U.S. patent number 3,791,863 [Application Number 05/256,757] was granted by the patent office on 1974-02-12 for method of making electrical resistance devices and articles made thereby.
This patent grant is currently assigned to Stackpole Carbon Company. Invention is credited to Virgil P. Quirk.
United States Patent |
3,791,863 |
Quirk |
February 12, 1974 |
METHOD OF MAKING ELECTRICAL RESISTANCE DEVICES AND ARTICLES MADE
THEREBY
Abstract
An insulating substrate or surface is provided with a
flame-sprayed porous electrical resistance coating, impregnated
with dielectric material to fill its pores. If the support is
metal, it is first provided with a flame-sprayed porous insulating
coating that likewise is impregnated with dielectric material.
Metal is flame-sprayed onto the resistance coating to form
terminals. By using resistance material with a negative temperature
coefficient of resistivity, such as a ceramic ferrite, when the
resistance coating is used for heating purposes, the article to
which it is applied can be prevented from becoming overheated.
Inventors: |
Quirk; Virgil P. (St. Marys,
PA) |
Assignee: |
Stackpole Carbon Company (St.
Marys, PA)
|
Family
ID: |
22973474 |
Appl.
No.: |
05/256,757 |
Filed: |
May 25, 1972 |
Current U.S.
Class: |
392/459; 427/123;
219/543; 338/309; 392/480; 427/404; 427/454; 428/209; 428/316.6;
428/469; 338/308; 427/448; 427/455; 428/312.8 |
Current CPC
Class: |
H01C
7/046 (20130101); H01C 17/10 (20130101); Y10T
428/24917 (20150115); Y10T 428/24997 (20150401); Y10T
428/249981 (20150401); H05B 2203/021 (20130101) |
Current International
Class: |
H01C
17/10 (20060101); H01C 7/04 (20060101); H01C
17/075 (20060101); C23b 005/64 (); B05b
007/20 () |
Field of
Search: |
;219/311,543
;338/308,309 ;117/105.2,215,217,119,94 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Leavitt; Alfred L.
Assistant Examiner: Esposito; M. F.
Attorney, Agent or Firm: Brown, Murray, Flick &
Peckham
Claims
I claim:
1. The method of making an electrical resistance device subject to
thermal cycling, comprising flame-spraying on an insulating surface
an electrical resistance powder to form a porous coating, and
impregnating said coating with dielectric material to fill its
pores to avoid high voltage breakdown.
2. The method according to claim 1, in which the porosity of said
coating reduces the density of the coating to less than about 93
percent of theoretical density.
3. The method according to claim 1, in which said powder is ceramic
ferrite powder.
4. The method according to claim 1, in which metal is flame-sprayed
onto said resistance coating before said impregnating step to form
electric terminals.
5. The method according to claim 1, including first flame-spraying
a porous insulating coating on a substrate, and then flame-spraying
said resistance powder over the insulating coating, said porous
insulating coating being impregnated with said dielectric material
when said porous resistance coating is impregnated.
6. The method of making an electric water heater, comprising
flame-spraying a porous insulating coating on a water tank,
flame-spraying an electrical resistance powder over said coating to
form a porous resistance coating adhering to said insulating
coating, and impregnating both coatings with a dielectric material
to fill their pores.
7. The method according to claim 6, in which said resistance
material powder has a negative temperature coefficient of
resistivity.
8. The method according to claim 7, in which said resistance
material powder is ceramic ferrite powder.
9. The method according to claim 6, in which terminals are formed
by flame-spraying metal onto the resistance coating before said
impregnating step.
10. The method according to claim 6, in which said coatings are
sprayed onto the bottom surface of the tank.
11. An electric water heater comprising a water tank, a
flame-sprayed porous layer of insulating material powder on the
tank and adhering thereto, a flame-sprayed porous layer of
electrical resistance material powder covering the insulating layer
and adhering thereto, spaced flame-sprayed coatings of metal on
said resistance layer forming electric terminals, and dielectric
material filling the pores of said layers between said
terminals.
12. An electric water heater according to claim 11, in which said
resistance material powder is ceramic ferrite powder.
Description
It is known that carbon or graphite particles dispersed in organic
binders and carriers have been sprayed on substrates to form
electrical resistance film, but such films are not stable
electrically in heating applications, and particularly when the
electrical load on the films exceeds 10 watts per square inch. It
also has been proposed to spray tin oxide onto a vitreous coating
on a water heater tank while the tank is in an oven, to thereby
provide it with an electrical resistance film for heating water in
the tank. A heater made in that manner suffers from minute faults
in the vitreous coating and fissures and cracks in the resistance
coating. These are caused by the heat treatment of the insulating
coating on the tank at the time the resistance coating is applied,
and by the subsequent cooling of the massive composite structure.
Moreover, pin holes are formed in fired-on insulative coatings.
These fissures, cracks and pin holes lead to electrical breakdown
of the resistance coating or of the insulating coating or both.
Also, the adherence between the coatings and between the insulating
coating and the tank is faulty.
It is further known that fine particles or powdered materials have
been deposited on substrates by passing the particles through a
high temperature flame, which can be either arc plasma or gas. For
example, ceramic ferrite powder has been flame-sprayed on
substrates to absorb X-rays or to make use of the electromagnetic
properties of the ferrite. Piezoelectric material also has been
flame-sprayed onto substrates. In these applications dense coatings
are required in order to maintain the desired properties. On the
other hand, the flame-spraying of electrical resistance material,
and especially of ceramic ferrites, for electrical resistance
purposes has not proved to be satisfactory because the resistance
coatings, used either as electrical resistors or as heating
elements, have tended to spall due to thermal cycling. That is,
when such elements become heated the resistance coatings have
expanded at a different rate than the insulative film beneath them
and at a different rate than the substrates and have broken
away.
It is an object of this invention to provide a method and articles
in which electrical resistance coatings are sprayed on substrates
and effectively resist spalling and electrical breakdown. Another
object is to provide such articles in which the resistance elements
carry loads in excess of 10 watts but have a long life and are
electrically stable. A further object is to provide a fail-safe
electric water heater.
The invention is illustrated in the accompanying drawing, in
which
FIG. 1 is a side view of an electric water heater without its
thermal insulation;
FIG. 2 is an enlarged fragmentary vertical section taken on the
line II--II of FIG. 1;
FIG. 3 is a side view of a modification;
FIG. 4 is a fragmentary central vertical section of a further
embodiment;
FIG. 5 is a bottom view of another embodiment of the invention;
and
FIG. 6 is a perspective view of an electrical resistor.
Referring to FIGS. 1 and 2 of the drawings, an electric water
heater is shown that includes the usual metal tank 1, to which cold
water is delivered and from which hot water is withdrawn through
pipes 2 and 3, respectively, that enter the top of the tank. In
accordance with this invention, finely powdered electrical
insulating material is flame-sprayed onto the outside of the tank
to form a thin coating or layer 4, generally between about 0.010
and 0.020 inch thick. Alumina powder, preferably between 100 and
250 mesh, is suitable for this purpose, but other dielectric
materials such as steatite or mullite can be used, provided they
are not reactive with the material that is to cover the insulation.
The powdered material is fed in a carrier gas to a flame-spray gun
or torch, either arc plasma or gas, to heat the powder and it is
sprayed onto the tank all around its circumference for best
results. The hot powder fuses together and to the metal tank. The
height of the sleeve thus formed will depend on different
circumstances. It can either extend the full height of the tank or
only part way along it. Also, it may be located near the bottom,
near the top or at the middle of the tank, depending upon what is
found to be the best location for the particular application in
mind.
Over the insulating layer a coating or very thin layer or film of
electrical resistance material 6 is flame-sprayed. This film may be
between 0.004 and 0.020 inch thick, preferably about 0.006. The
longer the resistance sleeve, the thicker the film should be. It is
preferred that a fine ceramic ferrite powder be used for reasons
that will be explained later, but other finely powdered resistive
materials, such as metal oxides or metal carbides, can be used.
Here again the powder may be between 100 and 250 mesh. The
particles of the resistance material fuse together and to the
underlying insulating layer when they strike the insulation.
I have discovered that the spalling problem can be solved by
flame-spraying both layers in such a manner that they are porous.
"Porous" as used herein means not more than about 93 percent of
theoretical density, but more than about 60 percent of theoretical
density because with greater porosity the coatings are not as
continuous as they should be; they are more fibrous and subject to
deterioration. Also, with greater porosity the particles of
resistance material could be sprayed into the pores in the
insulating layer and reach the metal tank. The porosity for any
given thickness of coating can be controlled in several ways, such
as by flame temperature, spray flame velocity, particle size and
velocity, or distance of spray gun from the tank. The porous
layers, due to their honeycomb structure, are flexible or "give" to
some extent as compared with the flame-sprayed rigid dense coatings
that have been required heretofore in other applications. As a
result of this flexibility, the flame-sprayed layers can expand and
contract relative to each other and the tank, due to temperature
changes, sufficiently to avoid separating from each other or from
the metal tank. Consequently, fissures or cracks are not formed
that would lead to electrical breakdown.
In order to connect the resistance coating or sleeve into an
electric circuit so that the water in the tank can be heated,
terminals 7 are joined to the top and bottom areas of the coating.
These terminals are formed by flame-spraying highly conductive
metal powder or wire, such as copper, onto the resistance layer to
form thin metal bands fused to it and extending around the tank.
These terminals should be wide enough to make good and sufficient
electrical contact with the resistance material. Terminals from 3/4
to 1/2 inch wide have been used satisfactorily. If the resistance
sleeve extends very far along the tank, it may be desirable to
flame-spray additional terminals 8 in the same manner between the
end terminals and to electrically connect alternate terminals by
wires 9 as shown in FIG. 3. In such a case the resistance film can
be made thinner than the long resistance sleeve shown in FIG.
1.
After the terminals have been formed in this manner, a further
procedure is required in order to avoid a disadvantage that
otherwise may result from the use of porous coatings. That is,
unless something further is done to increase the electrical
stability of the coatings, it is likely that there will be high
voltage transient breakdown of the resistance layer because of
moisture from the atmosphere entering the pores of the two layers.
Therefore, to avoid this problem the two coatings are impregnated
with a high dielectric material to fill their pores and thereby do
away with all voids in the coatings. This material can be an epoxy
or resin, such as Dow Corning R7 521 silicone resin. The impregnant
does not interfere with the desired flexibility of the coatings. In
order to impregnate the coatings with the dielectric material, the
coated tank may be preheated to about 150.degree.F and then
subjected to a vacuum of about 20 inches of water to remove the air
from the pores. While still under vacuum, the tank is immersed in
the liquid resin and then the vacuum is released and a pressure of
about 80 psig is applied to fill the pores with the resin. After
that the pressure is released, the unit is drained and resin on its
surface is wiped off. Following this the resin or other dielectric
is cured in the manner appropriate for the particular material
used. This curing may be simply air curing or it may require
considerable heat for several hours. If the porosity of the
coatings were so low that the density of the coatings was more than
about 93 percent of theoretical density, the pores would be too
small to be impregnated, so voids would be left in the coatings
that could lead to electrical breakdown. Also, the coatings would
be too rigid and not tolerant of expansion differentials.
Separate metal bands 11 are then clamped around the sprayed-on
terminal bands 7. The clamping bands are provided with means, such
as screws 12, for connecting them to the wires 13 of the electric
circuit that is to supply the current for heating the resistance
coating. The entire unit then is encased in thermal insulation 14,
shown only in FIG. 2.
Such a water tank will have an extremely long life and it has the
additional advantage that it does not have to be provided with any
openings for the insertion of electric heating elements, since the
heating element encircles the outside of the tank. One of the
advantages of using ceramic ferrites over other resistance
materials to form the heating element is that ferrites are a single
phase material and therefore it heats uniformly throughout the
mass. Because of that, the material has a uniform coefficient of
expansion, which avoids possible strain in the material. It also is
chemically inert at water heater temperatures.
A further big advantage is that ferrites have a negative
coefficient of resistivity, which means that as the ferrite coating
is allowed to be heated due to the water temperature increasing in
the tank the electrical resistance of the coating decreases. The
electric circuit for the tank is provided with a fuse 15 or circuit
breaker that will open the circuit in case the current flow through
the ferrite increases to a predetermined point. This much increase
will not occur unless the temperature of the ferrite reaches an
unsafe level due to a transient or permanent fault in the
resistance coating causing an area of it to start to overheat.
Consequently, this water heater is failsafe. Also, due to the same
property of the ferrite when the coated heater is series connected
as shown in FIG. 1, it delivers the heat to the tank in the
location where it is most needed. That is, as the water in the top
of the tank reaches the desired temperature the upper part of the
ferrite coating will become hotter than its lower part and the
resistance of the upper part will decrease. According to Power Law
(P=I.sup.2 R), the power is equal to the square of the current
through the entire resistance coating, times the resistance of that
layer. With resistance in series, the same current passes through
the upper portion and the lower portion of the coating, and since
the resistance of the upper portion is less, more power will be
delivered to the lower portion to be conducted through the tank
wall to the cold water, thus delivering the power to the coldest
spot where needed.
As is well known, ceramic ferrites are ferrogmagnetic compounds
containing Fe.sub.2 O.sub.3 ; that is, one or more metal oxides in
combination with Fe.sub.2 O.sub.3. They are principally in two
forms; a spinel crystal structure or a hexagonal crystal structure.
Ceramic ferrites generally are made by dissolving hydrated ferric
oxide in concentrated alkali solution, by fusing ferric oxide with
alkali metal chloride, carbonate or hydroxide, or by heating ferric
oxide in contact with metal oxides. Different ceramic ferrites have
different electrical conductivity. Some typical values are as
follows:
NiFe.sub.2 O.sub.4 greater than 10.sup.9 ohm cm. MgFe.sub.2 O.sub.4
10.sup.6 ohm cm. Cu.sub.0.5 Zn.sub.0.5 Fe.sub.2 O.sub.4 10.sup.5
ohm cm. Ni.sub.0.5 Zn.sub.0.5 Fe.sub.2 O.sub.4 10.sup.3 ohm cm.
Cu.sub.0.5 Li.sub.0.25 Fe.sub.2.25 O.sub.4 500 ohm cm. Mn.sub.0.66
Zn.sub.0.28 Fe.sub.0.06 Fe.sub.2 O.sub.4 150 ohm cm. Ni.sub.0.99
Fe.sub.0.01 Fe.sub.2 O.sub.4 30 ohm cm. Ni.sub.0.85 Fe.sub.0.15
Fe.sub.2 O.sub.4 5 ohm cm.
The method of making an electric water heater disclosed herein
assures good heat transfer between the heating element and the
metal wall of the tank, together with a resistance to
thermo-mechanical spalling not experienced heretofore with fired-on
virtreous type coatings. Moreover, when the resistance material is
a ceramic ferrite, a negative temperature coefficient of
resistivity is present with the advantage that the heater can be
controlled and made fail-safe. The difference in thermal expansion
of the resistance coating and the metal tank is reduced by the fact
that the resistance coating runs considerably hotter than the metal
tank, which is in contact with the water.
In the modification shown in FIG. 4, a vertical metal tube 20
extends through the center of the tank 21 and the water is around
this tube. The inner surface of the tube is provided with a
flame-sprayed electrical insulating coating like coating 4 in FIGS.
1 and 2. A coating or film 22 of flame-sprayed electrical
resistance powder covers the insulating coating, and metal
terminals (not shown) are flame-sprayed onto the resistance
material. In this case the water in the tank is heated by an
internal, instead of an external, electric heater.
A further modification is to apply the heater to the lower surface
of the bottom of a tank. Again it would be done by flame-spraying.
As shown in FIG. 5, the resistance material may be applied in
circumferentially spaced porous radial bands 25 to the tank bottom
26, with all of the bands joined at the center of the bottom where
they are covered by a flame-sprayed metal terminal 27 that is
applied before the insulating and resistance layers are impregnated
with a dielectric material. Similar flame-sprayed metal terminals
28 are joined to the outer ends of the bands. Of course, if
desired, the entire tank bottom could be covered with the
resistance material, with a terminal at its center and a circular
terminal covering its marginal area.
The method explained herein can also be used for making other kinds
of liquid heaters, such as laboratory flasks or beakers, baby
bottle warmers, cups, and beverage and soup warmers. Where the
substrate, such as a cup, is ceramic it is unnecessary to first
apply an insulative coating. The resistance material can be
flame-sprayed directly onto the substrate. Also, when used as the
heating source for a fluorescent light tube, the resistance
material is flame-sprayed directly onto the glass tube.
The invention likewise is applicable to heating units that may be
separate from the articles that they are designed to heat.
Another application of the invention is not for heating purposes,
but as electrical resistors for controlling electric current. Thus,
as shown in FIG. 6 of the drawings, an insulating substrate 30 can
be flame-sprayed with ferrite powder to provide it with a thick
film resistor 31. The film is made porous as explained before to
prevent spalling due to the different coefficients of thermal
expansion of the substrate and film. Metal then is flame-sprayed
onto the end areas of the resistor film to form terminals 32 so
that wires can be attached to it. Then the porous film is
impregnated with a liquid dielectric which is subsequently cured,
so that the resistance film will not break down electrically.
According to the provisions of the patent statutes, I have
explained the principle of my invention and have illustrated and
described what I now consider to represent its best embodiment.
However, I desire to have it understood that, within the scope of
the appended claims, the invention may be practiced otherwise than
as specifically illustrated and described.
* * * * *