U.S. patent number 3,929,627 [Application Number 05/530,395] was granted by the patent office on 1975-12-30 for magnetic beneficiation for magnesite ores.
This patent grant is currently assigned to Financial Mining - Industrial and Shipping Corporation. Invention is credited to Antonios Frangiskos, Theodor Gambopoulos.
United States Patent |
3,929,627 |
Frangiskos , et al. |
December 30, 1975 |
Magnetic beneficiation for magnesite ores
Abstract
A process for the beneficiation of magnesite ores includes the
selective enhancement of the magnetic properties of the gangue
constituents so that said constituents can be easily separated by
magnetic separators.
Inventors: |
Frangiskos; Antonios (Athens,
GR), Gambopoulos; Theodor (Athens, GR) |
Assignee: |
Financial Mining - Industrial and
Shipping Corporation (Athens, GR)
|
Family
ID: |
10922932 |
Appl.
No.: |
05/530,395 |
Filed: |
December 6, 1974 |
Foreign Application Priority Data
Current U.S.
Class: |
209/9; 209/47;
209/214 |
Current CPC
Class: |
B03C
1/01 (20130101) |
Current International
Class: |
B03C
1/005 (20060101); B03C 1/01 (20060101); B03B
001/04 () |
Field of
Search: |
;209/5,9,214,47,49,38-40
;241/20,24 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Halper; Robert
Attorney, Agent or Firm: Watson, Cole, Grindle &
Watson
Claims
What is claimed is:
1. A process for the recovery of pure magnesite from magnesite ores
containing magnesite, serpentine and other gangue material,
comprising:
crushing a quantity of magnesite ore;
conditioning the crushed ore in an aqueous suspension containing by
volume 1 percent diesel oil and 0.15 percent of a mixture of
cationic collectors comprising quaternary ammonium chlorides and
primary amines for activating the surface of the serpentine and the
other gangue material;
again conditioning the crushed ore in a suspension of a finely
divided strongly ferromagnetic material so as to achieve selective
absorption on the surface of the serpentine and the other gangue
material as well as on the strongly siliceous and carbonaceous
particles of the ore; and
removing the serpentine and the other gangue material as well as
the strongly siliceous and carbonaceous particles of the ore from
the remainder of the ore by means of a magnetic separator to obtain
a concentrate of magnesite.
2. The process according to claim 1, comprising the further step of
first classifying the crushed magnesite ore into particle size
fractions of less than 1 mm., 1 mm. to 15 mm. and greater than 15
mm., each of the fractions being separately subjected to the
recovery process.
3. The process according to claim 1, comprising the further step of
first subjecting the crushed magnesite ore to a mechanical
pre-concentration process to further effect a concentrate of the
magnesite.
4. The process according to claim 1, comprising the further step of
repeating the entire beneficiation process on the concentrate
obtained to improve its quality.
5. The process according to claim 3, comprising the further step of
repeating the entire beneficiation process on the concentrate
obtained to improve its quality.
Description
BACKGROUND OF THE INVENTION
This invention relates generally to a beneficiation process for
ores or minerals, and more particularly to such a process for the
recovery of pure magnesite from magnesite ores containing magnesite
serpentine and other gangue material.
SUMMARY OF THE INVENTION
In accordance with the invention a mineral is separated from its
gangue, or the gangue is separated from the mineral contained
therein, by artificially increasing in a selective manner the
magnetic properties of the mineral or the gangue. With the present
process the magnetic separation of diamagnetic or slightly
paramagnetic ores or minerals can be effected by using magnetic
separators, e.g., permanent magnets, of low or medium strength. The
increase of the magnetic properties of the ore or mineral to be
separated is achieved by selective absorption on the surface of one
or more constituents of the ore or mineral of a finely divided,
highly magnetic substance such as a magnetite or a ferrosilicon.
The thusly conditioned ore or mineral therefore has increased
magnetic properties.
Such selective absorption is achieved by conditioning the crushed
ore or mineral in an aqueous mixture of suitable reagents for
activating the surface of the constituents to be magnetically
separated. The crushed ore or mineral is again conditioned in an
aqueous suspension of a finely divided, strongly magnetic material
such as magnetite or ferrosilicon. This strongly magnetic material
is selectively absorbed on the surface of one or more constituents
of the ore or mineral and thus increases their magnetic properties.
The constituents of the ore or mineral that have absorbed the
strongly magnetic material are then separated from the remainder of
the constituents by means of a magnetic separat r so as to obtain a
concentrate of the remainder of the constituents.
After magnetic separation, recovery of the finely ground magnetic
material from the surface of the ore or mineral constituents is
carried out with water under pressure or with the use of
detergents, or by agitation in another magnetic field.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The ore or mineral is crushed into small particles, as for example
less than 15 mm., although particles larger than 15 mm. may be
subjected to the present process. The crushed ore or mineral is
then thoroughly washed and the various sized particles may be
classified into fractions of less than 1 mm., 1 mm. to 15 mm., and
greater than 15 mm. Each of the fractions are then conditioned for
about 10 to 20 minutes in an aqueous mixture of suitable reagents
for activation of the surface of the constituents thereof to be
magnetically removed. After undergoing such conditioning the
material is drained and fed into a second conditioner of a
suspension of finely ground magnetite or ferrosilicon materials and
is stirred for about 5 to 10 minutes.
After this further conditioning step, during which the selective
absorption of the magnetic material on the surface of the particles
to be magnetically removed takes place, the material is drained and
then fed into wet and dry magnetic separators for separating the
absorbed magnetic material from the remainder of the material so as
to obtain a concentrate of this remainder of the separated
material.
It should be pointed out that the crushed ore or mineral may be
first subjected to a mechanical pre-concentration process to
further ultimately effect a concentrate of the remainder of the
constituents.
This concentrate of non-magnetic material is washed and, according
to its purity, constitutes the intermediate or final product. This
concentrate can be further subjected to the beneficiation process
as above described so as to improve its quality. This will depend
on the quality of the first recovery treatment of the ore or
mineral, or upon the specifications required of the final
product.
The particles which absorbed the magnetic material may be
thoroughly washed with water under pressure or with the use of a
detergent, or by agitation in a magnetic field, so that the
absorbed film of the highly magnetic material may be removed. This
recovery of the finely ground magnetic material from the surface of
the ore or mineral constituents is carried out by known methods, as
for example thickening, washing, magnetic separation or the use of
a demagnetizing coil.
The above sequence is carried out separately on each granulometric
fraction as set forth hereinabove.
In particular, a magnesite ore containing slightly magnetic
serpentine and non-magnetic feldspars and silica was subjected to
the beneficiation process as in the manner above-described. The
first conditioning was carried out in an aqueous suspension of, by
volume, 1 percent diesel oil and 0.15 percent of a mixture of a
dialkyl quaternary ammonium chloride such as ARQUAD 2C-75 and
primary amines such as ARMAC T and ARMAC C. The first conditioning
lasted for ten minutes and the second conditioning step was carried
out in an aqueous suspension of finely ground magnetite of 1
percent by volume.
Magnetic separation of for example the 1 to 3 mm. fraction yielded
a product of pure magnesite with 0.72 percent SiO.sub.2 and 1.08
percent CaO, by volume, constituting a fraction of 36.4 percent of
the magnesite ore feed which has an analysis of 16.92 percent
SiO.sub.2 and 4.9 percent CaO. The reagents used for activation of
the surface of the constituents of the ore to be magnetically
separated are the same as those used for the flotation process
disclosed in commonly owned U.S. application Ser. No. 530,396,
filed on even date herewith. Only very small quantities of these
reagents are required for the present process thereby rendering the
first conditioning step quite economical.
Another advantage with the use of the present process is that
relatively coarse crushed ore can be used provided that the
intended concentration can be carried out for such sized particles.
The costly grinding operation normally required for flotation is
therefore avoided.
Other advantages of the present process are that simple, high
output devices such as wet magnetic separators may be used for the
magnetic separation, and an almost complete recovery of the
magnetic medium used is accomplished.
Obviously, many modifications and variations of the present
invention are possible in the light of the above teachings. It is
therefore to be understood that within the scope of the appended
claims, the invention may be practiced otherwise than as
specifically described.
* * * * *