U.S. patent number 3,790,079 [Application Number 05/259,374] was granted by the patent office on 1974-02-05 for method and apparatus for generating monodisperse aerosol.
This patent grant is currently assigned to RNB Associates, Inc.. Invention is credited to Richard N. Berglund, Benjamin Y. H. Liu.
United States Patent |
3,790,079 |
Berglund , et al. |
February 5, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
METHOD AND APPARATUS FOR GENERATING MONODISPERSE AEROSOL
Abstract
A vibrating orifice monodisperse aerosol generator usable as a
basic aerosol standard having a liquid feed system, a droplet
generator, a droplet dispersion system and an aerosol flow system.
The liquid feed system is a syringe pump operable to feed liquid
into the droplet generator. The liquid is discharged from the
droplet generator through a small orifice as a liquid jet. The jet
disturbed at a constant frequency with an oscillating piezoelectric
ceramic breaks up into uniform droplets. The droplets are dispersed
by a turbulent air jet and diluted into a monodispersed
aerosol.
Inventors: |
Berglund; Richard N. (St. Paul,
MN), Liu; Benjamin Y. H. (Minneapolis, MN) |
Assignee: |
RNB Associates, Inc.
(Minneapolis, MN)
|
Family
ID: |
22984678 |
Appl.
No.: |
05/259,374 |
Filed: |
June 5, 1972 |
Current U.S.
Class: |
239/3; 239/4;
239/8; 239/102.2; 366/115; 366/176.1; 366/127 |
Current CPC
Class: |
B05B
17/0607 (20130101) |
Current International
Class: |
B05B
17/04 (20060101); B05B 17/06 (20060101); B05b
005/00 (); B05b 007/00 (); B05b 017/06 () |
Field of
Search: |
;239/3,4,8,9,101,102
;259/DIG.44 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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|
|
|
|
205,195 |
|
Jun 1969 |
|
SU |
|
1,017,388 |
|
Sep 1952 |
|
FR |
|
1,198,514 |
|
Jul 1970 |
|
GB |
|
Primary Examiner: Ward, Jr.; Robert S.
Attorney, Agent or Firm: L. Paul Burd et al.
Claims
The embodiments of the invention in which an exclusive property
or
1. An aerosol generator comprising: housing means having at least
one outlet hole, an apparatus for generating liquid droplets
mounted on said housing means, said apparatus having a discharge
orifice generally axially aligned with said hole and spaced from
said hole, said housing means including means providing a chamber
between the apparatus and the outlet hole, means for supplying the
apparatus with liquid under pressure whereby the apparatus
generates droplets, and means operable to provide air under
pressure into the chamber whereby droplets emanating from the
apparatus into the chamber are dispersed into the air and
discharged with the air
2. The generator of claim 1 wherein: the apparatus for genereating
liquid droplets includes means operable to vibrate the apparatus at
a frequency
3. The generator of claim 2 wherein: said means to vibrate the
apparatus is
4. The generator of claim 1 including: means to apply a constant
frequency AC voltage to said apparatus to vibrate the apparatus
whereby the jet of liquid moving from the orifice breaks into
substantially equal size
5. The generator of claim 1 wherein: said apparatus for generating
liquid droplets includes housing means having a first member with a
first passage and a second member having an outlet opening attached
to the first member, and means having an orifice located between
the first member and the
6. The generator of claim 5 including: an annular member engageable
with said first member and said means having an orifice to position
said means
7. The generator of claim 6 wherein: the annular member is a
resilient
8. The generator of claim 1 in combination with: a porous support
means, tube means having a chamber extended from said support means
for receiving aerosol from the generator, said generator being
mounted on said porous support means within said tube means with
the outlet hole positioned to direct aerosol into the chamber of
the tube means, and means to supply air to said porous support
means whereby said air transports the dispersed
9. The aerosol generator of claim 8 wherein: said generator is
located generally along the longitudinal axis of the tube means and
on the support means so that a substantially uniform cylindrical
core of air surrounds
10. The generator of claim 1 wherein: the housing means has a side
wall surrounding a chamber, said apparatus for generating liquid
droplets being located in said chamber, and resilient means
mounting said apparatus on
11. The generator of claim 10 wherein: the resilient means is an
annular
12. An apparatus usable with a source of liquid under pressure to
generate droplets comprising: housing means having a passageway, an
inlet opening, and an outlet opening in communication with the
passageway, disc means having an orifice mounted on said housing
means, said orifice being open to liquid from said passageway
whereby a jet of liquid is discharged from the orifice, means
secured to the housing means operable to vibrate the disc means at
a frequency that breaks up the jet of liquid moving from the
13. The apparatus of claim 12 wherein: said means secured to the
housing
14. The apparatus of claim 13 wherein: said material of the annular
member
15. The apparatus of claim 13 including: means to apply a constant
frequency AC voltage to said annular member to cause said housing
means to vibrate whereby the jet of liquid moving from the orifice
breaks up into substantially equal size droplets related to the
frequency of the AC
16. The apparatus of claim 12 wherein: said housing means includes
a first member having a first passageway and said inlet opening,
and a second member having said outlet opening attached to the
first member, said disc
17. The apparatus of claim 16 wherein: said second member has a
cylindrical wall and the first member has a cylindrical portion
attached to said
18. An apparatus usable with a source of liquid under pressure to
generate droplets comprising: housing means having a passageway, an
inlet opening, and an outlet opening in communication with the
passageway, means having an orifice mounted on said housing means,
said orifice being generally axially aligned with said outlet
opening to direct a jet of liquid through the outlet opening, said
housing means including a first member having a first passageway
and said inlet opening and a second member having said outlet
opening attached to the first member, said means having an orifice
being located between said first member and said second member, and
annular means engageable with said first member and said means
having an orifice to position said means having an orifice on the
housing means.
19. The apparatus of claim 18 wherein: the annular means is a
resilient
20. The apparatus of claim 18 wherein: said second member has a
recess surrounding the inlet opening, a disc means being located in
said recess.
21. The apparatus of claim 12 wherein: said orifice in the disc
means is a
22. The apparatus of claim 12 wherein: the housing means comprises
a first member having a generally flat portion, cylindrical side
wall portion and an outwardly directed flange portion, said outlet
opening being in said generally flat portion, and a second member
attached to the side wall portion, said disc means being located
between the first member and second member, and said means operable
to vibrate the housing means being secured
23. The apparatus of claim 22 wherein: the flat portion has an
inwardly open recess, said disc means having an orifice is located
in said recess, and resilient means engageable with the disc means
and second member
24. The apparatus of claim 23 wherein: the resilient means is an
O-ring.
25. The apparatus of claim 22 wherein: the said means operable to
vibrate the housing is a piezoelectric ceramic ring surrounding the
side wall
26. A method of generating a monodispersed aerosol comprising:
discharging a liquid jet through an orifice in a member, vibrating
the member to break up the liquid jet passing through the orifice
into substantially uniform droplets, subjecting the droplets to a
flow of turbulent air to disperse the droplets in the air, and
discharging the droplets to a selected
27. The method of claim 26 wherein: the droplets are discharged
into a
28. The method of claim 26 wherein: the member is vibrated at a
frequency
29. The method of claim 26 wherein: the liquid jet is discharged
into a chamber having an outlet opening, said turbulent air being
introduced into said chamber, and said droplets and turbulent air
being discharged through
30. The method of claim 26 wherein: the liquid jet is discharged in
a direction in general alignment with the outlet opening for the
chamber.
31. The method of claim 26 wherein: the droplets are subjected to a
DC
32. An apparatus usable with a source of liquid under pressure to
generate substantially equalized droplets comprising: housing means
having a passageway, an inlet opening and an outlet opening in
communication with the passageway whereby the liquid can flow
through said housing means, means having an orifice mounted on said
housing means between said inlet opening and said outlet opening,
said orifice being open to liquid from said passageway whereby a
jet of liquid is discharged fom the orifice, means secured to the
housing means operable to vibrate the means having an orifice at a
frequency that breaks up the jet of liquid moving from the orifice
into substantially equal size droplets, said means secured to the
housing means being an annular member of piezoelectric material
33. The apparatus of claim 32 wherein: said means having an orifice
is a
34. The apparatus of claim 32 wherein: the housing means comprises
a first member having said outlet opening and a second member
secured to the first member having the inlet opening, said means
having an orifice being
35. The apparatus of claim 34 including: resilient means engageable
with one of said members and the means having an orifice to
position the means
36. The apparatus of claim 34 wherein: one member has an inwardly
open recess, said means having an orifice being located in said
recess, and means engageable with said means having an orifice and
the other member to
37. The apparatus of claim 36 wherein: said means is a resilient
O-ring.
38. The apparatus of claim 34 wherein: said one member has an
outwardly directed flange, said annular member of piezoelectric
material being secured to said flange.
Description
BACKGROUND OF THE INVENTION
Basic aerosol standards, consisting of monodispersed aerosols of a
high degree of monodispersity and accurately known particle size
are needed for a variety of purposes ranging from fundamental
aerosol research, calibration of aerosol sampling and measuring
instruments, testing of particulate control devices such as
cyclones, filters, scrubbers, and the like, to the study of health,
meteorological and other effects of particulate air pollutants. To
be generally useful, the aerosol standard must be sufficiently
flexible to permit aerosols to be generated from a variety of solid
and liquid materials having desired physical properties.
Conventional monodisperse aerosol generators, as the spinning-disc
aerosol generator, the atomizer-impactor generator, the
condensation generator and the polystyrene latex aerosol generator,
all have severe limitations for use as a basic aerosol standard.
The spinning-disc generator, while flexible in terms of the aerosol
material, can produce aerosols with geometrical standard deviations
of not better than 1.07 or a standard deviation of approximately 7
percent of the mean particle size. The spinning-disc generator is
also a relatively complex piece of apparatus. The atomizer-impactor
generator can only produce a moderately monodisperse aerosol with a
geometrical standard deviation of not better than 1.40. The
polystyrene latex generator can produce aerosols from only one
material and only of the discrete sizes provided by the polystyrene
latex manufacturer. This generator also produces residue particles
which are undesirable for many applications.
Vibrating orifice aerosol generators are based on the principle of
the breakup of a liquid jet. It is known that cylindrical liquid
jets are unstable to rotationally symmetric disturbances. These
disturbances will grow until the jet breaks. The known droplet
generators are not usable as a basic aerosol standard in their
present state of development as they need a droplet dispersion
system in an aerosol flow system of a well defined geometry to
provide stable operation.
SUMMARY OF THE INVENTION
The invention relates to an apparatus and method for generating a
monodispersed aerosol of any liquid or any solid material that can
be put in solution form. The apparatus for generating a
monodispersed aerosol has a housing means having at least one
outlet opening for discharging the aerosol. Mounted on the housing
means is an apparatus for generating liquid droplets. The apparatus
has a discharge orifice generally aligned with the outlet opening
the housing and spaced from the opening. The housing means includes
means providing a chamber between the apparatus and the outlet
opening. The liquid is supplied under pressure to the apparatus to
generate droplets. The apparatus has means subjected to a vibratory
force which breaks the liquid jet into substantially equal size
droplets which are discharged into the chamber. Air under pressure
is supplied to the chamber, whereby the droplets emanating from the
apparatus are dispersed into the air and discharged with the air
through the outlet opening. The dispersed aerosol then enters the
aerosol flow system which acts to dilute and transport the
aerosol.
IN THE DRAWINGS
FIG. 1 is a schematic view of the aerosol generator flow system of
the invention;
FIG. 2 is an enlarged fragmentary sectional view of the aerosol
generator of FIG. 1 located in the flow system;
FIG. 3 is a sectional view of the aerosol generator taken along
line 3--3 of FIG. 2;
FIG. 4 is an enlarged sectional view of the droplet generator
forming part of FIG. 2; and
FIG. 5 is an enlarged sectional view taken along line 5--5 of FIG.
4.
Referring to the drawings, there is shown in FIG. 1 the flow system
for the aerosol generator of the invention, indicated generally at
10. System 10 includes an aerosol generating assembly, indicated
generally at 11, containing the aerosol generator 12 for generating
droplets and dispersing the droplets in carrier air in the form of
a monodispersed aerosol.
As shown in FIG. 2, aerosol generator 12 is mounted on a support or
porous plate 13 located over an opening in a housing 14. The outer
peripheral edge portion of the plate 13 rests on and is attached to
the top of housing 14. The housing 14 surrounds an absolute filter
16 through which the air passes prior to its flow through the
porous plate 13. Positioned on top of plate 13 is an elongated tube
or cylinder 17 having an elongated chamber 18. The upper end of the
cylinder is tapered or cone-shaped and has an outlet opening 19,
providing an outlet passage for the discharge of monodispersed
aerosol, indicated by arrow 21. A plurality of fasteners 22, as
bolts, extend through suitable holes in an outwardly directed
flange 17A on the tubular member 17 and aligned holes in plate 13
to secure the tube 17 and plate 13 to the top of housing 14.
Air is supplied to the bottom of housing 14 with a blower 23 having
an electric motor (not shown) controlled with a variable
transformer 24. Air can also be obtained from a compressor having
appropriate pressure regulators. The outlet of blower 23 is
connected to a line or tube 26 leading to the bottom of housing 14.
A control valve 27 interposed in line 26 regulates the flow of air
into housing 14. A differential pressure gauge 28 is connected in
line 26 before valve 27 and an outlet portion of blower 23 to
provide means for determining the pressure of the air being
supplied to the housing 14.
The liquid feed system for the aerosol generator 12 has an infusion
pump or syringe 29 which forces the liquid under pressure through a
membrane filter 32 interposed in a line 31 connecting the pump 29
to the aerosol generator 12. Other types of pumps can be used to
provide the generator 12 with a substantially constant supply of
liquid under pressure.
Aerosol generator 12 has a droplet generator or apparatus operable
to form liquid droplets, indicated generally at 33 in FIGS. 2 and
4. The air supply system for the generator 33 is diagrammatically
shown in FIG. 1. Droplet generator 33 is connected to a high
pressure air line 34 providing a supply of air to a pressure
regulator 36 and an absolute filter 37. The air flows from filter
37 through a rotameter 38 into a feed line 39 connected to the
aerosol generator 12. The droplet generator 33 is subjected to a
vibratory force generated with a signal generator 41 coupled via
line or conductor 76 to a vibrating portion of the droplet
generator 33, as shown in FIG. 4.
As shown in FIG. 2, the aerosol generator 12 has a housing
comprising a generally cup-shaped base 42 mounted on the center
portion of plate 13. A plurality of fasteners 43, as bolts, attach
base 42 to plate 13. Base 42 has an upwardly directed cylindrical
side wall 44 surrounding a chamber 46. The top of base 42 is closed
wih an inverted, cup-shaped housing member 47 having a generally
flat top wall or metal plate 48. The center portion of top wall 48
has an outlet hole or outlet opening 49 located along the axial or
longitudinal center line of the chamber located along the axial or
longitudinal center line of the chambr r 18. Member 47 has a
cylindrical side wall 51 of electrical non-conductive material
telescoped over the side wall 44. Fasteners 52, as bolts, secure
the walls 44 and 51 together. An annular seal 53 is interposed
between walls 44 and 51. The top wall 48 is spaced from and located
above the top of the droplet generator 33 forming therewith a space
or chamber 54. An annular stop washer 55 secured to the inside of
side wall 51 rests on top of the side wall 44. Secured to side wall
51 is an inlet nipple 56 connecting the air line 39 to the
generator 12 so that air indicated by arrow 57 is introduced into
the chamber 54 and mixed with the droplets emanating from the
generator 33. The air is introduced into the side of chamber 54 and
is in a turbulent state as it mixes with the droplets. The air and
droplet mixture in chamber 54 is discharged through opening 49 into
the chamber 18 and is dispersed in a conical pattern, as shown in
FIG. 2. The dispersed aerosol is carried with the clean air flowing
through porous plate 13 in the chamber 18 toward the outlet opening
19. This clean air functions to dilute and transport the aerosol.
In the case of a nonvolatile solute in a volatile solvent, the
clean air also evaporates the solvent. The monodispersed aerosol 21
is discharged through the opening 19 at the top of the tube 17.
When it is desired to generate a monodispersed aerosol having a
unipolar electrical charge, a DC voltage can be applied to the
metal plate 48 to induce a charge on the generated droplets.
As shown in FIG. 2, droplet generator 33 is located in chamber 46
of the base 42. An annular O-ring 59 of resilient material, as
rubber, surrounds generator 33 to position the generator in chamber
46. The O-ring is in frictional engagement with an annular outer
portion of the generator. The outer peripheral portion of O-ring 59
is located in an annular groove 60 in the top of the inside face of
side wall 44.
Referring to FIGS. 4 and 5, there is shown droplet generator 33
operable to produce monodispersed liquid droplets. Generator 33 has
a housing having a second member including generally flat top plate
61. A center portion of plate 61 has a hole or outlet opening 62.
Extended downwardly from the bottom side of plate 61 is a
cylindrical side wall 63. The plate 61 and side wall 63 form an
inverted, generally cup-shaped housing member having an outwardly
directed top flange or lip 61A. The inner face of side wall 63 is
threaded to accommodate a threaded plug or cap 64 forming a first
housing member. Plug 64 has a longitudinal passageway 66. Line 31
is connected to the plug 64 to provide the inlet port or opening of
passageway 66 with fluid under pressure from the infusion pump 29.
The inside wall of plate 61 has a circular recess 67 accommodating
a removable disc or plate member 68. The center portion of disc 68
has a small discharge orifice or opening 69. The disc 68 is held in
recess 67 with an annular resilient member or an O-ring 71. A
compressive force is applied to the O-ring 71 by turning plug 64
into the side wall 63. The top face of plug 64 engages O-ring 71
and holds it in a compressive state against disc 68. The O-ring 71
surrounds a chamber 72 located at the upper end of passageway 66
adjacent the disc 68. The orifice 69 is in general axial or
longitudinal alignment with passageway 66 and outlet opening
49.
An annular means 73 surrounds the side wall 63 and is operable to
vibrate the generator 33 at a frequency that breaks the liquid jet
75 into substantially equal sized droplets 77. Annular means 73 is
an annular member or ring of piezoelectric ceramic secured to the
underside of flange 61A with an epoxy 74, or similar fastening
means. Signal generator 41 is electrically coupled to flange 61A
and annular means 73 with a line or conductor 76. Epoxy 74 is an
electrically conductive fastening adhesive. Other suitable
attaching or bonding means can be used to couple the vibrating
means to the flange 61A. The inside surface of vibrating means 63
is spaced, indicated at 78, from the outside surface of side wall
63, whereby all the vibratory forces are applied to the plate
61.
In operation, liquid is supplied to generator 33 via the line 31 on
operation of pump 29. The liquid flows through passageway 66 into
the chamber 72. The liquid is discharged as a jet 75 through the
orifice 69 which directs the liquid through hole 62. The signal
generator 41 provides a constant frequency AC voltage to the
piezoelectric ceramic 73. This AC voltage vibrates the cup-shaped
housing structure 61-63 and disturbs the liquid jet 75. Liquid jet
75 breaks up into equal size droplets 77 at the frequency of the AC
voltage. The droplets 77 enter the chamber 54. Air 57 enters the
chamber 54 in a turbulent state, thereby dispersing the droplets
77. The dispersed droplets and air are discharged into chamber 18
through opening 49 in a conical pattern, indicated at 58 in FIG. 2.
The dispersed aerosol is diluted by the moving clean air in chamber
18 and transported to the outlet opening 19. The clean air flows
from housing 14 through porous plate 13 in a generally linear
configuration whereby the dispersed aerosol is carried generally
linearly in the center or core section of chamber 18.
In terms of method of generating a monodispersed aerosol, the
droplet generator 33 functions to discharge a liquid jet 75 through
orifice 69. This jet is disturbed with a vibratory force to break
the jet into substantially uniform droplets 77. The liquid jet 75
is disturbed at a frequency established with an AC voltage on a
member, as piezoelectric ceramic ring 73, which will vibrate when
subjected to an AC voltage. The droplets 77 are directed into a
mixing or dispersion chamber 54 in a direction in general alignment
with the outlet opening 49 for the chamber. During the time the
droplets are in the chamber 54, they are subject to a flow of
turbulent air 57. Both the turbulent air and the dispersed droplets
are discharged from chamber 54 through outlet opening 49 into
chamber 18 which forms a passage to the outlet opening 19. A stream
of clean air in chamber 18 dilutes the aerosol and carries the
dispersed aerosol to the outlet opening 19.
The aerosol generator 12 produces particles that do not have to be
measured. The aerosol diameter can be calculated from the liquid
flow rate, the disturbance frequency, and non-volatile solute
concentration within 0.1 percent error by the following
formula:
Dp = [ 6QC/.pi.f] .sup.1/3
where
Q = volumetric flow rate,
C -- volumetric concentration of non-volatile solute in volatile
solvent,
f = disturbance frequency.
The particles are substantially uniform in that no size difference
can be detected between them by using an optical microscope.
While there have been shown and described a preferred apparatus and
method for generating a monodispersed aerosol, it is understood
that changes in the size, materials, electrical circuits, fluid and
air flow systems may be made by those skilled in the art without
departing from the spirit of the invention.
* * * * *