U.S. patent number RE33,464 [Application Number 07/306,816] was granted by the patent office on 1990-11-27 for method and apparatus for flame generation and utilization of the combustion products for heating, melting and refining.
This patent grant is currently assigned to American Combustion, Inc.. Invention is credited to Grigory M. Gitman.
United States Patent |
RE33,464 |
Gitman |
November 27, 1990 |
**Please see images for:
( Certificate of Correction ) ** |
Method and apparatus for flame generation and utilization of the
combustion products for heating, melting and refining
Abstract
Method and apparatus for high temperature heating, melting,
refining and superheating of materials, such a steel scrap, metals,
ceramics or glass. The invention provides an economizing method of
hydrocarbon fluid fuel combustion in an ongoing flame in a liquid
cooled combustion chamber by separately supplying streams of fuel
and at least two oxidizing gases wherein a first oxidizing gas
reacts with the fuel, and a second oxidizing gas is directed about
the flame core to further react with the fuel, while controlling
the flow of the fuel, the oxidizing gases and cooling liquid to
provide the required heat input, combustion product chemistry,
temperature, velocity, emissivity and combustion block temperature.
Also disclosed are burners for carrying out the invention.
Inventors: |
Gitman; Grigory M. (Duluth,
GA) |
Assignee: |
American Combustion, Inc.
(Norcross, GA)
|
Family
ID: |
24575371 |
Appl.
No.: |
07/306,816 |
Filed: |
February 3, 1989 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
642141 |
Aug 17, 1984 |
|
|
|
Reissue of: |
755831 |
Jul 15, 1985 |
04642047 |
Feb 10, 1987 |
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Current U.S.
Class: |
432/13; 432/37;
239/424; 431/10; 239/425; 239/433; 431/181 |
Current CPC
Class: |
F23G
5/32 (20130101); C03B 5/2353 (20130101); B05B
7/205 (20130101); F23L 7/00 (20130101); B05B
7/0861 (20130101); F23M 5/08 (20130101); F23N
1/022 (20130101); F23G 7/065 (20130101); F23G
5/16 (20130101); F23G 5/50 (20130101); F23G
2207/40 (20130101); F23N 2005/185 (20130101); F23G
2207/102 (20130101); F23N 2237/32 (20200101); F23N
5/08 (20130101); Y02E 20/34 (20130101); F23N
2225/08 (20200101); F23N 2223/08 (20200101); F23G
2900/50007 (20130101); F23G 2207/20 (20130101); F23N
5/003 (20130101); F23N 2237/28 (20200101); F23N
2233/06 (20200101); F23N 2225/06 (20200101); Y02P
40/50 (20151101); F23L 2900/07005 (20130101); F23N
2225/10 (20200101); F23G 2207/101 (20130101); F23N
2223/44 (20200101); F23G 2900/55002 (20130101); F23G
2900/55006 (20130101); F23G 2900/55007 (20130101); F23N
2005/181 (20130101); F23N 2235/16 (20200101); Y02E
20/344 (20130101); F23G 2207/30 (20130101); F23N
2221/12 (20200101); F23N 2225/04 (20200101); Y02P
40/55 (20151101) |
Current International
Class: |
B05B
7/20 (20060101); B05B 7/16 (20060101); F23G
5/16 (20060101); F23N 1/02 (20060101); F23M
5/08 (20060101); F23M 5/00 (20060101); F23L
7/00 (20060101); F23G 5/50 (20060101); F23G
7/06 (20060101); F23G 5/32 (20060101); F23N
5/00 (20060101); F23N 5/18 (20060101); F23N
5/08 (20060101); F27B 014/00 () |
Field of
Search: |
;432/13,37,222
;239/418,423,424,424.5,425,419.3,433 ;431/10,165,181,351,352 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Yuen; Henry C.
Attorney, Agent or Firm: Needle & Rosenberg
Parent Case Text
This application is a continuation-in-part of application Ser. No.
642,141, filed Aug. 17, 1984.Iadd., abandoned.Iaddend..
Claims
What is claimed is:
1. An economizing method of hydrocarbon fluid fuel combustion in an
ongoing hydrocarbon flame formed in a combustion chamber within
liquid cooled combustion block having an outlet nozzle directed
into a hot furnace interior, to reduce the consumption of fuel and
pure oxygen in heating processes, comprising the steps of:
separately supplying hydrocarbon fluid fuel and two different
oxygen based oxidizing gases to the combustion chamber;
directing said first oxidizing gas having a given oxygen
concentration through at least one opening in the combustion
chamber wall toward said combustion chamber outlet nozzle;
directing said hydrocarbon fuel into said combustion chamber in the
stream directed through at least one opening in the combustion
chamber wall above and toward said first oxidizing gas so that said
hydrocarbon fuel is caused to be mixed with said first oxidizing
gas to stabilize combustion within the combustion chamber thereby
creating a highly luminous hot flame core extending throughout said
combustion chamber;
directing said second oxidizing gas having different oxygen
concentrations from said first oxidizing gas through at least one
opening in the combustion chamber wall into said combustion chamber
is a stream directed about and toward said hydrocarbon fuel in the
flame core so that said second oxidizing gas initially insulates
said core from cooling by contact with the liquid cooled block
prior to being mixed with said hydrocarbon fuel for final
combustion;
discharging the products of combustion from the combustion chamber
through a liquid cooled nozzle opening toward the furnace interior;
and
controlling the flow of said hydrocarbon fuel, said two oxidizing
gases and cooling liquid.
2. The method of hydrocarbon fluid fuel combustion of claim 1,
wherein said flow controlling step comprises the steps of:
controlling the ratio of fuel to total oxygen in said two oxidizing
gases to enable efficient use of both said fuel and said oxidizing
gases; and
controlling the concentration of oxygen in said two oxidizing gases
by adding controlled amounts of air for controlling the temperature
of the hydrocarbon flame.
3. The method of hydrocarbon fluid fuel combustion of claim 2,
wherein said flow controlling step further comprises the step of
controlling the ratio of hydrocarbon fuel to the oxygen contained
in said first oxidizing gas for controlling the emissivity of the
hydrocarbon flame.
4. The method of hydrocarbon fluid fuel combustion of claim 3,
wherein said flow controlling step further comprises the step of
maximizing the ratio of air in said second oxidizing gas to the air
in said first oxidizing gas for minimizing NOx emissions by
reducing the amount of air inside the core of the hydrocarbon
flame.
5. The method of claims 2, 3 or 4 which further comprises the step
of monitoring the current process temperature for determining the
appropriate ratios for said controlling steps as the process
continues.
6. The method of claims 2, 3, or 4 which further comprises the
steps of measuring the accumulated energy input to the process for
determining the stage of the process and the ratios to be applied
in said controlling steps as the process continues.
7. The method of claims 2, 3 or 4 which further comprises the step
of timing the process for determining the stage of the process and
the ratios to be applied in said controlling steps.
8. The method of claim 5, wherein said controlling steps are
accomplished by electronic computer means.
9. The method of claim 6, wherein said controlling steps are
accomplished by electronic computer means.
10. The method of claim 7, wherein said controlling steps are
accomplished by electronic computer means.
11. The method of hydrocarbon fluid fuel combustion of claims 1, 2
or 3 wherein said first oxidizing gas is pure oxygen.
12. The method of hydrocarbon fluid fuel combustion of claims 1, 2
or 3, wherein said second oxidizing gas is air.
13. The method of hydrocarbon fluid fuel combustion of claims 1, 2
or 3, wherein said hydrocarbon fuel is introduced into said
combustion chamber through a multiplicity of openings in the
combustion chamber.
14. The method of claims 1 or 2, wherein said second oxidizing gas
is introduced into the combustion chamber in a plurality of jets
directed toward said flame core.
15. The method of claims 1 or 2, wherein said second oxidizing gas
is introduced into the combustion chamber in at least one
tangentially directed jet.
16. The method of claims 1 or 2, wherein said second oxidizing gas
is directed to the hot flame core in increments along the length of
the combustion chamber.
17. The method of hydrocarbon fluid fuel combustion of claims 2, 3
or 4 which further comprises the step of controlling the delivery
of said first oxidizing gas into the combustion chamber such that
the velocity of the jet entering the combustion chamber may range
from subsonic to supersonic.
18. The method of hydrocarbon fluid fuel combustion of claim 5,
which further comprises the step of controlling the delivery of
said first oxidizing gas into the combustion chamber such that the
velocity of the jet entering the combustion chamber may range from
subsonic to supersonic.
19. The method of hydrocarbon fluid fuel combustion of claim 6,
which further comprises the step of controlling the delivery of
said first oxidizing gas into the combustion chamber such that the
velocity of the jet entering the combustion chamber may range from
subsonic to supersonic.
20. The method of hydrocarbon fluid fuel combustion of claim 7,
which further comprises the step of controlling the delivery of
said first oxidizing gas into the combustion chamber such that the
velocity of the jet entering the combustion chamber may range from
subsonic to supersonic.
21. The method of claims 1, 2 or 3, which further comprises the
step of directing a third oxidizing gas from said combustion
chamber outlet nozzle downwardly with respect to the center line of
the combustion chamber, so that the third oxidizing gas may oxidize
a different area of product being heated.
22. The method of claim 21 wherein said third oxidizing gas is
oxygen introduced in a jet which has supersonic velocity.
23. A method of heating and melting materials in a furnace,
comprising the steps of:
directing a flame produced within a liquid cooled combustion tunnel
to the material to be heated, said flame formed by mixing and
combusting a hydrocarbon fuel stream with air and oxygen, at a
ratio of fuel to total oxygen about atoichiometric, said air and
oxygen being combined, in two oxidizing gas streams of different
oxygen concentrations, one of said gas streams being introduced
inside said fuel stream and the other gas stream being introduced
about said fuel stream;
raising the ratio of total oxygen to total air in the mixture, to
increase the adiabatic flame temperature, as the temperature of the
material increases, while maintaining the fuel to total oxygen
ratio about stoichiometric, to achieve a temperature of the
material at which an exothermic reaction of oxidation of some
component of the material can be initiated; and
then introducing excess oxygen to increase the ratio of total
oxygen to fuel substantially above stoichiometric to provide
additional heat from oxidation of some components of the materials
in the furnace being continuously heated by the products of
combustion.
24. The method of claim 23, when the opening of said combustion
tunnel is partially or completely blocked by materials to be heated
and melted, comprising the initial step of directing a hot flame at
the material blocking the opening, said flame formed by mixing and
combusting a hydrocarbon fuel stream with oxygen at a ratio about
stoichiometric to create a hot cavity in the material at the
opening of said combustion tunnel prior to carrying out the other
steps of the method, for improving the stability of the low
temperature flame in the following steps of the method.
25. The method of claim 23, also used to refine the material, which
further comprises the steps of:
after the material is generally melted, reducing the fuel and air
supplied to the combustion mixture, to rearrange the flame
pattern;
directing a jet of oxygen at supersonic velocity through the flame
to the material; and
penetrating said supersonic jet of oxygen within the molten
material at the zone at which the material is being heated by said
rearranged flame, to continue the exothermic oxidation reaction of
refining.
26. The method of claim 25 wherein said jet of oxygen is directed
downward with respect to the direction of the flame.
27. The method of claims 23, 24, 25 or 26, wherein each step
further comprises determining the most economical point at which to
proceed to the next step.
28. The method of claims 23, 25 or 26, wherein the step of
introducing excess oxygen includes the combustion of fuel without
the participation of air in the combustion process.
29. The method of claims 23, 25 or 26 further comprising the step
of preheating combustion air prior to its introduction into the
combustion process.
30. A method of controlling the heating of materials in furnaces by
introduction into the interior of the furnace of hot combustion
products of carbon containing fluid fuel through a burning device
having two separate oxidizing gas streams, each having individually
variable oxygen content in the range of between 20-100% oxygen and
also being directed separately through the combustion chamber of
the burning device toward the material being heated, comprising the
steps of:
continuously measuring representative technological parameters to
recognize the current stage of the heating process and using said
parameters as the base data for a programmed controlling
device;
continuously sensing the instant flow of air, fuel and oxygen and
supplying representative electrical signals for said flows to said
programmed controlling device;
continuously defining by said programmed controlling device, based
on the recognized current stage of heating process, the optimum
instant fuel flow and the air flow and oxygen flow to each separate
oxidizing gas stream to economize the heating cycle by maximizing
heat exchange between the flame and the material being heated;
continuously controlling, through flow regulating means, the fuel
supply and the air and oxygen supply to each of the separate
oxidizing gas streams to set the instant flow supplied to match the
optimum instant flows as defined by said programmed controlling
device to maintain the heat input, flame temperature, velocity and
emissivity of the combustion products.
31. The method of claim 30, wherein said representative
technological parameters include the temperature of the
process.
32. The method of claim 30, wherein said representative
technological parameters include the accumulated time of
heating.
33. The method of claim 30, wherein said representative
technological parameters include the accumulated energy
consumption.
34. The method of claim 30, further comprising the step of
continuously controlling the proportions of total flow of oxygen
and air supplied to the burning device in the first oxidizing gas
stream and separately controlling the oxygen and air in the second
oxidizing gas stream.
35. The method of claim 30, further comprising the step of
continuously controlling the flow of oxygen to balance the total
amount of oxygen being introduced throughout the combustion
chamber, to penetrate into the material being heated.
36. The method of claim 30, further comprising the step of
continuously controlling the flow of fuel to balance the total
amount of oxygen being introduced throughout the combustion
chamber, to correct any inability of the desired amount of air flow
to penetrate into the material being heated.
37. The method of claims 30, 31, 32, 33, 34, 35 or 36, further
comprising the step of continuously controlling the amount of
excess oxygen being introduced to the process to support an
exothermic oxidation reaction of certain components of the material
being heated or refined.
38. The method of claim 37, wherein said excess oxygen is
introduced to the process in a supersonic stream.
39. A hydrocarbon fluid fuel burner to reduce the comsumption of
fuel and pure oxygen in a heating process, which comprises:
a combustion block having a combustion chamber therein;
means for cooling said combustion chamber with a liquid;
liquid cooled outlet means of said communication block for
arranging a final flame pattern by discharging the products of
combustion from the combustion chamber;
means for separately supplying hydrocarbon fluid fuel and two
oxygen based oxidizing gases to said combustion block;
means for directing said first oxidizing gas having a given oxygen
concentration through at least one opening in the combustion
chamber wall toward said combustion chamber outlet nozzle;
means for directing said hydrocarbon fuel into said combustion
chamber in a stream directed through at least one opening in the
combustion chamber wall about said first oxidizing gas so that said
hydrocsrbon fuel is caused to be mixed with said first oxidizing
gas to stabilize combustion within said liquid cooled combustion
chamber by creating a highly luminous hot flame core extending
throughout said combustion chamber;
means for directing said second oxidizing gas having different
oxygen concentration from said first oxidizing gas through at least
one opening in the combustion chamber wall into said combustion
chamber in a stream direction about and toward said hydrocarbon
fuel in the flame core so that said second oxidizing gas initially
insulates said core from cooling by contact with the fluid cooled
block prior to being mixed with said hydrocarbon fuel; and
means for controlling the final flame pattern oxidizing ability,
temperature, luminousity and velocity by controlling distribution
and proportions of the amount of total oxygen being introduced by
oxygen and air containing first and second oxidizing gases.
40. The burner of claim 39, wherein said hydrocarbon fuel directing
means comprises a plurality of jets angled toward said first
oxidizing gas.
41. The burner of claim 39, wherein said second oxidizing gas
directing means comprises a plurality of jets angled toward said
flame core.
42. The burner of claim 39, wherein said second oxidizing gas
directing means comprises at least one tangentially directed
jet.
43. The burner of claim 39, wherein said second oxidizing gas
directing means directs said gas to the hot flame core in
increments along the length of the combustion chamber.
44. The burner of claim 39, wherein said combustion block is made
of a high thermal conductivity material.
45. The burner of claim 44, wherein said high thermal conductivity
material is copper.
46. The burner of claim 39, wherein the combustion chamber of said
combustion block is generally conical with the wider end at the
face of said burner, and wherein said second oxidizing gas channels
open onto the conical face of the combustion chamber to create film
cooling.
47. The burner of claim 39, wherein said means for directing said
first oxidizing gas includes means for introducing said first
oxidizing gas in a supersonic jet.
48. The burner of claim 39, which further comprises a means for
directing a third oxidizing gas from said combustion chamber outlet
nozzle downwardly with respect to the center line of the combustion
chamber, so that the third oxidizing gas may oxidize a different
area of product being heated.
49. The burner of claim 48, wherein said third oxidizing gas is
oxygen introduced in a jet which has supersonic velocity.
.Iadd.
50. An economizing method of fluid fuel combustion in an ongoing
flame formed in a combustion chamber within a liquid cooled
combustion block having an outlet nozzle directed into a hot
furnace interior, to reduce the consumption of fuel and pure oxygen
in heating processes, comprising the steps of:
separately supply fluid fuel and at least first and second oxygen
based oxidizing gases to the combustion chamber;
directing said fuel through at least one opening in the combustion
chamber wall into the combustion chamber;
directing said first oxidizing gas into said combustion chamber in
a stream directed through at least one opening in the combustion
chamber wall toward said fuel so that said first oxidizing gas is
caused to be mixed with said fuel to stabilize combustion within
the combustion chamber thereby creating a highly luminous hot flame
core extending throughout said combustion chamber;
directing said second oxidizing gas having different oxygen
concentration from said first oxiding gas through at least one
opening in the combustion chamber wall into said combustion chamber
in a stream directed about and toward said flame core so that said
second oxidizing gas initially insulates said core from cooling by
contact with the liquid cooled block prior to being mixed with
flame core for final combustion;
discharging the products of combustion from the combustion chamber
through a liquid cooled nozzle opening toward the furnace interior;
and
controlling the flow of said fuel and said first and second
oxidizing gases. .Iaddend. .Iadd.
51. The method of fluid fuel combustion of claim 50, wherein said
first oxidizing gas has a higher oxygen concentration than said
second oxidizing gas. .Iaddend. .Iadd.52. The method of fluid fuel
combustion of claim 50, wherein the amount of oxygen supplied by
said first oxidizing gas is less than fifty percent of the
stoichiometric amount of oxygen required to completely combust the
fuel. .Iaddend. .Iadd.53. The method of fluid fuel combustion of
claim 50, wherein said first oxidizing gas and said second
oxidizing gas are partially mixed together prior to said two
oxidizing gas streams reacting with said fluid fuel. .Iaddend.
.Iadd.54. The method of fluid fuel combustion of claim 50, wherein
said first oxidizing gas is directed into said combustion chamber
as a plurality of streams which surround each of said openings for
directing said fuel into said combustion chamber. .Iaddend.
.Iadd.55. The method of fluid fuel combustion of claim 50, wherein
said flow controlling step comprises the steps of:
controlling the ratio of fuel to the total oxygen in said two
oxidizing gases to control flame stoichiometry; and
controlling the ratio of said first oxidizing gas to said second
oxidizing gas being supplied to the combustion chamber to control
the adiabatic
temperature of the flame. .Iaddend. .Iadd.56. The method of fluid
fuel combustion of claim 55, which further comprises the step of
increasing the oxygen in said second oxidizing gas to further
increase the adiabatic flame temperature. .Iaddend. .Iadd.57. The
method of claims 55 or 56 which further comprises the step of
monitoring the current process temperature for determining the
appropriate ratios for said controlling steps as the process
continues. .Iaddend. .Iadd.58. The method of claims 55 or 56 which
further comprises the steps of measuring the accumulated energy
input to the process for determining the stage of the process and
the ratios to be applied in said controlling steps as the process
continues. .Iaddend. .Iadd.59. The method of claims 55 or 56 which
further comprises the step of timing the process for determining
the stage of the process and the ratios to be applied in said
controlling steps. .Iaddend. .Iadd.60. The method of claim 57,
wherein said controlling steps are accomplished by
electronic computer means. .Iaddend. .Iadd.61. The method of claim
58, wherein said controlling steps are accomplished by electronic
computer means. .Iaddend. .Iadd.62. The method of claim 59, wherein
said controlling steps are accomplished by electronic computer
means. .Iaddend. .Iadd.63. The method of claims 50 or 55, wherein
said first oxidizing gas is pure oxygen. .Iaddend. .Iadd.64. The
method of claims 50 or 55, wherein said second oxidizing gas is
air. .Iaddend. .Iadd.65. The method of claim 50, wherein said fuel
is directed into said combustion chamber through a multiplicity of
openings in the combustion chamber. .Iaddend. .Iadd.66. The method
of claim 50, wherein said first oxidizing gas is directed into said
combustion chamber through a multiplicity of openings in the
combustion chamber. .Iaddend. .Iadd.67. The method of claim 50,
wherein said second oxidizing gas is directed into said combustion
chamber through
a multiplicity of openings in the combustion chamber. .Iaddend.
.Iadd.68. The method of claim 50, wherein said second oxidizing gas
is introduced into the combustion chamber in at least one
tangentially directed jet. .Iaddend. .Iadd.69. The method of claim
50, wherein said second oxidizing gas is directed to the hot flame
core in increments along the length of the combustion chamber.
.Iaddend. .Iadd.70. The method of claim 50, which further comprises
the step of directing a third oxidizing gas from said combustion
chamber outlet nozzle downwardly with respect to the center line of
the combustion chamber, so that the third oxidizing gas may oxidize
a different area of product being heated. .Iaddend. .Iadd.71. The
method of claim 70, wherein said third oxidizing gas is oxygen
introduced in a jet which has supersonic velocity. .Iaddend.
.Iadd.72. A method of heating and melting materials in a furnace,
comprising the steps of:
directing a flame produced within liquid cooled combustion tunnel
of a burner to the material to be heated, said flame formed by
mixing and combusting a fuel stream with air and oxygen, at a ratio
of fuel to total oxygen about stoichiometric, said air and oxygen
being supplied in two oxidizing gas streams of different oxygen
concentrations;
raising the ratio of total oxygen to total air in the flame, to
increase the adiabatic flame temperature, as the temperature of the
material increases to achieve a temperature of the material at
which an exothermic reaction of oxidation of some component of the
material can be initiated; and
then directing through the combustion tunnel excess oxygen to
increase the ratio of total oxygen to fuel substantially above
stoichiometric to release exothermic heat from oxidation of some
components of the materials in the furnace being continuously
heated by said flame. .Iaddend.
.Iadd. The method of claim 72, also used to refine the material,
which further comprises the steps of:
after the material is generally melted, reducing the fuel and air
supplied to the combustion mixture, to rearrange the flame
pattern;
directing a jet of oxygen through the flame to the material;
and
contacting said jet of oxygen with the molten material at the zone
at which the material is being heated by said rearranged flame, to
conduct the exothermic oxidation reaction of refining. .Iaddend.
.Iadd.74. A method of controlling the heating of materials in
furnaces by introduction into the interior of the furnace, through
a burning device, of hot combustion products of carbon containing
fluid fuel and at least two different oxidizing gas streams
directed separately into the combustion chamber of the burning
device, said oxidizing gas streams having different oxygen content
in the range of between 20-100% oxygen, comprising the steps
of:
continuously measuring representative technological parameters to
recognize the current stage of the heating process and using said
parameters as the base data for a programmed controlling
device;
continuously defining by said programmed controlling device, based
on the recognized current stage of heating process, the optimum
instant flows of said fuel and said oxidizing gas streams to
economize the heating cycle by maximizing heat exchange between the
flame and the material being heated; and
continuously controlling, through flow regulation means, the flow
of said fuel and said oxidizing gas streams to set the instant flow
supplied to match the optimum instant flows as defined by said
programmed controlling device, to maintain the heat input, flame
temperature, velocity and emissivity of the combustion products.
.Iaddend. .Iadd.75. The method of claim 74, which further comprises
supplying air and concentrated oxygen to form at least one variable
oxidizing gas stream and wherein said controlling step comprises
controlling the air and concentrated oxygen
supplied to said variable stream. .Iaddend. .Iadd.76. The method of
claim 75, which further comprises the step of continuously sensing
the instant flows of air, fuel and oxygen and supplying
representative electrical signals for said flows to said programmed
controlling device. .Iaddend. .Iadd.77. The method of claim 74,
wherein one said at least two oxidizing gas streams is pure oxygen.
.Iaddend. .Iadd.78. The method of claim 77, wherein another
oxidizing gas stream is air. .Iaddend. .Iadd.79. The method of
claim 74, wherein said representative technological parameters
include the temperature of the process. .Iaddend. .Iadd.80. The
method of claim 74, wherein said representative technological
parameters include the accumulated time of heating. .Iaddend.
.Iadd.81. The method of claim 74, wherein said representative
technological parameters include the accumulated energy
consumption. .Iaddend. .Iadd.82. A fluid fuel burner to reduce the
consumption of fuel and pure oxygen in a heating process, which
comprises:
a combustion block having a combustion chamber therein;
means for cooling said combustion chamber with a liquid;
liquid cooled outlet means of said combustion block for arranging a
final flame pattern by discharging the products of combustion from
the combustion chamber;
means for separately supplying fluid fuel and two oxygen based
oxidizing gases, at least one of which comprises air, to said
combustion block;
means for directing said fuel through at least one opening in the
combustion chamber wall into said combustion chamber;
means for directing said first oxidizing gas having a given oxygen
concentration through at least one opening in the combustion
chamber wall into said combustion chamber in a stream directed so
that said first oxidizing gas is caused to be mixed with said fuel
to stabilize combustion with said liquid cooled combustion chamber
by creating a highly luminous hot flame core extending throughout
said combustion chamber;
means for directing said second oxidizing gas having different
oxygen concentration from said first oxidizing gas through at least
one opening in the combustion chamber wall into said combustion
chamber in a stream directed about and toward the flame core so
that said second oxidizing gas initially insulates said core from
cooling by contact with the fluid cooled block prior to being mixed
with the flame core; and
means for controlling the final flame pattern, oxidizing ability,
temperature, luminosity and velocity by controlling the total
amount of oxygen introduced in said oxidizing gases, and by
controlling the distribution of oxygen and air being introduced
with said first and second
oxidizing gases. .Iaddend. .Iadd.83. The burner of claim 82,
wherein said fuel directing means comprises a plurality of jets
directed to mix with said first oxidizing gas directing means.
.Iaddend. .Iadd.84. The burner of claim 82, wherein said first
oxidizing gas directing means comprises a plurality of jets
directed to mix with said fuel. .Iaddend. .Iadd.85. The burner of
claim 84, wherein said second oxidizing gas directing means
comprises a plurality of jets directed toward said flame core.
.Iaddend. .Iadd.86. The burner of claim 82, wherein said second
oxidizing gas directing means comprises at least one tangentially
directed jet. .Iaddend. .Iadd.87. The burner of claim 82, wherein
said second oxidizing gas directing means directs said gas to the
hot flame core in increments along the length of the combustion
chamber. .Iaddend. .Iadd.88. The burner of claim 82, wherein said
combustion block is made of a high thermal
conductivity material. .Iaddend. .Iadd.89. The burner of claim 88,
wherein said high thermal conductivity material is copper.
.Iaddend. .Iadd.90. The burner of claim 82, wherein the combustion
chamber of said combustion block is generally conical with the
wider end at the face of said burner, and wherein said second
oxidizing gas channels open onto the conical face of the combustion
chamber to create film cooling. .Iaddend. .Iadd.91. The burner of
claim 82, which further comprises a means for directing a third
oxidizing gas from said combustion chamber outlet nozzle downwardly
with respect to the center line of the combustion chamber, so that
the third oxidizing gas may oxidize a different area of product
being heated. .Iaddend. .Iadd.92. The burner of claim 91, wherein
said third oxidizing gas is oxygen introduced in a jet which has
supersonic velocity. .Iaddend. .Iadd.93. The burner of claim 82,
wherein said means for directing said first oxidizing gas and said
means for directing said second oxidizing gas causes said two
oxidizing gases to be partially mixed together prior to said first
and second oxidizing gases being mixed with
said fuel. .Iaddend. .Iadd.94. The burner of claim 82, wherein the
combustion chamber in said combustion block has a
converging-diverging shape to allow supersonic velocity at said
outlet means. .Iaddend.
Description
BACKGROUND OF THE INVENTION
This invention relates to a method and apparatus for high
temperature heating, melting, refining and superheating of
materials, such as steel scrap, metals, ceramics or glass. The
method and apparatus disclosed may be used as the major source of
energy and also as an assisting energy source in melting furnaces,
industrial heating and heat treating furnaces, kilns, incinerator
and other high temperature applications.
Today, scrap preheating and melting is accomplished by different
technologies, such as heat from the combustion of coke, oil or gas
with air or oxygen, or from electric arc. Each of these
technologies has some advantages and disadvantages. Using air from
combustion has the advantage of being a low cost oxidizer, but,
because air only contains 21% oxygen, it has the following
disadvantages: low flame temperature, combustion instability inside
cold scrap, low efficiency of heat utilization when scrap is hot
due to escaping flue gases which waste about 50% of heat released
by combustion.
The advantages of using essentially pure oxygen for combustion
include: high flame temperature, good combustion stability, and a
significant reduction of wasting heat with hot flue gases. The
disadvantages of oxygen include its high cost and the necessity to
cool the oxygen-fuel burner body.
The utilization of electrical energy is very expensive, but it
provides a convenient means of operation and high product
quality.
Four methods of oxygen introduction in the combustion process are
used today:
injecting an oxygen stream into the fuel/air flame after the flame
has left the fuel/air burner;
injecting an oxy-fuel burner flame into a fuel/air burner flame
after both flames have left their burners;
enriching combustion air with oxygen by injecting oxygen in
combustion air prior to supplying combustion air to the oxygen
enriched air burner; and
mixing of fuel, oxygen and air streams external to the burning
device by lancing the three streams inside a hot furnace where said
mixtures are burned.
The first two techniques of oxygen injection are recommended for
increasing liquid and solid flame temperatures at glass melting
furnaces or other high temperature furnaces where such fuel/air
flames have sufficient dimensions and are located above the work
being heated and are available for oxygen injection outside of the
burner body. A high velocity oxy-fuel flame or an oxygen jet
penetration into the core of a relatively cold oil or coal flame
will superheat said core, therefore increasing the radiative heat
flux of the micro-particles of carbon existing in such flame core
without overheating the burner body. Oxygen enrichment of
combustion air may be used for any fuel including hydrocarbon
gases, particularly, natural gas. The oxygen enriched air burner
has not found broad application for several reasons.
Burners for combusting fuel with air are old in the art, and
burners for combusting fuel with pure oxygen (oxy-fuel) or oxygen
enriched air are well known. However, the current state of the art
burners do not operate satisfactorily across the full range of
temperatures useful in high temperature heating, and do not allow
for economical operation through control of flame chemistry,
temperature, velocity and luminosity. Burners designed for use with
hot air or oxygen enriched air typically use refractory tiles in
the burners for continuous igniting of gases to stabilize the
flame. However, due to the very high temperature of an oxy-fuel
flame, refractory tiles cannot be used, and such burners are
internally water or air cooled. The elimination of the burner tiles
results in flame instability at lower temperatures and therefore
limits the turn-down ratio of oxygen enriched air burners.
Another problem that often arises in oxy-fuel and oxygen enriched
burners is the presence of excess oxygen in the flue gases. The hot
furnace temperatures, together with the excess oxidizing ability of
the flue gases, accelerate deterioration of expensive furnace
components.
Also, in cases where natural gas is utilized as a fuel, an
oxygen-fuel flame or an oxygen enriched air-fuel flame is not
emissive. To be able to transfer heat, the flame would therefore
have to touch the product being heated. This can create a problem
with product distortion and oxidation.
The above mentioned technical, environmental and economical
difficulties of oxygen enriched air burners are caused by the fact
that using oxygen enriched air makes the combustion of fuel faster
and less controllable inside of traditionally designed burning
devices. These typically have a refractory lined combustion tunnel
and use relatively lazy mixing techniques based on the low pressure
of oxygen enriched air, the flow of which can be regulated by a
traditional gas/air ratio regulator.
SUMMARY OF THE INVENTION
In general, the total cost (operating and capital) of transferring
of each BTU into a product being heated varies for each particular
application as a function of temperature. As the temperature of the
product increases, it becomes more expensive to transfer additional
BTU's from the source of energy into the product being heated. In
general, the same amount of hydrocarbon fuel being combusted by
various combustion devices at the same furnace temperature
conditions may result in a different total heat flux being directed
from the flame toward the work being heated. This is caused by
different flame chemistry, temperature, luminosity and velocity
resulting in different convective and radiative heat flux and by
the influence of additional heat input from chemical reaction which
may take place between work material and combustion gases.
The least expensive way to accomplish heat transfer to the product
at the low temperature stage of the heating cycle is to increse the
flame velocity to increase the conventive heat flux from the source
of energy to the product being heated. When the product temperature
exceeds approximately 1500.degree.-1700.degree. F. the most
efficient way of heat transfer is to increase the flame temperature
and flame luminosity to increase the radiative heat flux from the
source of energy to the product. Raising the temperature of the
flame increases the convection heat flux by the first power, but
increases the radiative heat flux by the fourth power. Hence,
oxygen utilization is more efficient during the high temperature
period. This changing of the flame, to go from convective heating
to radiative heating, is accomplished in this invention by
continuously optimizing the fuel-air-oxygen flame chemistry to
control temperature, velocity, luminosity and heat input.
Optimization by the invented combustion process is due to a more
controllable oxidation of the fuel stream by mixing said fuel
stream with two different oxygen and/or air based oxidizing gases,
having continuous control of the process oxidizing capability, and
by having said two oxidizing streams separately contact and mix
with the fuel stream being burned inside of the intensively liquid
cooled combustion chamber of the combustion device.
Controllable variation of proportions of air and oxygen contained
in said two different oxidizing gases during the firing cycle
provides a new method of controlling the flame characteristics
independent of the firing rate. This makes it possible to maximize
the efficiency of heat transfer from the flame toward the work
being heated by, for instance, increasing the flame velocity and,
therefore, convective heat transfer during a low temperature period
of the heating cycle, and by increasing the flame luminosity during
a high temperature period of the heating cycle.
Furthermore, in the case of melting, if some components of the
product being heated can be oxidized through exothermic reactions
without reducing the product quality, excess oxidizing mixture or
pure oxygen (metallurgical oxygen) can be directed toward the hot
zone of the product being heated to generate intensive exothermic
reactions on the surface and inside the product. To improve the
ability of the metallurgical oxygen to penetrate inside the
product, it may be introduced with supersonic velocity, or under
high pressure, along the central line of the flame pattern so as to
deliver a concentrated oxygen stream to the hottest zone of the
work surface being heated by the flame pattern.
In addition, it may be desirable to provide a separate stream of
oxygen directed downward toward the surface of the product being
heated closer to the furnace wall, so that a larger area of the
surface may be oxidized through exothermic reactions.
Utilization of the present invention for metal scrap heating,
melting and refining includes the steps of: initial heating of
scrap pile with a fluid fuel-air flame with some oxygen being
introduced inside the flame core for mixing with the fluid fuel to
form a stable combustion zone, which is used as a continuous
ignitor during the combustion step, with the total oxygen/fuel
ratio near stoichiometric; increasing the oxygen/air ratio to raise
the flame temperature with the total oxygen/fuel ratio still close
to stoichiometric; introducing through the fluid fuel-air-oxygen
flame a jet of excess oxygen directed to the hot scrap pile when it
is preheated above 1600.degree. F., to start exothermic oxidation
reactions to accelerate scrap melting; heating the molten metal
during refining with a fluid fuel-air flame (or a fluid
fuel-air-oxygen flame); refining the molten metal by oxidation of
the molten metal with a jet of excess metallurgical oxygen directed
through the fluid-air flame (or the fluid fuel-air-oxygen flame)
toward the molten metal with high velocity, which may be maintained
above sonic.
A number of the improvements resulting from the new combustion
method and flame generating apparatus are described.
First, intensive mixing of the oxygen stream with a hydrocarbon
fuel inside of a volume insulated by the air stream from contact
with the cold, water-cooled wall of the combustion chamber protects
such volume from cooling and at the same time provides residual
time for oxygen and gas to react to create a very high temperature
stabilizing zone prior to involving the major part of the air into
the combustion process. Also, the heat released by combusting part
of the hydrocarbon gas with the very high oxygen concentration of
the first oxidizing gas provides the heat release required for
partial pyrolysis of the remaining gas which forms a highly
luminous flame core.
Second, the very high rate of reaction of the gas with the oxygen
provides a very intensive heat release inside the combustion
chamber which results in a high level of combustion gases expansion
prior to leaving the combustion chamber, therefore providing a very
high flame velocity.
Third, in many melting operations, the high temperature flame
impinges upon scrap located at the nozzle of the combustion device
and can therefore experience high aerodynamic resistence due to
blockage. Because fuel, oxygen and air flow are introduced into the
flame generator combustion chamber with different pressures, each
of these flows may be differently affected by the scrap aerodynamic
resistance or blockage. The high pressures of the oxygen and gas
lines make their flows only slightly sensitive to such aerodynamic
variations throughout the heating and melting cycles, but the
relatively large amounts of combustion air with relatively low
pressure would be measurably affected. In such a situation, despite
the complete opening of the flow regulating valves, the air flow
would not be able to deliver the required amount of oxygen to the
combustion tunnel to maintain the desired firing rate. The control
system of the flame generator is capable of recognizing this
problem through continuous air flow sensors and reacting properly
by increasing oxygen flow to make up for the air deficiency and to
create a hotter flame in order to melt through material blocking
the burner outlet. Similar problems can occur during the period of
excess oxygen blowing if oxygen flow is affected by scrap
aerodynamic resistence.
It is an object of this invention to minimize energy consumption
and cost of heating, melting and refining operations by increasing
the efficiency of heat generation and utilization by continuously
optimizing the fuel-air-oxygen flame chemistry, temperature,
velocity, luminosity, and heat input.
It is also an object of this invention to introduce throuqh a
burner flame subsonic on supersonic oxyqen jets for oxidation and
refining of hot materials.
It is a further object of this invention to provide a burner with
assured flame stability over a broad opeating range.
It is a still further object of this invention to provide a heating
method and apparatus which reduces flue gas volume and
pollutants.
It is yet another object of this invention to automatically control
and optimize the heating, melting and refining of materials.
These and other objects and advantages will appear from the
following description with reference to the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a side cross-sectional view through the center of a flame
generator illustrating a first embodiment of the invention.
FIG. 2 is a rear cross-sectional view of the flame generator of
FIG. 1, taken along line II--II of FIG. 1.
FIG. 3 is a side cross-sectional view through the center of a flame
generator illustrating a second embodiment of the invention.
FIG. 4 is a rear cross-sectional view of the flame generator of
FIG. 3, taken along line IV--IV of FIG. 3.
FIG. 5 is a schematic diagram of the control system for a first
embodiment of the invention.
FIG. 6 is a schematic diagram of the control system for a second
embodiment of the invention.
DESCRIPTION OF PREFERRED EMBODIMENTS
The preferred embodiments are now described with reference to the
drawings, in which like numbers indicate like parts throughout the
views.
FIGS. 1 and 2 show a first embodiment of the flame generator 1,
which comprises a generator combustion block 2. A water cooling
jacket 3 surrounds the generator combustion block 2, and has a
water inlet 4 and outlet 5 located next to each other, and a
dividing plate 6 between the inlet 4 and the outlet 5 to cause the
cooling water to circulate around the combustion block 2. An oxygen
conduit 7 connects to the oxygen channel 8 through the combustion
block 2 for introducing oxygen into the combustion chamber 9 of the
combustion block. A fluid fuel conduit 10 provides a fluid fuel to
a plurality of fuel channels 11 through the combustion block 2,
said channels spaced symmetrically around the oxygen channel 8
angled to direct the fuel to a point on the center line of the
combustion block within the combustion zone 9. The oxygen channel
may have a converging-diverging nozzle 17 for directing a
supersonic jet of oxygen to a product being heated. Additionally,
an air supply conduit 13 provides air to a plurality of air
channels 14 through the combustion block 2. Preferably, the air
channels 14 are symmetrically spaced and tangentially directed into
the combustion chamber with openings on the face of the combustion
zone 9. In addition to supplying oxidizing gas to participate in
the combustion reaction, gas introduced through openings 14 will
serve to protect the wall of the combustion chamber from the high
temperature combustion product and also to protect the flame from
cooling by contact with the liquid cooled body, by creating a thin
gas film between the wall and the combustion product. Furthermore,
the combustion block 2 may be further cooled by the passing of cool
air through the air channels 14 and cool fuel through the fuel
channels 11 as they are introduced into the combustion chamber 9. A
slot 15 is provided to the cooling jacket 3 for evacuation of air
and steam bubbles. Flange 16 provides a means for affixing the
flame generator to a furnace.
Oxygen channel 8 can have a multiplicity of holes at the nozzle.
This option increases the flexibility of the flame generator to
vary the properties of the flame and the excess oxygen jet directed
through the central portion of the combustion chamber.
In certain cases it can be beneficial to introduce fuel as the
central stream through conduit 7 and oxygen or air-oxygen mixture
through conduit 11 to maximize the flame length or emissivity.
FIGS. 3 and 4 show a second embodiment of a flame generator 20.
Similar to the previous embodiment, this embodiment includes a
combustion block 21, a water cooling jacket 22 with water passages
26. Additionally, the fuel conduit 27, fuel channels 28, oxygen
conduit 31 and oxygen channel 32 are similar to the previous
embodiment. Air introduction is accomplished through a channel 29
which goes through the combustion block 21 and directs the air
tangential to the inner surface of the combustion channel 9. Also,
a second oxygen conduit 23 supplies oxygen through channel 24
through the top of the combustion block along its length until the
passage turns downward and opens near the opening of the combustion
block such that oxygen may be directed in a stream out of the
combustion chamber angled downward with respect to the centerline
of the flame generator 20. This opening may comprise a
converging-diverging nozzle 25 for producing a supersonic jet of
oxygen.
FIG. 5 shows the control system for the first embodiment of the
flame generator. When the flame generator 1 is in operation,
cooling water is supplied from a water supply line to water inlet 4
then around the combustion block 2 inside the water jacket and
escapes through outlet 5. The required cooling rate is controlled
by thermometer 33 and pressure gauge 34. To provide intensive
cooling of all surface areas of the flame generator block 2 said
block is made of copper or other material with very high thermal
conductivity.
Concurrently, fuel is delivered from fuel supplying line 35 through
valve 36, flowmeter 37 and controlling valve 38 to the flame
generator 1 and then through fuel conduit 10 and the plurality of
fuel channels into the combustion chamber. The oxidizer is
delivered into the combustion chamber by different ways depending
on whether the process is in the stage of heating, melting or
superheating. When the temperature of the material being heated is
relatively low, the ratio of air/oxygen will be relatively high and
an air jet is delivered from blower 39, through flow meter 40,
controlling valve 41, air conduit 13 and the plurality of air
channels, into the combustion chamber. At the same time, an oxygen
jet can be delivered from oxygen line 42 into the combustion
chamber by any or both of the following two ways: first, through
valve 43, flow meter 44, controlling valve 45, oxygen conduit 7 and
oxygen channel 8; and second, through valve 46, flow meter 47,
controlling valve 48, air conduit 13, and the plurality of air
channels 14.
An automatic control device 49 controls the various instant flows
of oxygen, air and fuel based on the current stage of the heating
cycle as determined by certain sensors, such as temperature
sensors, energy totalizers and timers. The control device may also
include metering of instant fuel, air and oxygen flows to provide
electrical inputs to the control device, which is preferably
micro-processor programmed to control optimum flame characteristics
throughout the heating cycle.
FIG. 6 shows the second embodiment of the flame generator control
system which provides additional flexibility to flame generator
operation by making it possible to introduce a controllable amount
of air into the first oxidizing gas through line 60, motorized
valve 56, and solenoid 54 to oxygen conduit 31. This embodiment
also makes it possible to change the flame pattern and flame
luminosity by introducing a fuel stream along the central line of
the combustion chamber through line 61 and solenoid 55 to conduit
31 instead of the first oxidizing gas, which is blocked by solenoid
valve 50, and, at the same time, by introducing the first oxidizing
gas into the combustion chamber about said central fuel stream
through line 59 and solenoid valve 57 to conduit 27 instead of
fuel, which is blocked by solenoid 53.
Prior to the above mentioned exchange between the fuel and first
oxidizing gas flow, air purging needs to be accomplished by flowing
air through line 60, motorized valve 56 and solenoid 54 to oxygen
conduit 31, and also through line 62, solenoid 63 to conduit
27.
In a typical process, utilizing the first embodiment, as the
temperature of the material being heated increases, more oxygen is
introduced into the combustion chamber 9, thereby lowering the
air/oxygen ratio and increasing the temperature of combustion. The
ratio of fuel/total oxygen during this stage is maintained close to
stoichiometric.
When the temperature of the material being heated achieves a point
that makes utilization of heat of the exothermic reactions of
oxidation economically reasonable, a jet of excess oxygen will be
directed through oxygen conduit 7 and oxygen channel 8, through the
center of the flame filling the combustion chamber 9, toward the
hot product for the generation of heat of oxidation reactions for
melting purposes. To increase the ability of the jet of excess
oxygen to penetrate into the material being heated, the oxygen jet
can be blown through a converging-diverging nozzle 17 with
supersonic velocity. This will also reduce dilution of oxygen with
the combustion product and the furnace atmosphere.
A jet of excess oxygen can also be directed through the flame
filling the combustion chamber 9 toward molten material for
refining or other purposes. The velocity of this excess oxygen jet
can be increased above sonic to improve the ability of the jet to
penetrate into the molten material by use of a convergingdiverging
nozzle. At the same time, a fuel-air, fuel-oxygen, or
fuel-air-oxygen flame can be directed at the molten material to
heat the material about and inside the oxidation zone.
During the heating, melting, refining and superheating cycles the
heat input, flame velocity, temperature, luminosity, shape of the
flame envelope and the chemistry of the combustion product are
controlled continuously by variation of the supply of fuel, air,
and oxygen and also by variation of the ways these components are
introduced into the combustion chamber, in order to satisfy the
heating requirements with minimum operating costs. Thus, the amount
of heat input from a burner is directly related to the amount of
hydrocarbon fuel delivered into the burner. As described above, the
invented process or apparatus provides oxygen to the combustion
process either as pure oxygen or as air or a mixture of both. By
controlling the ratio of fuel/total oxygen provided to the
combustion process, the stoichiometric ratio at which complete
combustion of the oxygen and fuel occurs may be maintained as
desired to efficiently utilize the substance introduced into the
burner. Furthermore, at any given fuel/total oxygen ratio, the
temperature of the flame may be increased by causing the oxidizing
gas to have a higher oxygen concentration. This is accomplished by
varying the air and pure oxygen supplied to the burner to control
the air/total oxygen ratio. Although supplying pure oxygen is
clearly more expensive than the use of air, at some point in a
process the higher flame temperature may be desirable to more
efficiently transfer hear to the product.
Another way to improve heat transfer is to increase the emissivity
of the flame. A highly emissive flame comes from the conversion of
atomic carbon from the hydrocarbon fuel into highly emissive
molecular carbon inside the core of the flame. This is accomplished
in the present invention by providing initial mixing of pure oxygen
with the fuel to conduct fuel pyrolysis in the core of the flame,
the flame being isolated from the intensively cooled combustion
chamber wall by a stream of a second oxidizer of lower oxygen
concentration, such as air or an air/oxygen mixture. Therefore, by
controlling the ratio of hydrocarbon fuel/oxygen in the center of
the flame while maintaining all other parameters at the desired
values, the emissivity of the flame may be controlled.
Additionally, it is desirable to provide a burner that will
eliminate or substantially reduce the NOx emissions which result
from combustion with air at high temperatures (e.g., core
temperature over 2700.degree. F.). This may be accomplished by
reducing air inside the flame core. Therefore, NOx may be reduced
by controlling and maximizing the ratio of air introduced to the
outside of the flame/air introduced to the center of the flame, for
any given total air content to be introduced into the combustion
chamber.
The burner described herein may utilize preheated air or a
preheated air-oxygen mixture as an oxidizing gas. This may allow
recovery of waste heat from the proess to provide the preheated air
or a preheated air-oxygen mixture and make the operation more
efficient.
While the preferable embodiments of the invention have been
described, it will be understood that other apparatus can be
designed where more than two different air and oxygen contained
oxidizing gases may be used for further improving of combustion
controllability of flame generator. Also it will be understood that
other apparatus can be designed wherein a partial premixing of fuel
with oxidizer or partial mixing of two oxidizing gases may be
accomplished outside or inside of flame generator body.
While this invention has been described in detail with particular
reference to preferred embodiments thereof, it will be understood
that variations and modifications can be effected within the spirit
and scope of the invention as previously described and as defined
in the claims.
* * * * *