applying first RF power at a first frequency to the upper electrode
that generates a plasma in the chamber and generates an electron
beam from the upper electrode toward the workpiece, the electron
beam impinging the layer of diamond-like carbon.
[0010] Implementations may include one or more of the following
features.
[0011] Impinging the layer of diamond-like carbon with the electron
beam may reduce internal stress in the layer. Second RF power may
be applied at a second frequency to a lower electrode in a pedestal
that supports the workpiece. The first frequency may be equal to or
less than the second frequency. The inert gas may include argon or
helium.
[0012] In another aspect, a method of treating a layer of
diamond-like carbon on a workpiece, includes supporting the
workpiece in a chamber with the layer of diamond-like carbon facing
an upper electrode, introducing an inert gas into the chamber, and
applying first RF power at a first frequency to the upper electrode
such that a plasma of the inert gas is generated in the chamber and
the layer of diamond-like carbon is exposed to the plasma of the
inert gas.
[0013] Implementations may include one or more of the following
features.
[0014] The inert gas may include argon or helium. Second RF power
may be applied at a second frequency to a lower electrode in a
pedestal that supports the workpiece.
[0015] In another aspect, an electron beam plasma reactor includes
a plasma chamber having a side wall, an upper electrode, a first RF
source power generator coupled to the upper electrode, a gas supply
to provide a hydrocarbon gas, a gas distributor to deliver the
hydrocarbon gas to the chamber, a vacuum pump coupled to the
chamber to evacuate the chamber, a workpiece support pedestal to
hold a workpiece facing the upper electrode, and a controller
configured to operate the upper electrode, gas distributor and
vacuum pump to generate a plasma in the chamber that produces a
deposition of diamond-like carbon on the workpiece and cause the
first RF source to apply an RF power that generates an electron
beam from the upper electrode toward the workpiece to enhance
ionization of the hydrocarbon gas.
[0016] In another aspect, an electron beam plasma reactor includes
a plasma chamber having a side wall, an upper electrode, a first RF
source power generator coupled to the upper electrode, a gas supply
to provide an inert gas, a gas distributor to deliver the inert gas
to the chamber, a vacuum pump coupled to the chamber to evacuate
the chamber, a workpiece support pedestal to hold a workpiece
facing the upper electrode, and a controller configured to operate
the upper electrode, gas distributor and vacuum pump to generate a
plasma in the chamber that anneals a layer of diamond-like carbon
on the workpiece and to cause the first RF source to apply an RF
power that generates an electron beam from the upper electrode
toward the workpiece to impinge the layer of diamond-like
carbon.
[0017] In another aspect, an electron beam plasma reactor includes
a plasma chamber having a side wall, an upper electrode, a first RF
source power generator coupled to said upper electrode, a first gas
supply to provide a hydrocarbon gas, a second gas supply to provide
an inert gas, a gas distributor to deliver the hydrocarbon gas and
the inert gas to the chamber, a vacuum pump coupled to the chamber
to evacuate the chamber, a workpiece support pedestal to hold a
workpiece facing the upper electrode, and a controller configured
to operate the upper electrode, gas distributor and vacuum pump to
alternate between depositing a layer of diamond-like carbon on the
workpiece and treating the workpiece with an electron beam from the
upper electrode.
[0018] Implementations may include one or more of the following
features.
[0019] The controller may be configured to cause the gas
distributor to deliver the hydrocarbon gas from the first gas
supply into the chamber, and cause the first RF power source to
apply first RF power at a first frequency to the upper electrode to
generate a plasma in the chamber and produce deposition of the
layer of diamond-like carbon on the workpiece. A lower electrode
and a second RF source power generator may be coupled to the lower
electrode and configured to apply second RF power at a second
frequency to the upper electrode. The controller may be configured
to cause the vacuum pump to remove the hydrocarbon gas from the
chamber after deposition of the layer of diamond-like carbon on the
workpiece. The controller may be configured to cause the gas
distributor to deliver the inert gas from the second gas supply
into the chamber after the hydrocarbon gas is removed, and cause
the first RF power source to apply third RF power at a third
frequency to the upper electrode to generate a plasma of the inert
gas in the chamber and generate an electron beam from the upper
electrode toward the workpiece, the electron beam impinging the
layer of diamond-like carbon to treat the workpiece.
[0020] In another aspect, a method of forming a layer of
diamond-like carbon on a workpiece includes supporting the
workpiece in a chamber with the workpiece facing an upper
electrode, and forming a plurality of successive sublayers to form
the layer of layer of diamond-like carbon by alternating between
depositing a sublayer of diamond-like carbon on the workpiece in
the chamber and treating the sublayer with a plasma of the inert
gas or an electron beam from the upper electrode.
[0021] Implementations may include one or more of the following
features.
[0022] Depositing a sublayer of diamond-like carbon on the
workpiece comprises introducing a hydrocarbon gas into the chamber
and applying first RF power at a first frequency to the upper
electrode that generates a plasma in the chamber and produces a
deposition of the sublayer of diamond-like carbon on the workpiece.
Applying the first RF power may generate an electron beam from the
upper electrode toward the workpiece to enhance ionization of the
hydrocarbon gas.
[0023] Treating the sublayer may include introducing an inert gas
into the chamber and applying first RF power at a second frequency
to the upper electrode that generates a plasma of the inert gas in
the chamber. Applying the second RF power may generate an electron
beam from the upper electrode that impinges the sublayer of
diamond-like carbon on the workpiece.
[0024] In another aspect, a method of treating or depositing a
layer of diamond-like carbon on a workpiece in a chamber includes
supporting the workpiece on a pedestal in the chamber, the
workpiece facing an upper electrode suspended from a ceiling of the
chamber, introducing an inert gas and/or hydrocarbon gas into the
chamber, applying first RF power at a first frequency to the upper
electrode that generates a plasma of the inert an inert gas and/or
hydrocarbon gas in the chamber to anneal a layer of diamond-like
carbon on the substrate or produce a deposition of diamond-like
carbon on the workpiece, and applying second RF power at a
plurality of discrete frequencies simultaneously to a lower
electrode in the pedestal, the plurality of frequencies including
second frequency and a third frequency that is higher than the
second frequency.
[0025] Implementations may include one or more of the following
features.
[0026] The first frequency may be less than the third frequency.
The first frequency may be equal to or less than the second
frequency. The second frequency may be less than 2 MHz. The third
frequency may be greater than 2 MHz.
[0027] In another aspect, an electron beam plasma reactor includes
a plasma chamber having a side wall, an upper electrode, a first RF
source power generator coupled to said upper electrode, the first
RF source power generator configured to apply first RF power at a
first frequency to the upper electrode, a first gas supply to
provide a hydrocarbon gas, a second gas supply to provide an inert
gas, a gas distributor to deliver the hydrocarbon gas and the inert
gas to the chamber, a vacuum pump coupled to the chamber to
evacuate the chamber, a workpiece support pedestal to hold a
workpiece facing the upper electrode, a lower electrode, a second
RF source power generator coupled to the lower electrode, the
second RF RF source power generator configured to apply second RF
power at a plurality of frequencies simultaneously to the lower
electrode, the plurality of frequencies including second frequency
and a third frequency that is higher than the second frequency, and
a controller configured to operate the upper electrode, lower
electrode, gas distributor and vacuum pump to deposit or anneal a
layer of diamond-like carbon on the workpiece.
[0028] Implementations may include one or more of the following
features.
[0029] The lower electrode may be supported by the workpiece
support pedestal.
[0030] The first frequency may be less than the third frequency.
The first frequency may be equal to or less than the second
frequency. The second frequency may be less than 2 MHz. The third
frequency may be greater than 2 MHz.
[0031] Implementation may include, but are not limited to, one or
more of the following advantages. The deposition can be rate can be
increased, e.g., to greater than 6 .mu.m/hour at intermediate power
levels. The electron beam may enhance ionization of the hydrocarbon
gasses and increase the hydrocarbon density. The proportion of high
energy electrons can be increased, and the ratio of ions to
neutrals can be increased. This can increase the film density,
e.g., to about 2 g/cm.sup.3. In addition, the electron beam can
"cure" the deposited diamond-like carbon film to reduce film
stress. For example, the film stress can be less than 500 MPa. The
support pedestal for the workpiece does not need to be heated.
[0032] The details of one or more implementations are set forth in
the accompanying drawings and the description below. Other
potential features, aspects, and advantages will become apparent
from the description, the drawings, and the claims.
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] FIG. 1 depicts a plasma reactor.
[0034] FIG. 2 depicts another implementation of a plasma reactor in
accordance with a second embodiment.
[0035] FIG. 3 is a block diagram flow chart depicting a method of
depositing a film of diamond-like carbon.
[0036] FIG. 4 is a block diagram flow chart depicting a method of
treating a film of diamond-like carbon.
[0037] Like reference numbers and designations in the various
drawings indicate like elements.
DETAILED DESCRIPTION
Introduction
[0038] In general, it is desirable to increase the density of a
film of diamond-like carbon deposited on a workpiece, e.g., a
semiconductor wafer being used for fabrication of integrated
circuits. For example, an increased film density can provide
superior performance as an etch stop layer. Increased film density
can also reduce critical dimension variation across the workpiece.
Unfortunately, increasing the film density can cause the film
stress to increase, which can cause the diamond-like carbon film to
peel off the workpiece or cause the workpiece to bow. For example,
a diamond-like carbon film having a density greater than 2
g/cm.sup.3, at about 1 .mu.m thickness of the film, a stress less
than 500 MPa and workpiece bowing less than 200 .mu.m, could
provide could provide superior characteristics.
[0039] Two techniques can be used to improve fabrication of a film
of diamond-like carbon. First, during deposition, a high energy
electron beam can be used to enhance ionization of hydrocarbon gas;
these hydrocarbon ions are implanted into the growing film to
increase the film density. Second, during or after deposition, the
film of diamond-like carbon can be exposed to the high energy
electron beam; this "cures" (or anneals) the diamond-like carbon
film and reduces the film stress. Without being limited to any
particular theory, this curing or annealing can change the bonding
structure of the carbon film, e.g., decrease dangling bonds and
increase cross-linking.
System
[0040] Referring to FIG. 1, an electron beam plasma reactor has a
vacuum chamber body defining a chamber 100 including a side wall
102 of cylindrical shape. A ceiling 106 overlies the chamber 100,
and supports an upper electrode 108. The electrode 108 can be
formed of a process-compatible material such as silicon, carbon,
silicon carbon compound or a silicon-oxide compound, or of a metal
oxide such as aluminum oxide, yttrium oxide, or zirconium oxide.
The ceiling 106 and the upper electrode 108 may be disk-shaped. In
some implementations, an insulator or dielectric ring 109 surrounds
the upper electrode 108.
[0041] A workpiece support pedestal 110 for supporting a workpiece
111 is positioned in the chamber 100. The pedestal 110 has a
workpiece support surface 110a facing the upper electrode 108 and
can be movable in the axial direction by a lift servo 112. In some
implementations, the workpiece support pedestal 110 includes an
insulating puck 302 forming the workpiece support surface 110a, a
workpiece electrode 304 inside the insulating puck 302, and a
chucking voltage supply 305 connected to the workpiece electrode
304. Additionally, a base layer 306 underlying the insulating puck
302 has internal passages 308 for circulating a thermal medium
(e.g., a liquid) from a circulation supply 310. The circulation
supply 310 may function as a heat sink or as a heat source.
[0042] An RF power generator 120 having a VHF frequency (e.g., 160
MHz) and a lower frequency RF power generator 122 having a
frequency below the VHF range or below the HF range (e.g., in the
MF or LF range, e.g., 2 MHz) are coupled to the upper electrode 108
through an impedance match 124 via an RF feed conductor 123. The
impedance match 124 can be adapted to provide an impedance match at
the different frequencies of the RF power generators 120 and 122,
as well as filtering to isolate the power generators from one
another. The output power levels of the RF generators 120, 122 are
independently controlled by a controller 126. As will be described
in detail below, power from the RF power generators 120, 122 is
coupled to the upper electrode 108.
[0043] In some implementations, the ceiling 106 can be electrically
conductive and in electrical contact with the upper electrode 108,
and the power from the impedance match 124 can be conducted through
the ceiling 106 to the upper electrode 108. The side wall 102 can
be formed of metal and is grounded. The surface area of grounded
internal surfaces inside the upper chamber 100a can be at least
twice the surface area of the upper electrode 108. The grounded
internal surfaces inside the chamber 100 can be coated with a
process compatible material such as silicon, carbon, silicon carbon
compound or a silicon-oxide compound, or with a material such as
aluminum oxide, yttrium oxide, or zirconium oxide.
[0044] In some implementations, the ceiling 106 is a support for
the upper electrode 108 and includes an insulating layer 150
containing a chucking electrode 152 facing the upper electrode 108.
A D.C. chucking voltage supply 154 is coupled to the chucking
electrode 152 via the feed conductor 155, for electrostatically
clamping the electrode 108 to the ceiling 106. A D.C. blocking
capacitor 156 may be connected in series with the output of the
impedance match 124. The controller 126 may control the D.C.
chucking voltage supply 154. The RF feed conductor 123 from the
impedance match 124 can be connected to the electrode support or
ceiling 106 rather than being directly connected to the upper
electrode 108. In such an embodiment, RF power from the RF feed
conductor 123 can be capacitively coupled from the electrode
support to the electrode 108.
[0045] In one embodiment, gas injectors 130 provide one or more
process gases into the chamber 100 through a valve 132 and/or valve
134. A vaccum pump 320 can be used to evacuate the chamber 100.
[0046] Plasma can be produced in the chamber 100 by various bulk
and surface processes, including energetic ion bombardment of the
interior surface of the electron-emitting upper electrode 108. The
ion bombardment energy of the upper electrode 108 and the plasma
density are functions of both RF power generators 120 and 122. The
ion bombardment energy of the upper electrode 108 can be
substantially controlled by the lower frequency power from the RF
power generator 122 and the plasma density in the chamber 100 can
be substantially controlled (enhanced) by the VHF power from the RF
power generator 120. Energetic secondary electrons may be emitted
from the interior surface of the upper electrode 108. The flux of
energetic electrons from the emitting surface may comprise an
electron beam, and may have a direction substantially perpendicular
to the interior surface of the upper electrode 108, and a beam
energy of approximately the ion bombardment energy of the upper
electrode 108, which typically can range from about 10 eV to 5000
eV. The collision cross-sections for different processes depend
upon the electron energy. At low energies, cross-sections for
excitation (and dissociation in molecular gases) are larger than
for ionization, while at high energies the reverse is true. The RF
power level(s) may be advantageously selected to target various
inelastic electron collision processes.
[0047] In some implementations, the plasma density in the chamber
100 can be substantially controlled (enhanced) by the RF power from
the an optional RF power generator 174 and coil antenna 172.
[0048] At least a portion of the electron beam, comprised of the
secondary electron flux emitted from upper electrode 108 due to
energetic ion bombardment of the electrode surface, propagates
through chamber 100, producing a low electron temperature plasma,
with a plasma density that depends upon beam energy and flux, as
well as other factors such as pressure and gas composition. The
energetic beam electrons can also impinge upon the workpiece 111 or
workpiece support pedestal 110. The plasma left behind may readily
discharge any resultant surface charge caused by the electron beam
flux.
[0049] A substantially axially-directed magnetic field,
substantially parallel to the electron beam, can be optionally used
to help guide the electron beam, improving beam transport through
the chamber 100. A low frequency bias voltage or arbitrary waveform
of low repetition frequency may be applied a lower electrode 114
that is on or in the workpiece support pedestal 110. The lower
electrode 114 can be provided by the workpiece electrode 304, or
can be a separate electrode in or on the pedestal 110. The low
frequency bias voltage or waveform can selectively or alternately
extract positive and/or negative ions from the plasma and
accelerate those ions at desired energy levels to impact the
surface of the workpiece 111 for etching, cleaning, deposition, or
other materials modification.
[0050] In some implementations, an RF bias power generator 142 is
coupled through an impedance match 144 to the workpiece electrode
304 of the workpiece support pedestal 110.
[0051] In some implementations, a magnet 160 surrounds the chamber
100. The magnet can comprise a pair of magnets 160-1, 160-2
adjacent the upper and lower chambers 100a, 100b, respectively. The
pair of magnets 160-1, 160-2 can provide an axial magnetic field
suitable for confining an electron beam that is propagating from
the upper chamber 100a to the lower chamber 100b.
[0052] In some implementations, a side window 170 in the side wall
102 to the chamber 100 is formed of a material (e.g., quartz or
aluminum oxide) through which RF power may be inductively coupled.
An inductive coil antenna 172 surrounds the side window 170 and is
driven by an RF power generator 174 through an impedance match 176.
The remote plasma source 280 may introduce plasma species into the
lower chamber 100b.
[0053] In some implementations, internal passages 178 for
conducting a thermally conductive liquid or media inside the
ceiling 106 are connected to a thermal media circulation supply
180. The thermal media circulation supply 180 acts as a heat sink
or a heat source. The mechanical contact between the electrode 108
and the ceiling 106 is sufficient to maintain high thermal
conductance between the electrode 108 and the ceiling 106. In the
embodiment of FIG. 1, the force of the mechanical contact is
regulated by the electrostatic clamping force provided by the D.C.
chucking voltage supply 154.
[0054] In an alternative embodiment, an RF-driven coil antenna 290
may be provided over the ceiling 106.
[0055] A master controller 128, e.g., general purpose programmable
computer, is connected to and operable to control some or all of
the various components of the plasma reactor, e.g., the RF power
supplies 120, 122, 142, 154, 174, 350, the pumps and valves 132,
136, 140, 320, the actuators 112, and circulation supplies 180,
310.
[0056] FIG. 2 depicts a modification of the embodiment of FIG. 1 in
which the RF power (from the RF generator 120) and the lower
frequency RF power (from the RF generator 122) are delivered to the
electrode 108 through separate paths. In the embodiment of FIG. 2,
the RF generator 120 is coupled to the electrode 108 through a
folded resonator 195 overlying an edge of the electrode 108. The
lower frequency RF generator 122 is coupled to the electrode 108
via the RF feed conductor 123 through an RF impedance match 194.
The D.C. chucking voltage supply 154 is coupled to the chucking
electrode 152 through the feed conductor 155 extending through a
passage in the ceiling 106.
[0057] For some processes, a hydrocarbon gas is furnished into the
chamber 100, and RF power is applied to the electrode 108, RF power
is optionally applied to coil antenna 172 and RPS power is
optionally applied to a remote plasma source (RPS) 280. Optionally
an inert gas can be furnished into the chamber as well. A plasma is
generated in the upper chamber 100 and an accelerating voltage is
developed on the electrode 108 with respect to ground and with
respect to the plasma. The resulting energetic ion bombardment of
the electrode 108 produces secondary electron emission from
electrode surface, which constitutes an electron beam flux from the
electrode surface. This electron beam flux provides an electron
beam which enhances ionization of hydrocarbon gas.
[0058] For some processes, an inert gas is furnished into the
chamber 100, and RF power is applied to the electrode 108, RF power
is optionally applied to coil antenna 172 and RPS power is
optionally applied to a remote plasma source (RPS) 280. A plasma is
generated in the upper chamber 100 and an accelerating voltage is
developed on the electrode 108 with respect to ground and with
respect to the plasma. The resulting energetic ion bombardment of
the electrode 108 produces secondary electron emission from
electrode surface, which constitutes an electron beam flux from the
electrode surface. This electron beam flux provides an electron
beam which impinges the surface of the workpiece.
[0059] Any one the electron beam plasma reactors described above
may be employed to carry out the following method of processing a
workpiece in an electron beam plasma reactor.
[0060] Referring now to FIG. 3, a gas is supplied to the chamber
100 (610). As discussed below, the gas can be a hydrocarbon gas
and/or an inert gas, depending on the process, e.g., deposition or
"curing." RF power is applied to the upper electrode 108 to
generate a plasma that includes beam electrons (620). The beam
electrons provide an electron beam having a beam propagation
direction substantially perpendicular to both the surface of the
electrode 108 and the surface of the workpiece 111. The method can
optionally include applying RF power to the lower electrode 114
(630). The method can further include applying coupling a bias
voltage to the workpiece 111 (640).
[0061] Where the gas includes hydrocarbons, the RF power applied to
the upper electrode 108 can ionize and dissociate the hydrocarbon
gas. RF power applied to the lower electrode can main accelerates
hydrocarbon ions to implant into the film being grown, but can also
ionize and dissociate the hydrocarbon gas. In addition, the beam
electrons can also ionize and dissociate the hydrocarbon gas.
[0062] Where the gas is purely inert, the beam electrons can also
ionize and dissociate the inert gas, but can pass through and
impinge the workpiece.
[0063] The controllers, e.g., the controller 126 and/or 128, can be
implemented in digital electronic circuitry, or in computer
software, firmware, or hardware, or in combinations of them. The
controller can include one or more computer program products, i.e.,
one or more computer programs tangibly embodied in an information
carrier, e.g., in a non-transitory machine readable storage medium
or in a propagated signal, for execution by, or to control the
operation of, data processing apparatus, e.g., a programmable
processor, a computer, or multiple processors or computers. A
computer program (also known as a program, software, software
application, or code) can be written in any form of programming
language, including compiled or interpreted languages, and it can
be deployed in any form, including as a standalone program or as a
module, component, subroutine, or other unit suitable for use in a
computing environment. A computer program can be deployed to be
executed on one computer or on multiple computers at one site or
distributed across multiple sites and interconnected by a
communication network.
[0064] The processes and logic flows described in this
specification can be performed by one or more programmable
processors executing one or more computer programs to perform
functions by operating on input data and generating output. The
processes and logic flows can also be performed by, and apparatus
can also be implemented as, special purpose logic circuitry, e.g.,
an FPGA (field programmable gate array) or an ASIC (application
specific integrated circuit).
[0065] For example, the controller 128 can be programmed to
generate control signals that cause the components of the plasma
reactor to carry out the process described below.
Deposition or Treatment of Diamond-Like Carbon
[0066] The reactor of FIG. 1 or FIG. 2 may be employed to perform
deposition or treatment of a film of diamond-like carbon. In one
example, the workpiece 111 includes a semiconductive bulk layer
(e.g., monocrystalline Silicon) onto which the film of diamond-like
carbon is to be deposited.
[0067] In a process for deposition of the diamond-like carbon, a
feedstock gas is supplied to the chamber 100 by the gas supply 138.
The feedstock gas includes at least a hydrocarbon compound, e.g.,
C.sub.2H.sub.2, CH.sub.2H.sub.2, C.sub.3H.sub.6, norbornadinene,
etc.
[0068] An inert gas, e.g., argon or helium, can also be supplied to
the chamber 100. The inert gas can be used to dilute the feedstock
gas; this can increase plasma density. The inert gas can be mixed
with the feedstock gas before being delivered into the chamber 100,
or the inert gas could be delivered by separate nozzles 130, 134,
and mix in the chamber. In some implementations, the gas supply can
establish a total pressure (feedstock and inert gas) of 2 to 100
mTorr.
[0069] RF power at a first frequency is applied to the upper
electrode 108. The first frequency is a generally "low frequency,"
e.g., 100 kHz to 27 MHz. The first frequency can be less than 13
MHz, e.g., the first frequency can be 2 MHz.
[0070] RF power at a second frequency is also applied to the lower
electrode 114. The second frequency is a generally "low frequency,"
e.g., 100 kHz to 27 MHz. In some implementations, the first and
second frequency can be the same frequency. In some
implementations, the second frequency is higher than the first
frequency. For example, the second frequency can be greater than 2
MHz, e.g., the second frequency can be about 13 MHz.
[0071] Application of the RF power to the upper electrode 108 will
ignite plasma in the chamber 100. The mere presence of the plasma
will generate some hydrocarbon ions (as well as ions of the inert
gas), which can be deposited on the workpiece to grow the
diamond-like carbon film.
[0072] In addition, the electrode 108 is bombarded by the sheath
accelerated ions, causing the electrode 108 to emit secondary
electrons. The secondary electrons are accelerated by the plasma
sheath voltage to an energy on the order of hundreds to thousands
of electron volts, thus providing the secondary electron beam from
the upper electrode 108 that propagates toward the workpiece
111.
[0073] Without being limited to any particular theory, a portion of
the secondary electron beam can ionize the hydrocarbon feedstock
gas in the chamber 100, thus increasing the hydrocarbon ion density
in the plasma. The hydrocarbon ions in the plasma can be
accelerated toward the workpiece 111 by the bias power applied to
the lower electrode 114. This can cause the hydrocarbon ions to be
implanted in the diamond-like carbon film as it is being deposited,
thus increasing the film density. In effect, the film can be grown
in an ion-implantation manner.
[0074] Still without being limited to any particular theory, this
processing technique can provide a higher ratio of high energy
electrons to low energy electrons in comparison to conventional
plasmas in which electrodes are heated by RF fields to disassociate
and ionize background gases. Thus, this processing technique can
increase the ion-to-neutral ratio in comparison to conventional
plasmas.
[0075] This deposition process can be carried out with the
workpiece at a relatively low temperature, e.g., 10-60.degree. C.
Consequently, the pedestal 110 supporting the workpiece 111 does
not need to be heated. In some implementations, the pedestal 110 is
cooled. A coolant gas, e.g., helium, can flow between the pedestal
110 and the backside of the workpiece 111 to improve heat transfer
between the workpiece 111 and the pedestal 110. The workpiece 111
can be electrostatically clamped to the pedestal 110, e.g., by
application of a chucking voltage to the electrode 304.
[0076] The deposition process can proceed, e.g., for 5-100 seconds.
Selection of appropriate power levels and other processing
conditions according to the guidelines above can provide deposition
rate greater than 6 .mu.m/hour. In addition, the resulting film of
diamond-like carbon can have a density greater than 2
g/cm.sup.3.
[0077] For deposition, the electrode 108 can be formed of carbon.
In addition to generating secondary electron beams, the sputtered
carbon atoms can also redeposit on the workpiece, thus contributing
to the hydrocarbon plasma DLC deposition. As sputtered carbon atoms
do not have hydrogen atoms bonded to them, this sputtering
deposition component tends to increase film density. Therefore, a
carbon electrode can be used to increase film density and modulate
film stress.
[0078] A process for "curing" of a diamond-like carbon film begins
with the film of diamond-like carbon already formed on the
substrate. The film of diamond-like carbon could be formed
according to the process laid out above, or by a different process.
In addition, the diamond-like carbon film could be cured in the
same chamber that was used for deposition of the diamond-like
carbon film, or in a different chamber. If curing occurs in the
same chamber, then the workpiece need not be removed from the
chamber between the deposition and curing steps.
[0079] In the "curing" process, an inert gas, e.g., argon or
helium, is be supplied to the chamber 100 (the feedstock gas is not
supplied in this process). The gas supply can establish a pressure
of 10 to 200 mTorr.
[0080] RF power is supplied to the upper electrode 108 and the
lower electrode 114 as described above. In some implementations,
the frequencies used for curing can be the same as the frequencies
used for deposition. In some implementations, the frequencies used
for curing are different than the frequencies used for deposition.
The frequencies can be in the range of 100 KHz to 80 MHz.
[0081] The workpiece can be subjected to these conditions for,
e.g., 2 seconds to 5 minutes.
[0082] Without being limited to any particular theory, a portion of
the secondary electron beam can pass through the plasma of inert
gas and directly impinge the layer on the workpiece 111. These
electrons can drive off hydrogen from the layer, and can decrease
dangling bonds and increase cross-linking. As a result, stress in
the deposited layer can be reduced.
[0083] An alternative process for "curing" of a diamond-like carbon
film is performed as the process discussed above, e.g., with a
plasma of inert gas, but the power and frequencies applied to the
upper electrode 108 and lower electrode 110 are such that a
secondary electron beam is not generated. Thus, the workpiece is
simply exposed to the plasma of inert gas.
[0084] In some implementations, a film of diamond-like carbon can
be grown by repeatedly alternating between the deposition and
"curing" processes. The same chamber can be used for both
processes; the workpiece does not need to be removed between
processes. For example, after deposition of an initial layer of
diamond-like carbon, the chamber the feedstock gas can be evacuated
from the chamber 100 and the chamber 100 refilled with the inert
gas. This inert gas is then used to perform the "curing" process.
After the curing process, the feedstock gas is reintroduced into
the chamber 100, and the deposition process is repeated to form
another layer of diamond-like carbon over the initial layer. The
second layer of diamond-like carbon can then be subjected to the
"curing" process. Referring to FIG. 8, the deposition step (650)
and "curing" step (660) can be iterated (670), thus depositing and
treating consecutive layers onto the workpiece, until a film of a
desired thickness has been formed.
[0085] In some implementations, multiple frequencies of bias power
can be applied simultaneously to the same electrode, e.g., to the
lower electrode 114. Use of multiple frequencies of bias power can
enhance the film density and reduce the film stress. The lower
frequency RF power can boost ion bombarding energy, and applying
higher frequencies RF power simultaneously can increase ion flux.
Each of the frequencies can be in the range of 100 KHz to 80 MHz.
The lower frequency can be at 2 MHz or below, whereas the higher
frequency can be above 2 MHz. For example, a combination of 2 MHz
and 13 MHz, or 400 KHz and 13 MHz, etc., can be applied to the
lower electrode 114. In addition, three or more frequencies could
be applied.
[0086] While the foregoing is directed to various implementations,
other and implementations may be devised that are within the scope
of the claims that follow.
* * * * *