U.S. patent number 3,898,039 [Application Number 05/430,281] was granted by the patent office on 1975-08-05 for article having fumigant containing substrate for diffusion promoting candle.
Invention is credited to Tong Joe Lin.
United States Patent |
3,898,039 |
Lin |
August 5, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Article having fumigant containing substrate for diffusion
promoting candle
Abstract
An article of manufacture comprising a substrate, a particulate
carrier and a binder at least part of at least one surface of said
substrate bearing a fumigant, said fumigant diffusible from said
article upon exposure to the thermal energy of a candle. The
fumigant-bearing substrate in combination with a candle is
particularly useful as a fragrance candle.
Inventors: |
Lin; Tong Joe (Los Angeles,
CA) |
Family
ID: |
26949641 |
Appl.
No.: |
05/430,281 |
Filed: |
January 2, 1974 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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263060 |
Jun 15, 1972 |
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Current U.S.
Class: |
422/125; 424/40;
431/288; 44/275; 424/416 |
Current CPC
Class: |
F21V
33/0004 (20130101); F21S 13/00 (20130101); C11C
5/002 (20130101); C11C 5/008 (20130101) |
Current International
Class: |
C11C
5/00 (20060101); F21V 33/00 (20060101); F21S
13/00 (20060101); A61l 009/02 (); C11c 005/00 ();
A01n 017/08 () |
Field of
Search: |
;21/55,108-111,116-120
;424/18,15,16,17,19-24 ;117/121.2,137 ;44/7.5 ;431/126,288
;252/425.5,449,451,315,316 ;161/168-170 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Hawley, Gessner G., The Condensed Chemical Dictionary, 8th ed., Van
Nostrand Reinhold Company, New York, N.Y., 1971, p. 714..
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Primary Examiner: Wolk; Morris O.
Assistant Examiner: Lovercheck; Dale
Parent Case Text
This application is a continuation-in-part of application Ser. No.
263,060, filed June 15, now abandoned.
Claims
I claim:
1. An article of manufacture comprising a substrate, a coating on
at least part of at least one surface of said substrate, said
coating consisting essentially of a mixture of at least one
fumigant and at least one carrier in particulate form, said mixture
being dispersed in a binder having a melting point of about
100.degree. to about 300.degree. C, said coating being at least
partially permeable to permit the escape of the fumigant to the
surrounding atmosphere when said coating is exposed to the thermal
energy of a lighted candle.
2. Article of claim 1 in which the substrate is of hollow
cylindrical shape.
3. Article of claim 2 in which the substrate is about 6 cm internal
diameter.
4. Article of claim 2 in which the substrate is wax, glass,
ceramic, earthenware, plastic or metal.
5. Article of claim 3 in which the substrate is wax, glass,
ceramic, earthenware, plastic or metal.
6. Article of claim 4 in which the fumigant is an incense, a
perfume, a medicament, an insecticide or an insect repellent.
7. Article of claim 5 in which the fumigant is an incense, a
perfume, a medicament, an insecticide or an insect repellent.
8. Article of claim 1 in which said carrier is calcium sulfate,
talc, silica gel, titanium dioxide, iron oxide or bentonite.
9. Article of claim 1 in which said binder is carboxy methyl
cellulose, polyvinyl alcohol, polyvinyl acetate or hydroxy propyl
cellulose.
10. Article of claim 8 in which said binder is carboxy methyl
cellulose, polyvinyl alcohol, polyvinyl acetate or hydroxypropyl
cellulose.
11. Article of claim 10 in which the coating contains a
colorant.
12. Article of claim 11 in which the coating contains a filler.
13. Article of claim 12 in which the coating contains a
plasticizer.
14. In combination, the article of claim 4 and a candle, said
surface bearing said fumigant being substantially parallel to a
longitudinal axis of said candle and wherein said fumigant is
diffusible from said article when said coating is exposed to
thermal energy from said candle when lighted.
15. In combination, the article of claim 8 and a candle, said
surface bearing said fumigant being substantially parallel to a
longitudinal axis of said candle and wherein said fumigant is
diffusible from said article when said coating is exposed to
thermal energy from said candle when lighted.
16. In combination, the article of claim 10 and a candle, said
surface bearing said fumigant being substantially parallel to a
longitudinal axis of said candle and wherein said fumigant is
diffusible from said article when said coating is exposed to
thermal energy from said candle when lighted.
17. In combination, the article of claim 11 and a candle, said
surface bearing said fumigant being substantially parallel to a
longitudinal axis of said candle and wherein said fumigant is
diffusible from said article when said coating is exposed to
thermal energy from said candle when lighted.
18. In combination, the article of claim 1 and a candle, a
longitudinal axis of said surface bearing said fumigant being
substantially parallel to a longitudinal axis of said candle, and
wherein said fumigant is diffusible from said article when said
coating is exposed to thermal energy from said candle when
lighted.
19. Article according to claim 1 in which said fumigant is in an
amount of about 0.2 - 8 weight percent based on the weight of the
binder.
20. Article according to claim 19 in which the fumigant is about
2.5 - 3.5 weight percent.
21. Article according to claim 20 in which the fumigant is about 3
weight percent.
22. Article according to claim 2 in which said cylinder has a
diameter of about 3 - 10 cm.
23. Article according to claim 22 in which said diameter is about 5
- 7 cm.
24. Article according to claim 1 in which said fumigant is an
encapsulated liquid.
25. Article according to claim 24 in which said fumigant is
microencapsulated in a gelatin.
26. Article according to claim 1 in which said fumigant diffuses
into surrounding atmosphere by vaporization or sublimation after
exposure of said article to the thermal energy from a lighted
candle.
27. An article of manufacture comprising a substrate, a coating on
at least part of at least one surface of said substrate, said
coating consisting essentially of a mixture of:
a. at least one fumigant;
b. at least one carrier in particle form selected from the group
consisting of calcium sulfate, talc, silica gel, dicalcium
phosphate, kaolin, titanium dioxide, iron oxide and bentonite;
and
c. a binder having a melting point of about 100.degree. to about
300.degree.C, wherein said binder is a polymer of methyl acrylate,
ethyl acrylate, n-butyl acrylate, methyl methacrylate, isobutyl
acrylate, t-butyl acrylate, 2-ethyl hexyl acrylate, 2-ethoxyethyl
acrylate, 2-hydroxy propyl acrylate, ethyl methacrylate, butyl
methacrylate or a copolymer comprised of said monomers, and further
wherein said fumigant is diffusible from said article into
surrounding atmosphere upon exposure of said article to the thermal
energy of a lighted candle.
28. Article according to claim 27 in which said fumigant is an
incense, perfume, medicament, insecticide or insect repellent.
29. Article according to claim 28 in which said coating has a
thickness of about 1 - 5 mm.
30. An article according to claim 29 in which said substrate is of
hollow cylindrical shape having an inside diameter of about 3 - 10
cm.
31. Article according to claim 30 in which said substrate is
frosted glass.
32. Article according to claim 31 in which said coating contains a
plasticizer for said binder.
33. Article according to claim 31 in which said fumigant is an
encapsulated liquid.
34. Article according to claim 33 in which said fumigant is
microencapsulated in a gelatin.
35. Article according to claim 28 in which said fumigant is present
in an amount of about 0.2 - 8 weight percent based on the weight of
the binder.
36. In combination, the article of claim 27 and a candle, a
longitudinal axis of said surface bearing said fumigant being
substantially parallel to a longitudinal axis of said candle, and
wherein said fumigant is diffusible from said article when said
coating is exposed to thermal energy from said candle when
lighted.
37. In combination, the article of claim 31 and a candle, a
longitudinal axis of said surface bearing said fumigant being
substantially parallel to a longitudinal axis of said candle, and
wherein said fumigant is diffusible from said article when said
coating is exposed to thermal energy from said candle when lighted.
Description
This invention relates to a fumigant containing substrate. More
particularly, this invention relates to a fumigantcontaining
substrate for use with a candle to promote diffusion of fragrances,
insect repellents, medicaments, etc. into the atmosphere.
Decorative and fragrance candles are widely sold and used in the
United States and European countries. The conventional fragrance
candles are generally made by dissolving a perfume oil into a
melted wax, sometimes with the aid of a solubilizer. The resulting
wax mixture is then poured into a mold or a glass container, and
provided with a wick to form a candle.
Most of the so-called fragrance candles sold today do not liberate
much fragrance when the candles are lighted. The reason is that the
perfume oil dissolved in the wax is readily absorbed by the candle
wick before the oil is diffused into the atmosphere. Also, amounts
of the perfume oil are burned and converted into odorless gases and
other compounds. Although some of the perfume in the pool of melted
wax will diffuse into the air, the amount is not great since the
temperature of the melted wax surrounding a lighted candle is only
about 60.degree.C. Moreover, the wax reduces the vapor pressure of
the perfume oil and suppresses the diffusion of the fragrance.
For these reasons, the portion of the perfume in an ordinary
fragrance candle diffusing into the surrounding atmosphere is
generally very small in comparison to the portion which is simply
burned away or converted to other compounds. For example, even when
the fragrance candle contains as much as 6% by weight of perfume
oil, the fragrance diffused while burning the candle may not be
very great. Moreover, the quality and fidelity of the fragrance can
be quite poor due to a partial conversion of the fragrance into
other compounds having an undesirable odor.
Another disadvantage of an ordinary fragrance candle is the perfume
loss during the manufacturing process. Since the perfume is
generally incorporated into a batch of hot melted wax, a
considerable amount of fragrance can be lost in mixing, pouring and
cooling the perfurmed wax mixture.
An additional problem encountered with the conventional fragrance
candles is the compatibility between the wax and the perfume oil.
For example, it is known in the art that stearic acid adds firmness
and improves the appearance of a candle. However, the use of
stearic acid in a fragrance candle is known to suppress the
diffusion of the perfume oil. It is also known that some perfume
oils discolor the candle or weaken its structure.
Accordingly, this invention provides an article of manufacture
comprising a substrate bearing a fumigant. The fumigant is
contained on at least part of at least one surface of the
substrate, and is diffusible from the article into the surrounding
atmosphere upon exposure of the substrate to the thermal energy of
a lighted candle.
According to this invention there is also provided, in combination,
the fumigant bearing substrate with a candle. The surface of the
substrate bearing the fumigant is preferably substantially parallel
to a longitudinal axis of the candle. Other configurations are
illustrated hereinafter.
This invention aids in overcoming the previously mentioned problems
encountered in the prior art. When the fumigant-bearing substrate
of this invention is used in combination with a lighted candle,
larger amounts of the fumigant diffuse into the surrounding
atmosphere, while small amounts, if any, are consumed by the candle
flame. Also, the fumigant does not weaken or generally discolor the
candle material. Furthermore, fumigant loss during the substrate
manufacturing process is minimized because the process can be
conducted at relatively low temperatures, for example, room
temperature. The fragrance quality and fidelity are generally good
since the fragrance is not masked by compounds having undesirable
odors generated as substances burn in the lighted candle.
This invention will be more clearly understood by reference to the
drawings in which FIGS. 1, 2, 3, 4 and 5 are elevation views in
cross-section of various embodiments of the fumigant-bearing
substrate of this invention in combination with a lighted
candle.
According to a preferred embodiment shown in FIG. 1, a candle 1
having a flame 2 is surrounded by a container 3 which comprises the
substrate. Container 3 has an outer surface 4 and an inner surface
5. Either the outer surface 4 or inner surface 5 or both bear a
fumigant or fumigant-containing composition 6. As shown in FIG. 1,
inner surface 5 has a fumigant containing coating 6.
The combination shown in FIG. 1 can readily be prepared. For
example, a perfume oil can be mixed with an absorbing solid or
carrier, such as talc or silica gel. This mixture can then be
combined with a binder, such as an aqueous solution of polyvinyl
alcohol. The resulting mixture can then be applied to the inner
surface 5 of container 3. When the resulting coating 6 is dry, a
molten wax normally used in making candles can be poured into
container 3, and an ordinary candle wick 9 inserted.
FIG. 2 depicts a slightly different preferred embodiment of this
invention. In FIG. 2, an ordinary free-standing candle 1 having a
flame 2 is used. However, a hollow cylinder 3 comprising the
substrate is placed around candle 1. The perfume oil or other
fumigant can be painted on the inner wall 5 of the cylindrical
container 3 to form a coating 6. It will of course be understood
that a coating 6 can also be provided on outer surface 4 of
cylinder 3; however, this is not shown in FIG. 2.
FIG. 3 depicts another preferred embodiment of this invention. The
combination shown in FIG. 3 is similar to that of FIG. 1 except
that container 3 is provided with multiple fumigant-containing
layers 6, 7 and 8. By using multiple layers, a novel candle is
obtained which will release the fragrance or other fumigants in two
or more stages into the atmosphere. Here again it is possible to
coat not only the inner surface 5, but also the outer surface 4 or
both surfaces 4 and 5.
FIG. 4 depicts a further preferred embodiment of this invention.
The diffusion-promoting candle of FIG. 4 can be prepared by pouring
a wax into a mold to form an outer shell 3. The perfume oil or
other fumigant mixed with a binder and carrier can be applied to
the inner wall 5 or outer wall 4 of the wax shell. The inner core
or candle 1 can be made by simply inserting a ready-made candle in
the hollow opening in shell 3. Also, candle 1 can be prepared by
pouring melted wax into the opening in shell 3 and inserting a wick
9. The melting point of the wax used for shell 3 can be slightly
higher than the wax used for candle 1. In the alternative, the same
wax can be used for both candle 1 and shell 3.
It is apparent from FIGS. 1, 2, 3 and 4 that the surface of the
fumigant bearing substrate be substantially parallel to the
longitudinal axis of the candle. In fact, when the substrate is a
hollow cylinder, the longitudinal axis of the cylinder is
preferably practically coincident with the longitudinal axis of the
candle. Nevertheless, the art skilled will recognize that other
arrangements are feasible. For example, in FIG. 5 a decorative vase
10 is provided with a candle 1. The vase is contoured at its mouth
to form a recess 11 which will accept a ring 13 of lamp shade
support 12. The lamp shade support 12 is also provided with a ring
14 at its upper end. Ring 14 will accept a spring clip 16 secured
to fumigant bearing substrate 15 in the shape of a removable shade.
A coating 6 containing the fumigant is applied to the inner surface
of substrate 15 to form a diffusion promoting candle of this
invention. It is apparent from FIG. 5 that the longitudinal axis of
the substrate, rather than the substrate surface, is substantially
parallel to the longitudinal axis of the candle. This combination
has the advantage of allowing easy change or replacement of the
fragrance merely by replacing the removable shade 15.
It will be apparent to one skilled in the art that numerous other
variations of this invention are possible. FIGS. 1 through 5 merely
depict several preferred embodiments.
In describing this invention, the term "diffusible" is used. By
this term it is meant that a fumigant passes from a substrate into
the surrounding atmosphere after exposure to the thermal energy
from a lighted candle. In practicing this invention, at least one
of three possible mechanisms is employed. First, the fumigant can
be a material which diffuses into the surrounding atmosphere by
buring or combustion. Also, the fumigant can be a material which
passes into the surrounding atmosphere by vaporization. Finally,
the fumigant can be a material which sublimates upon exposure to
the thermal energy from a lighted candle.
Based on this discussion it will be clear to one skilled in the art
that the term "fumigant" is to be given a broad interpretation. As
used herein the term "fumigant" means any material which will pass
from the substrate to the surrounding atmosphere upon exposure to
the thermal energy of a lighted candle to produce an odor
perceptible by the human sense. As used herein the term "fumigant"
includes fragrances such as perfumes and incense. The term also
includes vermin destroying or repelling agents, such as
insecticides and insect repellents. Typical insect repellents are
citronella, dimethyl phthalate, 2-ethyl-hexane-diol-1,3;
.alpha.,.alpha.-dimethyl-.alpha.-carbobutoxy-.gamma.-dihydropyrene,
diethyltoluamide, etc. As used herein, the term "fumigant" also
includes medicaments, disinfectants and cleansing agents.
Medicaments are particularly useful for relieving the symptoms of a
cold. The term includes not only odor-producing agents, but also
odor-masking agents the diffusion of which is increased by the
application of heat from a lighted candle. It will be understood
that mixtures of fumigants can be used.
As used herein the term "substrate" is any material which is solid
at room temperature and has a vapor pressure less than the vapor
pressure of the fumigant at the diffusion temperature. The
diffusion temperature is the temperature under conditions of actual
usage at which the fumigant diffuses into the surrounding
atmosphere upon exposure to heat from a lighted candle. The
substrate is preferably a hollow cylindrical shape as shown in FIG.
2, or a hollow container having a bottom and substantially parallel
walls as shown in FIG. 1. The substrate can also be planar,
triangular, eliptical, conical (e.g. truncated) or rectangular
cross-section. It will be apparent to those skilled in the art that
the substrate can be almost any other geometrical or decorative
shape. A particularly preferred shape is a hollow cylinder, with or
without a bottom, and having an inside diameter of about 3-10 cm,
preferably about 5-7 cm. A 6 cm internal diameter cylinder is
particularly preferred. The exact dimensions and configuration of
the substrate will of course depend on the fumigant and its
diffusion temperature. Typically, the interior walls of a
cylindrical container having a diameter of about 6 cm attain a
temperature of about 70.degree.-200.degree.C.
Typical of substrate materials are wax, glass, asbestos, ceramics,
earthenware, metals and plastics, such as polyethylene,
polypropylene, polyvinylchloride, polycarbonates and acrylics.
Other materials will be apparent to those skilled in the art. The
substrate can be clear, opaque, translucent colored or otherwise
decorated. A particularly preferred substrate is frosted glass i.e.
a glass, having a roughened surface texture. It will be apparent
that at least part of at least one surface of the substrate must
bear the fumigant material.
In describing this invention, it has been stated that the substrate
"bears" the fumigant material. It will be apparent from this term
that the substrate and fumigant can be combined in numerous ways.
The fumigant can be dispersed in a carrier and binder which is then
coated on at least part of at least one surface of the substrate.
The fumigant can be a microencapsulated solid, liquid or gas
adhered to the surface of the substrate. As described in FIG. 3,
multiple layers or coatings of fumigant containing material can be
used.
When the fumigant is applied to the substrate as a coating, the
fumigant can be combined with an adsorbent or absorbent particulate
carrier. Typical carriers are talc, silica gel, titanium dioxide,
kaolin, dicalciumphosphate, powdered glass, iron oxide, bentonite,
calcium sulfate or polymers. Mixtures of different carriers can
also be used. In general, the carrier can be any particulate
material which will absorb or adsorb the fumigant and which has a
vapor pressure less than the vapor pressure of the fumigant at the
diffusion temperature.
The carrier and fumigant are generally combined with a binder which
exhibits adhesive properties with respect to the carrier and
substrate. The binder can be any material which is not soluble in
the wax for the candle. Preferably, the binder is water soluble for
ease of application and clean-up. The binder should form a film
which is at least partially permeable in order to permit the escape
of the fumigant. Thus, the binder should have a vapor pressure less
than the vapor pressure of the fumigant at the diffusion
temperature. The binder can be a low melting, e.g. about
100.degree.-300.degree.C., material. Preferred binders are carboxy
methyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol,
polyvinyl acetate and carboxy vinyl polymers. Preferred carboxy
vinyl polymers are polymers of acrylic acid, methacrylic acid,
maleic acid, fumaric acid, itaconic acid and crotonic acid, and
copolymers thereof. It has been found that the binder need not melt
under the conditions of actual usage in the diffusion promoting
candle of this invention. It is only necessary that the binder be
at least partially permeable to the fumigant under conditions of
actual usage.
When the fumigant is combined with a carrier and binder, the
resulting mixture is conveniently applied to the substrate as a
coating by brushing, spraying, dipping or roller coating. The
amount of the carrier employed should be sufficient to completely
absorb the fumigant. An insufficient amount of carrier results in
excessive loss of fumigant, while too great an amount of carrier
retards diffusion. Typical amounts of carriers employed for given
applications are shown in the following examples. Other amounts can
be determined with a minimum of experimentation.
The thickness of the coating supplied to the substrate will of
course vary with the fumigant and intended application. Generally,
when a large amount of fumigant is desired, a relatively thick
coating is applied. Also, the thicker coatings tend to reduce heat
loss from the candle flame. Typically, the thickness of the coating
is about 1-5 mm; however, other thicknesses can be employed.
When diffusion is accomplished by means of vaporization of the
fumigant, the substrate can bear an encapsulated liquid. Methods
for encapsulating liquids are well-known to those skilled in the
art, and means for preparing these fumigant-containing substrates
will be readily apparent. A typical method involves
microencapsulation in a gelatin.
The amount of fumigant used with each binder will of course vary
depending on the type of binder, type of fumigant, geometry of the
candle and substrate, intensity of fragrance desired, etc. Optimum
amounts can be determined with a minimum of experimentation.
Typically, about 0.2-8 weight percent of the fumigant is used based
on the weight of the binder. Preferably, about 2.5-3.5 weight
percent fumigant is used with the preferred binders previously
mentioned. About 3 weight percent fumigant is particularly
preferred.
The candle can be comprised of any of the well-known candle making
materials. Typical materials are tallow, paraffin wax, carnauba
wax, stearic acid, and beeswax. The candle can contain the usual
additives, colorants and decorations.
Similarly, when the fumigant is coated on the substrate as a
mixture with a carrier and binder, the resulting coating can
contain a plasticizer to improve its mechanical and structural
properties. Typical plasticizers are epoxy tallate, epoxidized
oils, medium molecular weight polyesters, di-2-ethylhexyl
phthalate, di(isodecyl)phthalates, alkyl di(tridecyl)phthalate,
di(linear alkyl)phthalates, alkyl di(phenyl) phosphate and
di(2-ethylhexyl)adipate. The coating can also contain fillers or
extenders which may or may not absorb the fumigant. Typical fillers
are barium sulphate, fumed colloidal silica, calcium carbonate,
calcium silicate, and clay. The coating can also contain a fibrous
reinforcement, such as asbestos, ceramic fibers, fibrous glass or
polyvinyl alcohol fibers. Further, the coating can contain flame
retardants, heat stabilizers, preservatives, adhesion promoters,
surfactants and other processing aids.
This invention will be more fully understood by reference to the
following examples in which all parts, proportions and percentages
are by weight unless otherwise indicated.
EXAMPLE 1
Fragrance Candle
Perfume oil 4 parts Talc 10 parts Polyvinyl alcohol, 10% aqueous
solution 8 parts
The perfume oil is mixed with the talc until the oil is completely
absorbed. The polyvinyl alcohol solution is then added and mixed
thoroughly until a moderately thick paste is obtained. The mixture
is then evenly applied on the inner wall of a cylindrical glass cup
having a 6 cm diameter and 12 cm height. If the mixture is too
thick to paint, a little water can be added. If the mixture is too
thin, more talc can be added. After the surface is completely dry,
a mixture of wax consisting of 10% stearic acid and 90% paraffin
wax (M.P. 133.degree. to 138.degree.F.) is poured into the cup. A
candle wick is placed at the center of the candle, and the candle
is allowed to cool. The rate of the fragrance release can be
adjusted by adjusting the ratio of the perfume oil to the solid
substrate.
EXAMPLE 2
Fragrance Candle
Perfume oil 4 parts Silica gel 5 parts Polyvinyl alcohol, 10%
aqueous solution 10 parts
The mixture is prepared as in the previous example and applied on a
glass container. A mixture of wax consisting of 70% paraffin wax,
20% stearic acid and 10% beeswax is poured into the container to
make a candle.
Pearlescent materials such as guanine, bismuth oxychloride,
titanium dioxide coated mica, etc. can be added or used in place of
the silica gel to obtain a pearlescent candle.
EXAMPLE 3
Fragrance Candle
Perfume oil 5 parts Polyvinyl alcohol, 10% aqueous solution 6
parts
The perfume oil and polyvinyl alcohol solution are emulsified, and
then a candle is prepared as before. If necessary, a small amount
of emulsifier can be added to facilitate emulsification. When this
compound is painted on a clear glass cup, it will dry to a nearly
transparent film. Coloring materials can be added to enhance the
appearance.
EXAMPLE 4
Insect Repellent Candle
Insect repellent 4 parts Silica gel 5 parts Polyvinyl alcohol, 10%
aqueous solution 10 parts
The candle is prepared like before. For insect repellents one can
use dimethyl phthalate; 2-ethyl-hexane-diol-1,3;
.alpha.,.alpha.-dimethyl-.alpha.-carbobutoxy-.gamma.-dihydropyrene;
diethyl-toluamide; etc.
Candles prepared according to this invention have many distinct
advantages over conventional fragrance or fumigant candles. First
of all, perfume oil embedded in the substrate can be protected by a
thick layer of wax from the candle, resulting in very little loss
of oil before actual usage. When the candle is lighted, the
substrate becomes hot and the fumigant gradually diffuses into the
atmosphere. As the wax in the candle is consumed, fresh surface of
the substrate is exposed to heat, and thereby results in continuous
diffusion of the fumigant into the atmosphere.
The temperature of the melted wax in an ordinary lighted candle
does not get much higher than the melting point of the wax. The
temperature of the substrate used in combination with a candle
according to this invention can, nevertheless, get much higher.
This is because the wall receives heat not only by conduction and
convection of hot air, but also by radiation from the hot candle
flame. The high temperature of the substrate effectively promotes
the gradual and complete duffision of the fumigant borne by the
substrate. The rate of diffusion and substrate temperature can
readily be controlled by properly selecting the size and shape of
the substrate.
Additionally, this invention is advantageous since a perfume oil
mixture can be prepared and applied to a substrate cold.
Consequently, there is less loss of the perfume during the
manufacturing operation. Furthermore, compatibility problems can be
avoided since the wax need not be in direct contact with the
perfume oil. Thus, the need for solubilizers is obviated, and
fragrance suppression or discoloration problems are avoided.
Among other binders which can be used in practicing this invention
are acrylic ester polymers. Preferred, especially in aqueous
emulsion form are polymers of methyl acrylate, ethyl acrylate,
n-butyl acrylate, methyl methacrylate; isobutyl acrylate, t-butyl
acrylate, 2-ethyl hexyl acrylate, 2-ethoxy-ethyl acrylate,
2-hydroxy propyl acrylate, ethyl methacrylate and butyl
methacrylate, or copolymers of corresponding monomers.
* * * * *