U.S. patent number 3,852,091 [Application Number 05/288,016] was granted by the patent office on 1974-12-03 for thermographic transfer sheets.
This patent grant is currently assigned to Columbia Ribbon & Carbon Manufacturing Co., Inc.. Invention is credited to Douglas A. Newman.
United States Patent |
3,852,091 |
Newman |
December 3, 1974 |
THERMOGRAPHIC TRANSFER SHEETS
Abstract
Thermographic transfer sheets having a heat-transferable layer
comprising discrete particles which are capable of softening and
adhering to a copy sheet at thermographic temperatures, said
particles being separated by an interface and air voids which
provide a thermal insulation and weakened severing points between
heated and unheated particles.
Inventors: |
Newman; Douglas A. (Glen Cove,
NY) |
Assignee: |
Columbia Ribbon & Carbon
Manufacturing Co., Inc. (Glen Cove, NY)
|
Family
ID: |
26806646 |
Appl.
No.: |
05/288,016 |
Filed: |
September 11, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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109132 |
Jan 25, 1971 |
3751318 |
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Current U.S.
Class: |
428/323; 156/234;
428/914; 428/913 |
Current CPC
Class: |
B41C
1/1091 (20130101); B41M 5/395 (20130101); Y10T
428/25 (20150115); Y10S 428/913 (20130101); Y10S
428/914 (20130101) |
Current International
Class: |
B41C
1/10 (20060101); B41c 001/06 () |
Field of
Search: |
;117/36.1,1.7,3.4,13,21,35.6 ;156/234 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Herbert, Jr.; Thomas J.
Attorney, Agent or Firm: Tully; Thomas L.
Parent Case Text
This application is a division of parent application Ser. No.
109,132, filed Jan. 25, 1971, now U.S. Pat. No. 3,751,318.
Claims
I claim:
1. Thermographic transfer sheet comprising a flexible foundation
carrying a uniform thin volatile-liquid-applied imaging layer of
discrete particles which soften at a temperature within the range
of from about 150.degree. F to 220.degree. F comprising a major
amount by weight of wax and a minor amount by weight of resinous
film-former having a higher melting point than the wax, the
particles being separated, at least partially, by an interface and
air avoids to form areas which are transferable to a copy sheet,
the said air voids and interfaces providing a thermal insulation
and weakened severing points between heated and unheated
particles.
2. Transfer sheet according to claim 1 in which the particles
comprise a low molecular weight polyethylene.
3. Transfer sheet according to claim 1 in which the imaging layer
is present in a weight within the range of from about 1 to 4 pounds
per 3,300 square feet of foundation.
4. Transfer sheet according to claim 1 in which the imaging layer
contains a minor amount by weight of coloring matter.
Description
The thermographic transfer duplication process is in current
commercial use for the imaging of single copies, hectograph masters
and planographic printing plates corresponding to an imaged
original sheet by means of infrared radiation and a thermographic
transfer layer. The original images become heated by the infrared
and the heat melts corresponding areas of the transfer layer to
cause it to wet and adhere to the receptive sheet to produce the
desired copy, master or plate.
One important disadvantage of the known thermographic transfer
sheets and processes is their inability to produce imaged copies,
masters or plates (hereinafter referred to collectively as copy
sheets) which are as sharp and clear as the original images on the
original sheet. Hot melt wax thermographic transfer layers have a
certain narrow threshold temperature range below which they will
not transfer and above which they flow excessively. However even
within the limits of the narrow threshold temperature range, a wax
transfer layer conducts heat laterally as well as through the
thickness of the layer and such lateral conduction causes
broadening of the imagewise heat pattern. Thus the wax layer
softens and melts in an area which is slightly broader than the
dimensions of the original image, whereby the image transferred to
the copy sheet is not as sharp or clear as the original. The
defects in the copy are magnified in cases where the copy sheet is
a master or plate from which hundreds of duplicate copies are made
in the spirit or planographic processes, thus reducing the number
of acceptable duplicate copies that can be made.
Conventional solvent-applied resinous thermographic transfer layers
resist liquefaction at thermographic temperatures but also have
cohesive properties which resist sharp separation between the
heated and unheated areas during transfer. Such layers also
generally have higher softening temperatures than wax layers, and
are as heat-conductive as wax layers, so that heat spreads from the
image areas to adjacent areas to cause broadening of the imagewise
heat pattern.
Another important disadvantage of prior known thermographic
transfer sheets, leading to the production of imperfect
thermographic copies, is due to the nature of the process itself.
During thermal exposure the thermographic transfer layer becomes
imagewise welded to the copy sheet. After exposure and cooling, the
transfer sheet and copy sheet must be stripped apart whereby the
areas of the transfer layer which are welded to the copy sheet are
torn from the remainder of the transfer layer. This often results
in the welded areas pulling over to the copy sheet adjacent
non-welded areas of the transfer layer which have rebonded to the
heated areas of the transfer layer during cooling. This is commonly
evidenced by the formation of filled-in characters and occurs with
both conventional wax and resinous thermographic transfer
layers.
It is the principal object of the present invention to provide
novel thermographic transfer layers which produce sharper and more
perfect thermographic copies than heretofore possible.
It is another object of this invention to provide an improved
thermographic transfer sheet which simplifies the final step of
separating the transfer sheet and the copy sheet to avoid the
transfer of unheated areas of the transfer layer.
These and other objects and advantages of this invention will be
clear to those skilled in the art in the light of the present
disclosure.
The accompanying drawing illustrates the use of the present
transfer sheets in one embodiment of the thermographic copying
process.
The present invention involves the discovery that improved
thermographic transfer layers can be produced by formulating the
transfer composition as a dispersion in a volatile vehicle,
applying the dispersion to a receptive flexible foundation and
evaporating the vehicle to provide a discontinuous layer of
discrete solid heat-softenable particles.
I have discovered that such a discontinuous layer of discrete
particles has at least two critical properties which give rise to
an unexpected improvement in the thermographic transfer process.
First, the discontinuous nature of the transfer layer provides a
multiplicity of discrete particles, each separated at least
partially from the next by means of an interface and air voids. The
air voids provide an insulation between particles and reduce
substantially the thermal transfer between particles, whereby the
ability of heat to spread laterally across the transfer layer is
substantially reduced.
Second, the discontinuous structure of the transfer layer enables
the heated, coalesced portions of the transfer layer to separate
sharply from the unheated areas. The air voids and interfaces
provide weakened severing points between heated and unheated areas
whereby the heated areas, bonded to the copy sheet, break easily
and sharply from the unheated areas. This facilitates the
separating of the transfer sheet and the imaged copy sheet and
substantially reduces the ability of the portions of the transfer
layer welded to the copy sheet to pull adjacent portions of
unheated transfer composition from the transfer sheet.
The transfer compositions of the present invention comprise a major
amount by weight of a waxy binder material and a minor amount by
weight of a resinous binder material and, in most cases, softeners
or plasticizers and coloring matter. The waxy binder material may
be a conventional wax such as carnauba, ouricury, microcrystalline,
beeswax, montan wax, or a mixture thereof. Other waxy materials
having the properties of wax are also suitable alone or mixed with
waxes. These include the lower molecular weight polyethylenes such
as A-C Polyethylene 400, solid Carbowaxes, polyvinyl stearate, and
the like. In addition, a minor amount of resinous film-forming
binder material having a higher melting temperature than the wax is
included as part of the binder material in order to increase the
melting temperature of the dispersion and to render the heated
areas more adhesive with respect to the copy sheet. Suitable
film-formers include cellulose materials such as ethyl cellulose,
vinyls such as polyvinyl butyrate, polybutene resins, and the like.
The film-forming binder may be used in amounts ranging from about 5
percent up to about 35 percent of the total weight of the binder
material.
Resinous dispersions are also suitable and these generally contain
compatible oil softeners or plasticizers to provide resinous
particles having the desired softening point within the
thermographic temperature range of from about 150.degree. F up to
about 220.degree. F. Preferred resins include polyvinyl acetate,
polystyrene, styrene-butadiene copolymers, cellulose esters and
ethers such as ethyl cellulose and cellulose acetate-butyrate, and
acrylic resins such as methyl methacrylate and ethyl acrylate and
copolymers of each. Suitable plasticizers and compatible oils vary
from resin to resin and the selection of appropriate materials and
amounts to provide the required softening temperature is within the
skill of the art.
The coloring matter, if present, must be one which does not absorb
infrared radiation to any substantial extent. The preferred
materials are the crystal violet dyes which are used in small
dissolved amounts in the case of making single copies, and in large
undissolved amounts in the case of making hectograph masters.
Conventional colorless color-forming reactive chemicals also can be
used. In the case of imaging planographic plates, no imaging
material is necessary since the wax binder is oleophilic, although
a small amount of dissolved dye is preferably included for
proofreading purposes.
The transfer composition is applied to a receptive flexible
foundation such as thin paper or plastic film as a dispersion in a
volatile vehicle, the dispersion comprising from about 3 percent to
about 10 percent solids. The vehicle may be water or a volatile
organic solvent such as alcohol, toluol, mineral spirits, or the
like. The dispersion may be produced in any known manner such as by
grinding and agitating the binder material and coloring matter in
the vehicle. Preferably the waxy material is melted with the
coloring matter and is poured slowly in the vehicle, which is
chilled, to form the dispersion.
The dispersion is applied as a thin layer having a dry weight of
from about 1 to 4 pounds per ream of 3,300 square feet. The vehicle
is evaporated at a moderately low temperature, below the softening
temperature of the particles. The waxy particles generally have a
softening and melting temperature within the range of from about
150.degree. F to 200.degree. F.
The following example is given as an illustration of one embodiment
of this invention.
Eighty grams of carnauba wax and twenty grams of ethyl cellulose
are melted together at a temperature of 200.degree. F. The ethyl
cellulose apparently dissolves in the molten carnauba wax rather
than melting, but the melt is homogeneous. Next the melt is slowly
poured into 1,900 grams of ethyl alcohol chilled to a temperature
of 20.degree. F. The alcohol is agitated during pouring and a fine
milky dispersion of the melt is formed having a solids content of
about 5 percent.
Next the dispersion is applied as a uniformly thin layer to a film
of 1/2 mil Mylar polyethylene terephthalate and the alcohol is
evaporated to leave a deposit of about 21/2 pounds of the dry
dispersion per 3,300 square feet of film. The alcohol gives the
dispersion an affinity for the Mylar. Drying of the layer occurs at
slightly elevated temperatures, well below the melting temperature
of the dispersed particles, and the formed layer has a whitish,
beady appearance and is translucent. Referring to the drawing, the
formed transfer sheet 10 comprises the film foundation 11 and the
dispersion transfer layer 12.
The transfer sheet is used to produce sharp, clear oleophilic
images on a thermal planographic printing plate corresponding to
images present on an imaged original sheet in the manner
illustrated by the drawing. The plate 20 comprises a film
foundation 21 having a planographic surface 22. The original sheet
30 may be any sheet carrying infrared radiationabsorbing images 31.
The sheets are superposed in the order shown and are exposed to an
infrared source 40. The infrared penetrates through to the original
image 31 where it is absorbed to generate an imagewise heat pattern
which is conducted back to soften a corresponding area of the
particulate layer 12. The softened area adheres to the surface 22
of the plate 20 and transfers thereto in the form of a
non-particulate, oleophilic image 23 when the sheets are separated.
Image 23 separates sharply and easily from the adjacent areas of
transfer layer 12 since the adjacent areas are particulate and are
not strongly bonded to the portion which was heated and transferred
to produce image 23.
Variations and modifications may be made within the scope of the
claims and portions of the improvements may be used without
others.
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