U.S. patent number 3,926,716 [Application Number 05/452,610] was granted by the patent office on 1975-12-16 for transfer and adherence of relatively dry paper web to a rotating cylindrical surface.
This patent grant is currently assigned to The Procter & Gamble Company. Invention is credited to Gregory A. Bates.
United States Patent |
3,926,716 |
Bates |
December 16, 1975 |
Transfer and adherence of relatively dry paper web to a rotating
cylindrical surface
Abstract
In manufacturing a soft and absorbent tissue paper, a moist web
deposited from a fiber-water slurry, is contoured with the pattern
from an open mesh conveying fabric and thermally dried to a
relatively high fiber consistency. Following these steps, the
resulting relatively dry patterned web is imprinted as it is
transferred and adhered to a rotating cylindrical surface in the
form of a Yankee dryer utilizing an aqueous polyvinyl alcohol
solution where the polyvinyl alcohol is characterized by a
particular degree of hydrolysis and particular viscosity
characteristics. By thermally drying to a high fiber consistency
prior to the transfer step, the amount of drying load required to
be carried by the Yankee dryer is reduced resulting in either (1)
increased line speed as a result of reduced Yankee drying load,
which reduces the required residence time of the web on the dryer
or (2) a reduction in the required diameter of the Yankee dryer, a
significant reduction in capital equipment cost. By thermally
drying the web to a relatively high consistency on the conveying
fabric, a deeper more pronounced pattern in the Z direction is
obtained due to an increase in web structure strength and
resistance to compaction of the pattern. This results in increased
bulk (lower density) and increased softness. As a result of
utilizing the particular polyvinyl alcohol, transfer and adherence
of the relatively dry web to the Yankee dryer is obtained so as to
minimize the amount of skipped crepe whereby the problem of web
breakage downstream of creping is eliminated.
Inventors: |
Bates; Gregory A. (Cincinnati,
OH) |
Assignee: |
The Procter & Gamble
Company (Cincinnati, OH)
|
Family
ID: |
23797173 |
Appl.
No.: |
05/452,610 |
Filed: |
March 19, 1974 |
Current U.S.
Class: |
162/113;
162/168.1; 162/206 |
Current CPC
Class: |
D21F
11/14 (20130101); D21H 21/146 (20130101); D21F
11/006 (20130101); D21H 17/36 (20130101) |
Current International
Class: |
D21H
21/14 (20060101); D21F 11/14 (20060101); D21F
11/00 (20060101); D21H 17/00 (20060101); D21H
17/36 (20060101); B31F 001/12 () |
Field of
Search: |
;162/111,113,112,164,206,168 ;161/128 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Casey "Pulp & Paper," Vol. II (1960) p. 1141..
|
Primary Examiner: Bashore; S. Leon
Assistant Examiner: Chin; Peter
Attorney, Agent or Firm: Spector; Eric S. Braun; Fredrick
H.
Claims
I claim:
1. A process for manufacturing a soft and absorbent tissue paper
web having a uniform basis weight of about 5 to about 40 pounds per
3000 square feet, said process comprising the steps of
a. drying without compacting a moist paper web to provide a fiber
consistency exceeding about 68% and ranging up to about 98% while
said web is on a patterned imprinting fabric;
b. imprinting the resulting relatively dry web with the pattern of
the imprinting fabric;
c. applying an aqueous polyvinyl alcohol solution to cause transfer
and adherence of the imprinted web to a rotating cylindrical
surface, said polyvinyl alcohol being characterized by a degree of
hyrolysis ranging from about 80% to about 90% and a viscosity as a
4% aqueous solution at 20.degree.C. exceeding about 20
centipoises.
2. A process as recited in claim 1, in which said polyvinyl alcohol
is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
3. A process as recited in claim 2, in which said polyvinyl alcohol
is characterized by a degree of hydrolysis ranging from about 86%
to about 90%.
4. A process as recited in claim 3, in which the rotating
cylindrical surface is a Yankee dryer surface.
5. A process as recited in claim 1, in which the rotating
cylindrical surface is a Yankee dryer surface.
6. A process as recited in claim 5, in which said polyvinyl alcohol
is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
7. A process as recited in claim 1, in which said polyvinyl alcohol
solution is applied to provide an amount of polyvinyl alcohol on a
dry basis ranging from about 0.05 pounds to about 2 pounds per ton
of paper on a dry basis.
8. A process as recited in claim 7, in which said polyvinyl alcohol
solution is applied to provide an amount of polyvinyl alcohol on a
dry basis ranging from about 0.3 pounds to about 1 pound per ton of
paper on a dry basis.
9. A process for manufacturing a soft and absorbent tissue paper
web having a uniform basis weight of about 5 to about 40 pounds per
3000 square feet, said process comprising the steps of
a. causing a moist paper web to conform to the pattern of a
patterned imprinting fabric utilizing vacuum and then drying the
moist web on the fabric without compacting to provide a fiber
consistency exceeding about 68% and ranging up to about 98%;
b. imprinting the resulting relatively dry web with the pattern of
the imprinting fabric by use of roll pressure;
c. applying an aqueous polyvinyl alcohol solution to cause transfer
and adherence of the imprinted web to a rotating cylindrical
surface, said polyvinyl alcohol being characterized by a degree of
hydrolysis ranging from about 80% to about 90% and a viscosity as a
4% aqueous solution at 20.degree.C. exceeding about 20
centipoises.
10. A process for manufacturing a soft and absorbent tissue paper
web having a uniform basis weight of about 5 to about 40 pounds per
3000 square feet, said process comprising the steps of
a. drying a moist paper web to provide a fiber consistency
exceeding about 68% and ranging up to about 98% while said web is
on a patterned imprinting fabric without utilizing roll pressure to
compact the web;
b. imprinting the resulting relatively dry web with the pattern of
the imprinting fabric by use of roll pressure;
c. applying an aqueous polyvinyl alcohol solution to cause transfer
and adherence of the imprinted web to a rotating cylindrical
surface, said polyvinyl alcohol being characterized by a degree of
hydrolysis ranging from about 80% to about 90% and a viscosity as a
4% aqueous solution at 20.degree.C. exceeding about 20
centipoises.
11. A process for manufacturing a soft and absorbent tissue paper
web having a uniform basis weight of about 5 to about 40 pounds per
3000 square feet, said process comprising the steps of
a. drying a moist paper web to provide a fiber consistency
exceeding about 68% and ranging up to about 98% while said web is
on a patterned imprinting fabric by directing hot air at the
web;
b. imprinting the resulting relatively dry web with the pattern of
the imprinting fabric;
c. applying an aqueous polyvinyl alcohol solution to cause transfer
and adherence of the imprinted web to a rotating cylindrical
surface, said polyvinyl alcohol being characterized by a degree of
hydrolysis ranging from about 80% to about 90% and a viscosity as a
4% aqueous solution at 20.degree.C. exceeding about 20
centipoises.
12. A process as recited in claim 9, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
13. A process as recited in claim 12, in which said polyvinyl
alcohol is characterized by a degree of hydrolysis ranging from
about 86% to about 90%.
14. A process as recited in claim 13, in which the rotating
cylindrical surface is a Yankee dryer surface.
15. A process as recited in claim 9, in which the rotating
cylindrical surface is a Yankee dryer surface.
16. A process as recited in claim 15, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
17. A process as recited in claim 16, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.05 pounds to about 2
pounds per ton of paper on a dry basis.
18. A process as recited in claim 17, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.3 pounds to about 1
pound per ton of paper on a dry basis.
19. A process as recited in claim 10, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
20. A process as recited in claim 19, in which said polyvinyl
alcohol is characterized by a degree of hydrolysis ranging from
about 86% to about 90%.
21. A process as recited in claim 20, in which the rotating
cylindrical surface is a Yankee dryer surface.
22. A process as recited in claim 10, in which the rotating
cylindrical surface is a Yankee dryer surface.
23. A process as recited in claim 22, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
24. A process as recited in claim 23, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.05 pounds to about 2
pounds per ton of paper on a dry basis.
25. A process as recited in claim 24, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.3 pounds to about 1
pound per ton of paper on a dry basis.
26. A process as recited in claim 11, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% solution at
20.degree.C. above about 35 centipoises.
27. A process as recited in claim 26, in which said polyvinyl
alcohol is characterized by a degree of hydrolysis ranging from
about 86% to about 90%.
28. A process as recited in claim 27, in which the rotating
cylindrical surface is a Yankee dryer surface.
29. A process as recited in claim 11, in which the rotating
cylindrical surface is a Yankee dryer surface.
30. A process as recited in claim 29, in which said polyvinyl
alcohol is characterized by a viscosity as a 4% aqueous solution at
20.degree.C. above about 35 centipoises.
31. A process as recited in claim 30, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.05 pounds to about 2
pounds per ton of paper on a dry basis.
32. A process as recited in claim 31, in which said polyvinyl
alcohol solution is applied to provide an amount of polyvinyl
alcohol on a dry basis ranging from about 0.3 pounds to about 1
pound per ton of paper on a dry basis.
Description
BACKGROUND OF THE INVENTION
This invention relates to the manufacture of a soft and absorbent
paper web especially suitable for use in tissue, towelling and
sanitary products.
More particularly, this invention relates to a manufacturing
process where a moist web is carried on an open mesh conveying
fabric and is thermally dried. The thermally dried web is imprinted
with the conveying fabric pattern as it is transferred and adhered
to a rotating cylindrical surface in the form of a Yankee dryer.
This type of process is disclosed in Sanford et al. U.S. Pat. No.
3,301,746, commonly owned by the assignee of the present
invention.
It has been discovered that drying the paper web to a relatively
high consistency prior to imprinting is advantageous, and the more
thorough that drying is, the more significant the advantages that
are achieved. In the present context the term "imprinting" is
intended to mean the impression of the fabric imprinted into the
web at the time of its transfer to the Yankee dryer. It is
recognized that some fabric pattern impression is imparted to the
moist paper web while being carried on the fabric but this is not
to the same degree or extent which occurs in the imprinting step
when the web is transferred to the Yankee dryer.
To particularize these advantages, it is noted that increasing the
thermal drying of the web prior to its transfer to the rotating
cylindrical surface allows a reduction in the Yankee drying load;
and this allows an increase in line speed, since the amount of time
required by the rotating cylindrical surface to provide the final
fiber consistency is line speed limiting. And if thermal drying is
carried out to higher web consistencies prior to transfer to the
rotating cylindrical surface, not only is line speed increased, but
a smaller diameter Yankee dryer can be used, resulting in
significant savings in equipment costs.
Besides providing processing and equipment advantages, drying to a
relatively high degree prior to transfer to the rotating
cylindrical surface provides product advantages. In particular, the
drier the web is at the time of transfer, the more permanent is the
fabric impression in the Z direction, that is in the direction
perpendicular to the web major surfaces, in other words, a more
distinct and deeper impression is obtained. This improved
impression results in greater bulk (lower density) and increased
softness.
However, drying the web to relatively high fiber consistencies
prior to transfer to the rotating cylindrical surface to obtain the
above advantages can result in a problem in transferring and
adhering the relatively dry web to the cylindrical surface. In
particular, when the conventional animal glue disclosed at column
10, lines 23-29 of the Sanford et al. patent is utilized in an
attempt to improve the bond between the imprints and a Yankee dryer
surface, a problem of insufficient bonding is noted when the web to
be transferred has an average fiber consistency exceeding about
68%. As a result of this insufficient bonding, very few imprints
are in contact with the Yankee dryer so that the web is not
uniformly dried, and this non-uniformly dried state in conjunction
with the insufficient bonding results in a very irregular crepe
(that is, an excessive amount of skipped crepe). This very
irregular crepe results in a significantly increased web breakage
problem in the processing sequence downstream of creping,
especially in the processing sequence between the creping blade and
the calendar stack. This web breakage problem becomes more severe
as the fiber consistency of the web to be transferred is increased.
When the fiber consistency of the web being transferred exceeds
about 80%, the adherence with the animal glue is to poor that the
resulting crepe has such irregularity that the web breaks in
substantially every instance and the resulting product has poor
softness characteristics.
The present invention is concerned with obtaining the advantages
resulting from drying to a relatively high consistency during
intermediate drying without the web breakage disadvantage
occurring, which results from insufficient bonding of imprints to
the rotating cylindrical surface upon which the subsequent creping
step takes place.
With this in mind, consideration was given to the use of adhering
agents other than the composition specifically described in Sanford
et al. Several classes of polymeric materials were considered of
which polyvinyl alcohols were preferred. It has been discovered
that only particular polyvinyl alcohols are operative to obtain the
advantages resulting from drying to a relatively high consistency
prior to transfer to the rotating cylindrical surface while
entirely eliminating the breakage problem which occurs upon the use
of the above described animal glue composition. The present
invention is concerned with the selection and definition of these
particular advantageous polyvinyl alcohols.
The objects and advantages of the invention will be evident from
the following detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1A and 1B schematically illustrate a papermaking process
where the instant invention is applicable. FIG. 1B follows FIG. 1A
in the processing sequence.
FIG. 2 is a view taken at line 2--2 of FIG. 1A and illustrates the
portion of the process concerning the make-up and use of adhering
agent solution.
FIG. 3 is a view taken at line 3--3 of FIG. 2 depicting details of
apparatus for applying adhering agent solution to a Yankee
surface.
DETAILED DESCRIPTION
With continuing reference to FIGS. 1A and 1B, a papermaking furnish
is delivered from a closed headbox 10 to a Fourdrinier wire 12.
The Fourdrinier wire 12 is supported by breast roll 14 adjacent to
headbox 10 and couch roll 16 which is spaced from and horizontally
aligned with breast roll 14. It follows a travel path defined by
breast roll 14, couch roll 16, and return roll 18 which is spaced
downwardly and vertically offset from couch roll 16. The
Fourdrinier wire 12 in following the travel path established by
rolls 14, 16 and 18 passes over roll 14, then moves horizontally
toward roll 16, then passes over roll 16 and moves downwardly, then
turns around and under roll 18, then moves toward roll 14 and
passes around and over roll 14.
The headbox 10 forms a paper web 20 on the Fourdrinier wire 12
having a dry basis weight ranging for example from about 5 to about
40 pounds per 3000 square feet and an initial fiber consistency
ranging for example from about 0.1% to about 0.3%. The formed web
travels along the Fourdrinier wire 12 between breast roll 14 and
couch roll 16 and continues along with Fourdrinier wire 12 during a
portion of its path between couch roll 16 and return roll 18.
Forming devices 22 and 24 positioned near breast roll 14
respectively and successively bear on the underside of Fourdrinier
wire 12 to remove water from the web 20.
Trimming nozzles 26 may be positioned downstream of forming device
24 to trim the sides of the web.
A suction box 28 is positioned under the Fourdrinier wire 12
adjacent couch roll 16 so as to draw water from the web 20 through
wire 12.
As a result of the action of the forming devices 22 and 24 and the
suction box 28, the web is dewatered to provide a fiber consistency
ranging for example from about 10% to about 25%.
As the Fourdrinier wire 12 is in the portion of its travel path
between couch roll 16 and return roll 18, the partially dewatered
web 20 is transferred to the conveying and imprinting fabric
30.
The fabric 30 follows a travel path defined by a guide roll 32, a
guide roll 34, a guide roll 36, a pressure roll 38, a guide roll
40, a guide roll 42 and a guide roll 44. The fabric in following
this travel path passes under guide roll 32, then moves in a
direction diagonally downwardly away from wire 12, then passes
under guide roll 34, then moves substantially horizontally, then
passes under guide roll 36 and turns upwardly therearound, then
moves upwardly and passes over and around pressure roll 38, then
moves back in the direction of Fourdrinier wire 12, then passes
under and around guide roll 40, then moves diagonally upwardly in a
direction away from Fourdrinier wire 12, then passes over and
around guide roll 42, then moves substantially horizontally in a
direction toward Fourdrinier wire 12, then passes over and around
guide roll 44 at a location adjacent couch roll 16, then passes
diagonally downwardly so as to be aligned with and adjacent the
initial portion of the travel path of wire 12 between couch roll 16
and return roll 18, then passes under roll 32.
The conveying and imprinting fabric 30 has a mesh structure and is
formed of filament so that when a vacuum is exerted to pull the
moist web against the fabric, the web partially assumes the contour
of the supporting surface of the fabric including its knuckle
pattern. The fabric may be a woven polyester monofilament as
described in U.S. Pat. No. 3,473,576 issued to John S. Amneus on
Oct. 21, 1969 or it may have the characteristics of the fabric
described in the application of Peter G. Ayers, Ser. No. 368,440,
filed June 8, 1973, both said patent and said application being
commonly owned by the assignee of the present invention. Preferably
the fabric has its knuckle surfaces abraded away in accordance with
the teachings of U.S. Pat. No. 3,573,164, issued Mar. 30, 1971 to
Norman D. Friedberg et al, said patent being also commonly owned by
the assignee of the present invention.
The transfer of the moist web from the Fourdrinier wire 12 to the
fabric 30 is accomplished utilizing a vacuum box 46 positioned
opposite fabric 30 between rolls 44 and 32. In this transfer the
partially dewatered web is separated from the wire 12 and attaches
to the fabric 30 and thereupon travels with fabric 30 through a
portion of its travel path as described hereinafter.
A multi-stage vacuum box 48 is positioned on the side of fabric 30
opposite that in contact with web 20 at a location between transfer
vacuum box 46 and guide roll 32. As depicted, the vacuum box 48 is
a three-stage vacuum box containing compartments with the vacuum in
each being independently adjustable. It functions to pull web 20
against fabric 30 so as to form a web conforming to the mesh
pattern of the fabric.
As the web 20 travels along with fabric 30 between guide rolls 32
and 34 it is thermally dried. This drying is carried out without
compacting the web. This is accomplished using a hot air drier 50
which is positioned on the same side of fabric 30 as is web 20 so
as to direct hot air at the web 20. The hot air dryer 50 is
preferably in the form illustrated and describd in U.S. Pat. No.
3,303,576 issued Feb. 14, 1967 to James B. Sisson, which patent is
commonly owned by the assignee of the present invention. An exhaust
fan 52 is positioned across from drier 50 on the opposite side of
fabric 30 to remove moisture evaporating from the web. This drying
is carried out to effect a fiber consistency in the web exceeding
about 68% and ranging up to about 98%, that is to relatively high
fiber consistencies. As previously explained, drying to these
relatively high fiber consistencies prior to imprinting against the
rotating cylindrical surface results in the obtainment of process
advantages (lower thermal load on the Yankee dryer which allows
increased line speed) and product advantages (increased softness
and absorbency) compared to drying to a lesser extent previous to
imprinting. The limitation of exceeding about 68% has been selected
in this case because the adhering agent invention has unique
advantage as explained previously with respect to webs dried
previous to imprinting to that extent, namely the elimination of
web breakage downstream of creping and more uniform cross direction
moisture profiles. The upper limit of about 98% has been selected
because at fiber consistencies exceeding this, overdrying of the
sheet occurs which will diminish subsequent sheet control.
The web 20 having been subjected to thermal drying by the drier 50
continues along with fabric 30 until both reach pressure roll 38
whereupon web 20 is transferred to the rotating cylindrical surface
of Yankee dryer 54.
As web 20 is being transferred to the rotating cylindrical surface
of the Yankee dryer 54 it is also being imprinted with a knuckle
pattern. This is effected by pressure roll 38 pressing web 20 and
fabric 30 against the rotating cylindrical surface.
After the web 20 is transferred from fabric 30 to the rotating
cylindrical surface, the fabric 30 having been freed of the web is
washed with water sprays 56 and dried by a vacuum box 58 and then
follows its travel path to pick up uncompacted web to be imprinted
in the manner previously described.
The web 20 having been transferred to the rotating cylindrical
surface is dried to final fiber consistency if not already at such
consistency, whereupon it is creped from the surface by a doctor
blade 60. While on a Yankee, the web is generally exposed to a
temperature of at least 212.degree.F. and usually not exceeding
350.degree.F. The creped dried web then passes under a guide roll
62 and over a Mt. Hope roll (not depicted), then through a calender
stack 64 and then is wound on take-up reel 66 which is driven by
driving roll 68.
Turning now to the transfer of web 20 from fabric 30 to the
rotating cylindrical surface of the Yankee dryer, the web is
transferred with the aid of an aqueous solution of adhering agent
which is sprayed on the rotating surface upstream of the point
where the web is transferred to it. This adhering agent solution
improves the bond between the imprints and the rotating cylindrical
surface. In other words, adhering agent solution is applied to
cause transfer and adherence of the imprinted web to a rotating
cylindrical surface. The adhering agent solution application is
generally denoted by numeral 70 on FIG. 1A.
Turning now with particularity to the adhering agent application
and with continuing reference to FIGS. 2 and 3, the adhering agent
application system comprises a make-up tank 72, a hold tank 74, an
applicator described in detail later, and means for recirculating
adhering agent solution between the hold tank and the
applicator.
The make-up tank 72 is equipped with an agitator 76. Provision is
made for adding water and steam into tank 72 as indicated by arrows
in FIG. 2. The agitation and steam are to effect solution of
adhering agent solids in water. The particular make-up procedure
will be described in detail later. After the adhering agent solids
have been dissolved in the water to make up the adhering agent
solution, the made-up solution is passed by gravity flow via a pipe
78 equipped with a valve 80 to the hold tank 74.
The hold tank 74 is in a recirculation loop with a trough 82 which
is positioned adjacent the surface of Yankee dryer 54 upstream of
the location where web 20 is to be transferred to that surface. The
recirculation loop comprises a feed line 84 equipped with a pump 85
which communicates between the bottom of hold tank 74 and the
bottom of trough 82 whereby adhering agent solution is fed from the
bottom of hold tank 74 into trough 82. The recirculation loop is
completed by a return line 86 which provides communication between
an overflow outlet in trough 82 and the open top of hold tank 74.
The overflow outlet in trough 82 coacts with the rest of the
recirculation means and functions to establish a constant level of
adhering agent solution in trough 82 as indicated in FIG. 3.
A device for applying adhering agent solution to the rotating
cylindrical surface is particularly disclosed in FIG. 3 and it
includes the trough 82. It also includes a rotating cylindrical
foraminous member 88 axially aligned with the long dimension of the
trough and with the surface of the Yankee 54 and positioned so that
a portion of it extends below the upper level of the adhering agent
solution in trough 82. The foraminous member 88 is adapted to be
rotated by means 89 (FIG. 2) so that a portion of its surface moves
into the liquid in trough 82 and lifts liquid from the trough
holding it in its interstices as a result of surface tension. A
pipe 90 is coaxial with and positioned inside of the cylindrical
foraminous member 88. It contains a slot 92 positioned to direct
air through member 88 in the direction of the rotating cylindrical
surface of the Yankee 54 whereby adhering agent solution is carried
from the interstices of member 88 and applied to the rotating
cylindrical surface.
Having described a milieu for the invention, the instant invention
is now turned to with particularlity. As previously explained, the
invention herein resides in the selection and definition of the
particular adhering agent which is applied. The preferred adhering
agent for use herein is used in aqueous solution and is a polyvinyl
alcohol characterized by a degree of hydrolysis ranging from about
80% to about 90% and a viscosity as a 4% aqueous solution at
20.degree.C. exceeding about 20 centipoises. Preferably the
polyvinyl alcohol is characterized by a degree of hydrolysis
ranging from about 86% to about 90% and a viscosity as a 4% aqueous
solution at 20.degree.C. above about 35 centipoises. Polyvinyl
alcohols having these properties are commercially available and
particular polyvinyl alcohols are disclosed in terms of degree of
hydrolysis and viscosity as a 4% aqueous solution at 20.degree.C.
in a book entitled "Polyvinyl Alcohol" by C. Finch, published by
John Wiley and Sons (New York 1973), a copy of which is in the
Patent Office Scientific Library under number TP1180.V48.P55.
The aqueous solution which is applied herein desirably contains a
concentration of the above described particular polyvinyl alcohol
ranging from about 0.1% to about 1% by weight. The lower limit is
related to the applicator design and is selected so that the
applicator will be able to apply the correct amount of adhering
agent to the rotating surface of the Yankee in the time available.
The upper limit is selected so as to minimize the amount of
adhering agent building up on the rotating cylindrical surface
which in turn minimizes wear on the stripping means used to control
such build-up.
The aqueous solution is applied to the rotating cylindrical surface
to provide from about 0.05 pounds to about 2 pounds of polyvinyl
alcohol (on a dry basis) per ton of paper produced (on a dry
basis), preferably from about 0.3 to about 1 pound of polyvinyl
alcohol (on a dry basis) per ton of paper produced (on a dry
basis). If less than about 0.05 pounds per ton of paper (on a dry
basis) is utilized, the adherence of the imprints to the rotating
cylindrical surface may not be sufficient to obtain the advantages
of the invention. If more than about 2 pounds of polyvinyl alcohol
solids per ton of paper on a dry basis is utilized, the adherence
can be so great that the doctor blade will have difficulty removing
the paper.
Turning now with particularity to the method of adhering agent
application depicted in FIGS. 2 and 3, water is added into tank 72
and polyvinyl alcohol solids are added thereto with agitator 76
being run at high speed. After the solids have been thoroughly
dispersed in the water steam is injected into the water to bring
its temperature to a level usually ranging from about 160.degree.F.
to about 190.degree.F. This temperature is maintained over a period
of time ranging for example from about 30 minutes to about one hour
by the periodic injection thereinto of steam. During the steam
injection the agitation is slowed so as to minimize the possibility
of foam production. As a result of this procedure the polyvinyl
alcohol solids are dissolved in the water. At this point valve 80
is opened and the adhesive solution is drained into hold tank 74.
Pump 85 is then started to provide a level of adhering agent
solution in trough 82 and a recirculation rate is provided between
hold tank 74 and trough 82 ranging for example from about 0.5
gallons per minute to about 1.5 gallons per minute. Foraminous
member 88 is rotated and air flow into nozzle 90 is effected.
Preferably the air flow is maintained constant and the rate of
application of adhering agent solution to the rotating surface is
adjusted by adjusting the speed of rotation of the foraminous
member 88.
As a result of the selection of the adhesive constituent in
accordance with the present invention the web 20 can be thermally
dried previous to imprinting to a fiber consistency exceeding about
68% and ranging up to about 98% without web breakage occurring
downstream of creping. Conventional animal glues and other
polyvinyl alcohols are disadvantageous in respect to web breakage
at these fiber consistencies.
Inasmuch as this invention allows drying previous to imprinting to
provide a relatively dry web, the process advantage described
hereinbefore of reducing the drying load on the Yankee thereby
allowing increase in line speed and the product advantage described
hereinbefore of greater bulk and increased softness compared to
where there is thermal drying to a lesser extend prior to
imprinting are obtained.
This invention also allows the reduction in the diameter of the
Yankee required thereby providing a significant reduction in
equipment cost.
The product obtained herein from the above described process is a
soft and absorbent tissue paper web. It can be characterized, for
example, by having a uniform basis weight of about 5 to about 40
pounds per 3000 square feet. It has impressed in its surface the
knuckle pattern and surface contour of the imprinting fabric. The
obtained paper web has a relatively low bulk density compared to
paper manufactured in a conventional tissue manufacturing
process.
The inventive concepts herein are illustrated in the following
specific example. In this example the system depicted in FIGS. 1A,
1B, 2 and 3 is utilized except that when the uncompacted web is
dried to between 85% and 98% while on fabric 30, a creping drum may
be utilized in place of a Yankee dryer 54.
EXAMPLE
A pulp slurry having 0.3% fiber consistency and containing 35%
bleached northern softwood kraft and 65% bleached poplar sulfite,
prerefined at 3.5% consistency in a conventional conical pulp
refiner at 100 kw.-hr./ton is distributed by the headbox which is
of conventional hydraulic design. The Fourdrinier wire 12 is of
polyester woven with 78 warp and 62 weft strands per inch moving
continuously at 1000 f.p.m. Flow and Fourdrinier wire movement are
regulated so that a uniform moist paper web, having a dry basis of
11.4 pounds per3000 square feet, is formed on the Fourdrinier wire.
The forming devices 22 and 24 and the suction box 28 remove water
from the web to provide a fiber consistency of 25%. The suction box
28 contacts the underside of the Fourdrinier wire with a vacuum
equivalent to 3 inches of Hg. The vacuum box 46 effects a vacuum of
8 psig to effect transfer of the uncompacted web from the
Fourdrinier to the fabric 30. The fabric 30 is woven with 36 warp
strands per inch made of 0.016 inch diameter crimped polyester
monofilament and 30 weft strands per inch similar to the warp
strands, particularly in that they are crimped to the same degree,
with a diameter of 0.016 inch. The three-stage box 48 is adjusted
so that the first compartment which affects the web exposes it to a
vacuum of 12 psig, the second compartment exposes the web to a
vacuum of 12 psig and the third compartment exposes the web to a
vacuum of 10 psig. The thermal dryer 50 supplies air at a
temperature required to effect a fiber consistency prior to
imprinting as indicated in the table below. The particular
temperature utilized depends upon the fiber consistency desired to
be achieved. A temperature of 380.degree.F. is utilized to achieve
the fiber consistency of 50% in the table below while a temperature
of 520.degree.F. is utilized to achieve the fiber consistency of
98% noted in the table below with the temperature regulated to
levels between 380.degree.F. and 520.degree.F. to achieve fiber
consistencies between 50% and 98%. The Yankee dryer has a diameter
of 8 feet and a width of 31 inches. The dried uncompacted web is
imprinted with a nip pressure at pressure roll 38 of 300 pounds
lineal inch to imprint the web with the pattern of the imprinting
fabric. Adhering agent solution is applied by applicator 70 at a
point 12 inches upstream of the nip between roll 38 and the drum of
Yankee 54 and it is applied in a pattern which extends
circumferentially on the surface of Yankee 54 about 3 to 4 inches.
Various polyvinyl alcohols are utilized as indicated in the table.
All of the polyvinyl alcohols utilized are readily commercially
obtainable from the Monsanto Chemical Company and others. In this
example, of the polyvinyl alcohols utilized, Gelvatol 20-90 and
Gelvatol 20-60 are within the scope of the invention. The other
polyvinyl alcohols utilized, namely Gelvatol 1-90, Gelvatol 3-60,
Gelvatol 20-30 and Gelvatol 1-30 are outside the scope of the
invention. In relation to the Gelvatols the first stated number
indicates the precentage residual polyvinyl acetate and the next
series of digits when multiplied by 1,000 gives the number
corresponding to the average molecular weight. As indicated in FIG.
2.1 of the book entitled "Polyvinyl Alcohol" by C. Finch described
earlier, Gelvatol 20-90 has a degree of hydrolysis of about 88% and
a viscosity as a 4% aqueous solution at 20.degree.C. of about 40
centipoises; Gelvatol 20-60 has a degree of hydrolysis of 86 to 87%
and a viscosity as a 4% aqueous solution at 20.degree.C. of
slightly over 20; Gelvatol 1-90 has a degree of hydrolysis from 99
to 100% and a viscosity of about 60 centipoises as a 4% aqueous
solution at 20.degree.C.; Gelvatol 3-60 has a degree of hydrolysis
ranging from about 99 to 100% and a viscosity as a 4% aqueous
solution at 20.degree.C. of about 28-29 centipoises; Gelvatol 20-30
has a degree of hydrolysis of about 88% and a viscosity as a 4%
aqueous solution at 20.degree.C. of approximately 6 centipoises;
Gelvatol 1-30 has a degree of hydrolysis ranging from about 99 to
100% and a viscosity as a 4% aqueous solution at 20.degree.C. of
approximately 4 to 5 centipoises. The animal glue referred to below
is formulated from a 100% liquid animal glue. The Gelvatols and
animal glue are applied as 1% by weight aqueous solutions. The
Gelvatol solutions are made up by introducing 100 liters of cold
tap water into make-up tank 72 with agitator 76 operated at high
speed. 1100 grams Gelvatol solids are then added. The high speed
agitation is continued for 20 minutes. At this point steam is
injected to bring the temperature of water to 180.degree.F. The
180.degree.F. temperature is maintained by the periodic injection
of steam during a 45-minute period. During the steam injection the
agitation is slowed to minimize foam formation. At this point
sufficient water is added to obtain a 1% weight concentration of
adhering agent solids. The above procedure is sufficient to form an
aqueous solution of the adhering agent solids. In the make-up of
the animal glue solution, the liquid animal glue is added into cold
water in tank 72 under slow agitation and steam is injected to heat
the water to 140.degree.F. whereupon the combination is held for 20
minutes under slow agitation. In each case the aqueous solution is
pumped from hold tank 74 at a rate of 1 gallon per minute.
Reticulated member 88 has a mesh of 30 .times. 28 and is
constructed of stainless steel wire; it is 21 inches wide and 12
inches in diameter. Pipe 90 is 2 inches in diameter and the slot 92
has a width of 0.025 inch; 3 psig air is utilized. The rate of
adhering agent application is at about 1 pound adhering agent (on a
dry basis) per ton of paper (on a dry basis). The paper produced in
all cases is very absorbent (Reid test of 7-9 seconds) and soft (at
least equivalent to commercially available products), and the
higher the fiber consistency prior to imprinting the better the
absorbency and the softer the paper is. The following table
presents a comparison of various adhering agent solutions used in
conjunction with webs having various fiber consistencies as noted
in the table prior to imprinting and indicates the advantage of the
selected adhering agents of the instant invention over other
adhering agents in respect to web breakage downstream of creping.
In the following table, "0" denotes no breaks in a 24 hour period;
"Few" denotes a few breaks in a 24 hour period; "Several" denotes
several breaks in a 24 hour period; and "Continual" denotes
breakage every time the web was attempted to be reeled up.
TABLE
__________________________________________________________________________
FREQUENCY OF WEB BREAKAGE (TIMES IN A 24 HOUR PERIOD) ADHERING
FIBER CONSISTENCY PRIOR AGENT TO IMPRINTING (PERCENT).fwdarw. TYPE
50 60 70 80 90 98
__________________________________________________________________________
Gelvatol 20-90* 0 0 0 0 0 0 Gelvatol 20-60* 0 0 0 0 0 0 Gelvatol
1-90** 0 0 Few Several Continual Continual Gelvatol 3-60** 0 0 Few
Several Continual Continual Animal Glue** 0 0 Few Several Continual
Continual Gelvatol 20-30** 0 Few Several Continual Continual
Continual Gelvatol 1-30** Continual Continual Continual Continual
Continual Continual
__________________________________________________________________________
*within scope of invention **outside scope of invention As
indicated by the above table web breakage downstream of creping is
entirely eliminated even at fiber consistencies prior to imprinting
as high as 98% when polyvinyl alcohols within the scope of the
invention are utilized. On the other hand when other polyvinyl
alcohols or animal glues are utilized there is at least some web
breakage at fiber consistencies prior to imprinting greater than
about 68%. The above table clearly indicates the advantage of the
present invention over the use of other adhering agents when fiber
consistencies prior to imprinting greater than about 68% are
utilized.
While not wishing to be bound to any theory, it is speculated that
the better adherence obtained by utilizing polyvinyl alcohols in
accordance with the invention is obtained due to surface tension
adhesion and hydrogen bonding supplied by the water solution of
polyvinyl alcohol which is held as a film against the rotating
drying cylinder and the polyvinyl alcohols of the invention act as
a means for retaining the water at the rotating drum surface. This
would explain why the polyvinyl alcohols that are operative have
relatively low degrees of hydrolysis. It would also explain why
higher fiber consistencies prior to imprinting are more difficult
to transfer; this would probably be because there would not be
enough surface water in the web so that the surface tension
adhesion and hydrogen bonding mechanism could come into play. It is
speculated that polyvinyl alcohols of medium high and high
viscosity are required because these have a stable viscosity at the
temperatures at the surface of the Yankee.
The fiber consistencies herein are average fiber consistencies.
The invention may be embodied in other specific forms without
departing from the spirit or essential characteristics thereof. For
example, the particular polyvinyl alcohols selected and defined
above have use in providing adherence between a web and a rotating
cylindrical surface without web breakage occurring downstream of
creping in papermaking processes other than the one particularly
depicted in the Figures of the drawing as long as the process
involves thermally drying without compacting a moist web to a fiber
consistency exceeding about 68% and ranging up to about 98%,
imprinting the resulting relatively dry web with a pattern and
transferring and adhering the imprinted web to a rotating
cylindrical surface in the form of a Yankee dryer where the web is
dried to final fiber consistency (if not already at that
consistency) and creped. For example, the papermaking process can
be one in which the web forming carrier and the conveying and
imprinting fabric are one and the same. Moreover, the adhering
agent solution can be applied in ways other than that specifically
described, for example utilizing spray nozzles, separate water and
glue sprays, etc. In view of the variations that are readily
understood to come within the limits of the invention, such limits
are defined by the scope of the claims.
* * * * *