U.S. patent number 3,558,881 [Application Number 04/401,215] was granted by the patent office on 1971-01-26 for thermographic image formation utilizing a copy sheet of discrete thermoplastic particles and a powder developer.
This patent grant is currently assigned to Keuffel & Esser Company. Invention is credited to Robert M. Gold.
United States Patent |
3,558,881 |
Gold |
January 26, 1971 |
THERMOGRAPHIC IMAGE FORMATION UTILIZING A COPY SHEET OF DISCRETE
THERMOPLASTIC PARTICLES AND A POWDER DEVELOPER
Abstract
A copying process wherein a copy sheet comprising a support and
layer thereon of discrete thermoplastic particles is exposed to
infrared radiation while in heat conductive contact with an
original bearing an infrared absorbing image, thereby causing the
coalescence of the particles in the areas corresponding to the
original image. A finely divided thermoplastic powder is applied to
the exposed copy sheet and selectively adheres to the coalesced
areas, thereby forming a powder image. The powder image is then
transferred to a receptor sheet.
Inventors: |
Gold; Robert M. (Brooklyn,
NY) |
Assignee: |
Keuffel & Esser Company
(Hoboken, NJ)
|
Family
ID: |
27017255 |
Appl.
No.: |
04/401,215 |
Filed: |
October 2, 1964 |
Current U.S.
Class: |
430/348; 427/466;
427/510; 430/200; 427/474; 427/521 |
Current CPC
Class: |
B41M
5/398 (20130101); G03G 5/028 (20130101); B41C
1/1066 (20130101) |
Current International
Class: |
B41C
1/10 (20060101); G03G 5/028 (20060101); G03b
000/41 () |
Field of
Search: |
;250/65.1
;117/1.7,3.2,10 ;101/149.2 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
VAN DER GRINTEN BULLETIN; August 1, 1963; Pgs. 5 and 6;
250-65.1.
|
Primary Examiner: Lawrence; James W.
Assistant Examiner: Birch; A.L.
Claims
I claim:
1. A method of recording a heat image which comprises the steps
of:
a. coating a support with a layer of discrete thermoplastic
particles;
b. drying the coating at a temperature below the coalescing
temperature of said particles;
c. impressing a heat image onto the layer;
d. applying a finely divided colored powder to said layer to
develop the heated areas corresponding to said heat image;
e. transferring the colored powder image from said layer to a
receiving layer; and
f. fusing the transferred colored powder image to said receiving
layer by means of heat.
2. The invention according to claim 1 in which the receiving layer
is charged with an electrostatic charge of sufficient force to
cause the transfer of said colored powder image from the layer of
discrete thermoplastic particles.
Description
IMAGE FORMATION
The present invention relates to image formation, and refers more
particularly to materials and methods for reproducing graphic
images by the use of heat.
In the prior art there are techniques for reproducing graphic
information utilizing various procedures, but these prior processes
lacked the utility, convenience, and ease of operation of the
present invention. For example, there are thermographic papers
which produce images directly upon being heated in image-wise
fashion by means of infrared-absorbing graphics in heat conductive
relation therewith. The disadvantage of such thermographic papers
is that they are not fixed after exposure and any subsequent heat
discolors the paper. Furthermore, there are xerographic processes
for copying graphic information which do not have this fixing
problem, but involve rather expensive and complex reproduction
machines, not a simple source of actinic radiation such as is
present in a thermal copying machine.
Therefore one object of the present invention is to provide
materials and methods for reproduction of graphic images by the use
of heat, which overcome the disadvantages of the prior art.
Another object is to provide methods and materials for reproducing
stable copies of graphic originals by means of actinic
radiation.
Another object is to provide methods and materials for making
multiple copies.
Another object is to provide methods and materials for making
reversal copies.
Another object is to provide methods and materials for making a
printing plate.
Other objects will become apparent during the course of the
following specification.
Normally when polymer layers are coated from emulsions or
dispersions, they are designed so that the disperse phase coalesces
on drying to form a uniform continuous layer. It is obvious that an
emulsion or dispersion which forms a discontinuous layer is useless
for binding purposes as in paints, paper coatings, and the like. It
has now been found, however, that the use of a discontinuous layer
enables the preparation of a reproduction material of unusual merit
and convenience.
The drawing depicts a copying process according to the present
invention wherein a copy sheet 10 comprising a support 12 and a
layer 14 thereon of discrete thermoplastic particles is exposed to
infrared radiation while in heat conductive contact with an
original 8 bearing an infrared radiation absorbing image 9, thereby
causing the coalescence of the particles in areas 16 corresponding
to the original image. Upon separation of original 8 and copy sheet
10 bearing the latent image of coalesced thermoplastic powder is
applied to surface of copy sheet 10 and selectively adheres to
coalesced areas 16, thereby forming a powder image 18. Subsequent
transfer of the powder image to a receptor sheet 20 and fusion of
the powder by the application of heat results in a copy 26 of the
original.
The following examples are given for purposes of illustration and
are not intended to limit the scope of the present invention.
EXAMPLE 1
A very dilute suspension of an acrylic resin latex such as Rhoplex
B-85 was coated upon a support such as a sheet of infrared
transparent paper and dried at a temperature of less than
100.degree. C. to produce a layer of discrete particles on the
support. The coated sheet was placed in heat conductive relation
with an original and the sandwich exposed to heat rays. Upon
separation of the latex-coated paper from the original, a very
slightly visible image of the heated areas was noticeable on the
paper. Present, however, was a very intense latent image
corresponding to the original image, which was developed by a
finely ground thermoplastic powder containing a dark colored
pigment or dye sprinkled over the surface of the coating. The
powder adhered only to the image areas.
It appeared that the brief heating rendered the heated areas
permanently sticky. Sixteen hours after heat exposure, it was still
possible to dust the sticky image and develop an excellent
reproduction of the original. The dark colored thermoplastic powder
may be fused if necessary to fix the image to the paper. Where the
thermoplastic powder contains an infrared absorber such as carbon
black, the fusing can take place by exposure to infrared radiation.
A suitable developing powder comprised about 4.5 percent carbon
black dispersed in a thermoplastic styrenated terpene resin. Where
the support is visually transparent or translucent, the developed
image may be used as a diapositive, and where the powder is
oleophilic, the record sheet may be used as a printing plate.
Other suitable latexes or emulsions successfully employed were
polyvinyl acetate emulsion (Vinac WR-20), nonionic polyethylene
emulsion (Poly-EM), polystyrene emulsion (Emulsion M), and anionic
polyethylene emulsion (Poly-EM-11). These emulsions may be mixed.
In addition, continuous-phase resins (that is, resins soluble in
the continuous phase of the dispersion) may be added as a binder.
For example, polyvinyl alcohol (Elvanol 52-22) may be added to
Poly-EM-11polyethylene emulsion in order to toughen the coating
Here the continuous phase is water.
The major criterion of selection of the nonfilm forming emulsion
for this coating was the temperature necessary to remove the
continuous phase and the temperature required for the disperse
phase to reach a sticky, adhesive state. For practical reasons, the
drying temperatures range from room temperature to about
100.degree. C. The heating temperature was greater than the drying
temperature. Otherwise, coalescence of the discrete particles
occurred prematurely.
Although quite unexpected, the explanation of the observed
phenomenon is quite possibly explainable by what is frequently
called the Kelvin Equation which shows that the vapor pressure of a
curved surface such as that found on a drop, is greater than for a
plane surface. Analogously, it can be shown that a finely powdered
substance melts at a lower temperature than a mass of material,
provided a continuous liquid is formed. These surface tension
effects reach large proportions when the particle size approaches
micron size, (the size of many of the latexes used). It is to be
noted that Folman and Shereshefski in the Journal of Physical
Chemistry, Vol. 59, p. 607, 1955 noted that vapor pressure effects
in fine capillaries of a few microns radius were 10 to 80 times as
great as those calculated by the Kelvin Equation.
The coated sheet comprising a support and a layer of discrete
particles may be treated instead with a heated stylus to form the
adhesive image. Here it was found that the support need not be
infrared transparent. Supports such as polymer films, metals,
glass, cloth and the like were suitable.
The developing powder may be selected so that it is relatively
oleophilic compared to the support material. Then the developed
sheet was usable as a printing plate. Conventional lithographic
printing processes were then used to print many copies of the
original image.
Where the support is visually transparent as well as actinically
transparent, the developed image may be used as a photographic
negative or diapositive for photoprinting or projection purposes.
Suitable supports are transparent polymer films such as
polyethylene terephthalate, cellulose acetate and cellophane.
The unheated particles were easily removed by simple mechanical
means such as brushing during the developing steps.
EXAMPLE 2
An important variation of this process was suitable for making
multiple copies. A latex-coated, translucent paper was exposed by
reflex or contact method to heat rays with an original. The copy
transfer paper was separated from the original and the former
dusted with powder developer as in Example 1. The developed copy
transfer paper was then sandwiched to a receiving sheet. The pair
was then run through a blanket charging device which placed a high
charge on the receiving sheet to attract the toner from the copy
sheet. The developer was then fused to the receiving sheet. The
copy transfer sheet still had an active, sticky image. This was
redeveloped without a second exposure. The process of transferring
to another receiving sheet was then repeated. This technique was
repeated many times to make many copies of the original.
A satisfactory coating mixture for this process was a mixture of
one part polyvinyl acetate emulsion, such as Vinac WR-20, diluted
to one-tenth its original solids content with water and one part of
acrylic resin emulsion, such as Rhoplex B-85, also diluted to
one-tenth its original solids content with water.
When this coating was applied to paper and exposed as described
above, the sticky image was developed with a colored powder. When a
blanket positive charge was applied before developing to the
surface of the copy paper, much greater contrast was obtained in
the image, that is, the lines looked darker against the
background.
When the above process was repeated with the copy paper given a
negative charge before developing, a reversal image was
unexpectedly obtained. In other words, the heated areas accepted
the developer less readily than the unheated background areas. This
provided a method for making reversal copies of the original.
It is apparent that the above-described examples are capable of
many variations and modifications. All such variations and
modifications are to be included within the scope of the present
invention.
* * * * *