U.S. patent number 3,926,690 [Application Number 05/386,992] was granted by the patent office on 1975-12-16 for aluminium alloys.
This patent grant is currently assigned to Alcan Research and Development Limited. Invention is credited to Frederick Barry Miners, Larry Roy Morris.
United States Patent |
3,926,690 |
Morris , et al. |
December 16, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Aluminium alloys
Abstract
Strontium and/or calcium in a total amount of 0.01-0.5% is added
to aluminium magnesium silicide extrusion alloys to reduce the
formation of "pick-up" on extrusion at high speeds.
Inventors: |
Morris; Larry Roy (Yarker,
CA), Miners; Frederick Barry (Kingston,
CA) |
Assignee: |
Alcan Research and Development
Limited (Montreal, CA)
|
Family
ID: |
10409110 |
Appl.
No.: |
05/386,992 |
Filed: |
August 9, 1973 |
Foreign Application Priority Data
|
|
|
|
|
Aug 23, 1972 [UK] |
|
|
39355/72 |
|
Current U.S.
Class: |
148/439;
148/440 |
Current CPC
Class: |
C22C
21/06 (20130101); C22C 21/08 (20130101) |
Current International
Class: |
C22C
21/08 (20060101); C22C 21/06 (20060101); C22C
021/02 () |
Field of
Search: |
;75/147,142,141,146,148
;148/32,32.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Dean; R.
Attorney, Agent or Firm: Cooper, Dunham, Clark, Griffin
& Moran
Claims
We claim:
1. An as-cast aluminium magnesium silicide alloy extrusion ingot
containing Al-Fe-Si, said alloy consisting essentially of 0.3-1.2%
Mg, 0.2-1.2% Si, up to 0.4% Cu and up to 0.1% each Zn, Mn,
0.05-0.3% Fe as impurity and 0.15% total (0.05% each) other
impurities, balance aluminum, characterized by the presence of Sr
and/or Ca in a total amount of 0.01-0.5% for causing at least a
major proportion of the Al-Fe-Si in the as-cast ingot to be in the
.alpha. phase, thereby to reduce pickup upon extrusion of the
ingot.
2. An aluminium alloy according to claim 1 in which the total
content of Sr and/or Ca is in the range of 0.02-0.05%.
3. An aluminium alloy according to claim 1 in which the content of
Mg is below 0.7% and the sum of the content of Mg and Si is below
1.5%.
4. A homogenized aluminium magnesium silicide alloy extrusion ingot
containing Al-Fe-Si, said alloy consisting essentially of 0.3-1.2%
Mg, 0.2-1.2% Si, up to 0.4% Cu and up to 0.1% each Zn, Mn,
0.05-0.3% Fe as impurity and 0.15% total (0.05% each) other
impurities, balance aluminium, characterized by the presence of Sr
and/or Ca in a total amount of 0.01-0.5%; at least a major
proportion of the Al-Fe-Si in the ingot being in the .alpha. phase,
thereby effecting reduction in pickup upon extrusion of the
ingot.
5. An aluminium alloy according to claim 4 in which the total
content of Sr and/or Ca is in the range of 0.02-0.055.
6. An aluminium alloy according to claim 4 in which the content of
Mg is below 0.7% and the sum of the content of Mg and Si is below
1.5%.
7. An aluminium alloy ingot extrusion containing Al-Fe-Si, said
alloy consisting essentially of 0.3-1.2% Mg, 0.2-1.2% Si, 0.01-0.5%
of an alloying element selected from the class consisting of Sr and
Ca, 0.05-0.3% Fe, up to 0.4% Cu, up to 0.1% each of Zn and Mn,
0.15% total (0.05% each) other impurities, balance Al,
characterized by being essentially free from pickup and having good
specular reflectivity, image clarity and whiteness; at least a
major proportion of the Al-Fe-Si in the extrusion being in the
.alpha. phase.
Description
The present invention relates to aluminium alloys containing
magnesium and silicon in the general range of 0.3 to 1.2 weight %
Mg and 0.2 to 1.2 weight % Si. An alloy of this type containing
0.45- 0.9% Mg and 0.2- 0.6% Si is the most widely used for the
production of aluminium extrusions. This alloy is widely known
under the U.S. Aluminum Association Standards as Alloy 6063. Other
alloys with different ranges of Mg and Si or the addition of small
amounts of other elements are widely used for the production of
aluminium extrusions. Similar alloys are in use in other countries,
although the chemical composition limits may differ slightly from
those registered with The Aluminum Association.
The most generally used specifications for the AA 6063 class of
alloy permits Cu, Cr, Zn, Ti and Mn to be present as impurities in
amounts up to 0.1% each, while setting a maximum of 0.35% Fe and a
maximum of 0.15% for other inpurities (0.05% each). In normal
commercial practice, however, the total of the impurities
(including Fe) is about 0.3- 0.4%. It is also usual for the silicon
content to be in excess of that required to convert the whole
magnesium content to Mg.sub.2 Si.
In the as-cast condition the alloying elements and the impurities
present in the extrusion ingot are either in solid solution in the
aluminium matrix or segregated in the form of intermetallic phases
at the boundaries of the grains into which the alloy has
solidified, or at the boundaries of the dendrite cells within those
grains. It has been common practice for some years to homogenise
the structure of 6063 alloy by a heat treatment aimed at
eliminating coarse particles of the magnesium silicide phase and
the micro-segregation or `coring` of magnesium and silicon in the
dendrite cells, since it is not possible to obtain the optimum
properties or extrusion speeds in extrusions produced from ingots
containing such segregation of magnesium and silicon. In one widely
used practice the as-cast ingots are heated for several hours at a
temperature of about 550.degree.C. and cooled rapidly so as to lock
a large proportion of the magnesium silicide in solution and to
ensure that the remainder of this phase is precipitated in the form
of very finely dispersed particles. Extrusions with very good
mechanical properties can be produced at favourable extrusion
pressures and speeds if ingots homogenised in this way are reheated
quickly to the extrusion temperature. However the surface finish of
extrusions produced from such ingots is not always as good as is
desired.
The surface finish of an extrusion is to a large extent dependent
on the speed at which the metal is forced past the die. It is an
object of the present invention to provide an improvement of the
Alloy 6063 composition and of like Al-Mg-Si alloys having magnesium
and silicon levels in the ranges referred to above, which permits
an increase in the extrusion rate without loss of surface finish of
the extrusion or conversely to provide a better standard of surface
finish without change of extrusion rate as compared with a typical
specimen of Alloy 6063 coming within the general specification.
A principal cause of defects in the quality of the surface finish
of Alloy 6063 extrusions is the breaking away of solid components
from the surface of the metal as it is forced through the die
orifice. These defects manifest themselves as light-coloured micro
score-lines or tears on the surface of the extrusion and are
commonly referred to as pick-up. Generally, the incidence of
pick-up and its deleterious effect on the reflectivity and
smoothness of the surface of the extruded metal increase with the
extrusion speed.
It has now been postulated that one of the principal causes of
surface defects from pick-up is due to the presence of the
intermetallic phase called .beta.-Al-Fe-Si in the ingot during the
extrusion process. This phase, which is insoluble under the normal
homogenisation conditions referred to above, grows in the form of
thin, brittle sheets and is formed during the production of the
ingot by the direct chill casting process. The .beta.-Al-Fe-Si is
believed to have the chemical formula Fe.sub.2 -Si.sub.2 -Al.sub.9
and has a monoclinic type crystal structure. The insoluble Fe-rich
phase can also be present in a different form, .alpha.-Al-Fe-Si.
This phase is believed to have a chemical formula Fe.sub.3
-Si-Al.sub.12 and has a cubic type crystal structure. It has now
been found that substantial reduction in pick-up defects can be
achieved if the Al-Fe-Si phase present in the ingot during
extrusion is in the .alpha.-phase, believed to be because it is
less mechanically brittle than the .beta.-form. This is
particularly true whilst the level of iron in the alloy is
maintained within the range of 0.05- 0.3%. Above 0.3 % Fe pick-up
tends to increase, irrespective of the phase of the
aluminium-iron-silicon intermetallic compound, whilst below 0.05%
Fe the iron-rich phases are not detrimental to the surface quality
of the extruded section.
It has now been found that the addition of strontium or calcium in
amounts of 0.01-0.5% in aluminium-magnesium-silicon alloys of the
type under discussion results in at least a major proportion of the
Al-Fe-Si phase in the as-cast ingot being in the .alpha.-phase.
Other elements can be tolerated in the alloy in substantial amount.
Thus the alloy may contain up to 0.4% Cu, up to 0.1% each of Mn and
Zn and a total of up to 0.15% (0.05% each) of additional impurities
without losing the benefits arising from the Ca or Sr addition.
Whilst the addition of calcium or strontium in the stated amounts
is helpful in the improvement in the surface characteristics of
extrusions throughout the whole range of the magnesium and silicon
contents stated initially, it is preferred to hold the magnesium
content below 0.7% and the combined total of magnesium plus silicon
below 1.5%.
Whilst, as stated above, addition of calcium or strontium in
amounts of 0.01 to 0.5% is envisaged, most of the benefits of the
invention are obtained by an addition of about 0.02-0.05%. With the
addition of Sr or Ca in an amount of about 0.05% substantially the
whole of the Al-Fe-Si phase is in the .alpha.-form in the as-cast
ingot. Whilst the as-cast ingot can be extruded quite
satisfactorily at relatively low speeds without further heat
treatment, higher extrusion rates may be achieved by heating the
ingot above the Mg.sub.2 Si solvus temperature for sufficient time
to bring the Mg.sub.2 Si phase into solution. The level of the Sr
or Ca addition is preferably held at about 0.02-0.05% because
substantially the whole of the benefit of the addition has been
achieved at that level. Above that level little, if any,
improvement in surface properties is obtained and there is a
gradual decrease in the strength of the alloy. It is possible to
add both Ca and Sr, the effect being substantially additive.
However, there is no advantage in so doing and it is inconvenient
operationally. Where Sr and Ca are added together the total
addition of the two components should be within the range above
stated.
We have found that the .alpha.-Al-Fe-Si phase is also promoted by
the addition of one or more of Na, Be and B to alloys falling
within the present class. However it is not practicable, for
various reasons, to incorporate these elements in the required
amount in normal commercial operations. For example, additions of
Be would introduce potential toxicity problems.
One alloy according to the invention had the following composition:
Si 0.40-0.50%, Mg 0.45-0.55%, Fe 0.15- 0.25%; Sr or Ca 0.015-0.05%;
total other impurities 0.2% (max.); Al balance. This alloy was cast
into round extrusion ingots by the D.C. casting process and the
ingots were heat treated at temperatures between 500.degree. and
580.degree.C, for about 1 hour, to solutionise the magnesium
silicide. When this material was extruded it was found that there
was a significant improvement in the specular reflectivity and
smoothness of the extrusions as compared with the extrusions of the
same alloy (but without either the Sr or Ca addition).
In one series of tests this alloy containing 0.018% Ca (a), and
0.05% Ca (b), was compared with the standard, Ca-free, alloy (c).
The ingots were extruded, after reheating to 425.degree.C, at 150
ft./min. with the following results:
(a) (b) (c) ______________________________________ Specular
Reflectivity 46% 72% 23% * Image Clarity 19 25 17 * Whiteness 48 38
72 Visual Comparison Nil pick-up Nil pick-up Pick-up
______________________________________ * Measured by methods
described by B.W. Robinson in "Metal Finishing", February 1970.
In another series of tests the alloy containing 0.015% Sr (a), and
0.05% Sr (b), was compared with the standard, Sr-free, alloy (c).
The ingots were extruded after reheating to 400.degree.C, at 225
ft./min. with the following results:
(a) (b) (c) ______________________________________ Specular
Reflectivity 35% 51% 30% Image Clarity 36 37 29 Whiteness 61 51 66
Light Heavy Visual Comparison pick-up Nil pick-up pick-up
______________________________________
It will thus be seen that significant improvement in extrusion
characteristics has been obtained.
In further tests the same alloy was tested at levels of Sr 0.2% and
0.5% and Ca at 0.2 and 0.5%.
These were extruded through the same die as in the preceding test
at 275 ft./min. and were compared with the standard alloy (c) under
the same conditions.
The alloys having Ca and Sr additions extruded with a very bright
and pick-up-free surface, whereas the surface of the extrusions
from the standard alloy were dull and exhibited heavy pick-up.
* * * * *