U.S. patent number 3,882,941 [Application Number 05/425,449] was granted by the patent office on 1975-05-13 for in situ production of bitumen from oil shale.
This patent grant is currently assigned to Cities Service Research & Development Co.. Invention is credited to Arnold H. Pelofsky.
United States Patent |
3,882,941 |
Pelofsky |
May 13, 1975 |
In situ production of bitumen from oil shale
Abstract
Hydrocarbons are recovered from oil shale deposits by
introducing hot fluids into the deposits through wells and then
shutting in the wells to allow kerogen in the deposits to be
converted to bitumen which is then recovered through the wells
after an extended period of soaking.
Inventors: |
Pelofsky; Arnold H. (East
Brunswick, NJ) |
Assignee: |
Cities Service Research &
Development Co. (Cranbury, NJ)
|
Family
ID: |
23686622 |
Appl.
No.: |
05/425,449 |
Filed: |
December 17, 1973 |
Current U.S.
Class: |
166/303;
166/263 |
Current CPC
Class: |
E21B
43/18 (20130101); E21B 43/24 (20130101) |
Current International
Class: |
E21B
43/24 (20060101); E21B 43/16 (20060101); E21B
43/18 (20060101); E21b 043/24 () |
Field of
Search: |
;166/302,303,272,263 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Novosad; Stephen J.
Attorney, Agent or Firm: Ward; Joshua J. Rushton; George
L.
Claims
What is claimed is:
1. A process for recovering hydrocarbon product from asubterranean
deposit of oil shale which comprises the steps of:
a. introducing heat energy in the form of hot fluids not containing
oxygen into said deposit through one or more wells extending into
the deposit, said heat energy being introduced in quantities
sufficient to heat the deposit in the vicinity of the wells to more
than about 50.degree.F above its transition temperature and until
the pressure at the bottom of the wells is from at least 200 to
about 1,000 psi about the formation pressure of the deposit;
b. then shutting in said wells until the temperature in the
vicinity of the wells drops to less than about 50.degree.F above
the transition temperature of the deposit until the pressure at the
bottom thereof drops to less than about 50 psi above formation
pressure, with the shutting in period lasting from about two weeks
to about 6 months;
c. repeating steps (a) and (b) for a period of from about 1 to
about 10 years; and
d. producing bitumen through said wells.
2. The process of claim 1 in which steps (a) and (b) are repeated
until the deposit has been heated to more than 50F.degree. above
its transition temperature and then allowed to drop to less than
50F.degree. above its transition temperature throughout a sphere
having a radius of at least about 50 feet from the bottom of each
of said wells.
3. The process of claim 2 in which at least about 75 percent of the
kerogen in the spheres is converted to bitumen before bitumen is
produced through the wells.
4. The process of claim 2 in which the deposit of oil shale is at
least about 200 feet thick, the radius of each of the spheres is
between about 50 and about 500 feet and the periphery of each
sphere is at least 50 feet from the boundary of the deposit.
5. The process of claim 1 in which heat energy is injected in the
form of hot fluids at a temperature of between about 500.degree.and
about 2,000.degree.F.
6. The process of claim 1 in which step (b) takes at least about 6
months.
Description
BACKGROUND OF THE INVENTION
This invention relates to the recovery of bitumen from oil shale
and more particularly to an in situ process for conversion of
kerogen to bitumen and recovery of the resulting bitumen.
Oil shale deposits are found in many locations throughout the world
and are a potential source of extremely large quantities of
hydrocarbon products. Oil shale is generally a laminated,
nonporous, impermeable, fine-grained dolomitic marlstone containing
variable but relatively large amounts of organic matter known as
kerogen. Kerogen is a high molecular weight substance largely
insoluble in benzene and which is dispersed throughout an inorganic
matric composed principally of carbonates along with other minor
constituents. The kerogen in oil shale is relatively rich in
hydrogen and will yield a benzene soluble material (bitumen) on
heating.
Many proposals have been made for recovering usuable hydrocarbons
from oil shales, most of which involve the use of heat in one form
or another to soften or liquefy the kerogen for conversion to
bitumen or for further conversion to produce both liquid and
gaseous products. The heat may be applied in situ or the shale may
be mined by conventional mining methods with subsequent heating or
retorting of the mined shale. In conventional in situ retorting, a
heating agent is injected into one or more wells extending into the
shale deposit and product is produced through the same or separate
wells. It is also known to inject air into the formation to ignite
the kerogen and form a combustion front which is then moved through
the formation in a conventional manner to liquefy and partially
gasify the kerogen and carry the liquid and gaseous product through
the formation to wells from which it may be recovered. In situ
processes frequently involve fracturing the shale deposit to
facilitate contact between heating agents and kerogen.
In all of the previously known in situ processes for recovery of
bitumen from shale deposits, thermal efficiency has been extremely
low because, once formed from the kerogen, bitumen has been
recovered at relatively high temperatures. Also a significant
amount of the bitumen that has been formed migrates through the
formation and is not recovered. It is therefore an object of the
present invention to recover bitumen from shale deposits by means
of a novel in situ recovery process which involves recovery of
substantial quantities of bitumen with a high degree of thermal
efficiency and to reduce the migration of the bitumen out of the
formation.
SUMMARY OF THE INVENTION
Hydrocarbon product is recovered from a subterranean deposit of oil
shale by introducing heat energy into the deposit through one or
more wells extending into the deposit. Heat energy is introduced in
quantities sufficient to heat the deposit in the vicinity of the
wells to more than 50F.degree. (Fahrenheit Degrees) above its
transition temperature (the temperature at which exfoliation of the
shale structure commences). The wells are then shut in until the
temperature in the vicinity of the wells drops to less than
50.degree. above transition temperature, at which time the wells
are again opened and bitumen is produced therefrom.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a vertical cross-sectional view illustrating use of the
present invention in recovery of hydrocarbons from an oil shale
deposit.
FIG. 2 is a horizontal cross-sectional view further illustrating
use of the invention in recovering hydrocarbons from oil shale
deposits.
DETAILED DESCRIPTION OF THE INVENTION
As mentioned above, the prior art in situ processes for recovery of
hydrocarbons from shale deposits have suffered from extreme
inefficiency. By use of the process of the present invention it is
possible to convert lkerogen to bitumen and recover the bitumen
from the shale deposit at significantly lower temperatures than
those at which bitumen is normally recovered from such deposits
while achieving at the same time recovery of substantial quantities
of the total possible recoverable hydrocarbons. As mentioned above,
this is accomplished by introducing heat energy into the deposit
through one or more wells extending into the deposit with the heat
energy being introduced in quantities sufficient to heat the
deposit in the vicinity of the wells to more than 50F.degree. above
its transition temperature. The transition temperature is
considered to be that temperature at which exfoliation (swelling)
of the shale structure begins to take place. The wells are then
shut in until the temperature of the deposit in the vicinity of the
wells drops to less than 50F.degree. above the transition
temperature of the deposit at which point the wells may be opened
and bitumen produced therefrom or additional heat energy may be
introduced for conversion of additional kerogen to bitumen. If the
bitumen is not removed, it will act as a solvent and tend to
solubilize more of the kerogen.
The exfoliation temperature for a particular shale deposit varies
depending on the amount of kerogen contained in the shale between
about 600.degree. and about 700.degree.F. with the lower transition
temperatures occuring in connection with relatively richer shale
deposits. When an oil shale deposit is heated to above its
transition temperature in the absence of oxygen, exfoliation is
accompanied by a marked increase in permeability. If the shale is
allowed to remain above the transition temperature for a few hours,
the permeability decreases again to the original value, usually
essentially zero. If, however, the shale deposit is maintained
above its transition temperature for a substantial length of time,
such as weeks or months, significant portions of the kerogen are
converted to bitumen which has substantially lower viscosity than
the kerogen and can flow freely through the inorganic matrix of the
shale deposit. In accordance with this invention, the shale deposit
is heated to more than 50F.degree. and preferably at least about
100F.degree. above its transition temperature and then allowed to
cool to less than 50F.degree., preferably to about 25F.degree. or
less above its transition temperature before recovery of any
bitumen therefrom. This allows ample time for substantial
quantities of kerogen to convert to bitumen and allows heat to be
transferred to further portions of the formation to avoid loss of
thermal efficiency in recovery of bitumen from the deposit. It also
allows the bitumen to act as a solubilizing agent on the
undissolved or unconverted kerogen.
Introduction of heat energy to a shale deposit in accordance with
the invention can be by any suitable means with use of hot fluids
at temperatures between about 700.degree. and about 2,000.degree.F.
being preferred. Preferred fluids include steam and hot water
although other fluids not containing free oxygen, such as liquid or
vaporous hydrocarbons, flue gas, etc. may be used.
Because of the extremely low permeability of oil shale deposits, it
is usually not possible to inject hot fluids at normal injection
rates without increasing pressure in the injection well to an
undesirable degree before the desired rise in temperature has taken
place in significant portions of the surrounding shale deposit. It
is therefore preferred that the initial step of heating the deposit
in the vicinity of the wellbores to more than 50F.degree. above its
transition temperature be done in stages. In this preferred
embodiment of the invention, hot fluid is injected through the
wells until the pressure is raised to between about 200 and about
1,000 psi above normal formation pressure of the deposit. The wells
are then shut in for a period of time necessary to allow the
pressure to drop to less than about 50 psi above the formation
pressure of the deposit. This frequently takes between about 2
weeks and about six months. Additional hot fluid is then injected
until the pressure again rises more than 200 psi above formation
pressure. Similar cycles of injection and shut in are continued
until the temperature in the vicinity of the injection wells
reaches the desired range of more than 50F.degree. above the
transition temperature of the deposit. The injection wells are then
shut in until the temperature in the vicinity of the wells drops to
less than 50F.degree. above the transition temperature of the
deposit at which time bitumen may be produced from the wells or,
preferably, injection of hot fluids as described above is again
resumed. By so resuming injection of hot fluids, the affected area
of the shale deposit may be extended beyond that possible by merely
raising the temperature in the immediate vicinity of the wells.
This is possible because of the increased permeability of the
formation in the vicinity of the wells due to conversion of kerogen
to lower viscosity bitumen during the injection and shut in cycles
mentioned above and also because the bitumen tends to solubilize
additional kerogen.
Once the deposit in the immediate vicinity of the injection wells
has been heated to more than 50F.degree. above its transition
temperature, it is preferred that the wells be shut in for between
about 6 months and about 1 year to allow the temperature to drop to
less than 50F.degree. and more preferably to less than 25F.degree.
above transition temperature. Bitumen may then be produced from the
wells or more preferably injection of hot fluids may be resumed to
extend the affected area of the deposit before production of any
bitumen therefrom. Such expansion of the effected area of the
deposit preferably is carried out in the same manner as the
original heating of the deposit described above, i.e., hot fluids
are injected into the deposit until the well pressures rise to
between about 200 and about 1,000 psi above normal formation
pressures, the wells are shut in for between about 2 weeks and
about 6 months to allow pressure to return to less than 50 psi
above formation pressure and injection of hot fluids is then
resumed on the same basis until temperatures in the previously
unaffected portions of the shale deposit surrounding the wells have
been raised to more than 50.degree.F. above their transition
temperatures. The increase in temperature of previously unaffected
shale deposit may in part or in whole be achieved by indirect
transfer of the heat from the injected hot fluids through
previously formed bitumen.
It is preferred that the introduction of heat energy into the shale
deposit as described above be continued until the deposit has been
heated to more than 50F.degree. above its transition temperature
throughout a sphere having a radius of at least about 50 feet from
the injection point of each well through which hot fluid has been
injected. Each portion of the deposit so heated should then be
allowed to "soak" with the wells shut in until the temperature
again drops to less than 50F.degree. above the transition
temperature (usually for a period of at least about 6 months) to
allow time for conversion of kerogen to bitumen. For maximum
efficiency of recovery, it is preferred that no bitumen be produced
from the deposit until all of the above heating and soaking cycles
have been completed at least once for each portion of the deposit
contained within the spheres mentioned above.
In practicing the invention, it is important to avoid fracturing
the shale deposit since any fractures formed beyond the area of the
deposit in which kerogen is transformed to bitumen will result in
excessive loss of bitumen into other portions of the deposit or
surrounding formations. For the same reason, it is not desirable to
allow the portions of the deposit in which kerogen is converted to
bitumen to extend to the boundaries of the shale deposit if the
surrounding or underlying formations or overburden are permeable.
For this reason, it is preferred that the invention be practiced in
shale deposits having a thickness of at least about 200 feet and
that the periphery of each of the spheres of affected area in which
kerogen is converted to bitumen remain a minimum of at least about
50 feet from the boundary of the deposit. Overlapping of affected
spheres is, of course, permissible and frequently desirable to
ensure maximum recovery of hydrocarbons but it is preferred that
overlapping be kept to the minimum necessary to obtain desired
recovery of hydrocarbons. Otherwise, excessive temperatures may
build up in portions of the deposit thereby resulting in thermal
inefficiency of undesirably long periods of time being required for
heat to be transferred to other portions of the deposit. For this
reason, it is preferred that the average temperature of affected
portions of the shale deposits not rise above about900.degree.F.
and that, to the extent practical, temperatures above about
1200.degree.F. be avoided completely.
In practicing the invention, the temperature of the shale deposit
may be determined by temperature sensing means introduced into the
deposit such as through the wells used to inject hot fluids or by
means such as infrared aerial photography which allows reasonably
accurate determination of temperatures throughout the deposit. Most
accurate temperature information is usually obtained by a
combination of these or other temperature measuring means.
If the invention is carried out using the preferred embodiments
described above, it is normally feasible to convert at least about
70 percent and frequently at least about 90 percent of the kerogen
in the affected areas of the deposit into bitumen and to recover at
least about 65 percent of such bitumen from the deposit. Recovery
initially is by merely opening the injection wells as described
above but it should be understood that in addition, other
conventional primary, secondary and even tertiary recovery
processes may be used as desired to recover bitumen.
Referring to the drawings, FIG. 1 shows a well 12 extending from
the surface of the earth 14 through overburden formation 16 into a
shale oil deposit 18. An underlying formation 20 is also indicated.
The well 12 may be suitably lined and equipped with tubing, etc. in
a conventional manner. A conduit 22 communicates at one end thereof
to the top of the well 12. The other end of conduit 22 may be
connected to a source of hot injection fluids (not shown) or may be
connected to means for recovering bitumen produced from the shale
deposit 18. Means (not shown) are also provided for closing off the
conduit 22 completely to shut in the well 12.
As an example of recovery of hydrocarbons from oil shale in
accordance with a preferred embodiment of the invention,
superheated steam at a temperature of about 1,000.degree.F. may be
introduced through the conduit 22 and well 12 into the shale
deposit 18. The shale deposit 18 for this example begins about
2,000 feet below the surface and has a thickness of 200 feet from
top to bottom and a normal formation pressure of about 1,000 psi.
Injection of steam at the rate of 4,000 pounds per hour through the
well 12 for up to 8 hours will increase the well pressure to 2000
psi at which time the well is shut in for 4 weeks to allow the
pressure to return to less than 50 psi above the formation
pressure. Three subsequent similar cycles of injection and shutting
in are required to raise the temperature of the shale deposit in
the vicinity of the well (within a sphere 24 as represented in FIG.
1) to a temperature 100.degree.F. above the formation transition
temperature of 562.degree.F. The well 12 is then shut in for 6
months during which time the temperature within the sphere 24
diminishes to 587.degree.F. (25.degree. above formation transitions
temperature). At this time at least about 20 percent of the kerogen
contained within the sphere 24 has been converted to bitumen. A
series of injections and shut ins similar to that described
immediately above is then used to extend the affected area of the
shale deposit to encompass all the material within a sphere 26
(FIG. 1). Also during this period of time more of the kerogen is
converted to bitumen by the action of not only the heat energy but
also the solubilizing effect of the bitumen itself until about 90%
of the kerogen is converted. Another complete series of injections
and shut ins as described above is used to extend the effected area
of the shale deposit in which kerogen is converted to bitumen to
encompass material within the sphere 28 as shown in FIG. 1. At this
time (a total of 10 years after the start of the injections)
bitumen is produced from the shale deposit through the well 12. A
total of 65 percent of the bitumen contained within the deposit is
produced by primary recovery and an additional 25 percent is
available for production by conventional secondary and tertiary
methods.
To recover the maximum amount of hydrocarbons from a shale
formation it is generally desirable to use more than one well as is
depicted in FIG. 2 which shows an oil shale deposit 32 with a
number of wells such as 34 and 40 completed within the shale
deposit. By injection of hot fluids and periodic shutting in of
wells as described above, kerogen within a wide area of the deposit
may be converted to bitumen. The spheres of affected shale deposit
in which this occurs are indicated generally in FIG. 2 by dashed
circles such as 36 and 40. It will be noted that these spheres
overlap so as to convert kerogen to bitumen throughout the maximum
possible volume of the deposit and that none of the spheres reaches
the boundary of the deposit. By keeping the spheres from reaching
the boundary of the shale deposit and avoiding fracturing of the
shale, it is possible to take advantage of the extremely low
permeability of the natural shale deposit to prevent loss of
bitumen before it can be produced from the deposit.
While the invention has been described above with respect to
certain preferred embodiments thereof, it will be understood by
those skilled in the art that various changes and modifications may
be made without departing from the spirit or scope of the
invention.
* * * * *