U.S. patent number 3,838,692 [Application Number 05/309,855] was granted by the patent office on 1974-10-01 for hydrophobic sheet with hydrophilic passages.
This patent grant is currently assigned to Johnson & Johnson. Invention is credited to Yvon G. Levesque.
United States Patent |
3,838,692 |
Levesque |
October 1, 1974 |
HYDROPHOBIC SHEET WITH HYDROPHILIC PASSAGES
Abstract
Sheet material, suitable for use as a diaper liner or the like,
which is of a generally hydrophobic nature but includes hydrophilic
passages in the product to permit liquid to be transmitted through
the product.
Inventors: |
Levesque; Yvon G. (Montreal,
Quebec, CA) |
Assignee: |
Johnson & Johnson (New
Brunswick, NJ)
|
Family
ID: |
23199961 |
Appl.
No.: |
05/309,855 |
Filed: |
November 27, 1972 |
Current U.S.
Class: |
604/382; 604/373;
604/372; 604/394 |
Current CPC
Class: |
A61F
13/51305 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A41b 013/02 () |
Field of
Search: |
;128/284,286,287,285,290,296 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Claims
I claim:
1. A disposable, liquid permeable, diaper liner product comprising
a length of a nonwoven fabric having opposed major surfaces, said
nonwoven fabric having a sufficiently fine porosity to prevent the
passage of particulate matter therethrough, a major proportion of
at least one surface of said fabric being of a hydrophobic nature
and the minor proportion of said one surface being of a hydrophilic
nature, said proportion of said fabric of a hydrophilic nature
comprising discrete, spaced apart hydrophilic areas said areas
extending between said opposed surfaces of the nonwoven fabric.
2. The product of claim 1 wherein said product is incorporated as
part of a further structure with said product forming the outer
layer of said structure.
Description
This invention relates to hydrophobic sheets. More particularly,
this invention relates to hydrophobic material having hydrophilic
passages therein.
Inasmuch as the present invention has particular application to the
art of diaper liners, particular reference will be made thereto --
it being understood that the products of the present invention will
find other uses in various fields as described hereinafter.
Diaper liners are used for the purpose of providing an intermediate
substrate between the lower body area of a baby or infant and an
actual absorbent layer or diaper per se, for the purpose of
preventing or reducing soiling of the diapers by solid body
discharge. As such, diaper liners must be capable of permitting
fluids to pass through the liner to be absorbed by the absorbent
diaper, and conversely, retain the solid discharges. One type of
diaper liner commercially used is based on a substrate or layer of
material which is highly liquid permeable, and is of a hydrophilic
nature having a porosity such that it reduces diaper soiling by
preventing the passage of solid particulate matter through it. This
type of liner more or less acts as a "filter," in that it is
essentially of a structure for optimum filtering efficiency of the
solid particulate matter. However, due to the fine porosity and
hydrophilicity of such types of diaper liners, it is evident that
the major proportion of the liner per se will remain wet and in
contact with the skin of the wearer's body. This should preferably
be avoided, as it could lead to skin irritation.
A further type of liner known in the prior art comprises a
substrate of a hydrophobic nature -- for example, such liners are
constructed of hydrophobic synthetic fibers which may either be
inherently hydrophobic or alternately, fibers which have been
rendered hydrophobic in nature (as in the case of cellulose fibers
which are conventionally rendered hydrophobic by chemical treatment
to alter their properties). While possessing several advantageous
features in its own right, such diaper liners have several
disadvantages including, for example, that in order to assure the
passage of liquids through the hydrophobic sheet to an underlying
absorbent diaper, the porosity of the hydrophobic sheet has to be
sufficiently coarse to allow "strike through" (or otherwise the
surface tension of saline body liquids could prevent or reduce
penetration of the liquid through the liner). This coarse porosity
inherently results in a lower soiling resistance (i.e., the
filtering availability or capacity of the liner). Still further,
depending on the water-retentivity characteristics of the
underlying absorbent diaper, secondary "strike through" from a
saturated absorbent diaper back to the skin of the infant's body
(through the diaper liner) occurs, even at points removed or spaced
from the zone of liquid impact.
Accordingly, there is a need today for a product suitable for use
as a diaper liner or diaper facing, which overcomes the
disadvantages of the prior art products. Applicant has now
developed such a product in accordance with this invention, which
not only overcomes the prior art disadvantages with such products,
but at the same time, provides several advantageous features in its
own right.
More particularly, in accordance with this invention, there is
provided a product overcoming the disadvantages of the prior art
and comprising a sheet of flexible material having opposed major
surfaces, said sheet having a porosity fine enough to reduce
substantially the passage of particulate matter therethrough. The
product, as a diaper liner, has in a most preferred form a major
proportion of at least one surface of said sheet being of a
hydrophobic nature, and a minor proportion of said one surface
being of a hydrophilic nature, said hydrophilic proportion of said
sheet comprising in the most preferred form, spaced-apart areas of
hydrophilic passages extending inwardly from said surface of said
sheet.
In accordance with a further aspect of this invention, there is
provided a method of preparing the abovedescribed products, which
method according to one aspect, includes the steps of providing a
length of flexible sheet material having a pair of opposed major
surfaces, at least one surface being of a hydrophilic nature, the
material being selected so that it has a fine enough porosity to
prevent the passage of particulate matter therethrough, treating
the hydrophilic surface of said material so as to render at least
said one surface hydrophobic in nature, and subsequently treating
the hydrophobically rendered hydrophilic material at spaced-apart
points to provide spaced-apart hydrophilic passages extending
inwardly of said hydrophobic surface of said sheet.
In accordance with an alternate embodiment of the present
invention, the above products may be produced by the steps which
include providing a length of flexible sheet material having a pair
of opposed major surfaces, the length of sheet material being
generally hydrophobic or having at least one major surface thereof
which is hyrophobic in nature, said material having a fine enough
porosity to prevent the passage of particulate matter therethrough,
and treating said material, or at least said major surface which is
hydrophobic in nature, at spaced-apart points to provide
spaced-apart hydrophilic passages extending inwardly of said major
surface of said sheet material.
In greater detail, the products of the present invention as
described above, can be characterized as having a sufficiently fine
porosity such that, in the case of diaper liners used in
conjunction with diapers, the passage of solid particulate matter
through the product forming the diaper liner to the diaper per se,
is reduced or prevented, so as to reduce or prevent diaper soiling
by the solid particulate matter, while also, the repellency of the
product is normally augmented. Still further, at the same time, the
products of this invention possess the property of passing body
liquids through the hydrophilic passages so that they may be
absorbed by an underlying absorbent diaper or absorbent substrate.
In this manner, such products as in the case of diaper liners, and
due to the characteristics of the product, prevent secondary
strike-through (except at the hydrophilic passages) and
substantially reduce skin irritation which could otherwise be
caused by body fluids remaining in contact with a wet diaper liner
and the skin.
The products of the present invention, when used as diaper liners,
have a major proportion of at least one surface thereof which is
hydrophobic in nature, and conversely, a minor proportion of said
one surface which has hydrophilic passageways extending inwardly of
that surface. To this end, the hydrophilic passageways are in the
form of spaced-apart passages, preferably as outlined hereinafter.
These passages permit the transmission of liquids through the
material into the absorbent substrate. In the case of diaper
liners, the hydrophilic passages may extend only over a selected
area of the total area of the material -- that is in the area of
the diaper liner where the body discharges occur. Thus, for
example, only a central area of the material which is intended for
use as a diaper liner may be provided with the spaced-apart
hydrophilic passages, so that when the diaper liner is used, it
will be positioned with respect to, e.g., a diaper, such that the
area with the hydrophilic passages will be located in the required
place when in use.
In the area where the hydrophilic passages are located, they are
most preferably of a type wherein the spacedapart passages have
intervening areas of a hydrophobic nature. In this respect, the
geometrical surface configuration of the hydrophilic passages may
vary as desired, ranging from spacedapart "dots" to geometrical
configurations such as circles, parallelograms, lines, etc. Still
further, the surface area of each individual hydrophilic passage
may vary considerably, depending on the intended use of the
product; in general, the total cumulative area of all hydrophilic
passages may amount to 1 percent to about 90 percent of the total
area of the material; for most diaper liner applications, the total
cumulative hydrophilic surface area may be in the order of from
about 5 to about 40 percent, desirably about 10 percent to 35
percent, which has been found to impart sufficient and most
desirable properties. As indicated previously, most of the
hydrophilic passages will be located in a given area -- e.g., the
central area of a diaper liner and hence, for diaper liners, the
above preferred total hydrophilic cumulative area will be located
in said central area, with intervening hydrophobic areas between
the hydrophilic areas. However, if desired, a single hydrophilic
area, of any suitable shape, may be employed to form a large
hydrophilic passage with an area within the above ranges. If
desired, the hydrophilic area may be centrally located, and
preferably surrounded by the hydrophobic portion of the
material.
In one preferred embodiment, the total product is hydrophobic
throughout, and between the opposed major surfaces thereof except
for the hydrophilic passages extending therethrough between the
opposed surfaces. In an alternate embodiment and for preferred
applications as described hereinafter, the material may have the
property of being hydrophobic on one surface thereof with the
hydrophobic characteristics extending inwardly of said surface but
not through to the opposed major surface, and with the spaced-apart
hydrophilic areas on the hydrophobic surface defining passages
extending from the hydrophobic surface into operative relationship
with an absorbent portion, to permit the passage of liquids from
the hydrophobic to the absorbent portion.
The material forming the products of the present invention may be
any suitable material having the desired and required
characteristics for the products for any intended use. Thus, in the
case of diaper liners, the material must be one which is flexible,
and non-harmful or non-irritating to the body when placed in use. A
particularly preferred material from which the diaper liner
products are derived are conventional commercially available
non-woven materials of wood fibers or the like, which may include
synthetic fibers (such as rayon fibers). However, other types of
sheet materials such as woven materials, paper or paper-like
material, etc., may also be used depending on the intended purpose
of the products of the present invention. Without being limiting,
the products of the present invention may be derived from materials
which are initially hydrophobic or hydrophilic. In turn, such
materials, may be derived from or include fibers such as pulp
fibers, cotton linters, synthetic fibers such as cellulose acetate
fibers, vinyl chloride, vinyl acetate (e.g., the product marketed
under the trade mark "VINYON"), polyamides, viscose staple rayon,
rayon or other regenerated cellulose fibers such as cellulose
acetate or cellulose triacetate, acrylic fibers, polyester fibers,
polyolefin fibers such as polypropylene fibers, and natural fibers
such as wool and silk fibers, protein fibers such as those products
marketed under the trade mark "VICARA," combinations of the above
fibers, etc.
The particular physical shape of the sheet material of the products
of the present invention is not critical, and will of course vary
according to the intended use of such products. Conventionally,
products such as diaper liners are of a generally rectangular shape
measuring about nine inches by thirteen inches or larger. Likewise,
the thickness of the material of the present invention is not
critical, but for most applications like diaper liners, the
thickness is normally kept to a minimum weight for economic
reasons.
Although reference in the above description has been generally made
to sheet material functioning as a separate entity and capable of
reducing or preventing the passage of solid particulate matter
therethrough but permitting the passage of liquids, within the
scope of this invention it is also contemplated that such a product
may in fact form a separate layer or layers of a composite
multi-layered product -- or still further, form an integral part of
a total product as an outer portion thereof. Thus, for example, it
may be desirable in certain instances to employ the products of the
present invention in a multi-layered product, and to this end, the
additional layers of such a multi-layered product may have
different functional purposes for any intended or given
application. Thus, the products of the present invention may form
an outer covering layer adhesively or otherwise secured to one or
more inner layers or cores of absorbent material, etc. for certain
applications.
The porosity of the products of the present invention is such that
the material is capable of substantially preventing the passage of
solid particulate matter and at the same time, remain hydrophobic
in nature to liquids (except of course at the hydrophilic
passages). To this end, the generally hydrophobic products with the
hydrophilic passages should have a porosity, as calculated on the
basis of the permeability of the product to water under a pressure
head of 60 cm. of water, above about 1 cc/sq. cm/sec. and up to
about 200 cc/sq. cm/sec., or higher, preferably above 50-75 cc/sq.
cm/sec. Products having the above preferred ranges have been found
to perform very satisfactorily where such materials are used as
diaper liners. To this end, the materials for the products of this
invention will be chosen accordingly, depending on the requirements
for any given application.
The above products may be obtained by the methods previously
briefly outlined. In greater detail, and in both embodiments of
such methods, the starting materials are initially chosen to have
the desired porosity factor as described above; such starting
materials being in any desired form -- e.g., sheet form of either a
continuous length or individual precut lengths. In the case of a
normally hydrophilic starting material, one or both opposed major
surfaces, or still further, the toal hydrophilic material is
treated to render the same substantially hydrophobic in nature. For
this purpose, and depending on the type of material employed, the
treatment is preferably of a chemical nature wherein a liquid
repellent composition is applied to the material in an amount
sufficient to provide the hydrophobic characteristics on one, or
both of the opposed major surfaces, or throughout the material.
Thus, for example, liquid repellent compositions in a liquid form
may be employed to provide the liquid repellency or hydrophobic
characteristics by saturation or other equivalent techniques as
required. In this first or initial step of forming the products
when starting with a hydrophilic material, the type of liquid
repellent composition employed may be any suitable composition
which imparts the desired properties to the material. However,
depending on the intended use of the end products, the type of
composition and active ingredients therein will have to be chosen
to provide any additional characteristics required; by way of
example, such treating compositions may be chosen from those which
do not impart stiffness (i.e., the material remains sufficiently
flexible), it should be non-toxic and non-irritating in the case of
diaper liners, etc.
Typical of the compositions which may be used for the purpose of
rendering the material liquid repellent are such compositions or
products marketed under the trade marks "PHOBOTEX FTC," "PHOBOTEX
FTA," "PARAMUL DC--1," "PARAMUL DC--2," "PARAMUL 115," as well as
silicone compositions, fluorine derivative compositions such as
those marketed under the trade mark "SCOTCHGARD FC--208," repellent
rubber or latex compositions, repellent plastic or resinous
compositions such as vinyl polymers and copolymer-based
compositions, various types of wax derivatives or waxes, as well as
such products marketed under the trade marks "QUILON," "AQUAPEL
EMULSION 360 XC," "KROMYLL-S," "ARIDEX," liquid repellent "AEROTEX"
compositions, "ZELAN," etc.
The liquid repellent treating composition may be in any form
suitable for application to the hydrophilic material, for example,
it may be a gaseous composition, liquid composition or a powder. In
gas phase treating compositions, the compositions are normally
impregnated into the material by exposing the material to the gas
for a sufficient period of time to permit the gaseous composition
to permeate the material, whereafter it is permitted to set and
cure. In the case of compositions in powder form, they may be
applied to the hydrophilic material by any suitable means,
whereafter they may be set and cured according to conventional
procedures. In the case of liquid compositions, as previously
mentioned, the hydrophilic material may be treated by a saturation
technique, or alternately by a spray or like technique. Again,
following evaporation of any carrier, the liquid repellent is
permitted to set and cure as required. In all cases, the setting or
curing of the liquid repellent may vary according to the type of
composition.
Normally, for most applications, only a minimum amount of liquid
repellent composition is applied to the hydrophilic materials for
economic reasons and to avoid any subsequent complications due to
excess repellents being present in the treated material. In this
respect, a total amount of repellent applied to the material will,
of course, vary depending on the type of repellent, the amount of
material to be treated, etc., and hence wide limits will obviously
be used for different compositions.
Upon obtaining a normally hydrophobic surface or product using a
hydrophilic starting material, or alternately starting with a
hydrophobic material, and according to both aspects of the method
of this invention, the hydrophobic material is then treated to
provide spaced-apart hydrophilic passages therein. To this end, the
treatment may either be of a chemical, electrical or thermal nature
-- the choice of which will depend on the type of material and in
the case where a liquid repellent has been used, the type of liquid
repellent employed to render the normally hydrophilic starting
material hydrophobic. By way of example, the hydrophobic material
may be provided with hydrophilic passages by treating spaced-apart
selected areas with a chemical composition capable of nullifying
the hydrophobic properties of such material whereby the treated
areas thus form hydrophilic passages, or in the case of normally
hydrophilic starting material, revert back to a hydrophilic nature.
Typical of the treating compositions which may accomplish this are
compositions functioning as a wetting composition -- such
compositions being, e.g., those products marketed under the trade
marks "TRITON GR--5," surfactants such as "AEROSOL OT," "HYAMINE
1622," "DUPONOL-EP," "COMPOUND TL," "HIGH FOAM BASE B," "STANDOPOL
WAQ," etc., as well as other chemicals which can function to coat
the fibers and provide the hydrophilic passages.
Again, as mentioned above with respect to the liquid repellent
composition, the wetting agent composition will likewise have to be
selected depending on the characteristics desired in the end
product -- e.g., the wetting agent employed may have to be one
which is capable of being sterilized, is non-toxic, etc. Likewise,
as outlined above, the concentration of the wetting agent in the
treating composition, and the amount required to provide
hydrophilic passageways, will vary depending on the type of
composition, its effectiveness, etc. Various techniques can be
employed for applying the treating composition to the hydrophobic
material -- for example, predetermined amounts of the wetting agent
compositions may be applied to at least one major surface of the
material (or to both opposed major surfaces) in a pattern
conforming generally to the configuration of the spaced-apart
hydrophilic passages desired in the products. Thus, for example,
the wetting agent compositions may be applied in the form of
"dots," a pattern of lines, intersecting or otherwise, etc.
Whatever type of treatment is employed to treat the hydrophobic
material and provide hydrophilic passages therein, it should be
chosen and selected such that the porosity of the material is not
destroyed or deleteriously affected during treatment, in order to
maintain the desirable characteristics of the product.
Following both the treatment to render the normally hydrophilic
material hydrophobic (when employed), and the treatment used to
provide hydrophilic passages in the resulting hydrophobic material,
when employing chemical treatment compositions which otherwise
moisten or wet the product entirely or partially, drying of the
product is carried out as an intermediate step. The drying step may
be carried out by any suitable treatment, ranging from exposure to
the atmosphere for a sufficient period of time to permit the
evaporation of the solvents or the like, or by subjecting the
treated material to elevated temperatures (but not at a temperature
sufficient to destroy the treating agents or impart undesirable
properties to the material per se).
Following production of the sheet materials, if not pre-cut to a
desired shape or size before treatment, they may be subsequently
passed to further processing stages to carry this out - or in the
alternative to combine the sheet materials with additional
layers.
Tests carried out on the products of the present invention, in the
case of diaper liners, have demonstrated that the products
substantially prevent soiling of underlying absorbent diapers by
preventing the passage of particulate solid matter through to the
underlying diaper, and at the same time, permitting the passage of
liquid body discharges through the products into the absorbent
diaper. At the same time, products of the present invention provide
a substantial reduction in the area of a wearer's body in contact
with wet or moistened materials, thereby reducing substantially the
possibility of skin irritation. Still further, the above-described
method permits the production of such products in a very economical
and feasible manner.
In addition to use as diaper liners, products of the present
invention may be used for various other industrial applications or
consumer products - for example, such products may be used
individually or in combination with substrate layers of, e.g. an
absorbent nature for underpads or the like, surgical dressings,
sanitary napkins, etc. de
Having thus generally described the invention, reference will now
be made to the following Examples, illustrating preferred
embodiments only.
EXAMPLE 1
A length of hydrophilic non-woven fabric of cellulosic fibers, and
having a weight of from 300 to 600 grains/square yard, and of a
generally rectangular shape grains/square yard, and of a generally
rectangular shape suitable for use as a diaper liner was provided.
A liquid repellent composition was formulated based on the product
marketed under the trade mark "KROMYL-S" in a solvent (water) at a
concentration of 1 percent active. The above-described non-woven
material was impregnated to a wet pick-up of 250 percent. The
treated material was then subjected to a drying step at
140.degree.C. to permit evaporation of the solvent. After testing,
it was found that the material was substantially hydrophobic
throughout.
The thus-obtained hydrophobic non-woven fabric material was then
treated in spaced-apart areas with a solution of a wetting agent
composition. This latter composition was formulated based on the
product marketed under the trade mark "TRITON GR--5," the
composition having a concentration of 0.5 percent by weight. The
composition was applied to one major surface of the hydrophobic
material in an area which, in actual use for a diaper liner, would
be that area normally susceptible to liquid body discharge. In this
embodiment, the wetting agent composition was applied to form a
pattern of "dots" which were spaced-apart a distance of
approximately 5 mm, the diameter of the "dots" being in the order
of from about 1 to about 2 mm. The total area of the hydrophilic
passages thus formed in the material amounted to approximately 10
percent of the total surface area of the non-woven fabric.
Following application of the wetting agent, the material was
permitted to dry and subsequently tested as described
hereinafter.
Products formed according to the above procedure were tested for
use as diaper liners, in which the products of the present
invention were interposed between a conventional absorbent diaper
and an infant's body. When in use, it was found that liquid
discharges from the body which occurred readily passed through the
hydrophilic passages of the diaper liner into the absorbent diaper
per se; but on the other hand the particulate matter of solid body
discharges did not pass through the liner to any extent. Thus, the
diaper liner of the present invention prevented soiling of the
underlying absorbent diaper by its properties.
EXAMPLE 2
A product according to the present invention similar to that
described above was prepared. In this case, the product was tested
by pouring a 1 percent sodium chloride aqueous solution onto the
product. It was observed that all of the fluid passed through the
spaced-apart hydrophilic channels or passages created by the
hydrophilic dots and no strike-through occurred from the balance of
the product. Still further, where the underlying absorbent was not
totally saturated, strike-through would not occur even through the
hydrophilic passages. Conversely, even when the underlying
absorbent diaper was saturated, no strike-through in the area that
did not have the hydrophilic passages was found, whereas this would
have been the case with coarse porosity hydrophobic liners.
EXAMPLE 3
The products of this Example illustrate a further form of this
invention, in which there is provided but a single large area of a
hydrophilic nature surrounded by a hydrophobic area.
In one form, a hydrophobic non-woven fabric similar to that of
Example 1, was treated with a solution of a wetting agent
composition as described in that Example. In that case, the
solution was applied to an eliptically shaped area of the material,
generally centrally located of the material. The total area of the
hydrophobic material which was treated was approximately 20 percent
of the surface area of the material, thereby forming an eliptically
shaped hydrophilic passage in the otherwise hydrophobic material.
The product was then tested as a diaper liner and was found to
perform satisfactorily, in that liquid discharges readily passed
through the eliptically shaped hydrophilic central portion of the
diaper liner, while particulate matter was retained by the
liner.
A similar product to that described above was prepared, but in this
case, the material used was hydrophobic in nature. Thereafter, by
treating the material in the above described manner with the
wetting agent, and again forming a single eliptically shaped
hydrophilic passageway generally centrally located in the sheet
material, which was approximately 20% of the total area of the
material, the product when used as a diaper liner was found to have
the advantageous properties described above.
From the above Examples, it will be evident that the products of
this invention provide many advantageous features over conventional
products. It will be understood that various modifications can be
made to the above-described embodiments without dparting from the
spirit and scope of the invention.
* * * * *