U.S. patent application number 13/204062 was filed with the patent office on 2011-11-24 for light reflecting mask, exposure apparatus, and measuring method.
This patent application is currently assigned to Kabushiki Kaisha Toshiba. Invention is credited to Kosuke TAKAI.
Application Number | 20110286002 13/204062 |
Document ID | / |
Family ID | 41256879 |
Filed Date | 2011-11-24 |
United States Patent
Application |
20110286002 |
Kind Code |
A1 |
TAKAI; Kosuke |
November 24, 2011 |
LIGHT REFLECTING MASK, EXPOSURE APPARATUS, AND MEASURING METHOD
Abstract
A light reflecting mask includes a reflecting layer which is
provided on a substrate and reflects light, an absorbing layer
which is provided on the reflecting layer and absorbs light, a
device pattern which is formed in a first region of the absorbing
layer, and a reflectance measuring pattern which is formed in a
second region of the absorbing layer. The reflectance measuring
pattern is a diffraction grating.
Inventors: |
TAKAI; Kosuke;
(Yokohama-shi, JP) |
Assignee: |
Kabushiki Kaisha Toshiba
|
Family ID: |
41256879 |
Appl. No.: |
13/204062 |
Filed: |
August 5, 2011 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
12405557 |
Mar 17, 2009 |
8007960 |
|
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13204062 |
|
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Current U.S.
Class: |
356/445 |
Current CPC
Class: |
G02B 17/0657 20130101;
G03F 1/24 20130101; G03F 1/44 20130101; B82Y 40/00 20130101; B82Y
10/00 20130101 |
Class at
Publication: |
356/445 |
International
Class: |
G01N 21/55 20060101
G01N021/55 |
Foreign Application Data
Date |
Code |
Application Number |
Apr 30, 2008 |
JP |
2008-119293 |
Claims
1.-6. (canceled)
7. An exposure apparatus comprising: a first light source which
emits exposure light; a holding mechanism which holds a light
reflecting mask having a reflectance measuring pattern; and a first
photosensor which detects an intensity of light reflected by the
reflectance measuring pattern.
8. The apparatus according to claim 7, wherein the first
photosensor detects diffraction light of not lower than first
order.
9. The apparatus according to claim 7, wherein the light reflecting
mask further includes a device pattern, and the first photosensor
is arranged outside a path of the exposure light reflected by the
device pattern.
10. The apparatus according to claim 9, further comprising an
illumination optical system which illuminates the device pattern
and the reflectance measuring pattern with the exposure light.
11. The apparatus according to claim 7, further comprising a second
photosensor which detects the intensity of the exposure light
before illuminating the reflectance measuring pattern.
12. The apparatus according to claim 7, further comprising a second
light source which illuminates the reflectance measuring pattern
with measuring light.
13. The apparatus according to claim 12, wherein the first
photosensor detects diffraction light of the measuring light.
14. The apparatus according to claim 7, wherein the exposure light
is extreme ultraviolet (EUV) light.
15. A measuring method comprising: arranging a light reflecting
mask having a device pattern and a reflectance measuring pattern;
illuminating the device pattern and the reflectance measuring
pattern with exposure light; and detecting an intensity of light
reflected by the reflectance measuring pattern.
16. The method according to claim 15, wherein detecting the
intensity of the light is performed in an exposure process using
the device pattern.
17. The method according to claim 15, further comprising arranging
a photosensor outside a path of the exposure light reflected by the
device pattern, wherein the photosensor detects the intensity of
the light.
18. The method according to claim 17, wherein the photosensor
detects diffraction light of not lower than first order.
19. The method according to claim 15, further comprising detecting
the intensity of the exposure light before illuminating the
reflectance measuring pattern.
20. The method according to claim 19, further comprising arranging
a photosensor outside a path of the exposure light illuminating the
reflectance measuring pattern, wherein the photosensor detects the
intensity of the exposure light.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application is based upon and claims the benefit of
priority from prior Japanese Patent Application No. 2008-119293,
filed Apr. 30, 2008, the entire contents of which are incorporated
herein by reference.
BACKGROUND OF THE INVENTION
[0002] 1. Field of the Invention
[0003] The present invention relates to a light reflecting mask, an
exposure apparatus, and a measuring method used for lithography
using extreme ultraviolet (EUV) light.
[0004] 2. Description of the Related Art
[0005] In lithography using EUV light having a wavelength of about
13.5 nm, a light reflecting mask capable of transferring a pattern
by reflecting exposure light is used. The light reflecting mask is
formed by, e.g., sequentially stacking, on a glass substrate, a
reflecting layer which reflects light, a cap layer made of silicon
(Si) or the like, and an absorbing layer which absorbs light. A
pattern is formed by partially etching the absorbing layer.
[0006] The reflectance of the light reflecting mask having such a
structure decreases along with the repeat of exposure because of
the influence of oxidation or corrosion of the exposed cap layer
surface or substances sticking to it. This degrades the image
contrast when transferring the pattern onto a wafer.
[0007] A reference (Jpn. Pat. Appln. KOKAI Publication No.
2004-61177) discloses a technique of measuring degradation in an
optical element such as a mirror arranged in an exposure apparatus.
However, regarding degradation in a light reflecting mask, it is
difficult to measure the characteristics and change because the
pattern formed on the mask is not uniform in general.
BRIEF SUMMARY OF THE INVENTION
[0008] According to an aspect of the present invention, there is
provided a light reflecting mask comprising: a reflecting layer
which is provided on a substrate and reflects light; an absorbing
layer which is provided on the reflecting layer and absorbs light;
a device pattern which is formed in a first region of the absorbing
layer; and a reflectance measuring pattern which is formed in a
second region of the absorbing layer. The reflectance measuring
pattern is a diffraction grating.
[0009] According to an aspect of the present invention, there is
provided an exposure apparatus comprising: a first light source
which emits exposure light; a holding mechanism which holds a light
reflecting mask having a reflectance measuring pattern; and a first
photosensor which detects an intensity of light reflected by the
reflectance measuring pattern.
[0010] According to an aspect of the present invention, there is
provided a measuring method comprising: arranging a light
reflecting mask having a device pattern and a reflectance measuring
pattern; illuminating the device pattern and the reflectance
measuring pattern with exposure light; and detecting an intensity
of light reflected by the reflectance measuring pattern.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING
[0011] FIG. 1 is a sectional view showing the structure of a blank
substrate used for a light reflecting mask 100 according to the
first embodiment of the present invention;
[0012] FIG. 2 is a sectional view showing steps in the manufacture
of the light reflecting mask 100;
[0013] FIG. 3 is a sectional view showing steps in the manufacture
of the light reflecting mask 100 following FIG. 2;
[0014] FIG. 4 is a sectional view showing steps in the manufacture
of the light reflecting mask 100 following FIG. 3;
[0015] FIG. 5 is a sectional view showing the structure of the
light reflecting mask 100;
[0016] FIG. 6 is a schematic view showing the arrangement of an
exposure apparatus 200 according to the first embodiment;
[0017] FIG. 7 is a flowchart illustrating a lithography method;
[0018] FIG. 8 is a schematic view for explaining detection of
higher order diffraction light by a photosensor 301;
[0019] FIG. 9 is a schematic view showing the arrangement of the
main part of an exposure apparatus 200 according to the second
embodiment of the present invention;
[0020] FIG. 10 is a schematic view showing the arrangement of the
main part of an exposure apparatus 200 according to the third
embodiment of the present invention; and
[0021] FIG. 11 is a schematic view showing another arrangement of
the exposure apparatus 200 according to the third embodiment.
DETAILED DESCRIPTION OF THE INVENTION
[0022] The embodiments of the present invention will be described
hereinafter with reference to the accompanying drawings. In the
description which follows, the same or functionally equivalent
elements are denoted by the same reference numerals, to thereby
simplify the description.
First Embodiment
[0023] FIG. 1 is a sectional view showing the structure of a blank
substrate used for a light reflecting mask 100 according to the
first embodiment of the present invention.
[0024] A reflecting layer 102 to reflect light is provided on the
upper surface of a glass substrate 101 having a very small thermal
expansion coefficient. The reflecting layer 102 is formed by
stacking about 40 multilayered films of molybdenum (Mo)/silicon
(Si) using sputtering. To protect the upper surface of the
reflecting layer 102, a cap layer 103 made of, e.g., silicon (Si)
or ruthenium (Ru) is provided on the reflecting layer 102.
[0025] A buffer layer 104 made of, e.g., chromium (Cr) is provided
on the cap layer 103. To absorb EUV light, an absorbing layer 105
is provided on the buffer layer 104. A material containing tantalum
(Ta) or chromium (Cr), e.g., tantalum nitride (TaN) is used as the
absorbing layer 105.
[0026] To absorb inspection light having a wavelength of about 250
nm, an absorbing layer 106 made of, e.g., tantalum oxide (TaO) is
provided on the absorbing layer 105. For an electrostatic chuck at
the time of EUV exposure, a conductive layer 107 made of, e.g.,
chromium nitride (CrN) is provided on the lower surface of the
glass substrate 101. In this way, a blank substrate used for the
light reflecting mask 100 is obtained.
[0027] A method of manufacturing a light reflecting mask obtained
having a desired pattern formed on a blank substrate will be
explained next.
[0028] First, the blank substrate shown in FIG. 1 without any
pattern is prepared. Next, a photosensitive resin (resist) 108 is
applied to the upper surface of the blank substrate (i.e., the
upper surface of the absorbing layer 106), as shown in FIG. 2. A
desired pattern is drawn on the resist 108 using an electron beam.
A post-exposure bake (PEB) step that is an annealing step after
exposure, and a developing step are performed, thereby forming a
resist pattern on the blank substrate.
[0029] Subsequently, the absorbing layers 105 and 106 are
selectively etched by, e.g., a plasma process using the resist
pattern as a mask, as shown in FIG. 3. Then, the resist pattern is
removed.
[0030] The buffer layer 104 is selectively etched by, e.g., a
plasma process using the absorbing layers 105 and 106 as a mask, as
shown in FIG. 4. With this process, the light reflecting surface
(cap layer 103) is exposed, thus completing the light reflecting
mask 100.
[0031] The light reflecting mask 100 of this embodiment includes a
device pattern region 100A where a device pattern having device
information is formed, and a reflectance measuring pattern region
100B where a reflectance measuring pattern to measure the
reflectance of the light reflecting mask 100 is formed, as shown in
FIG. 5. A diffraction grating is used as the reflectance measuring
pattern.
[0032] In this embodiment, a line-and-space pattern is used as the
diffraction grating, as shown in FIG. 5. Another example of the
diffraction grating is a checkered pattern. The reflectance
measuring pattern region 100B is provided adjacent to the device
pattern region 100A. In a lithography step, the reflectance
measuring pattern region 100B is illuminated with exposure light as
much as the device pattern region 100A.
[0033] The arrangement of an exposure apparatus 200 will be
described next. FIG. 6 is a schematic view showing the arrangement
of the exposure apparatus 200. The exposure apparatus 200 includes
an EUV light source 201, an illumination optical system 202, a mask
holder (mask holding mechanism) 203 which holds the light
reflecting mask 100, an imaging optical system 204, and a wafer
stage (wafer holding mechanism) 205 which holds a wafer 206.
[0034] The EUV light source 201 supplies (emits) exposure light
(EUV light). The illumination optical system 202 shapes the
exposure light emitted by the EUV light source 201 and illuminates
the light reflecting mask 100. The illumination optical system 202
also illuminates the device pattern region 100A and the reflectance
measuring pattern region 100B of the light reflecting mask 100 with
the exposure light. The mask holder 203 is formed from, e.g., an
electrostatic chuck to fix the light reflecting mask 100. The
imaging optical system 204 reduces and projects the exposure light
reflected by the light reflecting mask 100 onto the wafer 206.
[0035] The exposure apparatus 200 of this embodiment also includes
a photosensor 301 to detect, of the light reflected (diffracted) by
the reflectance measuring pattern region 100B, higher order
diffraction light that does not illuminate the wafer 206. More
specifically, assume that zero-order diffraction light illuminates
the wafer 206. In this case, the photosensor 301 detects higher
order diffraction light of first order or higher. In other words,
the photosensor 301 detects diffraction light having a diffraction
angle larger than that of zero-order diffraction light. The
photosensor 301 is arranged closer to the wafer 206 as compared to
the light reflecting mask 100, and located at a place outside the
path of the exposure light (zero-order diffraction light 303),
where higher order diffraction light of first order or higher
enters.
[0036] A lithography method using the light reflecting mask 100
will be described next. FIG. 7 is a flowchart illustrating a
lithography method.
[0037] First, the light reflecting mask 100 and the wafer 206
having an applied resist are prepared (step S100). The light
reflecting mask 100 is fixed on the mask holder 203 in the exposure
apparatus 200. The wafer 206 is placed on the wafer stage 205. The
photosensor 301 is arranged at a place outside the path of the
exposure light, where higher order diffraction light reflected by
the reflectance measuring pattern region 100B enters (step
S101).
[0038] The device pattern formed in the device pattern region 100A
is exposed to the wafer 206 using the EUV light source 201,
illumination optical system 202, and imaging optical system 204
(step S102). At this time, the illumination optical system 202
illuminates even the reflectance measuring pattern region 100B with
the EUV light from the EUV light source 201.
[0039] More specifically, exposure light emitted by the EUV light
source 201 passes through the illumination optical system 202 and
reaches the light reflecting mask 100 fixed on the mask holder 203
formed from, e.g., an electrostatic chuck, as shown in FIG. 6. The
exposure light reflected by the light reflecting mask 100 passes
through the imaging optical system 204 together with the pattern
information of the light reflecting mask 100 and illuminates the
wafer 206 fixed on the wafer stage 205. With this process, the
pattern information of the light reflecting mask 100 is transferred
to the resist on the wafer 206.
[0040] The illumination optical system 202 illuminates the
reflectance measuring pattern region 100B with exposure light 302
as much as the device pattern region 100A, as shown in FIG. 8. Out
of light components (zero-order diffraction light 303 and higher
order diffraction light 304) reflected by the device pattern region
100A, the higher order diffraction light 304 enters the photosensor
301 during exposure of the wafer 206. The photosensor 301 detects
the intensity of the received higher order diffraction light 304
(step S103). Measuring the light intensity enables in situ
observation of a change in the reflectance of the light reflecting
mask 100 during exposure.
[0041] After that, the wafer 206 is developed (step 5104) to form,
on it, the resist pattern having device information. The wafer 206
is etched using the resist pattern, thereby forming the device
pattern on the wafer 206.
[0042] As described above in detail, according to this embodiment,
the light reflecting mask 100 includes the device pattern region
100A where a pattern having device information is formed, and the
reflectance measuring pattern region 100B where a reflectance
measuring pattern to measure the degree of degradation in the mask
reflectance is formed. It is possible to measure the degree of
degradation in the reflectance of the light reflecting mask 100 by
detecting the intensity of diffraction light from the reflectance
measuring pattern region 100B.
[0043] The photosensor 301 to detect higher order diffraction light
out of diffraction light components reflected by the light
reflecting mask 100 is arranged outside the path of exposure light
that illuminates the wafer 206. This enables to detect the
intensity of light having a higher order diffraction angle during
exposure. It is therefore possible to measure a change in the
intensity of light that enters the imaging optical system 204
without any influence on wafer exposure.
Second Embodiment
[0044] In the second embodiment, a photosensor 401 to receive
exposure light immediately before .entering a light reflecting mask
100 is added. The photosensor 401 detects the intensity of exposure
light immediately before entering the light reflecting mask
100.
[0045] FIG. 9 is a schematic view showing the arrangement of the
main part of an exposure apparatus 200 according to the second
embodiment of the present invention. The exposure apparatus 200
includes the photosensor 401 which detects the intensity of
exposure light 302 from an illumination optical system 202 (i.e.,
the exposure light 302 immediately before it enters the light
reflecting mask 100).
[0046] The photosensor 401 is arranged to receive the exposure
light immediately before it enters the light reflecting mask 100.
More specifically, the photosensor 401 is fixed on a holding
mechanism 402 which has an aperture to pass the exposure light 302
from the illumination optical system 202. A photosensor 301 is
arranged closer to the wafer as compared to the light reflecting
mask 100, and located outside the path of zero-order diffraction
light 303, as in the first embodiment.
[0047] When wafer exposure is performed in this state, the
photosensor 401 can detect a light intensity equal to that of the
exposure light 302 which enters the light reflecting mask 100. The
photosensor 301 can detect the intensity of higher order
diffraction light 304 reflected by a reflectance measuring pattern
region 100B of the light reflecting mask 100, as in the first
embodiment. It is therefore possible to separately measure a change
in the reflection coefficient of the light reflecting mask 100
using the two kinds of light intensities obtained by the
photosensors 401 and 301.
[0048] As described above in detail, according to this embodiment,
it is possible to detect, during exposure, the intensity of light
which enters the light reflecting mask 100 and the intensity of
light reflected by the reflectance measuring pattern region 100B of
the light reflecting mask 100.
Third Embodiment
[0049] In the third embodiment, a reflectance measuring pattern
region 100B of a light reflecting mask 100 is directly illuminated
with EUV light, and a photosensor 301 detects reflected light.
[0050] FIG. 10 is a schematic view showing the arrangement of the
main part of an exposure apparatus 200 according to the third
embodiment of the present invention. The exposure apparatus 200
includes an EUV light source 501 which supplies EUV light
separately from an EUV light source 201 which supplies exposure
light. The EUV light source 501 is arranged outside the path of
exposure light 302 from an illumination optical system 202. The
photosensor 301 is arranged closer to the wafer as compared to the
light reflecting mask 100, and located outside the path of
zero-order diffraction light 303.
[0051] During exposure, EUV light 502 emitted by the EUV light
source 501 illuminates the reflectance measuring pattern region
100B of the light reflecting mask 100. The photosensor 301 detects
the intensity of zero-order diffraction light 503 reflected by the
reflectance measuring pattern region 100B. Measuring the light
intensity enables in situ observation of a change in the
reflectance of the light reflecting mask 100 during exposure.
[0052] Instead of providing the new EUV light source 501 in the
exposure apparatus 200, EUV light emitted by the EUV light source
201 which supplies exposure light may directly illuminate the
reflectance measuring pattern region 100B of the light reflecting
mask 100. FIG. 11 is a schematic view showing another arrangement
of the exposure apparatus 200.
[0053] The exposure apparatus 200 includes mirrors 505 and 506
necessary for directly illuminating the reflectance measuring
pattern region 100B of the light reflecting mask 100 with the EUV
light emitted by the EUV light source 201. The mirror 505 is fixed
on a holding mechanism 504 which has an aperture to pass the EUV
light from the EUV light source 201.
[0054] The EUV light 502 reflected by the mirror 506 illuminates
the reflectance measuring pattern region 100B of the light
reflecting mask 100 separately from the exposure light. The
photosensor 301 detects the intensity of the zero-order diffraction
light 503 reflected by the reflectance measuring pattern region
100B of the light reflecting mask 100. Measuring the light
intensity enables in situ observation of a change in the
reflectance of the light reflecting mask 100 during exposure.
[0055] Not EUV light but light having a wavelength longer than that
of EUV light may be used as the light to directly illuminate the
reflectance measuring pattern region 100B of the light reflecting
mask 100. As the wavelength longer than that of EUV light, a
wavelength capable of obtaining contrast on a mask and minimizing
exposure of a resist is selected. In this embodiment, an example of
light having a wavelength longer than that of EUV light is krypton
fluoride (KrF) excimer laser light which ensures high contrast
between an absorbing layer 105 and a reflecting layer 102.
[0056] In this case, the exposure apparatus 200 has the same
arrangement as in FIG. 10. The light source 501 emits the KrF
excimer laser light 502 during wafer exposure. The KrF excimer
laser light 502 emitted by the EUV light source 501 illuminates the
reflectance measuring pattern region 100B of the light reflecting
mask 100. The photosensor 301 detects the intensity of the
zero-order diffraction light 503 reflected by the reflectance
measuring pattern region 100B. Measuring the light intensity
enables measurement of the reflection coefficient of the light
reflecting mask 100 with respect to the wavelength of the KrF
excimer laser light 502.
[0057] Additionally, a database representing the relationship
between the reflectance of a mask material and the wavelengths of
the KrF excimer laser light 502 and the exposure light 302 is
acquired. Comparing the obtained reflection coefficient with the
database allows to measure a change in the reflectance with respect
to the exposure light wavelength.
[0058] Additional advantages and modifications will readily occur
to those skilled in the art. Therefore, the invention in its
broader aspects is not limited to the specific details and
representative embodiments shown and described herein. Accordingly,
various modifications may be made without departing from the spirit
or scope of the general inventive concept as defined by the
appended claims and their equivalents.
* * * * *