U.S. patent number 7,183,202 [Application Number 10/989,668] was granted by the patent office on 2007-02-27 for method of forming metal wiring in a semiconductor device.
This patent grant is currently assigned to Samsung Electronics Co., Ltd.. Invention is credited to Kyung-Tae Lee, Sang-Jin Lee, Byung-Jun Oh.
United States Patent |
7,183,202 |
Lee , et al. |
February 27, 2007 |
Method of forming metal wiring in a semiconductor device
Abstract
A method of forming metal wiring in a semiconductor device is
disclosed. The method uses a dual damascene process in which a
trench is formed prior to a via-hole.
Inventors: |
Lee; Sang-Jin (Seoul,
KR), Lee; Kyung-Tae (Gangnum-gu, KR), Oh;
Byung-Jun (Suwon-si, KR) |
Assignee: |
Samsung Electronics Co., Ltd.
(Gyeonggi-do, KR)
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Family
ID: |
34737859 |
Appl.
No.: |
10/989,668 |
Filed: |
November 17, 2004 |
Prior Publication Data
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Document
Identifier |
Publication Date |
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US 20050153541 A1 |
Jul 14, 2005 |
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Foreign Application Priority Data
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Dec 4, 2003 [KR] |
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10-2003-0087414 |
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Current U.S.
Class: |
438/638; 438/702;
257/E21.579 |
Current CPC
Class: |
H01L
21/76808 (20130101); H01L 2924/0002 (20130101); H01L
23/53295 (20130101); H01L 2924/0002 (20130101); H01L
2924/00 (20130101) |
Current International
Class: |
H01L
21/4763 (20060101) |
Field of
Search: |
;438/638,631,702
;257/E21.024,E21.035,E21.579 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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2002-124568 |
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Apr 2002 |
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JP |
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1020020037805 |
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May 2002 |
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KR |
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1020020088399 |
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Nov 2002 |
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KR |
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Primary Examiner: Everhart; Caridad
Attorney, Agent or Firm: Volentine & Whitt, PLLC
Claims
What is claimed is:
1. A method of forming metal wiring in a semiconductor device,
comprising: forming a first stopping layer on a semiconductor
substrate on which a conductive layer is formed; forming an
insulating interlayer on the first stopping layer; forming a second
stopping layer on the insulating interlayer; forming a preliminary
layer on the second stopping layer; partially removing the
preliminary layer to form a preliminary pattern, the preliminary
pattern defining a trench region by exposing a top surface of the
second stopping layer, wherein the trench region has a first width;
partially removing the second stopping layer and a portion of the
insulating interlayer using the preliminary pattern, thereby
forming a trench of first width; forming a first mask layer on the
second stopping layer, wherein the first mask layer fills the
trench; forming a second mask layer on the first mask layer;
forming a third mask layer on the second mask layer; partially
removing the third mask layer to form a third mask pattern, the
third mask pattern defining a via-hole region by exposing a top
surface of the second mask layer, wherein the via-hole region has a
second width smaller than the first width; partially removing the
second mask layer using the third mask pattern, thereby forming a
second mask pattern; partially removing the first mask layer using
the second mask pattern, thereby forming a first mask pattern;
partially removing the insulating interlayer using the first mask
pattern, thereby forming a via-hole of second width partially
exposing the first stopping layer.
2. The method of claim 1, further comprising: removing an exposed
portion of the first stopping layer, thereby exposing the
conductive layer.
3. The method of claim 1, wherein the first mask layer comprises a
photoresist film sensitive to an I-line ray or a krypton fluoride
(KrF) excimer laser, or a material layer including a spin-on-glass
(SOG) based material.
4. The method of claim 1, wherein forming the first mask layer
comprises: coating the first mask layer on the second stopping
layer to a predetermined thickness sufficient to fill the trench;
and planarizing the first mask layer.
5. The method of claim 1, wherein removing the first mask pattern
comprises: performing an ashing process or a stripping process
using a material having an etch selectivity relative to the
insulating interlayer, the first stopping layer, and the second
stopping layer.
6. The method of claim 1, wherein the second mask layer comprises a
spin-on-glass (SOG) based material including carbon (C) having an
etch selectivity relative to the first mask layer and the
insulating interlayer.
7. The method of claim 1, wherein the conductive layer comprises
copper.
8. The method of claim 1, wherein the insulating interlayer
comprises silicon oxycarbide (SiOC), fluorine doped silicate glass
(FSG), or spin-on-glass (SOG) having a low dielectric constant.
9. The method of claim 1, wherein the first stopping layer
comprises silicon nitride (SiN), silicon carbide (SiC), or silicon
carbon nitride (SiCN) having an etch selectivity relative to the
insulating interlayer.
10. The method of claim 1, wherein the second stopping layer
comprises fluorine doped silicate glass (FSG) or undoped silicate
glass (USG) having a low dielectric constant.
11. A method of forming metal wiring in a semiconductor device,
comprising: forming a first stopping layer on a semiconductor
substrate on which a conductive layer is formed; forming a first
insulating interlayer on the first stopping layer; forming a second
stopping layer on the first insulating interlayer; forming a second
insulating interlayer on the second stopping layer; forming a third
stopping layer on the second insulating interlayer; forming a
preliminary layer on the third stopping layer; partially removing
the preliminary layer to form a preliminary pattern, the
preliminary pattern defining a trench region by exposing a top
surface of the third stopping layer, wherein the trench region has
a first width; partially removing the third stopping layer and a
portion of the second insulating interlayer using the preliminary
pattern, thereby forming a trench of first width partially exposing
a top surface of the second stopping layer; forming a first mask
layer on the third stopping layer, wherein the first mask layer
fills the trench; forming a second mask layer on the first mask
layer; forming a third mask layer on the second mask layer;
partially removing the third mask layer to form a third mask
pattern, the third mask pattern defining a via-hole region by
exposing a top surface of the second mask layer, wherein the
via-hole region has a second width smaller than the first width;
partially removing the second mask layer using the third mask
pattern, thereby forming a second mask pattern; partially removing
the first mask layer using the second mask pattern, thereby forming
a first mask pattern; partially removing the second stopping layer
and the first insulating interlayer, thereby forming a via-hole of
second width partially exposing the first stopping layer.
12. The method of claim 11, wherein forming the first mask layer
comprises: coating the first mask layer on the third stopping layer
to a predetermined thickness sufficient to fill the trench; and,
planarizing the first mask layer.
13. The method of claim 11, wherein the first stopping layer
comprises silicon nitride (SiN), silicon carbide (SiC), or silicon
carbon nitride (SiCN) having an etch selectivity relative to the
first insulating interlayer.
14. The method of claim 11, wherein the second stopping layer
comprises silicon nitride (SiN), silicon carbide (SiC), or silicon
carbon nitride (SiCN) having an etch selectivity relative to the
second insulating interlayer.
15. The method of claim 11, wherein the third stopping layer
comprises fluorine doped silicate glass (FSG) or undoped silicate
glass (USG) having a low dielectric constant.
16. The method of claim 11, wherein the conductive layer comprises
copper.
17. The method of claim 11, further comprising: removing an exposed
portion of the first stopping layer, thereby exposing the
conductive layer.
18. The method of claim 11, wherein the second mask layer comprises
a spin-on-glass (SOG) based material including carbon (C) having an
etch selectivity relative to the first mask layer, the second
stopping layer, and the first insulating interlayer.
19. The method of claim 11, wherein the second insulating
interlayer comprises silicon oxycarbide (SiOC), fluorine doped
silicate glass (FSG), or spin-on-glass (SOG) having a low
dielectric constant.
20. The method of claim 11, wherein removing the first mask pattern
comprises: performing an ashing process or a stripping process
using a material having an etch selectivity relative to the first
insulating interlayer, the second insulating interlayer, and the
first through third stopping layers.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to a method of forming
metal wiring in a semiconductor device. More particularly, the
present invention relates to a method of forming metal wiring in a
semiconductor device using a dual damascene process in which a
trench is formed prior to a via-hole.
A claim of priority is made to Korean Patent Application No.
2003-87414, filed on Dec. 4, 2003, the disclosure of which is
incorporated herein by reference in its entirety.
2. Description of the Related Art
Due to the current level of integration in modern semiconductor
devices, metal wiring layer having a multi-layer structure has
become an important part of many semiconductor devices. As the
degree of integration in semiconductor devices continues to
increase, the space between the layers in the multi-layer wiring
structure decreases accordingly. As a result, parasitic resistance
and parasitic capacitance between horizontally and vertically
adjacent wiring layers increases, thereby causing an increasingly
significant impact on the performance of many semiconductor
devices.
Increasing parasitic resistance and capacitance in a semiconductor
device typically decreases the device's performance by causing
signal delays, increasing power consumption, and increasing leakage
current. Accordingly, a modern semiconductor device having a
multi-layer wiring structure with small parasitic resistance and
capacitance is desired.
Parasitic resistance and capacitance are typically minimized in a
multi-layer wiring structure where the wiring is formed from a
metal having a low specific resistance and where an insulating
layer formed from a dielectric material having a low dielectric
constant is used. Intensive research has been conducted on the use
of copper as a low specific resistance material for use in the
formation of metal wiring.
Where copper is used as a metal wiring material, the resulting
wiring pattern is generally formed not by a photolithography
process, but rather by a dual damascene process. FIGS. 1A through
1F are cross sectional views illustrating the formation of metal
wiring in a semiconductor device according to a conventional dual
damascene process.
Referring to FIG. 1A, a conductive layer 20 is formed on a
semiconductor substrate 10 and a first stopping layer 30 is formed
on conductive layer 20. An insulating interlayer 40 is formed on
first stopping layer 30 and a second stopping layer 50 is formed on
insulating interlayer 40.
Referring to FIG. 1B, a first photoresist pattern 60 is formed on
second stopping layer 50.
First photoresist pattern 60 comprises first and second openings
70a and 70b, which partially expose second stopping layer 50. First
opening 70a is wider than second opening 70b. Accordingly, first
opening 70a forms a relatively large via-hole and second opening
70b forms a relatively small via-hole.
Referring to FIG. 1C, second stopping layer 50 and insulating
interlayer 40 are partially etched using first photoresist pattern
60 as an etching mask to form a third opening 80a having a first
width W1 and a fourth opening 80b having a second width W2. Third
and fourth openings 80a and 80b form via-holes partially exposing
first stopping layer 30. Following the formation of third and
fourth openings 80a and 80b, first photoresist pattern 60 is
completely removed. After being partially etched, second stopping
layer 50 and insulating interlayer 40 are referred to as second
stopping layer 50a and insulating interlayer 40a, respectively.
Referring to FIG. 1D, a mask layer 90 filling third and fourth
openings 80a and 80b is formed on second stopping layer 50a and an
anti-reflection layer 100 is formed on mask layer 90 to prevent
reflection from the mask layer in a subsequent photolithography
process. Mask layer 90 prevents a focus failure from occurring in
the subsequent photolithography process. In the absence of a mask
layer, the focus failure generally occurs during an exposing
process of the subsequent photolithography process where light
fails to properly focus due to a large width of a pattern formed in
a device being etched. For example, a focus failure could occur due
to a width of a trench corresponding to first opening 70a formed in
photoresist pattern 60.
Referring to FIG. 1E, a second photoresist pattern 110 used to form
a trench is formed on anti-reflection layer 100. Second photoresist
pattern 110 includes a fifth opening 120a and a sixth opening 120b,
which partially expose anti-reflection layer 100. A width of a
trench corresponding to fifth opening 120a is greater than first
width W1 and a width of a trench corresponding to sixth opening
120b is greater than second width W2 of fourth opening 80b.
Photoresist pattern 110 is formed by first forming a photoresist
film (not shown) on anti-reflection layer 100 and then exposing and
developing the photoresist film.
Referring to FIG. 1F, anti-reflection layer 100, mask layer 90,
second stopping layer 50a, and insulating interlayer 40a are
successively etched using second photoresist pattern 110 as an
etching mask. Then, mask layer 90, second photoresist pattern 110
and anti-reflection layer 100 are completely removed. After second
stopping layer 50a and insulating interlayer 40a are etched, they
are referred to as second stopping layer 50b and insulating
interlayer 40b.
The foregoing etching and removing processes form third and fourth
openings 80a and 80b, which partially expose first stopping layer
30. The etching and removing processes further form seventh and
eighth openings 130a and 130b connected to third and fourth
openings 80a and 80b, respectively. Seventh opening 130a has a
third width W3, which is larger than first width W1, and eighth
opening 130b has a fourth width W4, which is larger than second
width W2.
Third and fourth openings 80a and 80b function as via-holes and
seventh and eighth openings 130a and 130b function as trenches in a
metal wiring of a semiconductor device.
FIG. 2 is a cross-sectional view illustrating some problems that
typically arise in the conventional dual damascene process.
Referring to FIG. 2, problems arise in the conventional dual
damascene process during the etching process using second
photoresist pattern 110 as an etching mask and also during the
process of removing second photoresist pattern 110 and mask layer
90.
A first problem arises where third opening 80a has a sufficiently
large width, as, for example, in a pad region. A portion of first
stopping layer 30 is etched away, thus partially exposing
conductive layer 20 as shown at a portion "A" in FIG. 2.
A second problem arises where a stepped portion at the interface of
third and fourth openings 80a and 80b and trenches 130a and 130b
respectively, is formed to be round, as shown at portion "B" in
FIG. 2.
A third problem arises where insulating interlayer 40b is partially
removed under second stopping layer 50b between insulating
interlayer 40b and second stopping layer 50b, as shown at portion
"C" in FIG. 2. The partial removal of insulating interlayer 40b
under second stopping layer 50b is called an undercut
phenomenon.
A fourth problem arises where second stopping layer 50b becomes
narrow between seventh and eighth openings 130a and 130b, as shown
at a portion "D" in FIG. 2.
The problems described above alter the electrical characteristics
of the semiconductor device and often cause metal wiring failures,
thereby reducing the reliability of the semiconductor device.
A dual damascene process is disclosed, for example, in U.S. Pat.
No. 6,589,711. U.S. Pat. No. 6,589,711 discloses a dual damascene
process using a bi-layered mask layer in which a metal wiring
pattern is formed using an imaging layer and a bottom
anti-reflection coating (BARC).
Because of the problems arising in the conventional dual damascene
process, an improved method of forming a metal wiring is
desired.
SUMMARY OF THE INVENTION
The present invention provides a method of forming a metal wiring
in a semiconductor device using a dual damascene process in which a
trench is formed prior to the formation of a via-hole.
According to one aspect of the present invention, a method of
forming a metal wiring in a semiconductor device is provided. The
method comprises; forming a first stopping layer on a semiconductor
substrate on which a conductive layer is formed, forming an
insulating interlayer on the first stopping layer, forming a second
stopping layer on the insulating interlayer, and forming a
preliminary layer on the second stopping layer.
The method further comprises; partially removing the preliminary
layer to form a preliminary pattern including a trench region
exposing a top surface of the second stopping layer, wherein the
trench region has a first width, partially removing the second
stopping layer and a portion of the insulating interlayer using the
preliminary pattern, thereby forming a trench having the first
width, and then removing the preliminary pattern.
The method further comprises; forming a first mask layer on the
second stopping layer, wherein the first mask layer fills the
trench, forming a second mask layer on the first mask layer,
forming a third mask layer on the second mask layer, and partially
removing the third mask layer to form a third mask pattern, wherein
the third mask pattern comprises a via-hole region exposing a top
surface of the second mask layer, wherein the via-hole region has a
second width smaller than the first width.
The method further comprises; partially removing the second mask
layer using the third mask pattern, thereby forming a second mask
pattern, removing the third mask pattern, partially removing the
first mask layer using the second mask pattern, thereby forming a
first mask pattern, removing the second mask pattern, partially
removing the insulating interlayer using the first mask pattern,
thereby forming a via-hole partially exposing the first stopping
layer, wherein the via-hole has the second width, and removing the
first mask pattern.
The first mask layer typically comprises a photoresist film
sensitive to an I-line ray or a krypton fluoride (KrF) excimer
laser, or a material layer including a spin-on-glass (SOG) based
material.
Forming the first mask layer preferably comprises; coating the
first mask layer on the second stopping layer to a predetermined
thickness sufficient to fill the trench, and planarizing the first
mask layer.
Removing the first mask pattern preferably comprises; performing an
ashing process or a stripping process using a material having an
etch selectivity relative to the insulating interlayer, the first
stopping layer and the second stopping layer.
The second mask layer preferably comprises a SOG-based material
including carbon (C) having an etch selectivity relative to the
first mask layer and the insulating interlayer.
The conductive layer typically comprises copper.
The insulating interlayer preferably comprises silicon oxycarbide
(SiOC), fluorine doped silicate glass (FSG) or spin-on-glass (SOG)
having a low dielectric constant.
The first stopping layer typically comprises silicon nitride (SiN),
silicon carbide (SiC) or silicon carbon nitride (SiCN) having an
etch selectivity relative to the insulating interlayer.
The second stopping layer typically comprises fluorine doped
silicate glass (FSG) or undoped silicate glass (USG) having a low
dielectric constant.
According to another aspect of the present invention, another
method of forming a metal wiring in a semiconductor device is
provided. The method comprises; forming a first stopping layer on a
semiconductor substrate on which a conductive layer is formed,
forming a first insulating interlayer on the first stopping layer,
forming a second stopping layer on the first insulating interlayer,
forming a second insulating interlayer on the second stopping
layer, forming a third stopping layer on the second insulating
interlayer, and forming a preliminary layer on the third stopping
layer.
The method further comprises; partially removing the preliminary
layer to form a preliminary pattern, thereby forming a trench
region exposing a top surface of the third stopping layer, wherein
the trench region has a first width, partially removing the third
stopping layer and a portion of the second insulating interlayer
using the preliminary pattern, thereby forming a trench partially
exposing a top surface of the second stopping layer, wherein the
trench has the first width.
The method further comprises; forming a first mask layer on the
third stopping layer, wherein the first mask layer fills the
trench, forming a second mask layer on the first mask layer,
forming a third mask layer on the second mask layer, and partially
removing the third mask layer to form a third mask pattern, wherein
the third mask pattern comprises a via-hole region exposing a top
surface of the second mask layer, wherein the via-hole region has a
second width smaller than the first width.
The method further comprises; partially removing the second mask
layer using the third mask pattern, thereby forming a second mask
pattern, removing the third mask pattern, partially removing the
first mask layer using the second mask pattern, thereby forming a
first mask pattern, removing the second mask pattern, partially
removing the second stopping layer and the first insulating
interlayer, thereby forming a via-hole partially exposing the first
stopping layer, wherein the via-hole has the second width, and
removing the first mask pattern.
Forming the first mask layer typically comprises; coating the first
mask layer on the third stopping layer to a predetermined thickness
sufficient to fill the trench, and planarizing the first mask
layer.
Preferably, the first stopping layer comprises silicon nitride
(SiN), silicon carbide (SiC) or silicon carbon nitride (SiCN)
having an etch selectivity relative to the first insulating
interlayer.
The second stopping layer preferably comprises silicon nitride
(SiN), silicon carbide (SiC) or silicon carbon nitride (SiCN)
having an etch selectivity relative to the second insulating
interlayer.
The third stopping layer preferably comprises fluorine doped
silicate glass (FSG) or undoped silicate glass (USG) having a low
dielectric constant.
According to the present invention, a via-hole and a trench used to
form a metal wiring in a semiconductor device are formed so that
the desired electrical characteristics of the metal wiring are
maintained. In particular, an electrical short due to a wiring
failure is sufficiently prevented.
BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings illustrate multiple selected embodiments
of the present invention. In the drawings:
FIGS. 1A through 1F are cross-sectional views illustrating a method
of forming a metal wiring in a semiconductor device according to a
conventional dual damascene process;
FIG. 2 is a cross-sectional view illustrating some problems that
typically arise in the conventional dual damascene process;
FIGS. 3A through 3J are cross-sectional views illustrating a method
of forming a metal wiring in a semiconductor device according to
one exemplary embodiment of the present invention; and
FIGS. 4A through 4J are cross-sectional views illustrating a method
of forming a metal wiring in a semiconductor device according to
another exemplary embodiment of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
The present invention will now be described more fully with
reference to the accompanying drawings, in which multiple
embodiments of the present invention are shown. In the drawings and
corresponding written description, like reference numerals refer to
like elements throughout.
FIGS. 3A through 3J are cross-sectional views illustrating a method
of forming metal wiring in a semiconductor device according to one
exemplary embodiment of the present invention. The metal wiring is
formed by a dual damascene process in which a trench is formed
prior to a via-hole, contrary to a conventional dual damascene
process in which the via-hole is formed prior to the trench.
Referring to FIG. 3A, a first conductive layer 210 is formed on a
semiconductor substrate and a first stopping layer 220 is formed on
the first conductive layer. An insulating interlayer 230 is formed
on first stopping layer 220, and a second stopping layer 240 is
formed on insulating interlayer 230.
First conductive layer 210 preferably comprises copper and first
stopping layer 220 preferably comprises silicon nitride (SiN),
silicon carbide (SiC) or silicon carbon nitride (SiCN) having an
etch selectivity relative to insulating interlayer 230. First
stopping layer 220 stops a removing process, such as an etching
process, used to form a via-hole. Insulating interlayer 230
preferably comprises silicon oxycarbide (SiOC), fluorine doped
silicate glass (FSG), or spin-on-glass (SOG) having a low
dielectric constant. Second stopping layer 240 preferably comprises
fluorine doped silicate glass (FSG), or undoped silicate glass
(USG) having a low dielectric constant.
Referring to FIG. 3B, a preliminary pattern 250 is formed on second
stopping layer 240 and comprises at least one trench region
partially exposing a top surface of second stopping layer 240. In
FIG. 3B, a first trench region 260a and a second trench region 260b
are formed in preliminary pattern 250. First trench region 260a is
wider than second trench region 260b, and therefore second stopping
layer 240 is more widely exposed through first trench region 260a
than through second trench region 260b. Accordingly, first trench
region 260a forms a wide pattern such as a trench in a pad region
of a wafer, and second trench region 260b forms a narrow pattern
such as a trench in a cell region of a wafer that is strongly
constrained by a semiconductor device design rule.
Preliminary pattern 250 is typically formed by first forming a
preliminary layer (not shown) on second stopping layer 240, and
then partially removing the preliminary layer to form preliminary
pattern 250 including first and second trench regions 260a and
260b.
Referring to FIG. 3C, portions of second stopping layer 240 and
portions of insulating interlayer 230 are successively removed
using preliminary pattern 250 as a mask. Portions of second
stopping layer 240 and insulating interlayer 230 are removed to a
predetermined depth from a top surface of second stopping layer 240
so that insulating interlayer 230 is partially recessed after
second stopping layer 240 is completely removed. Accordingly, at
least one trench penetrating second stopping layer 240 is formed on
insulating interlayer 230. Second stopping layer 240 and insulating
interlayer 230 are respectively referred to as second stopping
layer 240a and insulating interlayer 230a following the removal of
the aforementioned portions.
A first opening 270a and a second opening 270b now exist where
exposed portions of second stopping layer 240 and a portion of
insulating interlayer 230 were removed. First opening 270a has a
first width W1, and second opening 270b has a second width W2
smaller than the first width W1.
First and second openings 270a and 270b preferably function as
trenches. First opening 270a preferably functions as a first trench
having first width W1 formed in a pad region. Second opening 270b
preferably functions as a second trench having second width W2
formed in a cell region. After first and second openings 270a and
270b are formed, preliminary pattern 250 is completely removed from
second stopping layer 240.
Referring to FIG. 3D, a first mask layer 280 filling first and
second openings 270a and 270b is formed on second stopping layer
240a. First mask layer 280 is typically formed by coating second
stopping layer 240a to a predetermined thickness sufficient to fill
the trenches corresponding to first and second openings 270a and
270b. First mask layer 280 preferably comprises a photoresist film
sensitive to an I-line ray or a krypton fluoride (KrF) excimer
laser, or a layer including a spin-on-glass (SOG) based
material.
Where first mask layer 280 is formed to be very thick from the top
surface of second stopping layer 240a, first mask layer 280 is
planarized to reduce the thickness thereof. Planarizing first mask
layer 280 prevents a process failure from occurring due to a large
thickness between a top surface of first mask layer 280 and a
bottom surface of first and second openings 270a and 270b. For
example, a focus failure is prevented from occurring in a
photolithography process used to form a wide pattern such as first
opening 270a by reducing the thickness of first mask layer 280.
Referring to FIG. 3E, a second mask layer 290 is formed on first
mask layer 280. Second mask layer 290 preferably comprises a
SOG-based material including carbon (C), having an etch selectivity
relative to first mask layer 280 and insulating interlayer
230a.
Referring to FIG. 3F, a third mask pattern 300 is formed on second
mask layer 290 in order to form a via-hole in a subsequent process.
Third mask pattern 300 comprises first and second via-hole regions
310a and 310b partially exposing a top surface of second mask layer
290. First via-hole region 310a is formed to be larger than second
via-hole region 310b, and thus a portion of second mask layer 290
exposed through first via-hole region 310a is wider than a portion
of second mask layer 290 exposed through second via-hole region
310b. First via-hole region 310a is formed to correspond to first
trench region 260a, and second via-hole region 310b is formed to
correspond to second trench region 260b. First via-hole region 310a
is narrower than first trench region 260a, and second via-hole
region 310b is narrower than second trench region 260b.
Accordingly, via-holes formed by first and second via-hole regions
310a and 310b are narrower than corresponding trenches formed by
respective first and second trench regions 260a or 260b.
Third mask pattern 300 is formed by coating a third mask layer (not
shown) on second mask layer 290 and then partially removing third
mask layer to form first and second via-hole regions 310a and
310b.
Referring to FIG. 3G, second mask layer 290 is partially removed
using third mask pattern 300, thus forming a second mask pattern
290a on first mask layer 280. Second mask layer 290 is partially
dry-etched using third mask pattern 300 as an etching mask. After
second mask pattern 290a is formed, third mask pattern 300 is
removed from second mask pattern 290a.
Referring to FIG. 3H, first mask layer 280 is partially removed
using second mask pattern 290a, thus forming a first mask pattern
280a. First mask layer 280 is partially dry-etched using second
mask pattern 290a as an etching mask. After first mask pattern 280a
is formed, second mask pattern 290a is removed from first mask
pattern 280a.
Referring to FIG. 31, a portion of insulating interlayer 230a is
removed using first mask pattern 280a, so that at least one
via-hole partially exposing first stopping layer 220 is formed. The
remaining portion of insulating interlayer 230a is referred to as
insulating interlayer 230b.
As a result of removing the portion of insulating interlayer 230a,
third and fourth openings 320a and 320b are formed and first
stopping layer 220 is partially exposed through third and fourth
openings 320a and 320b. Third opening 320a is formed to correspond
to first opening 270a and fourth opening 320b is formed to
correspond to second opening 270b. Third opening 320a has a third
width W3, which is smaller than first width W1, and fourth opening
320b has a fourth width W4, which is smaller than second width W2.
Preferably, third and fourth openings 320a and 320b function as
via-holes. For example, third opening 320a preferably functions as
a first via-hole formed in a pad region and fourth opening 320b
preferably functions as a second via-hole formed in a cell region.
Accordingly, the first trench having first width W1 and the first
via-hole having third width W3 are formed in the pad region, and
the second trench having second width W2 and the second via-hole
having fourth width W4 are formed in the cell region.
First stopping layer 220 is preferably further removed after
insulating interlayer 230a is partially removed in order for first
conductive layer 210 to be electrically connected with a second
conductive layer (not shown) in a subsequent process.
Referring to FIG. 3J, after third and fourth openings 320a and 320b
are formed, first mask pattern 280a is completely removed.
Accordingly, first opening 270a is connected to third opening 320a,
and second opening 270b is connected to fourth opening 320b.
Insulating interlayer 230b has a first stepped portion S1 due to
the difference between first width W1 and third width W3 and a
second stepped portion S2 due to the difference between second
width W2 and fourth width W4. In other words, the first trench is
connected to the first via-hole, which has a smaller width than
first trench, and the second trench is connected to the second
via-hole, which has a smaller width than the second trench. Second
stopping layer 220 is partially exposed through the first and
second via-holes and trenches.
First mask pattern 280a is preferably removed by an ashing process
or a stripping process using a material having an etch selectivity
relative to insulating interlayer 230b, first stopping layer 220,
and second stopping layer 240a.
FIGS. 4A through 4J are cross-sectional views illustrating steps of
a method for forming metal wiring of the semiconductor device
according to another exemplary embodiment of the present invention.
The metal wiring is formed by a dual damascene process in which a
trench is formed prior to a via-hole, contrary to a conventional
dual damascene process in which the via-hole is formed prior to the
trench.
Referring to FIG. 4A, a first conductive layer 410 is formed on a
semiconductor substrate 400 and a first stopping layer 420 is
formed on first conductive layer 410. A first insulating interlayer
430, a second stopping layer 440, a second insulating interlayer
450 and a third stopping layer 460 are successively formed on first
stopping layer 420.
First conductive layer 410 preferably comprises copper and first
stopping layer 420 preferably comprises silicon nitride (SiN),
silicon carbide (SiC), or silicon carbon nitride (SiCN). First
stopping layer 420 preferably has an etch selectivity relative to
second insulating interlayer 450. First stopping layer 420 stops a
removing process, such as an etching process, used to form a
via-hole. First insulating interlayer 430 preferably comprises
silicon oxycarbide (SiOC), fluorine doped silicate glass (FSG), or
spin-on-glass (SOG) having a low dielectric constant. Second
stopping layer 440 preferably comprises silicon nitride (SiN),
silicon carbide (SiC), or silicon carbon nitride (SiCN) having an
etch selectivity relative to that of second insulating interlayer
450. Second stopping layer 440 stops a removing process, such as an
etching process, used to form a trench. Second insulating
interlayer 450 comprises silicon oxycarbide (SiOC), fluorine doped
silicate glass (FSG), or spin-on-glass (SOG) having a low
dielectric constant. Third stopping layer 460 comprises fluorine
doped silicate glass (FSG) or undoped silicate glass (USG) having a
low dielectric constant. Third stopping layer 460 stops a CMP
process used to planarize a layer.
Referring to FIG. 4B, a preliminary pattern 470 is formed on third
stopping layer 460. Preliminary pattern 470 comprises first and
second trench regions 480a and 480b, which partially expose third
stopping layer 460. First trench region 480a is wider than second
trench region 480b. Therefore, a portion of third stopping layer
460 exposed through first trench region 480a is wider than a
portion of third stopping layer 460 exposed through second trench
region 480b. Accordingly, first trench region 480a forms a wide
pattern such as a trench in a pad region, and second trench region
480b forms a narrow pattern such as a trench in a cell region that
is strongly constrained by a design rule of a semiconductor
device.
Preliminary pattern 470 is typically formed by first coating a
preliminary mask layer (not shown) on third stopping layer 460, and
then partially removing the preliminary mask, thereby completing
preliminary pattern 470 including first and second trench regions
480a and 480b.
Referring to FIG. 4C, portions of third stopping layer 460 and
second insulating interlayer 450 are removed using preliminary
pattern 470 as a mask. Following this removal, second insulating
interlayer 450 and third stopping layer 460 are respectively
referred to as second insulating interlayer 450a and third stopping
layer 460a.
A first opening 490a and a second opening 490b exist where portions
of second insulating interlayer 450 and third stopping layer 460
were removed. Accordingly, second stopping layer 440 is partially
exposed through first and second openings 490a and 490b. First
opening 490a has a first width W1, and second opening 490b has a
second width W2, which is smaller than first width W1. First and
second openings 490a and 490b preferably function as trenches in a
wafer. First opening 490a preferably functions as a first trench
having first width W1 and is typically formed in a pad region.
Second opening 490b preferably functions as a second trench having
second width W2 and is typically formed in a cell region. After
first and second openings 490a and 490b are formed, preliminary
pattern 470 is completely removed from third stopping layer
460a.
Referring to FIG. 4D, a first mask layer 500 filling first and
second openings 490a and 490b is formed on third stopping layer
460a. First mask layer 500 is coated on third stopping layer 460a
to a predetermined thickness sufficient to fill first and second
openings 490a and 490b. First mask layer 500 preferably includes a
photoresist film sensitive to an I-line ray or a krypton fluoride
(KrF) excimer laser, or a material layer including a spin-on-glass
(SOG) based material. Where first mask layer 500 is excessively
thick relative to a top surface of third stopping layer 460a, first
mask layer 500 is planarized to reduce the thickness thereof,
thereby preventing a process failure due to a large distance
between a top surface of first mask layer 500 and a bottom surface
of first and second openings 490a and 490b. For example, a focus
failure is typically prevented from occurring in a photolithography
process for forming a wide pattern such as first opening 490a by
reducing the thickness of first mask layer 500.
Referring to FIG. 4E, a second mask layer 510 is formed on first
mask layer 500. Second mask layer 510 preferably comprises a
SOG-based material including carbon (C) and preferably has an etch
selectivity relative to first mask layer 500, second stopping layer
440, and first insulating interlayer 430.
Referring to FIG. 4F, a third mask pattern 520 is formed on second
mask layer 510 in order to form via-holes in a subsequent process.
Third mask pattern 520 comprises a first via-hole region 530a and a
second via-hole region 530b, which partially expose second mask
layer 510. First via-hole region 530a is wider than second via-hole
region 530b, and therefore a portion of second mask layer 510
exposed through first via-hole region 530a is wider than a portion
of second mask layer 510 exposed through second via-hole region
530b.
Third mask pattern 520 is formed by coating a third mask layer (not
shown) on second mask layer 510 and then partially removing third
mask layer to form first and second via-hole regions 530a and
530b.
First via-hole region 530a is formed to correspond to first trench
region 480a and second via-hole region 530b is formed to correspond
to second trench region 480b. In addition, first via-hole region
530a is formed to be narrower than first trench region 480a, and
second via-hole region 530b is formed to be narrower than second
trench region 480b. Accordingly, via-holes formed by using first
and second via-hole regions 530a or 530b are narrower than their
respective trench counterparts formed by using first and second
trench regions 480a or 480b.
Referring to FIG. 4Q second mask layer 510 is partially removed
using third mask pattern 520 as a mask. As a result, a second mask
pattern 510a is formed on first mask layer 500. Second mask layer
510 is preferably partially dry-etched using third mask pattern 520
as an etching mask. After second mask pattern 510a is formed, third
mask pattern 520 is removed from second mask pattern 510a.
Referring to FIG. 4H, first mask layer 500 is partially removed
using second mask pattern 510a. As a result, a first mask pattern
500a is formed. First mask layer 500 is partially dry-etched using
second mask pattern 510a as an etching mask. After first mask
pattern 500a is formed, second mask pattern 510a is removed from
first mask pattern 500a.
Referring to FIG. 41, portions of second stopping layer 440 and
first insulating interlayer 430 are removed using first mask
pattern 500a, so that a third opening 540a and a fourth opening
540b are formed. Following this removing process, second stopping
layer 440 is referred to as second stopping layer 440a and first
insulating interlayer 430 is referred to as first insulating
interlayer 430a. First stopping layer 420 is partially exposed
through third and fourth openings 540a and 540b.
Third opening 540a is formed to correspond to first opening 490a
and fourth opening 540b is formed to correspond to second opening
490b. Third opening 540a has a third width W3 smaller than first
width W1 of first opening 490a and fourth opening 540b has a fourth
width W4 smaller than second width W2 of second opening 490b. Third
and fourth openings 540a and 540b function as via-holes in a wafer.
Third opening 540a typically functions as a first via-hole formed
in a pad region of the wafer and fourth opening 540b typically
functions as a second via-hole formed in a cell region of the
wafer. Accordingly, the first trench having first width W1 and the
first via-hole having third width W3 are formed in the pad region
of the wafer, and the second trench having second width W2 and the
second via-hole having fourth width W4 are formed in the cell
region of the wafer.
First stopping layer 420 is preferably further removed when first
insulating interlayer 430 is removed in order for first conductive
layer 410 to be electrically connected with a second conductive
layer (not shown) in a subsequent process.
Referring to FIG. 4J, after third and fourth openings 540a and 540b
are formed, first mask pattern 500a is completely removed.
Accordingly, first opening 490a is connected to third opening 540a
and second opening 490b is connected to fourth opening 540b.
As a result of removing first mask pattern 500a, second stopping
layer 440a has a stepped portion S1 due to a difference between
width W1 of the first trench and width W3 of the first via-hole,
and a second stepped portion S2 due to a difference between width
W2 of the second trench and width W4 of the second via-hole. The
first trench is connected to the first via-hole having a smaller
width than the width of the first trench, and the second trench is
connected to the second via-hole having a smaller width than the
width of the second trench.
First stopping layer 420 is partially exposed through the first and
second via-holes and trenches. First mask pattern 500a is removed
by an ashing process or a stripping process using a material having
an etch selectivity relative to first insulating interlayer 430a,
second insulating interlayer 450a, and first through third stopping
layers 420, 440a and 460a.
According to the present invention, via-holes and trenches used to
form a metal wiring in a semiconductor device are formed in
accordance with design conditions and shape which allow the
electrical characteristics of the metal wiring to be maintained
without alteration. In particular, an electrical short due to
wiring failures is sufficiently prevented.
The preferred embodiments disclosed in the drawings and the
corresponding written description are teaching examples. Those of
ordinary skill in the art will understand that various changes in
form and details may be made to the exemplary embodiments without
departing from the scope of the present invention which is defined
by the following claims.
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