U.S. patent number 3,927,199 [Application Number 05/388,325] was granted by the patent office on 1975-12-16 for hair fixing compositions containing n-alkyl acrylamide or methacrylamide interpolymer.
This patent grant is currently assigned to National Starch and Chemical Corporation. Invention is credited to Stuart H. Ganslaw, Gerard J. Legato, Albert L. Micchelli, Lawrence D. Schuler.
United States Patent |
3,927,199 |
Micchelli , et al. |
December 16, 1975 |
Hair fixing compositions containing N-alkyl acrylamide or
methacrylamide interpolymer
Abstract
Hair fixing compositions such as aerosol hair sprays and hair
setting lotions containing as the film forming resinous binder
therein an interpolymer derived from (1) N-alkyl acrylamides or
methacrylamides, (2) acidic film forming comonomers, and (3) at
least one polymerizable comonomer.
Inventors: |
Micchelli; Albert L.
(Middletown, NJ), Legato; Gerard J. (Stirling, NJ),
Ganslaw; Stuart H. (Piscataway, NJ), Schuler; Lawrence
D. (North Brunswick, NJ) |
Assignee: |
National Starch and Chemical
Corporation (Clifton, NJ)
|
Family
ID: |
26936432 |
Appl.
No.: |
05/388,325 |
Filed: |
August 13, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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244264 |
Apr 14, 1972 |
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Current U.S.
Class: |
424/47;
424/DIG.2; 524/473; 524/555; 526/923; 424/70.17; 526/303.1;
424/DIG.1; 524/379; 525/329.4 |
Current CPC
Class: |
C08F
20/54 (20130101); C08F 20/52 (20130101); A61Q
5/06 (20130101); A61K 8/8158 (20130101); Y10S
424/02 (20130101); Y10S 526/923 (20130101); Y10S
424/01 (20130101) |
Current International
Class: |
A61K
8/72 (20060101); A61K 8/81 (20060101); C08F
20/54 (20060101); C08F 20/52 (20060101); C08F
20/00 (20060101); A61Q 5/06 (20060101); A61K
007/11 () |
Field of
Search: |
;424/DIG.1,DIG.2,47,71,81,78
;260/78.5R,80.73,29.6T,29.6TA,29.6ME,33.8UA,33.4R |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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1,141,255 |
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Jan 1969 |
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UK |
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1,814,115 |
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Jul 1969 |
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DT |
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2,047,655 |
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Apr 1971 |
|
DT |
|
Primary Examiner: Rosen; Sam
Assistant Examiner: Clarke; Vera C.
Parent Case Text
This is a continuation-in-part application of our copending
application Ser. No. 244,264 filed Apr. 14, 1972, now abandoned.
Claims
We claim:
1. A hair fixing composition containing a solvent selected from the
group consisting of 1,1,1-trichloroethane, methylene chloride,
ethanol, isopropanol, and water, and from 0.25 to 7%, by weight, of
an interpolymer of (1) 30-60% of a comonomer selected from the
group consisting of N-alkyl acrylamide and N-alkyl methacrylamide
wherein the alkyl group thereof contains from 2 to 12 carbon atoms,
(2) 12-18% of an acidic copolymerizable comonomer selected from the
group consisting of acrylic acid, methacrylic acid, crotonic acid,
itaconic acid, maleic acid, fumaric acid, and the (C.sub.1
-C.sub.4) alkyl half esters of maleic and fumaric acids, and (3)
20-55% of at lest one copolymerizable comonomer selected from the
group consisting of (C.sub.1 -C.sub.12) alkyl acrylates, (C.sub.1
-C.sub.12) alkyl methacrylates, (C.sub.2 -C.sub.4) hydroxyalkyl
acrylates, hydroxystearyl acrylate, hydroxyalkyl methacrylates,
hydroxystearyl methacrylate, (C.sub.1 -C.sub.4) alkyl (C.sub.2
-C.sub.4) amino alkyl acrylates, (C.sub.1 -C.sub.4) alkyl (C.sub.2
-C.sub. 4) aminoalkyl methacrylates, vinyl acetate, vinyl
propionate, diacetone acrylamide, styrene, and alpha-methyl
styrene; said interpolymer being sufficiently neutralized with an
alkaline reagent to effect its solubility in water.
2. The hair fixing composition of claim 1, wherein from 50 to 100%
of the available carboxyl groups of the interpolymer are
neutralized with an alkaline reagent.
3. The hair fixing composition of claim 1, containing an
interpolymer of (1) 30-45% N-tert.octyl acrylamide, (2) 12-18%
acrylic or methacrylic acid, (3) 32-38% methyl methacrylate, (4)
2-10% hydroxypropyl acrylate, and (5) 2-10% of a (C.sub.1 -C.sub.4)
alkyl (C.sub.2 -C.sub.4) aminoalkyl acrylate or methacrylate.
4. The hair fixing composition of claim 3, wherein from 50 to 100%
of the available carboxyl groups of the interpolymer are
neutralized with an alkaline reagent.
5. The hair fixing composition of claim 1, wherein the composition
is in an aerosol container and also contains an aerosol propellant
therefor.
6. The hair fixing composition of claim 2, wherein the composition
is in an aerosol container and also contains an aerosol propellant
therefor.
7. The hair fixing composition of claim 3, wherein the composition
is in an aerosol container and also contains an aerosol propellant
therefor.
8. The hair fixing composition of claim 4, wherein the composition
is in an aerosol container and also contains an aerosol propellant
therefor.
9. A process for fixing hair comprising applying to the hair an
effective amount of the hair fixing composition of claim 1.
10. A process for fixing hair comprising spraying upon the hair an
effective amount of the hair fixing composition of claim 5.
Description
This invention relates to hair fixing compositions containing
unique film forming polymeric binders therein.
In order to be highly effective in hair fixing compositions such as
aerosol hair sprays and hair setting lotions, the film forming
polymeric binders utilized therein as well as the films derived
therefrom must meet a rigid set of requirements. Thus, the binders
used in such formulations should be soluble in anhydrous organic
solvents, yet the films cast from such hair fixing formulations
should, ordinarily, either be water soluble or water dispersible in
order to facilitate their easy removal from the user's hair. As is
readily visualized, this is an unusual combination of properties
which is further complicated by the requirement that the binder
used in such formulations be completely compatible with the
solvents and/or propellants ordinarily employed therein.
Furthermore, the binders used should show little or no tendency to
interact with the perfumes or other optional ingredients utilized
in hair fixing formulations.
In addition, the films cast from either aqueous or organic solvent
solutions of these binders should be flexible and should
simultaneously exhibit sufficient strength and elasticity; they
should exhibit good adhesion to hair so as to avoid the occurrence
of dusting or flaking when the hair is subjected to varying
stresses; they should readily allow the hair to be recombed; they
should maintain a non-tacky state despite humid conditions; they
should be clear, transparent and glossy and should possess good
antistatic properties; and they should be easily removable by the
use of water and/or soap or shampoo.
Needless to say, many polymeric systems have been utilized in an
attempt to meet these stringent requirements. Among these are
included: polyvinylpyrrolidone, copolymers of N-vinyl pyrrolidone
with vinyl acetate, 5-5'-dimethyl hydantoinformaldehyde resins, and
copolymers of methyl vinyl ethers and maleic acid half esters, etc.
Though each of the latter systems has met at least some of the
above cited requirements, none has exhibited all of these
requirements to an optimum degree.
It is the prime object of this invention to provide film forming
polymers for use as binders in hair fixing formulations, said
polymers exhibiting most or all of the above-described properties
required in such binders.
It is a further object to prepare effective aerosol hair sprays,
hair setting lotions and the like utilizing these polymeric
binders.
Various other objects and advantages of this invention will become
apparent from a reading of the disclosure which follows
hereinafter.
We have now discovered that all of the previously described
requirements for an effective hair fixing formulation are met by
utilizing the novel class of polymers hereinafter described as the
film forming binder component of the hair fixing compositions of
this invention. Particularly significant are the broadened
solubility and compatibility characteristics exhibited by these
binders. Thus, for example, they display a greater degree of
solubility in the organic solvents typically used in aerosol hair
sprays as well as in the aqueous solvent systems typically utilized
in wave set lotions. In addition, they exhibit greater
compatibility with the hydrocarbon propellants typically used in
aerosol hair sprays. Furthermore, if neutralization of these resins
is desired by the practitioner, the lower levels of neutralization
that can be used insure the deposition, onto the hair, of films
having a minimal degree of water sensitivity which, although they
are readily removable by washing, provide a greater degree of
holding power and thereby enable the thus treated hair to retain
its shape and body.
The film forming polymers (i.e. interpolymers) utilizable as
binders in the hair fixing compositions of this invention comprise
polymers containing moieties derived from (1) at least one
comonomer which is an N-alkyl acrylamide or methacrylamide, (2) at
least one acidic comonomer containing one or more available
carboxyl groups, and (3) at least one comonomer selected from a
group of copolymerizable comonomers.
The applicable N-substituted acrylamides or methacrylamides are
substituted with alkyl radicals containing from 2-12 carbon atoms.
Among the applicable acrylamides and methacrylamides are included
N-ethyl acrylamide, N-tertiary-butyl acrylamide, N-n-octyl
acrylamide, N-tertiary-octyl acrylamide, N-decyl acrylamide,
N-dodecyl acrylamide, as well as the corresponding
methacrylamides.
The following list of monomers are representative of the applicable
acidic film forming comonomers which contain at least one available
carboxylic acid group: acrylic acid, methacrylic acid, crotonic
acid, itaconic acid, maleic acid, fumaric acid and the C.sub.1
-C.sub.4 alkyl half esters of maleic and fumaric acids such, for
example, as methyl hydrogen maleate and butyl hydrogen fumarate as
well as any other acidic monomers which are capable of being
copolymerized with the particular interpolymer system whose use is
desired by the practitioner. As is known to those skilled in the
art, the acidic comonomer(s) must be so chosen as to be readily
polymerizable with the selected interpolymer system.
The acidic comonomers make it possible for the resultant copolymer
to be neutralized by reaction with an appropriate base in order
that it may ultimately exhibit the requisite water solubility.
These acidic comonomers may be neutralized prior to their being
incorporated into the ultimate hair fixing formulation thus
permitting these formulations to be removed from the hair merely by
rinsing with water. However, if such copolymers are not
pre-neutralized in this manner, removal may still be readily
effected by the application of an alkaline aqueous solution, for
example, soap and water. It should be noted that for purposes of
this invention the term "water solubility" is meant to include both
water solubility in its usual meaning as well as water
dispersibility wherein the resulting films are sufficiently
hydrated and softened by contact with water so as to be easily
removed from the hair by the application of water and either soap
or shampoo.
In order to modify or enhance certain properties of the polymeric
binder, for example, adherance to the hair, water solubility,
hardness, flexibility, antistatic properties, and the like, the
practitioner will utilize one or more of copolymerizable monomers
in the preparation of the polymeric binders of this invention.
Among these comonomers are the acrylic and methacrylic acid esters
of aliphatic alcohols having from 1-12 carbon atoms such as methyl,
ethyl, propyl, butyl, octyl and lauryl alcohols; hydroxyalkyl
esters of acrylic and methacrylic acids such as hydroxypropyl
acrylate and methacrylate, hydroxybutyl acrylate and methacrylate,
hydroxystearyl acrylate and methacrylate and hydroxyethyl acrylate
and methacrylate; alkyl (C.sub.1 -C.sub.4) amino alkyl (C.sub.2
-C.sub.4) esters of acrylic and methacrylic acids such as N, N' -
diethylaminoethyl acrylate, N-tert.-butylaminopropyl acrylate, N,
N' -dimethylaminoethyl methacrylate, N-tert.-butylaminoethyl
methacrylate and the quaternization product of dimethylaminoethyl
methacrylate and dimethyl sulfate, diethyl sulfate and the like;
diacetone acrylamide; vinyl esters such as vinyl acetate and vinyl
propionate; and styrene monomers such as styrene and alpha-methyl
styrene.
In order to provide binders which will function particularly
efficiently in the novel hair fixing compositions of this
invention, the interpolymer will contain from about 30-60% of the
N-substituted acrylamide or methacrylamide, from 10-20%, (and
12-18%, preferrably) of the acidic comonomer, and up to 55% of at
least one copolymerizable comonomer; these percentages being based
on the total weight of the interpolymer. The percentages given
herein and in the claims are to be taken so that the comonomers of
the interpolymer will total to 100%.
Applicants' preferred composition (preferred because of its
combination of excellent properties of curl retention, adherance to
the hair, clarity, gloss, and the like) will contain from 35-45% of
N-tert.-octyl acrylamide, from 12-18% of acrylic or methacrylic
acid, from 32-38% of methyl methacrylate, from 2-10% of
hydroxypropyl acrylate, and from 2-10% of an alkyl (C.sub.1
-C.sub.4) amino alkyl (C.sub.2 -C.sub.4) acrylate or
methacrylate.
As for the actual preparation of these polymeric film forming
binders, there may be employed any of the usual vinyl
polymerization methods which are well known to those skilled in the
art and which are particularly suited for the polymer whose
preparation is desired. Thus, the polymers may be prepared by means
of free radical initiated processes utilizing bulk, suspension,
solution, or emulsion polymerization techniques. The polymers may,
if desired, be converted into relatively large particles known as
beads or pearls by dispersing the solution polymerized polymer in
water and thereafter driving off the solvent followed by separating
and drying the particles.
It should be noted that the polymer binders of this invention may
be partially neutralized prior to their being incorporated into the
ultimate hair fixing formulation thus permitting them to be removed
from the hair merely by rinsing with water. This may be
accomplished by reacting the polymer, in the form of a solution in
an organic solvent, with or without added water, with a
concentration of an alkaline reagent (neutralizing agent) which is
equivalent on a molar basis to a minimum of about 50% of the
available carboxyl groups present on the polymer. Applicable
alkaline materials which may be utilized in this manner include:
sodium and potassium hydroxide; ammonia; primary, secondary and
tertiary amines; alkanolamines; and, hydroxyamines such as
2-amino-2-methyl-propanol and 2-amino-2-methyl-1,3-propanediol.
However, if such polymers are not pre-neutralized in this manner,
their eventual removal may still be readily effected by the
application of weak alkaline aqueous solution, e.g., soap and
water.
In utilizing the above-described polymeric binders in the
preparation of aerosol hair sprays, the other essential ingredients
which must be admixed therewith are a solvent and a propellant,
although in some instances the propellant will serve both the
latter functions. The preferred solvents are alcohols such as
ethanol and isopropanol. In addition to their solubility
properties, the prime advantages of these solvents are their
ability to dry quickly, their minimal effect on the metal
containers ordinarily utilized for these pressurized aerosol
formulations and their accepted use in cosmetic applications. Other
solvents which may be used include methylene chloride and
1,1,1-trichloroethane, etc.
Various types of aerosol propellants are well known to those
skilled in the art. Thus, the commonly used propellants include
trichlorofluoromethane, dichlorodifluoromethane, isobutane and
propane, etc., as well as mixtures of the latter propellants. These
propellants are readily compatible with the binder-solvent
solutions utilized in this invention.
In general, the method for preparing the hair spray formulations of
this invention merely involves dissolving or diluting the polymer
in the selected solvents, adding any modifying agents whose
presence may be desired, and thereupon combining the resulting
solution with the selected aerosol propellant.
Thus, it may be noted that the novel hair spray formulations of
this invention will in all cases contain at least three essential
components. The first of the latter components will be what may be
termed as the active ingredient comprising one or more of the
above-described polymers which serves as the binder for the
formulation. Secondly, there will be one or more solvents which
serve as vehicles for the binder. And, finally, there is the
propellant which serves to effect the discharge of the
aforedescribed binder and vehicle from the container wherein the
formulation is packaged. Water is not ordinarily present, but may
be included in some formulations.
With regard to proportions, the final hair spray formulations
typically contain the polymeric binder in a concentration ranging
from about 0.25 to 7%, by weight; the solvent in a concentration
ranging from about 8 to 90%, by weight; and, the propellant
concentration ranging from 10 to 85%, by weight. The latter
proportions should, however, be considered as being merely
illustrative inasmuch as it may well be possible to prepare
operable formulations having concentrations of components which
fall outside the above suggested ranges.
In addition, it should be noted that the unique film forming
polymers of this invention are equally effective when utilized in
hair setting lotions, which usually consist of a solution (or
dispersion) of the polymer in a suitable organic solvent, such as
alcohol, together with water. Such lotions may be directly applied
to the hair or they may be sprayed thereon utilizing conventional
spray nozzles. The application of such lotions may take place prior
to, during, or after the desired hair style has been achieved.
The latter hair lotions are prepared by merely admixing the film
forming polymer with the selected solvent, such solvents usually
comprising a mixture, with water, of an alcohol such as ethanol or
isopropanol. With regard to proportions, the lotions typically
contain from about 0.5 to 7%, by weight, of the polymeric binder,
while any desired ratio of alcohol to water in the solvent system
may be utilized therein. An all alcohol system may also be used in
some cases.
Optional additives may be incorporated into the hair fixing
formulations of this invention in order to modify certain
properties thereof. Among these additives may be included:
plasticizers such as glycols, phthalate esters and glycerine;
silicones; emollients, lubricants and penetrants such as lanolin
compounds, protein hydrolyzates and other protein derivatives,
ethylene oxide adducts, and polyoxyethylene cholesterol; U.V.
absorbers; dyes and other colorants; and, perfumes. As previously
noted, the polymeric binders of this invention show little or no
tendency to chemically interact with such additives.
The resulting hair fixing formulations exhibit all of the
characteristics required of such a product. Their films are
transparent, glossy, flexible, and strong. They possess good
antistatic properties, adhere well to hair, are easily removed by
soapy water or shampoos, allow the hair to be readily recombed, do
not yellow on aging, do not become tacky when exposed to high
humidities, and have excellent curl retention under high humidity
conditions.
In the following examples, which further illustrate the embodiment
of this invention, all parts given are by weight unless otherwise
indicated.
EXAMPLES 1-11
These examples illustrate a method for the polymerization of
typical polymers applicable for use in the hair fixing compositions
of this invention.
A reaction vessel fitted with a condenser and means for mechanical
agitation was charged with 60 parts tertiary-octyl acrylamide, 20
parts acrylic acid, 20 parts methyl methacrylate, 1.0 part benzoyl
peroxide and 100 parts of ethanol. The contents were heated to the
reflux temperature of the system and held there for a period of 6
hours whereupon an additional 1.0 part of benzoyl peroxide was
added thereto. The system was then held at reflux for an additional
4 hours whereafter the reaction was cooled to 30.degree.C and the
polymer No.1 recovered.
Additional polymers applicable for use in the hair fixing
formulations of this invention were also prepared by means of the
above-described procedure; the reagents and the concentrations in
which they were used to prepare the respective polymers being set
forth in the following table:
Parts Polymer (Example No.) Comonomers 2 3 4 5 6* 7* 8* 9* 10* 11*
__________________________________________________________________________
N-tert.-octyl methacrylamide 50 -- -- -- -- -- 40 60 -- --
N-tert.-octyl acrylamide -- 25 -- -- 30 40 -- -- -- --
N-tert.-butyl acrylamide -- 20 55 50 -- -- -- -- 35 40 Acrylic Acid
15 20 10 15 -- -- -- -- -- 15 Methacrylic Acid -- -- -- -- 15 15 --
20 10 -- Itaconic Acid -- -- -- -- -- -- 10 -- -- -- Methyl
Methacrylate -- 35 -- 35 35 15 -- -- 40 -- Methyl Acrylate 35 -- --
-- -- -- 25 -- -- 20 Tert.-Butyl Methacrylate -- -- 35 -- -- 20 --
-- -- -- Hydroxypropyl Methacrylate -- -- -- -- 10 -- 10 -- -- --
Hydroxypropyl Acrylate -- -- -- -- -- -- -- 5 5 -- Tert.-butyl
Aminoethyl -- -- -- -- -- -- -- 15 10 -- Methacrylate Dimethyl
Aminoethyl -- -- -- -- 10 5 -- -- -- -- Methacrylate
N.N'-Diethylaminoethyl -- -- -- -- -- 5 -- -- -- 5 Acrylate Vinyl
Acetate -- -- -- -- -- -- -- -- -- 20 Diacetone Acrylamide -- -- --
-- -- -- 15 -- -- --
__________________________________________________________________________
*Azobisisobutyronitrile substituted for benzoyl peroxide as free
radical initiator.
EXAMPLES 12-17
These examples illustrate a further method of polymerization
applicable to the instant invention.
A reaction vessel fitted with a condenser and means for mechanical
agitation was charged with 100 parts ethanol and 1.0 part benzoyl
peroxide. Thereafter the vessel was charged with 25% of a monomer
mix containing 40 parts tertiary-octyl acrylamide, 15 parts acrylic
acid, 35 parts methyl methacrylate, 5 parts hydroxpropyl acrylate
and 5 parts tertiary-butyl aminoethyl methacrylate. The system was
heated to its reflux temperature whereupon the remainder of the
monomer mix was added over a period of 4 hours. Upon completion of
the monomer addition, an additional 1.0 part of benzoyl peroxide
was added and the reaction held at reflux for further 4 hours. The
system was cooled and polymer No.12 recovered therefrom.
Additional copolymers applicable for use in the hair fixing
formulations of this invention were also prepared by the above
described procedure; the reagents and the concentrations in which
they were used to prepare the respective polymers being set forth
in the following table:
Parts Polymer (Example No.) Comonomers 13 14 15 16 17
______________________________________ N-decyl Methacrylamide -- --
-- 30 -- N-dodecyl Acrylamide 60 60 50 -- -- N-tert.-butyl
Acrylamide -- -- -- -- 40 Acrylic Acid 20 10 -- -- 10 Methacrylic
Acid -- 10 -- -- 5 Maleic Acid -- -- 15 -- -- Fumaric Acid -- -- --
10 -- Methyl Methacrylate 20 15 -- -- -- Methyl Acrylate -- -- 10
30 -- Iso-Butyl Methacrylate -- -- -- -- 25 Hydroxypropyl
Methacrylate -- -- -- 10 -- Hydroxypropyl Acrylate -- 5 10 -- 10
Quaternization product of -- -- -- -- 10 dimethyl- aminoethyl
methacrylate and dimethyl sulfate Styrene -- -- 15 20 --
______________________________________
EXAMPLES 18-23
These examples illustrate the preparation of aerosol hair spray
formulations typical of the novel products of this invention.
A solution of the desired polymer in anhydrous ethanol was prepared
and subsequently introduced into an aerosol container which had
been charged with the desired propellant to an internal pressure of
30 lbs. per square inch gauge. The various modifying agents were
added to the polymer-alcohol solutions prior to their introduction
into the propellant-charged aerosol container.
The reagents and the concentrations utilized for preparing the
various aerosol hair sprays are set forth in the following
table:
Parts Aerosol Spray (Example No.) 18 19 20 21 22 23
__________________________________________________________________________
Polymer No. 1 (dried) 0.50 -- -- -- -- -- Polymer No. 2 (dried) --
0.250 -- -- 7.000 -- Polymer No. 3 (dried) -- -- 0.500 2.000 -- --
Polymer No. 12 (dried) -- -- -- -- -- 0.50 2-amino-2 methyl
propanol -- 0.042 -- -- 1.750 -- 2-amino-2 methyl- -- -- 0.059
0.136 -- -- 1,3-propanediol Perfume oil 0.10 0.10 0.10 0.10 0.10
0.10 Polymethylpolysiloxane -- 0.250 -- -- -- -- Ethoxylated
lanolin oil 0.50 -- 0.500 -- -- 0.50 Propoxylated oleyl alcohol --
-- -- 0.400 -- -- Hydrolyzed protein -- -- -- -- 0.70 -- Anhydrous
ethanol 63.9 49.358 63.826 37.330 10.450 63.90 A 40:60 propellant
mixture of dichlorodifluorom- ethane and trichloro- fluoromethane
-- 50.0 -- -- 80.00 -- A 45:45:10 propellant mixture of trichloro-
fluoromethane: dichloro- difluoromethane: isobutane 35.0 -- 35.0 --
-- 35.00 Methylene Chloride -- -- -- 15.00 -- -- Vinyl Chloride --
-- -- 15.00 -- -- Isobutane -- -- -- 10.00 -- --
Dichlorodifluoromethane -- -- -- 20.00 -- -- % of available
carboxylic acid groups neutralized in polymer -- 55 100 58 81 --
__________________________________________________________________________
It was noted that each of the resulting hair sprays was completely
compatible. When utilized, each of the sprays deposited a film
which was characterized by its clarity, gloss and flexibility. Each
film retained its original non-tacky state and was resistant to the
build-up of electrostatic charge. It served to hold the desired
hair style in place while also allowing for its recombing. Of great
significance was the fact that it was readily removed from the hair
by the use of an aqueous soap solution.
EXAMPLES 24-26
These examples illustrate the preparation of wave setting lotions
typical of the products of this invention.
The lotions noted in the following table were prepared by charging
the specified ingredients into a reaction vessel equipped with
means for mechanical agitation.
______________________________________ Parts Wave Set Lotion
(Example No.) 24 25 26 ______________________________________
Polymer No. 2 (dried) 0.500 3.000 7.000 2-amino-2 methyl 0.156
0.750 1.300 propanol Anhydrous ethanol -- 46.25 91.70 Water 99.344
50.000 -- % of available carboxylic 100 80 60 acid groups
neutralized in polymer ______________________________________
When utilized, each of these wave setting lotions deposited a
clear, glossy, flexible film which was readily removed from the
hair by a thorough washing with water.
Summarizing, it is seen that this invention provides for the
preparation of novel hair fixing formulations which are
characterized by their excellent holding power as well as by their
ready removability.
Variations may be made in preparations, procedures and materials
without departing from the scope of the invention as defined by the
following claims:
* * * * *