U.S. patent number 5,984,988 [Application Number 09/061,262] was granted by the patent office on 1999-11-16 for shaped abrasive particles and method of making same.
This patent grant is currently assigned to Minnesota Minning & Manufacturing Company. Invention is credited to James G. Berg, Todd A. Berg, William K. Leonard, Donley D. Rowenhorst.
United States Patent |
5,984,988 |
Berg , et al. |
November 16, 1999 |
Shaped abrasive particles and method of making same
Abstract
A method of making abrasive particles having a specified shape
and abrasive articles containing abrasive particles having a
specified shape. The method for preparing such an abrasive particle
comprises the steps of: (a) providing a dispersion containing
particles of a precursor of alpha alumina, preferably particles of
alpha alumina monohydrate, in a liquid, which liquid comprises a
volatile component; (b) providing a mold having a first surface and
a second surface opposed to said first surface, said first surface
having an opening to a mold cavity having a specified shape; (c)
introducing the dispersion into said mold cavity; (d) removing a
sufficient portion of the volatile component of the liquid from the
dispersion while the dispersion is in the mold cavity, to form a
precursor of an abrasive particle having approximately the same
shape as the shape of the recess of the mold cavity; (e) removing
the precursor of the abrasive particle from the recess of the mold;
(f) calcining the removed precursor of the abrasive particle; and
(g) sintering the calcined precursor to form the desired abrasive
particle.
Inventors: |
Berg; Todd A. (St. Louis Park,
MN), Rowenhorst; Donley D. (Maplewood, MN), Berg; James
G. (Lino Lakes, MN), Leonard; William K. (River Falls,
WI) |
Assignee: |
Minnesota Minning &
Manufacturing Company (St. Paul, MN)
|
Family
ID: |
25440258 |
Appl.
No.: |
09/061,262 |
Filed: |
April 17, 1998 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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918360 |
Jul 23, 1992 |
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Current U.S.
Class: |
51/293; 264/6;
264/7; 51/309 |
Current CPC
Class: |
B24D
3/06 (20130101); C09K 3/1409 (20130101); C04B
35/1115 (20130101); B24D 18/0009 (20130101) |
Current International
Class: |
B24D
3/04 (20060101); B24D 18/00 (20060101); B24D
3/06 (20060101); C04B 35/111 (20060101); C09K
3/14 (20060101); C09C 001/68 () |
Field of
Search: |
;51/293,309
;264/6,7 |
References Cited
[Referenced By]
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JP |
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4159387 |
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Jun 1992 |
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JP |
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Primary Examiner: Jones; Deborah
Attorney, Agent or Firm: Busse; Paul W.
Parent Case Text
This application is a continuation of application Ser. No.
07/918,360, filed on Jul. 23, 1992, now abandoned.
Claims
What is claimed is:
1. Method for preparing an abrasive particle suitable for use as an
abrasive grit in an abrasive article, said method comprising the
steps of:
(a) providing a dispersion containing particles that can be
converted into alpha alumina in a liquid, which liquid comprises a
volatile component;
(b) providing a mold having a first surface and a second surface
opposed to said first surface, said first surface having an opening
to a mold cavity having a specified shape;
(c) introducing said dispersion into said mold cavity;
(d) removing a sufficient portion of said volatile component of
said liquid from said dispersion while said dispersion is in said
mold cavity to form a precursor of an abrasive particle having a
shape approximately corresponding to the shape of said mold
cavity;
(e) removing said precursor of said abrasive particle from said
mold;
(f) calcining said removed precursor of said abrasive particle;
and
(g) sintering said calcined precursor of said abrasive particle to
form said abrasive particle.
2. The method of claim 1, further comprising the step of gelling
said dispersion prior to introducing said dispersion into said mold
cavity.
3. The method of claim 1, wherein said dispersion is introduced
into said mold cavity under a pressure of less than 100 psi.
4. The method of claim 1, wherein said first surface of said mold
is exposed to the atmosphere surrounding said mold at least during
step (d).
5. The method of claim 1, wherein step (d) is conducted under
ambient temperature and pressure conditions.
6. The method of claim 1, wherein step (d) is accomplished by
evaporation.
7. The method of claim 1, further comprising the step of drying
said precursor of said abrasive particle after it is removed from
said mold and before said precursor of said abrasive particle is
calcined.
8. The method of claim 1, wherein said mold contains a plurality of
cavities having specified shapes.
9. The method of claim 8, wherein said mold contains at least 20
cavities.
10. The method of claim 1, wherein said particles that can be
converted into alpha alumina comprise alpha aluminum oxide
monohydrate.
11. The method of claim 1, wherein said dispersion further contains
a modifying additive or precursor of a modifying additive.
12. The method of claim 11, wherein said modifying additive or
precursor of a modifying additive is a soluble salt.
13. The method of claim 1, wherein said dispersion further contains
a nucleating agent.
14. The method of claim 13, wherein said nucleating agent includes
fine particles selected from the group consisting of alpha alumina,
alpha ferric oxide, precursor of alpha ferric oxide, chrome oxides,
titanium oxide, and titanates.
15. The method of claim 1 wherein said mold cavity extends
completely through said mold, whereby said second surface has an
opening to said mold cavity.
16. An abrasive particle prepared according to the method of claim
1.
17. The abrasive particle of claim 16, wherein said particle has a
front face and a back face, said front face having substantially
the same geometric shape as said back face, said faces being
separated by the thickness of said particle, wherein the ratio of
the length of the shortest facial dimension to the thickness of
said particle is at least 1:1.
18. The abrasive particle of claim 17, wherein said front face and
said back face each have three sides.
19. The abrasive particle of claim 16, wherein said particle has a
front face and a back face, said front face having substantially
the same geometric shape as said back face, said faces being
separated by the thickness of said particle, wherein the ratio of
the length of the shortest facial dimension to the thickness of
said particle is at least 2:1.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to abrasive particles, and, more
particularly, a method of making abrasive particles having
specified shapes.
2. Discussion of the Art
Three basic technologies that have been employed to produce
abrasive grains having a specified shape are (1) fusion, (2)
sintering, and (3) chemical ceramic.
In the fusion process, abrasive grains can be shaped by a chill
roll, the face of which may or may not be engraved, a mold into
which molten material is poured, or a heat sink material immersed
in an aluminum oxide melt. U.S. Pat. No. 3,377,660 discloses a
process comprising the steps of flowing molten abrasive material
from a furnace onto a cool rotating casting cylinder, rapidly
solidifying the material to form a thin semisolid curved sheet,
densifying the semisolid material with a pressure roll, and then
partially fracturing the strip of semisolid material by reversing
its curvature by pulling it away from the cylinder with a rapidly
driven cooled conveyor, whereupon the partially fractured strip is
deposited onto a collector in the form of large fragments, which,
upon being rapidly cooled and solidified, break up into smaller
fragments capable of being reduced in size to form conventional
abrasive grains. U.S. Pat. Nos. 4,073,096 and 4,194,887 disclose a
process comprising the steps of (1) fusing an abrasive mix in an
electric arc furnace, (2) dipping a relatively cold substrate into
the molten material, whereby a layer of solid abrasive material is
quickly frozen (or plated) on the substrate, (3) withdrawing the
plated substrate from the molten material, and (4) breaking the
solidified abrasive material away from the substrate and collecting
it for further processing to produce abrasive grains.
In the sintering process, abrasive grains can be formed from
refractory powders having a particle size of up to 10 micrometers
in diameter. Binders can be added to the powders along with a
lubricant and a suitable solvent, e.g., water. The resulting
mixtures, pastes, or slurries can be shaped into platelets or rods
of various lengths and diameters. The resulting shaped grains must
be fired at high temperatures, e.g., 1,400.degree. C. to
1,800.degree. C., at high pressures, or for long soak times, e.g.,
up to 10 hours. Crystal size may range from under one micrometer up
to 25 micrometers. To obtain shorter residence times and/or smaller
crystal size, either the pressure or temperature must be increased.
U.S. Pat. No. 3,079,242 discloses a method of making abrasive
grains from calcined bauxite material comprising the steps of (1)
reducing the material to a fine powder, (2) compacting under
affirmative pressure and forming the fine particles of said powder
into grain sized agglomerations, and (3) sintering the
agglomerations of particles at a temperature below the fusion
temperature of the bauxite to induce limited recrystallization of
the particles, whereby abrasive grains are produced directly to
size. U.S. Pat. No. 4,252,544 discloses alumina abrasive grains
produced by sintering wherein the grain structure is constructed of
alumina coarse crystal particles and alumina fine crystal particles
located between the alumina coarse crystal particles. U.S. Pat. No.
3,491,492 discloses a process for making an aluminous abrasive
grain formed from bauxite or mixtures of bauxite and Bayer process
alumina wherein the comminuted aluminous material is mixed with
water and ferric ammonium citrate, or with ferric ammonium citrate
and citric acid, and reduced to a state of fine subdivision by
milling to give a fluid slurry of high solid content, drying said
slurry to coherent cakes having a thickness equal to one dimension
of the final grain before sintering, breaking said cakes to grains,
screening, optionally rounding said grains by air mulling,
screening, sintering, cooling, and screening to yield the final
product. U.S. Pat. No. 3,637,630 discloses a process in which the
same type of slurry disclosed in U.S. Pat. No. 3,491,492 is plated
or coated on a rotating anode of an electrophoretic cell. The
plated aluminous material is removed from the rotating anode,
dried, broken to granules, screened, sintered, and screened to
final size.
Chemical ceramic technology involves converting a colloidal
dispersion or hydrosol (sometimes called a sol), optionally in a
mixture with solutions of other metal oxide precursors, to a gel or
any other physical state that restrains the mobility of the
components, drying, and firing to obtain a ceramic material. A sol
can be prepared by any of several methods, including precipitation
of a metal hydroxide from an aqueous solution followed by
peptization, dialysis of anions from a solution of metal salt,
solvent extraction of an anion from a solution of a metal salt,
hydrothermal decomposition of a solution of a metal salt having a
volatile anion. The sol optionally contains metal oxide or
precursor thereof and is transformed to a semi-rigid solid state of
limited mobility such as a gel by, e.g., partial extraction of the
solvent, e.g., water. Chemical ceramic technology has been employed
to produce ceramic materials such as fibers, films, flakes, and
microspheres. U.S. Pat. No. 4,314,827 discloses synthetic,
non-fused aluminum oxide based abrasive mineral having a
microcrystalline structure of randomly oriented crystallites
comprising a dominant continuous phase of alpha alumina and a
secondary phase. U.S. Pat. No. 4,744,802 discloses an abrasive
grain made by a chemical ceramic process that employs an iron oxide
nucleating agent to enhance the transformation to alpha alumina.
This patent also suggests that the gel can be shaped by any
convenient method such as pressing, molding, or extruding. U.S.
Pat. No. 4,848,041 discloses a shaped abrasive grain made by a
chemical ceramic process in which the abrasive grain has a mean
particle volume ratio of less than 0.8.
SUMMARY OF THE INVENTION
This invention provides a method of making abrasive particles
having specified shapes. This invention also provides abrasive
particles having specified shapes.
The method for preparing such an abrasive particle comprises the
steps of:
(a) providing a dispersion comprising particles that can be
converted into alpha alumina, preferably particles of alpha alumina
monohydrate, in a liquid, which liquid comprises a volatile
component;
(b) providing a mold having a first surface having an opening to a
mold cavity having a specified shape;
(c) introducing the dispersion into said mold cavity;
(d) removing a sufficient portion of said volatile component of
said liquid from the dispersion while the dispersion is in the mold
cavity, thereby forming a precursor of an abrasive particle having
a shape approximately corresponding to the shape of said mold
cavity;
(e) removing said precursor of the abrasive particle from said mold
cavity;
(f) calcining said removed precursor of the abrasive particle;
and
(g) sintering said calcined precursor to form the desired abrasive
particle.
In one variation of the process of this invention, after the
dispersion is formed, it is gelled prior to being introduced into
the mold cavity. As used herein, the term "to gel" means to
increase the viscosity of a substance sufficiently so that it will
not flow from an inverted test tube. In a second variation, the
dispersion is introduced into the mold cavity under a pressure of
less than 100 psi. In a third variation, at least one side of the
mold, i.e. the side in which the cavity is formed, is exposed to
the atmosphere surrounding the mold during the step in which the
volatile component is removed. In a fourth variation, the volatile
component of the dispersion is removed from the dispersion while
the dispersion is in the mold without the application of additional
heat or pressure. In a fifth variation, the volatile component of
the dispersion is removed from the dispersion by evaporation while
the dispersion is in the mold. In a sixth variation, an additional
drying step is utilized after the precursor of the abrasive
particle is removed from the mold.
Preferably, the mold contains a plurality of cavities, more
preferably at least twenty cavities. Preferably, the shape of the
cavities correspond approximately to the desired shape of the
abrasive particles.
A second aspect of the invention involves abrasive particles having
specified shapes. In particular, the abrasive particles have shapes
that can be characterized as thin bodies having triangular,
rectangular, including square, circular, or other geometric shape.
The abrasive particles have a front face and a back face, both of
which faces have substantially the same geometric shape. The faces
are separated by the thickness of the particle. The ratio of the
length of the shortest facial dimension of an abrasive particle to
its thickness is at least 1 to 1, preferably at least 2 to 1, more
preferably at least 5 to 1, and most preferably at least 6 to
1.
The use of the abrasive particles of this invention minimizes the
formation of flat surfaces on the cutting regions of the abrasive
material. These flat surfaces shorten the useful life of
conventional abrasive articles. During the abrading process, the
shaped particles of this invention continually fracture to expose
fresh cutting surfaces. Accordingly, they sharpen themselves during
use.
The abrasive particles of this invention can be used in coated
abrasive articles, bonded abrasive articles, non-woven abrasive
articles, and abrasive brushes. At least 10% by weight, and
preferably to 100% by weight, of the abrasive material of the
abrasive article should be of the abrasive particles of this
invention.
The particles prepared by the process of this invention can be used
to prepare a coated abrasive article. The coated abrasive article
comprises a backing having at least one layer of abrasive grits
adhered thereto by means of a binder. A portion of this layer
contains abrasive particles of this invention. It is preferred that
the geometric shape of the faces of these abrasive particles be
triangular. In order to efficiently align the abrasive particles of
this invention on the backing, the abrasive particles are
preferably coated in an electrostatic field. The electrostatic
field lines concentrate at the corners and along the edges of the
abrasive particles, and by means of mutual particle repulsion, the
particles orient in the electrostatic field in such a way that they
are deposited onto the binder on their thinnest edges, thereby
allowing thin edges of the particles to be in contact with the
workpiece during abrading operations. For triangular-shaped
particles, about 35% to about 65% of the particles are oriented
with a vertex pointing away from the backing and a base in contact
with the binder, with the remainder being oriented with a base
pointing away from the backing and a vertex in contact with the
binder. It is believed that when this configuration is used with
equilateral triangular-shaped particles, the sum of the surface
areas of each of the particles in contact with the workpiece
remains essentially constant during use, even though the surface
area of each individual abrasive particle in contact with the
workpiece varies during use.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a top view of a mold suitable for the process of this
invention.
FIG. 2 is a perspective view of a mold suitable for the process of
this invention.
FIG. 3 is a side view of a coated abrasive article that employs the
abrasive particle of this invention.
FIG. 4 is a photomicrograph taken at 12.times. illustrating
abrasive particles of this invention in which the planar shape is
triangular.
FIG. 5 is a photomicrograph taken at 12.times. illustrating
abrasive particles of this invention in which the planar shape is
rectangular.
FIG. 6 is a photomicrograph taken at 12.times. illustrating
abrasive particles of this invention in which the planar shape is
circular.
FIG. 7 is a side view of another embodiment of a coated abrasive
article that employs the abrasive particle of this invention.
FIG. 8 is a side view of an apparatus for preparing abrasive
particles of this invention.
FIG. 9 is a schematic perspective view of a die that can be used in
the apparatus of FIG. 8.
FIG. 10 is a sectional view of the auger and bore of the die body
of FIG. 9 .
DETAILED DESCRIPTION
As used herein, the term "dispersion" means the composition that is
introduced into the mold cavity--the composition will be referred
to as a dispersion until sufficient volatile component is removed
therefrom to bring about solidification of the dispersion; the term
"precursor of abrasive particle" means the unsintered particle
produced by removing a sufficient amount of the volatile component
from the dispersion, when it is in the mold cavity, to form a
solidified body having a shape corresponding approximately to the
shape of the mold cavity; the term "abrasive particle" means the
sintered particle produced by the process of this invention.
The first step of the process of this invention involves preparing
a dispersion containing particles that can be converted into alpha
alumina in a liquid, which liquid comprises a volatile component,
preferably water. The dispersion should comprise a sufficient
amount of liquid to cause the viscosity of the dispersion to be
sufficiently low to ensure ease of introduction into the mold
cavity but not so much liquid as to cause subsequent removal of the
liquid from the mold cavity to be prohibitively expensive. The
dispersion preferably comprises from about 2 to about 90% by weight
of the particles that can be converted into alpha alumina,
preferably particles of alpha aluminum oxide monohydrate
(boehmite), and at least 10% by weight, preferably from 50 to 70%,
more preferably 50 to 60%, by weight, volatile component,
preferably water. Conversely, the dispersion preferably contains
from 30 to 50%, more preferably 40 to 50% by weight, solids. If the
percentage of liquid is too high, too many cracks will develop in
the resulting particles upon drying thereof. If the percentage of
liquid is too low, pumping of the dispersion will be difficult.
Aluminum oxide hydrates other than boehmite can also be used.
Boehmite can be prepared by known techniques or can be obtained
commercially. Examples of commercially available boehmite include
products having the trademarks "DISPERAL", available from Condea
Chemie, GMBH and "DISPAL", available from Vista Chemical Company.
These aluminum oxide monohydrates are in the alpha form, are
relatively pure, i.e., they include relatively little, if any,
hydrate phases other than monohydrates, and have a high surface
area. The physical properties of the abrasive particles of this
invention will generally depend upon the type of material used in
the dispersion.
It is preferred that the dispersion be in a gel state. As used
herein, "a gel" is a three dimensional network of solids dispersed
in a liquid. A gel will not flow from an inverted test tube.
The dispersion may contain a modifying additive or precursor of a
modifying additive. The modifying additive can function to enhance
some desirable property of the abrasive particles or increase the
effectiveness of the subsequent sintering step. Modifying additives
or precursors of modifying additives can be in the form of soluble
salts, typically water soluble salts. They typically consist of a
metal-containing compound and can be a precursor of oxide of
magnesium, zinc, iron, silicon, cobalt, nickel, zirconium, hafnium,
chromium, yttrium, praseodymium, samarium, ytterbium, neodymium,
lanthanum, gadolinium, cerium, dysprosium, erbium, titanium, and
mixtures thereof. The particular concentrations of these additives
that can be present in the dispersion is not critical and can be
varied on the basis of convenience. Typically, the introduction of
a modifying additive or precursor of a modifying additive will
cause the dispersion to gel. The dispersion can also be induced to
gel by application of heat over a period of time.
The dispersion can also contain a nucleating agent to enhance the
transformation of hydrated or calcined aluminum oxide to alpha
alumina. Nucleating agents suitable for this invention include fine
particles of alpha alumina, alpha ferric oxide or its precursor,
titanium oxides and titanates, chrome oxides, or any other material
that will nucleate the transformation. The amount of nucleating
agent, if used, should be sufficient to effect the transformation
of alpha alumina. Nucleating such dispersions is disclosed in U.S.
Pat. No. 4,744,802, incorporated hereinafter by reference.
A peptizing agent can be added to the dispersion to produce a more
stable hydrosol or colloidal dispersion. Peptizing agents preferred
for this invention are monoprotic acids or acid compounds such as
acetic acid, hydrochloric acid, formic acid, and nitric acid, with
nitric acid being preferred. Multiprotic acids are less preferred
as peptizing agents because they rapidly gel the dispersion, making
it difficult to handle or to introduce additional components
thereto. Some commercial sources of boehmite contain an acid titer
(such as absorbed formic or nitric acid) that will assist in
forming a stable dispersion.
The dispersion can be formed by any suitable means, such as, for
example, simply by mixing aluminum oxide monohydrate with water
containing a peptizing agent or by forming an aluminum oxide
monohydrate slurry to which the peptizing agent is added.
The second step of the process of this invention involves providing
a mold having at least one cavity, preferably a plurality of
cavities. Referring to FIG. 1, a mold 10 has a surface 12 and a
plurality of cavities 14.
Mold 10 can be made from a rigid material, such as metal, e.g.,
steel. It is preferred that mold 10 be made from a relatively thin
aluminum or stainless steel sheet or belt, e.g., having a thickness
of less than 5 cm, preferably less than 2 cm. Referring to FIG. 2,
access to cavities 14 of mold 10 can be from an opening 15 in first
or top surface 16 of mold 10, from an opening (not shown) in second
or bottom surface 18 of mold 10, or from openings in both surfaces
of mold 10. In some instances, cavities 14 can extend for the
entire thickness of mold 10. Alternatively, cavities 14 can extend
only for a portion of the thickness of mold 10. At least one side
of mold 10, i.e. the side in which the cavity is formed, can remain
exposed to the surrounding atmosphere during the step in which the
volatile component is removed.
The cavities 14 have a specified three-dimensional shape. The
preferred shape of a cavity can be described as being a triangle
having a dimension of depth. However, other shapes can be used,
such as, circles, rectangles, squares, or combinations thereof, all
having a dimension of depth. The dimension of depth is equal to the
perpendicular distance from the surface 12 to the lowermost point
of cavity 14. In addition, a cavity can have the inverse of even
other solid geometric shapes, such as, for example, pyramidal,
frusto-pyramidal, truncated spherical, truncated spheroidal,
conical, and frusto-conical. There are preferably at least 20
cavities per mold, more preferably at least 100 cavities per mold.
The depth of the cavity can be uniform or can vary along its length
and/or width. The cavities of a given mold can be of the same shape
or of different shapes.
It is preferred that the dimensions of cavities 14 approximately
correspond to the desired dimensions of the abrasive particles,
taking expected shrinkage into account. Accordingly, it will not be
necessary to crush, break, or cut the abrasive particles to reduce
their size. Likewise, after the abrasive particles are made by the
process of this invention, it is not necessary to screen them to an
appropriate particle size. Moreover, the size of the abrasive
particles will essentially remain constant between different lots,
thereby assuring a very consistent particle size and distribution
of particle sizes from lot to lot. By using cavities of the same
size and shape, abrasive particles of substantially constant aspect
ratio can be made.
The third step of the process of this invention involves
introducing the dispersion into cavities 14 by any conventional
technique. It is preferred to flood surface 12 of mold 10 with the
dispersion. The dispersion can be pumped onto surface 12 of mold
10. Next, a scraper or leveler bar can be used to force some of the
dispersion into cavities 14 of mold 10. The remaining portion of
the dispersion that does not enter cavities 14 can be removed from
surface 12 of mold 10 and recycled. Although a small portion of the
dispersion can still be allowed to remain on surface 12 of mold 10,
this is not preferred. The pressure applied by the scraper or
leveler bar is typically less than 100 psi, preferably less than 50
psi, and most preferably less than 10 psi.
It is preferred that a release coating be applied to surface 12 of
mold 10 and on the surfaces of cavities 14 prior to the
introduction of the dispersion into cavities 14. The function of
the release coating is to allow ease of removal of the precursors
of the abrasive particles. Typical materials for preparing release
coatings are silicones and polytetrafluorethylene.
The fourth step of the process of this invention involves removing
a portion of the liquid, i.e. the volatile component thereof, from
the dispersion while the dispersion is in the mold cavity, thereby
resulting in an increase in the viscosity of the dispersion. It is
preferred that the volatile component be removed by evaporation
rather than by an external force such as filtration. Removal of
liquid by evaporation can occur at room temperature or at elevated
temperatures. The elevated temperatures can range from about
40.degree. C. to about 300.degree. C. However, at higher
temperatures, high drying rates are obtained that produce
undesirable cracks in the resulting abrasive particle. It is
preferred to heat the mold containing the dispersion at a
temperature of from about 50.degree. C. to about 80.degree. C. for
from about 10 to about 30 minutes in a forced air oven. A
sufficient amount of the volatile component must be removed from
the dispersion to bring about solidification thereof, thereby
forming a precursor of an abrasive particle having approximately
the same shape as the shape of the mold cavity. It is preferred
that a sufficient amount of volatile component be removed from the
dispersion so that the precursors of the abrasive particles can be
easily removed from the cavities of the mold. Typically, up to 40%
of the liquid is removed from the dispersion in this step. At this
point the precursors of the abrasive particles are sufficiently
nonsticky that they will not stick to one another when they are
removed from the mold.
The fifth step of the process of this invention involves removing
the precursors of the abrasive particle from the mold cavities.
This step is made possible by shrinkage of the dispersion, when the
liquid is removed therefrom. For example, it is not uncommon for
the dispersion to shrink 20% or more. The precursors of the
abrasive particles can be removed from the mold cavities either by
gravity or by applying a low pressure to force them out of the
cavities.
The removed precursors of the abrasive particles have approximately
the same shape as the cavities of the mold from which they were
formed. Exact replication is unlikely for three reasons. First, the
dispersion will shrink, so the precursors of the abrasive particles
will be smaller. Second, when the precursors of the abrasive
particles are removed from the mold cavities, some of their edges
may break off or become rounded. Third, when the dispersion is
introduced in the cavities, the dispersion may not completely fill
the cavities. It should be noted that care should be taken
throughout the process to minimize the foregoing factors.
The precursors of the abrasive particles can be further dried
outside of the mold. If the dispersion is dried to the desired
level in the mold, this additional drying step is not necessary.
However, in some instances it may be economical to employ this
additional drying step to minimize the time that the dispersion
resides in the mold. During this additional drying step, care must
be taken to prevent cracks from forming in the precursors of the
abrasive particles. Typically, the precursors of the abrasive
particles will be dried for from about 10 to about 480 minutes,
preferably from about 120 to about 400 minutes, at a temperature
from about 50.degree. C. to about 160.degree. C., preferably from
about 120.degree. C. to about 150.degree. C.
The sixth step of the process of this invention involves calcining
the precursors of the abrasive particles. During calcining,
essentially all the volatile material is removed, and the various
components that were present in the dispersion are transformed into
metal oxides. The precursors of the abrasive particle are generally
heated to a temperature of from about 400.degree. C. to about
800.degree. C., and maintained within this temperature range until
the free water and over 90% by weight of any bound volatile
material are removed. In an optional step, it may be desired to
introduce the modifying additive by an impregnation process. A
water-soluble salt can be introduced by impregnation into the pores
of the calcined precursors of the abrasive particles. Then the
precursors of the abrasive particles are prefired again. This
option is further described in European Patent Application No.
293,163, incorporated herein by reference.
The seventh step of the process of this invention involves
sintering the precursors of the abrasive particles to form the
abrasive particles. Prior to sintering, the precursors of the
abrasive particles are not completely densified and thus lack the
hardness to be used as abrasive particles of this invention.
Sintering takes place by heating the precursors of the abrasive
particle to a temperature of from about 1,000.degree. C. to about
1,650.degree. C. and maintaining them within this temperature range
until substantially all of the alpha alumina monohydrate (or
equivalent) is converted to alumina and porosity is reduced to less
than 15% by volume. The length of time to which the precursors of
the abrasive particles must be exposed to the sintering temperature
to achieve this level of conversion depends upon various factors
but usually from about five seconds to about 48 hours is typical.
The preferred duration for sintering ranges from about one minute
to about 90 minutes.
Other steps can be used to modify the process of this invention,
such as rapidly heating the material from the calcining temperature
to the sintering temperature, centrifuging the dispersion to remove
sludge, waste, etc. Moreover, this process can be modified by
combining two or more of the process steps, if desired.
Conventional process steps that can be used to modify the process
of this invention are more fully described in U.S. Pat. No.
4,314,827, incorporated herein by reference.
As shown in FIG. 8, a continuous process can be used to make the
abrasive particles of this invention. The apparatus 60 in FIG. 8
comprises a mold 62, a driving mechanism 64, a die body 66,
leading-edge wiper blades 68, levelling doctor blades 70, an oven
72, a collecting pan 74, and a brush 76. Referring now to FIG. 9,
an extrudable dispersion containing particles "P" of a material
that can be converted into alpha alumina (hereinafter "convertible
material") in a liquid is provided to a supply means 80 for
delivery to die body 66. Typical supply means can comprise a
combination kneader and extruder 82, which includes twin,
counter-rotating mixing blades that mix and pack the convertible
material into an auger channel 84 for delivery through exit port 86
by a supply auger 88. Mixing and packing the convertible material
aids in preventing voids that may produce a nonuniform sheet. The
exit port 86 is connected to a pump 90, which pressurizes the
convertible material and supplies it to a feed port 92 of die body
66.
Die body 66 includes a longitudinal bore 100 therein having first
and second ends 102 and 104, respectively. Feed port 92
communicates the exterior of die body 66 with bore 80 adjacent
second end 104. An auger 106 having first and second ends 108 and
110, respectively, is disposed within bore 100. Auger 106 comprises
a longitudinal root and a helical flight adjoining the root along
the length thereof. The flight diameter of auger 106 is constant,
and the root has a first diameter at the first end 108, and a
second diameter smaller than the first diameter at the second end
110. The flight depth of auger 106 is therefore greatest near feed
port 92, and gradually decreases toward the first end 108 of auger
106, although the overall flight diameter is constant. The material
conveying capacity of auger 106 thus gradually decreases along the
length of the auger due to the gradually decreasing flight
depth.
Die body 66 includes one or more elongate die openings 112 that
communicate the exterior of die body 66 with bore 100 along the
length of auger 106. In the preferred embodiment, die body 66
includes a single elongate die opening 112 that is adapted to form
a uniform sheet member having a width substantially in excess of
its thickness. The combination of the position of die opening 112
relative to auger 106 and the configuration of auger 106 tends to
produce a uniform extruded sheet 114 of convertible material.
A motor 116 rotates auger 106 within bore 100 to extrude the
convertible material in sheet form. The proper rotational speed of
auger 106 may be experimentally or analytically determined to
provide the desired uniform rate of extrusion. If auger 106 is
rotated too slowly, excess convertible material may be discharged
through the portion of die opening 112 nearest second end 104.
Similarly, if auger 106 is rotated too quickly, excess convertible
material may be discharged through the portion of die opening 112
nearest first end 102. At the proper rotational velocity, the
pressure along bore 100 is uniform, thereby forcing a sheet of
uniform thickness through die opening 112.
The dispersion is forced into cavities (not shown) of the mold 62
as it passes through the die opening 112. The die opening 112 is in
close registry with mold 62. The distance between the die opening
112 and the mold 62 is preferably about 0.2 inch (0.51 cm). The
mold 62 of FIG. 8 is a flexible belt, which is driven by the
driving mechanism 64. It is preferred to run the belt at a fixed
rate. The cavities in the mold 62 can have any desired geometric
shape, such as triangular, circular, or square. The cavities can be
formed by conventional means, such as by machining, punching, or
etching. The cavities can extend completely through the belt, such
that the belt has a multiplicity of perforations therein. The
flexible belt 62 can be made of any material that will withstand
the operating conditions of the process. A belt made of metal such
as stainless steel or aluminum is preferable. It is preferred that
the mold 62 be coated with a release coating, such as
polytetrafluoroethylene, to improve the release of the dried
precursor particles from the cavities of the mold 62.
It is preferred that the exposed surface or surfaces of the
dispersion in the cavities not extend substantially beyond the
plane of the belt in order to guarantee that the abrasive particles
prepared from the process be substantially uniform. Any excess
dispersion surrounding the openings of the cavities and remaining
on the non-recessed portion of the belt 62 is removed, preferably
by leading-edge wiper blades 68 positioned down the belt 62 from
the die body 66. The top and bottom surfaces of the belt 62 can be
wiped by the leading-edge wiper blades 68. These blades 68 are
mounted between leveling doctor blades 70 and the die body 66. The
leveling doctor blades 70 further ensure that abrasive precursor
particles will have a uniform thickness.
The filled cavities in the belt 62 are moved into the oven 72,
which is preferably an air circulating oven. The oven temperature
is preferably set at approximately 75.degree. C. However, the oven
temperature can be higher or lower depending on the speed of the
belt 62 and solids content of the dispersion. The dispersion in the
mold cavity retains sufficient liquid to remain sufficiently sticky
to adhere or stick to similar dispersion material if placed into
contact. The dispersion is also sufficiently sticky to remain
adhered to the belt. The volatile component of the liquid is
removed from the dispersion in the oven 72. Care should be taken to
solidify the dispersion sufficiently slowly so that the formation
of cracks in the abrasive particles is minimized. As the volatile
component is removed, the precursors of the abrasive particles
begin to form. Because their volume is less than that of the
dispersion from which they are formed, they will fall out of the
cavities in the belt 62, and can be collected in a collecting pan
74. The shaped, dried precursors of the abrasive particles are then
calcined and fired, preferably in a rotary kiln (not shown). Firing
is preferably carried out at a temperature of 1300.degree. C. to
1400.degree. C. for a period of 1 to 15 minutes. Any precursor
material remaining on the belt 62 or in the cavities of the belt
can be removed, preferably by a rotating brush 76 or other cleaning
process.
The second aspect of this invention pertains to abrasive particles
having specified three-dimensional shapes. In particular, abrasive
particles of this invention are preferably in the shape of bodies
having a front face and a back face, the front face and the back
face being separated by the thickness of the particle. The front
face and the back face have substantially the same geometric shape.
The geometric shape can be triangular, rectangular, circular,
elliptical, or that of other regular or irregular polygons. The
most preferred geometric shape is triangular. For the purposes of
this invention, triangular shapes also include three-sided polygons
wherein one or more of the sides can be arcuate, i.e., the
definition of triangular extends to spherical triangles. Of
triangular shapes, that of an equilateral triangle is the most
preferred. FIG. 4 illustrates a picture taken at 12.times.
magnification of a triangular-shaped abrasive particle. FIG. 5
illustrates a picture taken at 12.times. magnification of a
square-shaped abrasive particle. FIG. 6 illustrates a picture taken
at 12.times. magnification of a circular-shaped abrasive
particle.
In most cases, the ratio of the length of the shortest facial
dimension of the abrasive particle to the thickness of the abrasive
particle is at least 1 to 1, preferably at least 2 to 1, more
preferably at least 5 to 1, most preferably at least 6 to 1. As
used herein, the term "thickness", when applied to a particle
having a thickness that varies over its planar configuration, shall
mean the minimum thickness. If the particle is of substantially
uniform thickness, the values of minimum, maximum, mean, and median
thickness shall be substantially equal. For example, in the case of
a triangle, if the thickness is equivalent to "a" the length of the
shortest side of the triangle is preferably at least "2a". In the
case of a particle in which two or more of the shortest facial
dimensions are of equal length, the foregoing relationship
continues to hold. In most cases, the abrasive particles are
polygons having at least three sides, the length of each side being
greater than the thickness of the particle. In the special
situation of a circle, ellipse, or a polygon having very short
sides, the diameter of the circle, minimum diameter of the ellipse,
or the diameter of the circle that can be circumscribed about the
very short-sided polygon is considered to be the shortest facial
dimension of the particle. If an abrasive particle is prepared in a
mold cavity having a pyramidal, conical, frusto-pyramidal,
frusto-conical, truncated spherical, or a truncated spheroidal
shape, the thickness is determined as follows: (1) in the case of a
pyramid or cone, the thickness is the length of a line
perpendicular to the base of the particle and running to the apex
of the pyramid or cone; (2) in the case of a frusto-pyramid or
frusto-cone, the thickness is the length of a line perpendicular to
the center of the larger base of the frusto-pyramid or of the
frusto-cone and running to the smaller base of the frusto-pyramid
or of the frusto-cone; (3) in the case of a truncated sphere or
truncated spheroid, the thickness is the length of a line
perpendicular to the center of the base of the truncated sphere or
truncated spheroid and running to the curved boundary of the
truncated sphere or truncated spheroid. The length of the shortest
facial dimension of the particle is the length of the shortest
facial dimension of the base of the particle (if the particle has
only one base) or the length of the shortest facial dimension of
the larger base of the particle (if the particle has two bases).
The thickness of the particles preferably range from about 25
micrometers to 500 micrometers. This aspect ratio provides improved
performance of the abrasive particle as compared with conventional
unshaped abrasive grits.
The abrasive particles of this invention can be used in coated
abrasive articles, bonded abrasive articles, non-woven abrasive
articles, and abrasive brushes. The abrasive articles listed can
contain up to 100% of the abrasive particles of this invention.
Additionally, the abrasive articles may contain a blend of the
abrasive particles of this invention along with conventional
abrasive grains or diluent grains. Representative examples of
materials of conventional abrasive grains include fused aluminum
oxide, silicon carbide, garnet, fused alumina zirconia, cubic boron
nitride, diamond, and the like. Representative examples of
materials of diluent grains include marble, gypsum, and glass.
However, at least 10% by weight, preferably 50 to 100% by weight,
of the abrasive particles or grains of the abrasive articles of
this invention should be of the type of abrasive particle of this
invention. Blends of different shapes of the abrasive particles of
this invention can be used in the articles containing the abrasive
particles. The alumina based, ceramic abrasive particles of this
invention may also have a surface coating. Surface coatings are
known to improve the adhesion between abrasive grains and the
binder in abrasive articles. Additionally, the surface coating may
prevent the abrasive particle from capping. Capping is the term to
describe the phenomenon where metal particles from the workpiece
being abraded become welded to the tops of the abrasive particles.
Such surface coatings are described in U.S. Pat. Nos. 5,011,508;
1,910,444; 3,041,156; 5,009,675; 5,085,671; 4,997,461; and
5,042,991, all of which are incorporated herein by reference.
Referring to FIG. 3, coated abrasive article 30 comprises a backing
32 having a first layer of binder 34, hereinafter referred to as
the make coat, applied over one major surface of backing 32.
Partially embedded in make coat 34 are a plurality of abrasive
particles 36. Over the abrasive particles 36 is a second layer of
binder 38, hereinafter referred to as the size coat. The purpose of
make coat 34 is to secure abrasive particles 36 to backing 32 and
the purpose of size coat 38 is to reinforce abrasive particles 36.
It is preferred that a portion of the abrasive particles have a
triangular-shape. These abrasive particles will hereinafter be
designated as triangular-shaped abrasive particles. Of these
triangular-shaped abrasive particles, from about 35% to about 65%
are oriented on the backing with a vertex 40 of the triangle
pointing away from the backing as illustrated by FIG. 3. The
remainder of these triangular-shaped abrasive particles are
oriented with a base 42 of the triangle pointing away from the
backing. However, up to 20% of the particles may not be oriented in
either of the preceding ways, e.g., they may lay against the
backing with the triangular face of the particle being in contact
with the make coat. As used herein, the phrase "vertex pointing
away from the backing" means that a base of the triangular-shaped
particle is adhered to the backing via the make coat; the phrase
"vertex pointing away from the backing" also includes those
situations in which the line corresponding to the altitude of the
triangular-shaped particle is tilted from the perpendicular at a
small angle, typically less than 45.degree., preferably less than
30.degree.. As used herein, the phrase "base pointing away from the
backing" and the like means that a vertex of the triangular-shaped
particle is adhered to the backing via the make coat; the phrase
"base pointing away from the backing" includes those situations in
which the line corresponding to the altitude of the
triangular-shaped particle is tilted from the perpendicular at a
small angle, typically less than 45.degree., preferably less than
30.degree..
During the manufacture of the coated abrasive article, the
triangular-shaped abrasive particles are applied into the make coat
by electrostatic coating techniques. Electrostatic coating causes a
portion of the triangular-shaped abrasive particles to be oriented
with a base pointing away from the backing and a portion to be
oriented with a vertex pointing away from the backing. This manner
of orientation results in improved performance of the coated
abrasive article. Additionally, this manner of orientation results
in a coated abrasive article in which the sum of the surface areas
of the triangular-shaped abrasive particles in contact with the
workpiece remains essentially constant during abrading, even though
the surface area of any individual abrasive particle in contact
with the workpiece varies during abrading.
It is to be expected that a small number of triangular-shaped
abrasive particles will fail to become adhered to the backing by
way of a base or a vertex and will lie flat on the make coat such
that the triangular face is in contact with the binder. These
particles will perform no cutting. The number of particles lying
flat will increase at lower weights of abrasive mineral. During
electrostatic deposition of the abrasive particles, preferred
orientation of the abrasive particles is easier to maintain when
the space between the particles is so small that the particles do
not have sufficient room to tip over during deposition.
Preferably, throughout the abrading process, the total surface area
of the layer of abrasive particles in contact with the workpiece
will essentially remain constant. However, during abrading, the
surface area of the individual abrasive particles in contact with
the workpiece will vary. This effect can be achieved in the case in
which about 35% to about 65% of the abrasive particles have their
vertices pointing away from the backing and about 35% to about 65%
of the abrasive particles have their bases pointing away from the
backing. The cut and surface finish of the workpiece will remain
essentially consistent throughout the useful life of the abrasive
article.
The triangular-shaped abrasive particles can be oriented so that
the vertices of substantially all of the triangular-shaped abrasive
particles point away from the backing. This embodiment is shown in
FIG. 7. Referring to FIG. 7, coated abrasive article 50 comprises a
backing 52 having a first layer of binder 54, hereinafter referred
to as the make coat, applied over one major surface of backing 52.
Partially embedded in make coat 54 are a plurality of abrasive
particles 56. Over the abrasive particles 56 is a second layer of
binder 58, hereinafter referred to as the size coat. The purpose of
make coat 54 is to secure abrasive particles 56 to backing 52 and
the purpose of size coat 58 is to reinforce abrasive particles 56.
Some of the abrasive particles 56, generally no more than 20%, may
be oriented in such a way that their vertices are not pointing away
from the backing 52. Of course, the backing, the abrasive
particles, the make coat, and the size coat can be made from the
same materials that are useful for making the coated abrasive
article of FIG. 3.
The following examples are illustrative of specific embodiments of
this invention; however, these examples are for illustrative
purposes only and are not to be construed as limitations upon the
invention.
The following procedures were used for Examples 1-10.
Procedure for Making Shaped Abrasive Particles
A dispersion (44% solids) was made by the following procedure:
alpha aluminum oxide monohydrate powder (1,235 parts) having the
trade designation "DISPERAL" and alpha iron oxide (206 parts, 10%
FeOOH) were dispersed by continuous mixing in a solution containing
water (3,026 parts) and 70% aqueous nitric acid (71 parts). The sol
that resulted was mixed with magnesium nitrite (429 parts) to form
a gel which was then dried at a temperature of approximately
125.degree. C. in a continuous dryer to produce the 44% solids
dispersion. The dispersion was introduced into the cavities of the
desired shape in a mold by means of a rubber squeegee. The cavities
contained a release coating, either a silicone material or
polytetrafluoroethylene. The filled mold was placed in a forced air
oven maintained at a temperature of 71.degree. C. for 20 minutes.
The dispersion underwent substantial shrinkage as it dried, and the
dried precursors of the abrasive particles shrank in the cavities.
The precursors of the abrasive particles were removed from the mold
by gravity. After the precursors of the abrasive particles were
removed from the mold, they were dried at a temperature of
121.degree. C. for three hours.
The dried precursors of the abrasive particles were introduced into
the end of a calciner, which can be described as a 23 cm diameter,
4.3 m long stainless steel tube having a 2.9 m hot zone, the tube
being inclined at 2.4.degree. with respect to the horizontal, and
rotating at 6 rpm, providing residence time therein of about 15
minutes. The entry end temperature of the hot zone was 350.degree.
C. and the exit end temperature of the hot zone was 800.degree. C.
The material exiting the calciner was introduced into a kiln held
at a temperature of about 1,390.degree. C. The kiln was a 8.9 cm
diameter, 1.32 m long silicon carbide tube inclined at 4.4.degree.
with respect to the horizontal, having a 76 cm hot zone, and
rotating at 10.5 rpm, providing a residence time therein of about
four minutes. The material exited the kiln into air at room
temperature, where it was collected in a metal container and
allowed to cool to room temperature.
Procedure for Making and Testing Coated Abrasive Articles
The abrasive particles of the examples described herein were
utilized in coated abrasive articles made according to a
conventional procedure for preparing coated abrasive articles. The
abrasive particles were first screened to a screen size of 16-20
mesh U.S. Standard. A make coat was applied to a vulcanized fiber
backing in the shape of a disc by means of a paint brush. The make
coat consisted of conventional calcium carbonate-filled resole
phenolic resin. The abrasive particles were projected into the make
coat by means of a conventional electrostatic coating technique. A
size coat consisting of conventional calcium carbonate-filled
resole phenolic resin was applied over the abrasive particles and
make coat by means of a paint brush. The concentration of calcium
carbonate was 52% by weight and the concentration of resin was 48%
by weight in the make coat and the size coat. The resin of the make
coat was precured for 90 minutes at a temperature of 88.degree. C.
and the resin of the size coat was precured for 90 minutes at a
temperature of 88.degree. C. followed by a final cure of 10 hours
at a temperature of 100.degree. C. The approximate coating weights
were 160 g/m.sup.2 for the make coat, 905 g/m.sup.2 for the layer
of abrasive particles, and 987 g/m.sup.2 for the size coat.
The cured coated abrasive articles, which were in the form of discs
(having a diameter of 7 inches), were first flexed in a
conventional manner to controllably fracture the hard bonding
resins, then mounted on a beveled aluminum back-up pad, and used to
grind the face of a 1.25 cm by 18 cm 1018 mild steel workpiece. The
disc was driven at 5,000 rpm while the portion of the disc
overlaying the beveled edge of the back-up pad contacted the
workpiece at 6.81 kg load, generating a disc wear path of about 140
cm.sup.2. Each disc was used to grind a separate workpiece for one
minute each for a total time of 12 minutes for each disc or for
sufficient one minute time intervals until no more than 5 g of
metal were removed from the workpiece in any one minute time
interval. The performance of the coated abrasive article is
generally stated as a percent of Comparative Example A, that is,
the total amount of metal removed from the workpiece by the coated
abrasive article of Comparative Example A was set at 100% and the
amount of metal removed by the coated abrasive article of the
example was reported as a percent of that removed by the coated
abrasive article of Comparative Example A. For example, a coated
abrasive article made with abrasive particles according to one of
the working examples that performed 10% better than the coated
abrasive article of Comparative Example A has a performance of 110%
of the article of Comparative Example A.
EXAMPLE 1
This example demonstrates the grinding performance of coated
abrasive articles employing triangular-shaped abrasive particles
prepared according to the Procedure for Making Shaped Abrasive
Particles. The mold used to make the abrasive particles had
cavities in the shape of an equilateral triangle, the length of
each side of each cavity being 0.29 cm, and the depth of each
cavity being 0.05 cm. The abrasive particles formed from this mold
were triangular-shaped and had dimensions approximately 0.157 cm on
each side and 0.028 cm thick (FIG. 1). The performance of coated
abrasive articles employing the triangular-shaped abrasive
particles was compared with coated abrasive articles employing
equivalent screen sized (16-20 mesh U.S. Standard) randomly-shaped
abrasive grains as described in Comparative Example A.
COMPARATIVE EXAMPLE A
The abrasive grains utilized in Comparative Example A were
commercially available from Minnesota Mining and Manufacturing
Company, St. Paul, Minn., under the trade designation of CUBITRON
abrasive grain. CUBITRON abrasive grain comprises 93.5% alpha
aluminum which was nucleated with 2% by weight of iron oxide and
4.5% magnesium oxide. The abrasive grain was employed in a coated
abrasive article and tested as described above.
EXAMPLE 2
This example demonstrates the grinding performance of coated
abrasive articles employing disc-shaped abrasive particles prepared
according to the Procedure for Making Shaped Abrasive Particles.
The disc-shaped abrasive particles were prepared by using a mold
having cavities 0.23 cm in diameter and 0.05 cm deep (FIG. 6). The
performance of the coated abrasive articles employing the
disc-shaped abrasive particles was compared with coated abrasive
articles employing the triangular-shaped abrasive particles of
Example 1.
EXAMPLE 3
This example demonstrates the grinding performance of coated
abrasive articles employing square-shaped abrasive particles. The
abrasive particles were prepared according to the Procedure for
Making Shaped Abrasive Particles. The square-shaped abrasive
particles were prepared using a mold having cavities 0.23 cm on
each side and 0.06 cm deep (FIG. 5). The performance of coated
abrasive articles employing the square-shaped abrasive particles
was compared with the coated abrasive articles employing the
triangular-shaped abrasive particles of Example 1. Grinding
performance of the foregoing examples is set forth in Table I.
TABLE I ______________________________________ Total cut (% of
Example Shape of grain Comparative Example A)
______________________________________ Comparative A Random 100 1
Triangular 174 2 Disc 78 3 Square 114
______________________________________
The coated abrasive disc having the triangular-shaped abrasive
particles showed 74% improvement in total cut, and the disc having
the square-shaped abrasive particles showed 14% improvement in
total cut over the disc having the randomly-shaped abrasive
particles.
EXAMPLE 4
This example demonstrates the orientation of triangular-shaped
abrasive particles when coated onto a fiber backing in an
electrostatic field. Triangular-shaped abrasive particles were
prepared as in Example 1. Fiber discs were prepared according to
the Procedure for Testing and Making Coated Abrasive Articles.
The fiber discs bearing abrasive particles were observed under a
low power microscope (10.times.) and the number of particles with a
vertex pointing away from the backing and the number of particles
with the base pointing away from the backing in the field were
determined for four discs. Orientation of the particles is set
forth in Table II.
TABLE II ______________________________________ Percentage of
Percentage of particles having particles having vertex pointing
base pointing Disc away from backing.sup.1 away from backing.sup.1
______________________________________ I 53% 47% II 50% 50% III 65%
35% IV 55% 45% ______________________________________ .sup.1 Less
than 5% of the abrasive particles were oriented so that neither
their vertices nor bases pointed away from the backing.
When the abrasive particles are coated in an electrostatic field,
most of the particles orient so that a vertex point either toward
or away from the backing and only a small percentage of particles
lie flat. Moreover, the triangular-shaped abrasive particles orient
such that approximately 50% have a vertex pointing away from the
backing and approximately 50% have a base pointing away from the
backing.
EXAMPLE 5
This example demonstrates the nature of the surface finish produced
by coated abrasive articles employing triangular-shaped abrasive
particles prepared as in Example 1. The coated abrasive articles of
Comparative Examples B, C, and D employed randomly-shaped abrasive
grains made by conventional methods. These grains were screened to
ANSI grades 24, 36, and 50, respectively (ANSI Standard B74.18,
1984). The chemical composition of the abrasive grains of
Comparative Examples B, C, D was the same as that of the abrasive
particles of Example 1. The coated abrasive articles, i.e., discs,
of Comparative Examples B, C, and D were made of the same material
as described in Comparative Example A. The surface finish was
determined by grinding the paint off a 15 cm.times.60 cm steel
panel with a 6,000 rpm Black & Decker electric grinder. The
surface finish of the steel was measured by using a Taylor-Hobson
Surtronic 3 profile meter. The surface finish produced by the
various discs is set forth in Table III. As used herein, "Ra" means
the arithmetical mean deviation of the profile of the scratch;
"Rtm" means the maximum peak-to-valley height of the profile of the
scratch.
TABLE III ______________________________________ Ra Rtm Example
(micrometers) (micrometers) ______________________________________
5 4.1 25.1 Comparative B 7.8 41.9 Comparative C 6.9 37.2
Comparative D 4.5 25.6 ______________________________________
The surface finish produced by the coated abrasive disc having
triangular-shaped abrasive particles was superior to the finish
produced by the discs of the Comparative Examples B and C. The
finish produced by the triangular-shaped abrasive grains was
essentially the same as that produced by the disc of Comparative
Example D.
EXAMPLE 6
This example demonstrates grinding performance of coated abrasive
articles employing triangular-shaped abrasive particles prepared as
in Example 1.
The discs were tested according to the Procedure for Testing and
Making Coated Abrasive Articles, except that the test was extended
by one-minute intervals to the point at which each disc removed the
same amount of metal in the final one-minute interval. The discs
were compared with those of Comparative Example A. The results are
set forth in Table IV.
TABLE IV ______________________________________ Duration to reach
Amount of metal Example end point (min) removed by end point (g)
______________________________________ 6 26 2515 Comparative A 12
1033 ______________________________________
This example demonstrates that a disc having triangular-shaped
abrasive grains has a longer life than does a disc employing
conventional "CUBITRON" grains. The disc of this invention removed
143% more metal before reaching the equivalent end point.
EXAMPLE 7
This example demonstrates the grinding performance of coated
abrasive articles employing blends of triangular-shaped abrasive
particles of this invention and diluent grains, such as marble. The
triangular-shaped abrasive particles were prepared according to the
Procedure for Making Shaped Abrasive Particles. The mold used to
make the abrasive particles had cavities 0.190 cm on each side and
0.03 cm deep. The particles made with this mold were
triangular-shaped and equivalent in size to 25-30 mesh U.S.
Standard screen. The triangular-shaped abrasive particles were
blended with ANSI 36 marble on an equal weight basis. The abrasive
particle/marble blend was coated at a weight of 820 g/m.sup.2. The
weight of the make coat was 160 g/m.sup.2. The weight of the size
coat was 655 g/m.sup.2. The abrasive grains in Comparative Example
E (ANSI 36) was prepared as described in Comparative Example A. The
discs were tested as in Procedure for Testing Coated Abrasive
Articles. The results are set forth in Table V.
TABLE V ______________________________________ Total cut Example (%
of Comparative Example E) ______________________________________
Comparative E 100 7 114 ______________________________________
This example demonstrates that a disc having a blend of
triangular-shaped abrasive grains and marble showed 14% improvement
in total cut over a disc having conventional sol-gel abrasive
grains of random shape.
EXAMPLE 8
This example demonstrates the grinding performance of
triangular-shaped abrasive particles at high grinding pressures.
The samples were prepared and tested in the same manner as was used
in Example 1, except that the test load applied to the rotating
disc was increased to 8.6 kg. The abrasive grains in Comparative
Example F were prepared as was described in Comparative Example A.
The disc in Comparative Example F used ANSI 24 "CUBITRON"
randomly-shaped abrasive grains. The results are set forth in Table
VI.
TABLE VI ______________________________________ Total cut (% of
Example Comparative Example F)
______________________________________ Comparative F 100 8 143
______________________________________
This example demonstrates that a disc having triangular-shaped
abrasive particles showed improved grinding performance over a disc
having randomly-shaped abrasive grains at high grinding
pressures.
EXAMPLE 9
This example demonstrates the grinding performance of
triangular-shaped abrasive particles. The triangular-shaped
abrasive particles were prepared and tested in the same manner as
was used in Example 1, with the exception that magnesium nitrite
was not added to the sol. The abrasive grains in Comparative
Example G were prepared according to U.S. Pat. No. 4,964,883. The
abrasive grains contained 98% by weight alpha alumina and 2% by
weight iron oxide nucleating a gent. The disc in Comparative
Example G used ANSI 36 "CUBITRON" randomly-shaped abrasive grains.
The results are set forth in Table VII.
TABLE VII ______________________________________ Total cut (% of
Example Comparative Example G)
______________________________________ Comparative G 100 9 136
______________________________________
This example demonstrates that a disc having triangular-shaped
abrasive particles that were free of magnesium oxide showed
superior grinding performance to that of a disc having
randomly-shaped abrasive grains.
EXAMPLE 10
This example demonstrates the grinding performance of
triangular-shaped abrasive particles blended with erodable
agglomerates. The triangular-shaped abrasive particles were
prepared in the same manner as was used in Example 1. The erodable
agglomerates were prepared according to U.S. Pat. No. 5,078,753,
Example 1. The erodable agglomerates used in this example were
capable of passing through a 16 mesh screen and being retained on a
30 mesh screen. The triangular-shaped abrasive particles and the
erodable agglomerates were blended. Discs were prepared and tested
in the manner described in Procedure For Making and Testing Coated
Abrasive Articles. The coating weight of the triangular-shaped
abrasive particles was 614 g/m.sup.2. The coating weight of the
erodable agglomerates was 205 g/m.sup.2. The coating weight of the
make coat was 160 g/m.sup.2. The coating weight of the size coat
was 1065 g/m.sup.2. The abrasive grain in Comparative Example H was
prepared in the same manner as was described in Comparative Example
A. The results are set forth in Table VIII.
TABLE VIII ______________________________________ Total cut (% of
Example Comparative Example H)
______________________________________ Comparative H 100 10 130
______________________________________
This example demonstrates that open coat constructions providing
good performance can be made with triangular-shaped abrasive
particles. The erodable agglomerates support the triangular-shaped
abrasive particles and provide good orientation for the
triangular-shaped abrasive particles.
EXAMPLE 11
In this example, precursors of abrasive particles were prepared by
means of the apparatus shown in FIG. 8. The dispersion for this
example was prepared under the same conditions as were described in
Procedures for Making Shaped Abrasive Particles. One lot of
triangular-shaped abrasive grains was prepared without the wiping
technique, and another lot was prepared with the wiping technique.
The abrasive grains in Comparative Example J were prepared in the
same manner as was described in Comparative Example A. Discs were
prepared and tested in the manner described in Procedure for Making
and Testing Coated Abrasive Articles. The results are set forth in
Table IX.
TABLE XI ______________________________________ Total cut (% of
Example Comparative Example J)
______________________________________ Comparative J 100 11
(without wiping) 119 11 (with wiping) 140
______________________________________
This example demonstrates that wiping of the filled web is
beneficial to the grinding performance of discs employing
triangular-shaped abrasive particles.
Various modifications and alterations of this invention will become
apparent to those skilled in the art without departing from the
scope and spirit of this invention, and it should be understood
that this invention is not to be unduly limited to the illustrated
embodiments set forth herein.
* * * * *