U.S. patent number 3,645,836 [Application Number 04/757,760] was granted by the patent office on 1972-02-29 for water-absorption fibrous materials and method of making the same.
Invention is credited to David Torr.
United States Patent |
3,645,836 |
Torr |
* February 29, 1972 |
WATER-ABSORPTION FIBROUS MATERIALS AND METHOD OF MAKING THE
SAME
Abstract
A readily disposable water absorbent product, such as a diaper,
bed napkin or catamenial device, and process of making the same,
the product comprising a supporting sheet of cellulose fiber and a
layer of dry, flexible fibers which on contact with 20 times their
weight of water at 25.degree. C. lose their fibrous character and
form a soft plastic gel, said flexible fibers consisting
essentially of a polysaccharide gum or starch and the weight ratio
of said cellulose fibers to said gel-forming fibers being in the
range of 20:1 to 1:1.
Inventors: |
Torr; David (New York, NY) |
[*] Notice: |
The portion of the term of this patent
subsequent to October 17, 1984 has been disclaimed. |
Family
ID: |
25049107 |
Appl.
No.: |
04/757,760 |
Filed: |
September 5, 1968 |
Current U.S.
Class: |
442/389; 156/269;
427/394; 536/3; 156/62.4; 264/186; 604/368; 442/415 |
Current CPC
Class: |
A61F
13/15577 (20130101); D21H 5/2628 (20130101); D21H
23/04 (20130101); A61L 15/60 (20130101); D21H
17/31 (20130101); A61L 15/60 (20130101); A61L
15/60 (20130101); C08L 5/00 (20130101); C08L
3/02 (20130101); Y10T 442/697 (20150401); Y10T
442/668 (20150401); Y10T 156/1084 (20150115) |
Current International
Class: |
A61F
13/15 (20060101); A61L 15/60 (20060101); A61L
15/16 (20060101); A61f 013/18 (); B32b
005/22 () |
Field of
Search: |
;161/151,156,170
;128/284,285,287,290,296 ;264/186 ;260/209,209.6,212
;156/62.4,250,269 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Burnett; Robert F.
Assistant Examiner: May; Roger L.
Claims
I claim:
1. A readily disposable water adsorbent product comprised of a
supporting sheet of cellulose fiber said supporting sheet having
united therewith dry flexible fibers which on contact with 20 times
their weight of water at 25.degree. C. lose their fibrous character
rapidly and form a soft plastic gel, said flexible fibers
consisting essentially of a polysaccharide gum or starch and the
weight ratio of said cellulose fibers to said gel-forming fibers
being in the range of 20:1 to 1:1.
2. A product as in claim 1, such as a disposable diaper, bed napkin
or catamenial device, having a body-touching layer and an outer
layer, said fibers being positioned between said layers.
3. A product as in claim 1 in which said fibers are nonaligned.
4. A product as in claim 1 in which said fibers are of guar.
5. Product as in claim 1 in which said soft plastic gel has a pH of
about 5 to 8 and retains its water content under mechanical
pressure.
6. Product as in claim 5 in which said gel-forming fibers are
nonwoven.
7. A process for the manufacture of readily disposable water
absorbent products which comprises the steps of forming a dry
flexible fibrous material which fibrous material on contact with 20
times its weight of water at 25.degree. C. loses its fibrous
character rapidly and forms a soft plastic gel, and uniting said
fibrous material with a supporting sheet of cellulose fibers in a
weight ratio of said cellulose fibers to said fibrous material in
the range of 20:1 to 1:1, said fibrous material consisting
essentially of a polysaccharide gum or a starch.
8. A process as in claim 7 in which said dry flexible fibrous
material is made by bringing an aqueous solution of said gum or
starch into contact with a water-miscible nonsolvent therefor while
agitating, and then drying the resulting fibrous precipitate to
produce a dry flexible fibrous mass.
9. A process as in claim 8 in which said fibrous precipitate is
dried in air at a temperature below 60.degree. C.
10. A process as in claim 9 in which said uniting step forms a
length of sheet material, said process including the step of
cutting said length with individual diapers.
11. Process as in claim 7 in which said soft plastic gel has a pH
of about 5 to 8 and retains its water content under mechanical
pressure.
12. Process as in claim 11 in which said gel-forming fibers are
nonwoven.
Description
This invention relates to novel fibrous materials, their
manufacture and their use.
In accordance with one aspect of this invention there is produced a
dry flexible fibrous material which on contact with water (e.g., on
contact with 20 times its weight of water at 25.degree. C.) loses
its fibrous character within a very short period of time (e.g.,
less than a minute) and forms a soft plastic gel.
This fibrous material is suitable for use in structures designed
for absorbing body fluids, e.g., diapers, catamenial devices such
as sanitary napkins or vaginal tampons, pads for protecting the bed
against wetting, and surgical and medical applications. In such
cases the fibers are on a supporting sheet or between supporting
sheets or they may be present in a self-supporting sheet. The
supporting sheet or sheets may be of the disposable type (e.g., of
soft paper), so that the diaper or other structure may be disposed
by flushing it down toilet.
In a preferred form of the invention there is prepared a dry
flexible fibrous mass comprising intertangled fibers which on
contact with water, (e.g., 10 or 20 times its weight of water at
25.degree. C.) forms a soft plastic gel having a pH of about 5 to
8, which gel retains its water content under mechanical pressure
such as is exerted by the body when the gel is present as an
intermediate layer in a diaper. Thus, unlike ordinary diapers made
wholly of cellulose, which can give up their absorbed urine when
pressed or squeezed, diapers containing the fibers of this
invention retain the moisture in the form of the soft nonfibrous
gel and are therefore more comfortable in use. The gel is harmless
and inert to the body of the water.
In one preferred form of the invention the fibers are made of guar,
which is a natural gum of polysaccharide character, soluble in cold
water. Chemically guar is a galactomannan and is believed to
consist essentially of a straight chain of d-mannose units, linked
to each other by means of beta (1-4) glycosidic linkages, the chain
having single-membered d-galactose side branches; the branches are
found on alternate mannose units. The guar may be the natural
product or a chemically modified type such as the self-complexing
guars. The guar may be admixed with other hydrophilic materials;
good results have been obtained with fibrous products made from
mixture of guar gum and a proportion of a cold-water-swelling
starch such as pregelatinized starch or a chemically modified
starch. In place of, or in admixture with, the guar other suitable
water-soluble materials, including polysaccharide gums or starches,
may be used. For example, the guar may be mixed with natural gums
such as locust bean gum, gum karaya, and gum tragacanth, as such or
chemically modified, or with proteinaceous water-soluble materials
such as egg albumin or blood albumin; gums or other polymers, other
than guar, when formed into dry flexible fibers of the type
described herein, may be employed alone. Plasticizing agents may be
present in admixture; thus, the fibers may contain one half or 1
percent of water-soluble polyvinyl alcohol which may improve the
adhesion of the fibers to the sheet on which they are supported in
the final product. The fibrous material may be prepared by mixing a
well hydrated mass of the gum with a water-miscible nonsolvent for
the gum while agitating. Thus a smooth syrupy or thick honeylike
aqueous solution of the gum may be added to the water miscible
nonsolvent, or the nonsolvent may be added to the aqueous solution,
while agitating the resulting mixture (as by means of a rapidly
rotating stirrer or by blowing air bubbles through the mixture) to
form a fibrous mass which can then be freed of surface water and
dried under such conditions that a soft flexible fibrous mass, not
hard or horny, is obtained. In experimental work thus far moderate
drying temperatures, well below 60.degree. C. have given best
results.
In one preferred form of the invention the nonsolvent is
isopropanol. Other water-miscible alcohols, e.g., volatile alkanols
of lower molecular weight such as methanol, ethanol or n-propanol,
may also be used alone or in admixture with the isopropanol. It is
also within the scope of this invention to use such materials as
volatile ketones, e.g., acetone, or to use nonvolatile ketones,
alcohols or other organic liquids, or suitable aqueous salt
solutions where appropriate.
One typical fibrous product according to this invention comprises a
mass of fine fibers of various thicknesses and lengths which are
intertangled and also, at spaced points, adhered together, having
an appearance like that of loose well-opened blotting paper. The
mass is flexible; it is limp and gives substantially no resistance
to bending with one's fingers and its individual fibers are easily
pulled apart, torn, broken or disintegrated, as by a light pull
with one's fingers. In one form the fibers are present as small
clumps of tangled and adhered fibers, with each clump having a
length in the range of, say, about one quarter inch to 2 inches,
the clumps having on their surfaces a multiplicity of projecting
individual fine fiber ends or loops (bends), and the thickness of
these individual fine fibers being on the order of a thousandth of
an inch or so, the fibers of the mass generally having thicknesses
in the range of, say, about 0.0005 to 0.02 inch.
Any suitable technique may be employed for distributing the fibers
or clumps thereof onto the supporting sheet. Thus the material may
be rolled onto the supporting sheet, or the fibers may be chopped
up easily, to short lengths (e.g., one quarter inch) if desired,
and then, for example, sprinkled onto the supporting sheet. The
supporting sheet may be dampened with moisture to aid in anchoring
the fibers thereto without destroying their fibrous character. The
chopped fibers may be united to the sheet of cellulose fibers by
mixing them with paper fibers, or other cellulose fibers, in
varying proportions (such as a weight ratio of the cellulose fibers
to the water-absorption fibers of 20:1, 10:1, 5:1, 2:1, 1:1 or 1.2)
and forming the mixture into a soft sheet in which the
water-absorption fibers are interspersed among the cellulose
fibers. It is also within the broad scope of the invention to mix
the water-absorption fibers with other natural or synthetic
fibers.
In another aspect of this invention the fibrous material, which as
stated, is easily torn or broken, can be protected by a removable
coating of film-forming strengthening agent, the coating being
removed in whole or in part before the fibers are finally
positioned in the finished product whereby the fibers can be
effective in that finished product substantially unhindered by that
coating. For example, long discontinuous fibers of guar gum may be
made by extruding an aqueous syrupy solution of the gum through a
spinneret having fine orifices into a water-miscible nonsolvent for
the gum (e.g., isopropanol). The collected fibers are dried in air
and sprayed with a solution of a high polymer such as a cellulose
derivative (e.g., a solution of carboxymethyl cellulose or methyl
cellulose) or polyvinyl acetate and then formed into yarns (as by
conventional spinning methods which are thereafter woven, or
knitted, into fabric (e.g., a fabric of relatively open weave). The
coating can then be removed by passing the fabric through a bath of
a solvent for the coating which does not affect the fibers e.g.,
aqueous alcohol). The use of the coating facilitates the mechanical
operations of yarn-forming, weaving or knitting and helps avoid
fiber-breakage during these operations.
In one type of product utilizing the fibers of this invention there
is a body-touching sheet or ply and a second, strength-giving,
sheet. The body touching ply may be a thin, soft, absorbent
cellulose-type sheet. It is advantageously made of a fine soft
paper of a quality at least such as in a good grade of facial
tissue. It is of such quality so that in the dry state it does not
abrade or irritate the skin. It is beneficially relatively loosely
textured, for example, as in a soft quality facial or toilet
tissue, but yet of sufficient wet strength to retain its continuity
and not tear while in the wet state on the wearer. This is
desirable because, for example, it is not uncommon that when a
diaper-wearing child only wets the diaper, the wet diaper is not
replaced and the child continues to wear it and will wet it again
one or more times.
So long as it has the required softness, the body-touching ply need
not be restricted to a felted sheet, which is the preferred form;
it may be a loose weave, for example, a fine grade gauze treated
for softness. It can be made of cellulose, cotton, paper cotton,
rayon, or even synthetic celluloselike fiber, all of which and
others like them are embraced by the expression "cellulose-type."
In thickness, it can range from about one one-thousandth to about
two one-hundredths or even about three one-hundredths of an
inch.
The second sheet likewise can be composed of a cellulose type sheet
such as used for the body-touching ply. However, the second sheet
need not have the relatively open texture. It can be of fuller
texture to provide somewhat greater strength, for it generally is
the strongest of the three requisite component parts of the
product. The second sheet may also be coated with a moisture
resistant material on one or both sides, if desired.
Water-imperviousness is imparted to this sheet by application to
one or both sides of it of a water-repellant coating that is inert
or harmless to the skin of the wearer. Such coating can be of any
suitable natural or synthetic wax, such as paraffin wax, and
applied in known manner; or natural or synthetic resin, either
rolled on or applied dissolved in a volatile solvent, or of
lacquer.
However, whatever coating material is used should be applied
preferably only in quantity sufficient to impart the
water-imperviousness and should be one that leaves the coated sheet
sufficiently flexible. While this second sheet can be as thin as
the body-touching sheet, it desirably can be thicker. The
water-impervious coating, when employed, is applied to prevent
wetting, and particularly soiling, of any other garment worn next
to the napkin. Ordinarily, the coated side of this sheet can be the
exposed surface of it in the assembled finished napkin.
The surface of the second sheet and also of the body touching sheet
that is not an exposed surface in the assembled finished napkin is
conveniently referred to as the unexposed side of the second sheet
or of the body-touching sheet respectively.
The multiply products of this invention can be readily prepared by
continuous manufacturing processes. For example, the body-touching
sheet can be made available rolled up on a roller, and the second
sheet can be similarly set up. These rolls can be mounted spaced
apart from one another, e.g., one above the other, and arranged so
that both of the sheets can be rolled off toward a common meeting
point. If woven or knitted fibers are to be used as the
intermediate layer, sheets formed therefore can also be rolled up
on a roller and fed to the common meeting point between the
body-touching sheet and the second sheet to form the multiply
product of this invention. If nonwoven fibers are employed, they
can be sprayed or sprinkled on to the unexposed surface of either
of the two sheets at any time prior to the common meeting point and
the resulting combination passed to a set of rollers for pressing
operation. Alternatively, the fibers can be supported on a separate
cellulose-type sheet, a roll of which is so mounted that the sheet
coming off it can be fed toward the common meeting point between
the body-touching sheet and the second sheet feeding off their
respective rolls. In either case the body-touching sheet or the
second sheet may be premoistened with water (e.g., so that they are
damp to the touch) to aid in anchoring the fibers thereto without
destroying their fibrous character; the assembly may thereafter be
dried in any suitable way, e.g., with hot air. It should be
understood, however, that the exact manner of manufacturing the
multiply products, such as a napkin capable of being flushed away
by a toilet stream, is not one of the essential features of this
invention and that various known procedures for manufacturing
multiply products can be utilized with equal effectiveness. The use
of the fibrous material of this invention, instead of a powder or
flake, overcomes the problem of migration of the water-absorption
material, by which migration areas that have reduced moisture
absorption are formed during manufacture, shipment, storage, or use
of the multilayer product.
For the preparation of disposable diapers, the width of the sheets
can be the same as the width of the diapers. These can be sold on
rollers from which can be cut off any desired length, or they can
be cut into selected lengths, for example, separated by suitable
perforations or scoring. In the case of diapers or bed pads the
product may be scored the entire width and length of the product
for more simple disposition.
The edges of the two or three sheets pressed together can be sealed
by any suitable innocuous adhesive or heat sealable polymer, either
of which can be applied in known manner.
Bedpads to protect a bed surface against wetting can be prepared in
substantially the same way as are the disposable diapers.
Catamenial pads can be prepared in relatively the same way by
cutting them from sheets of suitable width, for example, a strip of
any suitable width cut from a wide sheet, or may be stamped out by
suitable dies from the sheets or wound around a core.
Tampons can be prepared, for example, by selecting sheets of
suitable width or cutting such widths from wider sheets, and
rolling the resulting strips into suitable tampon form; or by
rolling any number of turns of the moisture-absorption layer about
a tampon core, to either of which these can be attached in any
convenient known manner the strings for their removal after
use.
The products of the invention are not limited to the several herein
described uses. The combination can be applied to other uses
wherein their water absorbency serves effectively. Thus they can
serve to absorb any other moisture, blood or aqueous exudation from
any body opening, natural or otherwise, for example, as a bandage
over any form of open wound.
The intermediate layer of the multiply product can also be provided
with a minor amount of a suitable, capillary penetrating agent or
surfactant that is inert to the water-absorbent fibers or
filaments, the fibers of the other sheets and harmless to the body
in use. The capillary-penetrating agent may either be incorporated
into the water absorption fibers or admixed therewith in
particulated form.
While the products of the invention may be more generally embodied
in a disposable diaper their particular combination lends itself to
their being embodied also as sanitary napkins, vaginal tampons or
pads for protecting beds or cots or other surfaces against wetting
by children who have not yet develop control of their elimination
and voiding or by older people who during illness or otherwise have
temporary extended loss of such control.
The water-absorption fibers may also be used with other materials,
for example, in paper trays used for commercial packaging or frozen
foods such as chickens, meat, fish, etc., as in paper and fabric
wrapping of shipped products where high humidity may be a
factor.
The following Examples are given to illustrate this invention
further. All temperatures in the Examples are room temperature
(e.g., 25.degree. C) and pressures are atmospheric pressure, unless
otherwise indicated.
EXAMPLE 1
5 grams of guar gum ("Jaguar 315-CM" is added gradually to 325 ml.
of water with vigorous stirring until an apparently homogeneously
solution is obtained. The mixture is then allowed to stand, with
occasional stirring for 1 hour to hydrate more fully. Then one
liter of anhydrous isopropanol is added with stirring, forming a
fibrous precipitate, which was allowed to settle. After the
supernatant material is decanted off the fibrous precipitate is
washed with an additional 500 ml. of anhydrous isopropanol after
which the isopropanol is filtered off and a current of room
temperature air is drawn through the fibrous material until it has
a dry appearance. The fibrous material is then dried overnight in
air in a forced draft oven set at 40.degree.-50.degree. C.
Similar results are obtained when the aqueous solution is allowed
to stand for periods of 2, 3 or 4 hours instead of 1 hour.
The guar gum used in this Example 1 is of the well-known chemically
modified self-complexing type which shows exceptionally high
viscosity and forms solid gels at very low concentrations in
water.
EXAMPLE 2
200 grams of powered guar gum ("Jaguar 806" are wet with 400 ml. of
isopropanol and then dispersed in 20 liters of tapwater with the
aid of a mechanical stirrer. The mixture is allowed to stand for
2-3 days for further dehydration of the gum to occur, forming a
smooth moderately viscous dispersion. This dispersion is added
slowly in a continuous stream (at the rate of 10-15 ml. per minute)
to a bath of isopropanol which is mechanically stirred. As the gum
precipitates in the isopropanol it is feathered into a fibrous
white mass by the rotary mechanical stirrer. The white fibrous
precipitate is removed periodically during the process, gently
squeezed by hand to remove excess liquid and washed in fresh
isopropanol, then collected on an aluminum screen, dispersed in
fresh isopropanol for a second washing and spread out to dry at
room temperature (e.g., 25.degree. C.) overnight, and then fluffed
by whipping with a thin flexible tube attached to a rotary
mechanical stirrer.
EXAMPLE 3
Example 2 is repeated, using the guar gum sold under the
designation "A-20-D" (Stein Hall) with similar results.
EXAMPLE 4
Example 2 is repeated using a mixture of 190 grams of the guar gum
and 10 grams of pregelatinized starch (or of 180 or 170 grams of
guar and 20 or 30 grams, respectively, of pregelatinized starch) in
place of the 200 grams or guar gum.
The moisture content of dry guar gum is about 10-13 percent. Its
ash content is less than about 1 percent. (e.g.,
As will be seen in the Examples, it is often desirable to permit
the gum solution to stand for some time to hydrate fully before
forming it into fibers. In the case of guar, particularly if a
slow-hydrating type is used, a number of hours may be needed for
the solution to attain its full viscosity. The viscosity of
solutions of guar in water, after full hydration (e.g., after 24
hours) is often on the order of 3000-3500 centipoises (measured
with a Brookfield Viscometer Synchro Electric Model RVO at 20
r.p.m. at 25.degree. C. using spindle No. 3) for a 1 percent
solution; for a 3 percent solution it is over 50,000 centipoises
which is substantially a gel. The solutions are nonNewtonian, if
measured at 12 r.p.m. the viscosity of a 1 percent solution is
about 5,000 rather than 3,500 centipoises. For the self-complexing
type of guar gel-formation is attained at lower concentrations. It
will be seen that while the fibrous character of the product can be
destroyed very quickly on contact with water, full hydration and
gel formation is a slower process.
In general, the polysaccharide materials of this invention
preferably have viscosities (measured at 20 r.p.m. as described
above) of over 2,000 centipoises, more preferably at least 2,500
centipoises for a 1 percent aqueous solution, and well above 20,000
centipoises for a 3 percent solution.
Small amounts of borax or other materials may be present with the
fibrous material of this invention or in a separate layer of the
product (e.g., the second sheet or the body-contacting ply) to
modify the surface tension of the aqueous body fluid or the effect
thereof on the gum.
It is understood that the foregoing detailed description is given
merely by way of illustration and that variations may be made
therein without departing from the spirit of the invention. The
"Abstract" given above is merely for the convenience of technical
searchers and is not to be given any weight with respect to the
scope of the invention.
* * * * *