U.S. patent number 3,888,256 [Application Number 05/332,229] was granted by the patent office on 1975-06-10 for layered absorbant pad material.
Invention is credited to Hans Studinger.
United States Patent |
3,888,256 |
Studinger |
June 10, 1975 |
Layered absorbant pad material
Abstract
A layered absorbent pad material comprising an absorbent layer
disposed between upper and lower surface layers, is provided,
between the upper surface layer and the absorbent layer, with a
layer of particulate swelling substance which swells subsequent to
the material absorbing liquid, and thereafter prevents liquid being
displaced back into the upper surface layer upon squeezing of the
material.
Inventors: |
Studinger; Hans (8500 Nurnberg,
DT) |
Family
ID: |
5836625 |
Appl.
No.: |
05/332,229 |
Filed: |
February 13, 1973 |
Foreign Application Priority Data
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Feb 22, 1972 [DT] |
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2208126 |
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Current U.S.
Class: |
604/368;
428/479.3; 604/376; 604/378; 428/87; 428/510; 604/369; 604/377 |
Current CPC
Class: |
A61F
13/53747 (20130101); A61F 13/534 (20130101); A61L
15/60 (20130101); A61F 2013/53445 (20130101); A61F
2013/530481 (20130101); A61F 2013/53721 (20130101); A61F
2013/53051 (20130101); Y10T 428/31891 (20150401); A61F
13/8405 (20130101); Y10T 428/23921 (20150401); Y10T
428/31779 (20150401) |
Current International
Class: |
A61F
13/15 (20060101); A61L 15/16 (20060101); A61L
15/60 (20060101); B32b 005/16 (); A61f
013/16 () |
Field of
Search: |
;161/162,168,169,170,152,156 ;128/284,287,29R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: Kendell; L. T.
Attorney, Agent or Firm: Ross, Ross & Flavin
Claims
I claim:
1. A layered absorbent hygienic pad of joined-together layers
comprising:
an uppermost surface layer of plastics-bound fiber fleece, a
next-adjacent carrier filter sheet of cellucotton, a next-adjacent
layer of granulated particulate swelling substance formed from the
group consisting of polyacrylamide or sulphonated polystyrene with
spacings between adjacent particles,
an absorbent layer consisting of one or more laps of cellulose
wadding and being free of any swelling substance, and a lowermost
surface layer of a material formed from the group consisting of a
plastics-bound fiber fleece or a liquidimpervious foil with the
distribution of the particles of the layer of the swelling
substance being such that the spacing between adjacent particles is
no greater than half of the particle diameter increase realized
upon particle swelling.
Description
This invention relates to layered absorbent pad material for
hygienic purposes such as absorbent, sanitary or invalid's
underlays, diapers, sanitary towels and the like, and comprises an
absorbent layer disposed between an upper surface layer and a lower
surface layer and incorporating a swelling substance. As used
herein, the term "swelling substance" means a substance which
swells upon absorbing a liquid, such as water, the water being
retained by adsorption.
Absorbent pads of this kind are already known. For example in
German Patent Specification No. 489308 it has been proposed to
incorporate into absorbent pads, which are to be used, for example,
for the production of sanitary towels and for other sanitary and
surgical purposes, in order to increase their absorptive capacity,
adsorptive substances which are capable of combining chemically
with water contained in the liquid expected to be absorbed by the
pads. Organic natural products, such as potato flour, cereal
starch, gelatine and the like, have been proposed as agents on this
score.
Hydrophilic colloids of this kind are not, however, generally
acceptable as swelling substances in hygienic or sanitary articles
of the kinds mentioned. Only in recent times has it been possible
to find substances having better absorptive capacities and having
in addition, the property of being substantially immune to the
growth of bacteria. Thus, for example in German Patent
Specification No. 1,079,796 it is proposed to use, as swelling
substance, carboxymethyl cellulose of which the degree of
etherification is adjusted to values from 0.05 to 0.3. For the same
purposes, in German Offenlegungsschrift No. 1,642,072, polyacryl
amides, as well as sulphonated polystyrenes, having a specific
chemical structure are recommended. Finally, it can be understood
from German Offenlegungschrift No. 2,048,721 that cross-linked
polymers of the polyethylene oxide type or of the polyethylene
imine type are also suitable for the same purpose.
In most of these prior documents, it is proposed that the swelling
substances should be in the form of powder or granulate, and that
they should be accommodated either in a special bag or envelope of
a material which is pervious to liquid, or to introduce the
swelling substances into the absorbent pad in a mixture with
cellulose wadding. In the aforesaid German Offenlegungschrift No.
1,642,072, it has also been proposed initially to coat a suitable
liquid-pervious foil with a layer of adhesive and then to sprinkle
the layer of adhesive with swelling-substance in powder form. The
individual particles of the powder then stick fast by their
undersides on the layer of adhesive and are thus retained in
position. The flat product obtained in this way is then introduced
into the absorbent layer at the side which lies downwards in use or
is incorporated into the centre of the absorbent layer.
In comparison with the conventional absorbent hygienic pads
containing cellulose wadding, absorbent pads containing a swelling
substance have a considerably higher liquid absorption capacity.
Whereas cellulose can, as a rule, absorb only about 20 grammes of
water per gramme of cellulose, the liquid absorption capacity of
the said swelling substances can amount to up to 150 grammes of
water per gramme of swelling substances depending on the chemical
nature of the substance. Added to this is the fact that the water
is chemically completely adsorbed by the swelling substances and is
retained by chemical combination e.g. by principal valencies. This
means that the swelling substance, once it has taken up the water
does not release it again, even under pressure loading or upon
squeezing, which improves the utility of such substances. In
contrast thereto, the water in paper or cellulose is largely
retained by secondary valency forces or by capillary forces, which
means there is much weaker retention so that such substances will
readily give up the absorbed liquid under the effect of pressure,
like a sponge.
Despite the considerable advantages which absorbent pads, laden
with swelling substances, have in the hygienic or sanitary field,
naturally the liquid absorptioin capacity of such pads is likewise
limited. When the swelling substance has swollen to its maximum, it
is saturated and can no longer absorb any further liquid which may
be present. This excess liquid is stored in the pad in the
conventional manner, like a sponge, by the cellulose wadding or
crepe paper layers which are also present, and is yielded up again
when the absorbent pad is subjected to pressure or squeezed. Such
squeezing action cannot be avoided in the practical use of the
absorbent pads and it therefore necessarily leads to expression of
liquid from the pads and to the formation of pools of liquid on the
surfaces of the pads.
Having regard to this state of the prior art the problem still
exists of providing a faced or enveloped absorbent pad containing a
swelling substance, for hygienic purposes, the liquid retention
capacity of which is improved in comparison with the known
pads.
In accordance with the invention, this problem is solved in that
the pad material incorporates a particulate swelling substance is
arranged exclusively or additionally in one of the layers, lying at
the top in use, of the absorbent body or of the envelope and in
that the distribution of the particles throughout the layer of
swelling substance is such that the spacing between adjacent
particles is no greater than half of the particle diameter increase
which occurs upon swelling of said particles. With such
arrangement, upon swelling the particles coalesce, after the
fashion of a jelly, and form a barrier layer which is impervious to
liquid.
In the practical use of absorbent pads constructed in this way,
upon wetting of the pad the wetting liquid initially enters in the
conventional manner into the absorbent pad and flows through the
layer of swelling substance arranged at the top or largely at the
top, resulting in the particles of swelling substance being
moistened and slowly beginning to swell. Surplus liquid flows past
the particles of swelling substance and into the absorbent layer
lying therebelow, which absorbent layer consists, for example of
cellulose wadding, crepe paper plies or the like.
The swelling procedure itself may last, for example, from one to
five minutes depending on the fineness of grain of the swelling
substance. A considerable increase in diameter of the individual
particles occurs, so that these, because of their density of
distribution, coalesce into a poreless liquid-impervious gel-like
barrier layer. If subsequently to the swelling a fairly severe
pressure loading is imposed on the pad or the pad is squeezed
locally, the liquid stored like a sponge by the absorbent layer
(cellulose wadding layer or crepe paper layer) is no longer able to
penetrate the barrier layer and to rewet the exterior of the
absorbent pad outwardly. What is advantageous in this connection is
the fact that once the chemical reaction of liquid adsorption is
once initiated, the swelling proceeds initially slowly and then
comparatively rapidly. Towards the end of the reaction, the speed
of swelling dies away, which leads to the fact that the gel layer,
even though it may have coalesced to such an extent that it will
not let liquid pass through outwardly from the interior of the
absorbent layer, can still take up relatively small quantities of
liquid still present on the outside of the absorbent pad or which
may subsequently arise. An invalid or sanitary underlay, diaper,
sanitary towel or the like, conforming to the invention therefore
displays the advantageous property that it can initially absorb a
relatively large quantity of liquid during which the swelling
material layer correspondingly swells and coalesces despite
considerable pressure loading, to form an effective sealing layer
or skin with the result that the top surface of the pad becomes dry
again.
It is advantageous if the swelling substance is arranged directly
below the filter layer or one of the upper surface layers of the
pad material, and that it should be in one or more layers itself.
To this end, the swelling substance should preferably have a
granulate form and be held fast, by way of example adhered, on a
liquid-pervious carrier or support sheet. This carrier sheet or
several of these sheets arranged one above the other in layers can
then be introduced in the manufacture of the absorbent pad.
It is furthermore possible to confine the swelling substance
between two layers of cellucotton (or artificial cotton) and to
introduce it in this form into the absorbent pad during the
manufacture. In this connection, the cellucotton acts as a support
and filter layer which prevents the swelling substance from
escaping from the absorbent pad.
The invention will be described further, by way of example, with
reference to the accompanying drawings, in which:
FIG. 1 is an enlarged diagrammatic sectional view of a preferred
form of the absorbent pad material of the invention;
FIG. 2 is a view similar to FIG. 1, but showing the material
subjected to pressure after wetting and before completion of
swelling;
FIG. 3 is a view similar to FIG. 1 but showing the material after
swelling has taken place;
FIG. 4 is a view similar to FIG. 3, but showing the material
subjected to pressure loading; and
FIG. 5 is a diagrammatic plan illustrating the particle
distribution in the swelling substance layer in the material of
FIGS. 1 to 4.
The layered absorbent pad material illustrated in the drawings
comprises a plurality of superimposed layers consisting of flat
areal structures or sheets, and absorbent substances. Upper surface
layer 1 is in the form of a plastics-bound fibre fleece or web
which imparts to the entire absorbent pad material a textilelike
texture which is kind to the skin. Underneath this fleece substance
layer 1 there is disposed one, or several, layers 2 of cellucotton
acting as a filter layer and serving to prevent swelling substances
(yet to be described), in the unswollen state, from escaping from
the material, e.g. as a result of rough treatment of the absorbent
pad material.
Beneath the layer or layers 2 of cellucotton there is disposed one
or several layers 3 of swelling substance, which are preferably
prepared as has already been described above. In this connection,
the powdery or granular swelling substance (which may consist for
example of polyacrylamide, sulphonated polystyrene or other
suitable substance) is fixed, for example adhered, to a carrier
sheet of cellucotton. Underneath the layer 3 of swelling substance
there is disposed a relatively thick layer 4, which consists of one
or more laps of cellulose wadding. Crepe paper can, if desired, be
incorporated into this layer; furthermore, intermediate layers of
cellucotton can be present therein, those serving for example as
carriers for disinfecting or deodorising substances.
Finally, arranged as lower layer 5 there are once more one or more
surface layers which may also consist of cellucotton,
plastics-bound fibre fleece or which may be of liquid-impervious
foil, for example thin polyethylene foil.
Should the absorbent pad material be wetted, in other words if a
liquid, for instance water, impinges in the direction of arrows 6
(FIG. 1) on the upper surface layer 1 of the pad, this liquid is
absorbed instantaneously by the pad and becomes distributed in the
absorbent layer 4, as is indicated in FIG. 1 by arrows 7. Also the
layer 3 of swelling substance is penetrated and the particles of
swelling substance are moistened.
If, before the swelling substance of the layer 3 has swollen, the
pad is subjected to pressure as indicated in FIG. 2 by the arrow 8,
part of the liquid stored in the pad by the absorbent layer 4 is
expelled after the manner of squeezing a sponge. This expelled
liquid flows partially away from the location at which the pressure
is applied, as is indicated in FIG. 2 by the arrows 9. Part of this
expelled liquid will, however, as indicated by the arrows 10 in
FIG. 2, penetrate the still comparatively pervious layer 3 of
swelling substance and the layers 2 and 1 arranged thereabove and
flow back onto the upper surface of the absorbent pad. There it can
form a pool 11, which, of course, is undesirable.
Contact of the liquid with the swelling substance layer 3 results
in the particles of the swelling substance absorbing the liquid and
beginning to swell. This swelling proceeds slowly at first. After a
few minutes, however the reaction between the particles of swelling
substance and the liquid will have progressed to such an extent
that, as is shown in FIG. 3, the particles will have considerably
increased in diameter. As a result, the swollen particles coalesce
into a jellylike liquid-impervious layer 3' (FIGS. 3 and 4) which
creates a barrier for the liquid which is already present in the
suction layer 4. The layer 3' of swelling substance can still
absorb small quantities of liquid from above which leads to the
fact that the upper fleece material layer 1 as well as the
cellucotton layer 2 yield their residual liquid content to the
layer 3' of swelling substance and are caused to dry out. Should
the pad now be squeezed or subjected to pressure loading, as
indicated in FIG. 4 by the arrow 8', the layer 3' remains
liquid-impervious so that no liquid can be expressed upwards out of
the absorbent layer 4, and the diaper, invalid underlay, sanitary
towel or the like remains dry even if subjected to violent
treatment resulting in considerable surface deformation of the
pad.
The embodiment shown in the drawings is given only by way of
example and variations may be made thereto. For example, it is
possible to arrange the layer 3 of swelling substance not as shown
above the absorbent pad layer 4, but to accommodate it within this
layer, but near to its upper surface. This would be the equivalent,
of course, to providing a further thin absorbent layer between the
swelling substance layer 3 and the cellucotton layer 2. If the
layer 3 of swelling substance were, for example, accommodated in
the centre of the absorbent layer or in the latter near to its
lower surface, naturally the drying and barrier effect
above-discussed would not be achieved. However, this does not
preclude the possibility of providing additional swelling substance
layers in the centre and/or near the bottom surface of absorbent
layer, over and above the layer 3 at or near the top surface of the
absorbent layer 3, if this is desired and is acceptable for
economic reasons.
In FIG. 5, several particles 12 of the swelling substance are
shown, very diagrammatically, as lying side-by-side. In fact, the
particles of swelling substance naturally will not be
regularly-disposed as illustrated nor will they be in the form of
spheres, but will be more or less non-uniformly shaped structures;
the fundamental requirement for the distribution of the particles
remains however,, the same. The particles 12 of swelling substance
(which are shown in their non-swollen conditions in full lines)
absorb water in the swelling procedure, and combine chemically
therewith; as a result they increase in volume and consequently in
diameter as indicated in dotted lines at 12'. An essential feature
of the absorbent pad material of this invention is that the
distribution of the unswollen particles 12 of swelling substance is
such that at no point throughout the layer is the spacing 13 of the
particles 12 of swelling substance from one another greater than
half the increase in diameter which occurs upon swelling thereof.
Only with observance of this condition is it ensured that the
particles of swelling substance coalesce tightly and thus form the
liquid-impervious barrier layer 3'. Theoretically there could
remain, between the coalesced particles 12', a free space which
considered two-dimensionally is an enveloping rectangle, but
considered three-dimensionally is an enveloping octahedron.
Microscopic observations show, however, that this free space in
fact does not remain, but becomes filled as a result of deformation
of the swollen particles, and the entire layer thus coalesces into
a uniform mass.
To ensure that no liquid can be expressed from the pad when
subjected to all-over pressure, or pressure applied over large
areas thereof, the pad or the pad material may be enveloped or
faced, except at its upper surface layer, by an additional
water-impervious envelope or foil.
* * * * *