U.S. patent number 3,925,243 [Application Number 05/391,158] was granted by the patent office on 1975-12-09 for apparatus for the manufacture of emulsions.
Invention is credited to Hans G. Brogli, Werner F. Brogli.
United States Patent |
3,925,243 |
Brogli , et al. |
December 9, 1975 |
Apparatus for the manufacture of emulsions
Abstract
The disclosure relates to apparatus for the manufacture of
emulsions in which a first liquid is gradually introduced into a
second liquid while stirring. Due of the two liquids, for example a
fat or wax, may be heated, for example to melt it, and the other
liquid may be relatively cold. In order to ensure good emulsifying
in spite of such temperature differences, the apparatus comprises
nozzle means arranged to introduce said first liquid in fine
distribution into the draw in area of a rotating stirring member
running in the second liquid, which stirring member is the rotor
part of a mixing and homogenizing tool that also has a stator
surrounding the rotor.
Inventors: |
Brogli; Hans G. (Basel,
CH), Brogli; Werner F. (Reinach, Basel-Land,
CH) |
Family
ID: |
27175939 |
Appl.
No.: |
05/391,158 |
Filed: |
August 23, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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145853 |
May 21, 1971 |
3791984 |
Feb 12, 1974 |
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Foreign Application Priority Data
Current U.S.
Class: |
366/147; 366/279;
366/172.1 |
Current CPC
Class: |
B01F
3/0853 (20130101); B01F 3/0807 (20130101); B01F
15/00012 (20130101); B01F 7/00 (20130101) |
Current International
Class: |
B01F
3/08 (20060101); B01F 15/00 (20060101); B01F
7/00 (20060101); B01F 007/16 (); B01J 013/00 ();
B01F 005/16 () |
Field of
Search: |
;252/359C,359D,36-313NG
;259/23,24,96,DIG.30 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Sofer; Jack
Attorney, Agent or Firm: Eyre, Mann & Lucas
Parent Case Text
CROSS-REFERENCE
This application is a continuation-in-part of Ser. No. 145,853
which was filed May 21, 1971 now U.S. Pat. No. 3,791,984 issued
Feb. 12, 1974.
Claims
What is claimed is:
1. Apparatus for the manufacture of an emulsion from a first bath
liquid and a second feed liquid immiscible with said first liquid,
one of said liquids being heated and the other liquid being
relatively cool, said apparatus comprising:
a mixing and homogenizing tool immersed in said first liquid
comprising an annular stator and a stirring member disposed in said
stator, the stator having an inlet side and an outlet side, and
said stirring member being rotatable to form a draw in area for
drawing said first liquid from said inlet side into said mixing and
homogenizing tool,
and at least one nozzle disposed at said inlet side of said stator
and having a nozzle opening of shape and position to introduce said
second liquid in fine distribution in the draw in area of said
stirring member so that said second liquid is drawn into said
mixing and homogenizing tool together with said first liquid and
thoroughly mixed therewith in said tool before said liquids are
thrust out at said outlet side,
said nozzle having an annular gap which is formed by the inner
peropheries of coaxial annular plates which are fixed to said inlet
side of said stator, said nozzle gap being divided in the
peripheral direction into at least two sector-like chambers each of
which is connected to a separate supply pipe for different
liquids.
2. Apparatus for the manufacture of an emulsion from a first bath
liquid and a second feed liquid immiscible with said first liquid,
one of said liquids being heated and the other liquid being
relatively cool, said apparatus comprising:
a mixing and homogenizing tool immersed in said first liquid
comprising an annular stator and a stirring member disposed in said
stator, the stator having an inlet side and an outlet side, sand
said stirring member being rotatable to form a draw in area for
drawing said first liquid from said inlet side into said mixing and
homogenizing tool,
and at least one nozzle disposed at said inlet side of said stator
and having a nozzle opening of shape and position to introduce said
second liquid in fine distribution in the draw in area of said
stirring member so that said second liquid is drawn into said
mixing and homogenizing tool together with said first liquid and
thoroughly mixed therewith in said tool before said liquids are
thrust out at said outlet side,
said nozzle having an annular gap which is formed by the inner
peripheries of coaxial annular plates which are fixed to said inlet
side of said stator, said annular gap being disposed surrounding
said draw in area of said stirring member in such manner that said
first liquid sucked by the stirring member and flowing past the
annular gap produces a low pressure in the nozzle in order to suck
in said second liquid through a supply pipe connected to said
nozzle.
3. Apparatus for the manufacture of an emulsion from a first bath
liquid and a second feed liquid immiscible with said first liquid,
one of said liquids being heated and the other liquid being
relatively cool, said apparatus comprising:
a mixing and homogenizing tool immersed in said first liquid
comprising an annular stator and a stirring member disposed in said
stator, the stator having an inlet side and an outlet side, and
said stirring member being rotatable to form a draw in area for
drawing said first liquid from said inlet side into said mixing and
homogenizing tool,
and a ring of separate nozzles disposed annularly around said draw
in area of said stirring member,
said nozzles having nozzle openings of shape and position to
introduce said second liquid in fine distribution in the draw in
area of said stirring member so that said second liquid is drawn
into said mixing and homogenizing tool together with said first
liquid and thoroughly mixed therewith in said tool before said
liquids are thrust out at said outlet side.
Description
BACKGROUND OF THE INVENTION
This invention relates to the manufacture of an emulsion.
In the manufacture of emulsions it is usual to insert the media to
be emulsified at temperatures which differ only a little, or as far
as possible not at all, from one another.
If, for example, it is desired to produce an emulsion with fat or
wax it is as a rule necessary to melt the fat or wax. Then an
aqueous liquid can be allowed to run gradually whilst stirring into
the melt, which is heated for example at about 80.degree.C, whereby
experience has always shown that a satisfactory emulsion can only
be obtained if the aqueous liquid supplied is likewise heated, for
example to about 82.degree.C. From this experience there has
resulted the procedural rule already mentioned.
On the other hand it can be noted that emulsions are as a rule
stable against decomposition only at temperatures below a certain
specific value. This value may, for example, according to the type
and quantity of emulsifiers and other additions used, be at about
25.degree. to 30.degree. or 35.degree.C. If therefore according to
known methods an emulsion has been produced from a fat or wax
fusion and a likewise heated aqueous liquid then it is for the most
part necessary to cool the emulsion with further stirring until
below the stability limit in order to prevent a decomposition of
the emulsion. This cooling may under certain circumstances require
several hours whilst the actual emulsifying could frequently be
carried out in a few minutes. The cooling thus makes the
manufacture of the emulsion uneconomic because the emulsifying
devices remain filled for a very long time and it also renders a
continuous operation practically impossible. Attempts have been
made to accelerate the cooling by means of cooling surfaces; this
however has frequently the drawback that certain substances, for
example wax, become deposited on the cooling surfaces and are
thereby drawn out of the emulsion.
It has now been found that under certain circumstances and
conditions the traditional procedure aforementioned can be
disregarded with resultant advantages.
The parent application Ser. No. 145,853 thus claims a method for
the manufacture of an emulsion in which a first liquid is gradually
introduced while stirring into a second liquid which has been
heated to a temperature which is above the limit temperature up to
which the finished emulsion is stable and above the solidification
temperature of this first liquid, which method is characterized in
that the first liquid, at a temperature below the said limit
temperature and/or solidification temperature, is introduced in
fine distribution in the entry area of a stirring member which runs
in the heated second liquid.
The first liquid may be suitably introduced at a temperature which
is at least 25.degree.C preferably at least 50.degree.C below the
temperature at which the second liquid, for example melted fat or
wax, has been heated. In most cases the first liquid, for example
an aqueous liquid, may be practically cold, that is have room
temperature or tap water temperature. In this way the mixture
temperature of the finished emulsion after the total quantity
provided of the first liquid has been introduced may be below the
said limit temperature so that no more cooling with stirring is
necessary.
It is also possible to heat the first liquid, for example when this
is a fat or wax, and introduce it into a cold second liquid in the
manner described above.
SUMMARY OF THE INVENTION
The present application relates to apparatus suitable for carrying
out the method for making emulsions described above. The apparatus
comprises a mixing and homogenizing tool with an annular stator and
a stirring member disposed in the stator which is rotatable in
order to draw a medium from an inlet side of the stator to mix it
thoroughly and thrust it out at an outlet side, and it is
characterized in that at least one nozzle is disposed at the inlet
side of the stator with an opening directed towards the draw in
area of the stirring member, which nozzle is connected to a supply
pipe for the liquid which is to be introduced and emulsified.
The nozzle must be arranged close to the stirring member, in a
region where the medium flow rate is high, in such a manner that
the entire amount of liquid supplied by it in fine distribution is
at once drawn into the homogenizing tool and completely emulsified,
and the temperature equalization between this liquid and the medium
occurs substantially only in the homogenizing tool.
The nozzle may, for example, have a fine annular gap surrounding
the draw in area of the stirring member. Instead of this there
could also be arranged around the draw in area a ring of nozzles in
order to obtain the required fine distribution of the first
liquid.
In a particularly suitable construction the nozzle having an
annular gap may be formed by two annular plates which are fixed to
the inlet side of the stator. The annular space bounded by these
plates may be divided in the peripheral direction into two or more
partial spaces which are each connected to a separate supply pipe
so that several components of the first liquid or several first
liquids can be introduced separately into the draw in area of the
stirring tool. Furthermore the annular gap of the nozzle may be
arranged surrounding the draw in area of the stirring member such
that the medium drawn in by the stirring member and flowing past
the gap produces a low pressure in the nozzle in order to draw in
the first liquid through the supply pipe so that the use of a
pumping device specifically for the first liquid can be dispensed
with. In order to achieve an improved thorough mixing of the medium
in the stirring tool a third annular plate may be suitably disposed
on the stator which bounds a second nozzle space likewise leading
into an annular gap which is directly adjacent the mixing chamber
in the mixing tool and is connected to this via openings in the
uppermost plate. Thereby a portion of the medium is turned around
in the mixing chamber and fed again to the stirring member through
the said openings and the additional annular nozzle.
The necessary fine distribution of the liquid introduced into the
draw in area of the stirring member can be attained suitably also
with a rotatable nozzle wheel which is disposed on the inlet side
of the stator and connected to a supply pipe.
DESCRIPTION OF PREFERRED EMBODIMENTS
Embodiments of the apparatus according to the invention are
explained by way of example in the following description with
reference to the drawings. In the drawings:
FIG. 1 shows diagrammatically a vertical section through a stirring
tool with a ring nozzle on the inlet side,
FIG. 2 shows diagrammatically a horizontal section through a
particular embodiment of the ring nozzle according to FIG. 1
and
FIGS. 3, 4 and 5 show diagrammatic sections through stirring tools
with nozzles arranged differently on the inlet side.
The stirring and homogenizing tool shown in FIG. 1 has an annular
stator 1 which is carried via vertical bars 2 on a stand not shown
and is immersed, from above, into a medium in a vessel likewise not
shown. In the stator 1 a rotor or stirring member 3 is disposed
which may be rotated by means of a shaft 4 around its vertical axis
and then sucks, mixes and thrusts upwards medium from below as
indicated by the arrows.
On the underside of the stator 1 three annular plates 5, 6 and 7
are fixed, spaced apart from one another, and enclosing between
them annular chambers 8 and 9. These annular chambers are closed on
the outer periphery but open inside towards the draw in area of the
stirring member 3 via annular nozzle gaps 8a and 9a. The upper
annular chamber 8 is in communication, via openings in the plate 5,
with the mixing chamber in the stator 1 so that material to be
mixed is supplied to this annular chamber. The lower annular
chamber 9 is connected to a supply pipe 10 for a liquid to be
emulsified which is fed in fine distribution through the
corresponding annular gap 9a to the material to be mixed, which is
sucked in by the stirring member 3. The annular gap may have a
height of about 0.5 mm to a few mm, for example 3 mm, according to
the dimensions of the stirring tool.
In the example shown the annular gaps 8a and 9a are so arranged,
and the plates 5, 6 and 7 are so formed on their inner edges, that
the medium sucked by the stirring member flowing past the annular
gaps produces in these a low pressure in the manner of a jet pump.
This has the advantage that the liquid to be emulsified is sucked
automatically through the pipe 10. It would of course also be
possible to convey the liquid through the pipe 10 with pressure or
maintain a vacuum above the material to be mixed, with the use of a
closed vessel.
According to FIG. 2 if desired the annular space 9 above the plate
7 may be divided by means of radial partitions 9b into several
sector like areas and these separate areas may be connected to
separate supply pipes 10, 10.sup.1 and 10.sup.11. In this way
several different liquids to be emulsified can then be fed
separately simultaneously. The arrangement shown is intended for
three different liquids in mutual quantity ratios 50 percent; 30
percent; 20 percent (through the pipes 10 and 10.sup.1 and
10.sup.11 respectively).
If desired the liquid could be fed from the supply pipe also via an
annularly arranged rim of individual nozzles instead of through the
nozzle ring gap 9a. It is merely essential for the liquid to be
emulsified to be introduced in as fine a distribution as possible
directly into the draw in area of the stirring member.
Other different possible arrangements of nozzles are shown
diagrammatically, by way of example, in FIGS. 3, 4 and 5. Here also
the nozzles are arranged on the inlet side of a stirring and
homogenizing tool which, like that shown in FIG. 1, has a stator 1
and a rotor or stirring member 3. The nozzle openings are directed
towards the draw in area of the stirring member 3 in order to
introduce the second liquid to be emulsified in fine distribution
in this draw in area.
According to FIG. 3 several separate single nozzles 16 are
peripherally disposed on the inlet side of the stator 1, connected
to individual supply pipes 20.
According to FIG. 4 an annular nozzle 26 is disposed below the
stator 1. An annular chamber 29 in this nozzle 26 is connected to a
supply pipe 30. The chamber 29 is in communication with the draw in
area of the stirring member 3 via a plurality of nozzle openings
29a on the inside of the ring nozzle body.
According to FIG. 5 there is used, for the supply of the liquid to
be emulsified in the draw in area of the stirring member 3, a
rotatable and drivable nozzle wheel 36 which is disposed under the
stirring member 3 and approximately coaxially with this and to
which the liquid is fed via a supply pipe 40. The nozzles of this
nozzle wheel are directed upwardly towards the stirring member
3.
Emulsions can be made as follows with the apparatus described.
There is placed in a vessel, in which the stirring tool is
immersed, a liquid which for any reason, for example because it
would be congealed at room temperature, is heated to a temperature
which is above the limit temperature up to which the emulsion to be
made is stable and above the coagulation temperature or
solidification temperature of the liquid. This liquid may, for
example, be a melted fat or wax at a temperature of about
80.degree.C. The stirring tool is then allowed to run so that the
liquid is whirled or rolled around. Another liquid, which is to be
emulsified, for example an aqueous solution, is now supplied via
the supply pipe. This other liquid has a temperature below the said
limit temperature and/or below the coagulation temperature or
solidification temperature of the liquid in the vessel. One may
also, for example, with an arrangement according to FIG. 2 or with
single nozzles according to FIG. 3 supply several liquids
simultaneously; in this case at least one and preferably all of the
liquids supplied should then have a temperature below the said
value. As a rule the liquid to be emulsified may be introduced
cold, that is at about room temperature or tap water
temperture.
In the manner stated immediately with the commencement of the
introduction of the liquid to be emulsified, so long as the liquid
in the vessel is still hot, a good "parent emulsion" can be
obtained. With increasing quantity of liquid introduced the
temperature of course dops gradually. Surprisingly however it is
nevertheless possible without difficulties to emulsify further
quantities of cold liquid after the "parent emulsion" is formed,
although as a rule small quantities of suitable emulsifier must be
added.
It is also possible to interchange the heated liquid and the
relatively cold liquid, i.e. the cold liquid may be placed in the
vessel and the heated liquid, such as fat or wax, may be gradually
introduced via the supply pipe and nozzle. If it is intended to
carry out this mode of operation, heating means may be provided for
heating the supply pipe.
It is possible in the manner described to emulsify a liquid in
almost any desired quantity into the liquid in the vessel. One may,
for example, produce an emulsion from fat and an aqueous solution
in which the constituent parts are present in the weight ratio of 3
: 1 to 1 : 3 and which is solid at room temperature in that the fat
forms the outer phase. One may however also increase the quantity
of the aqueous liquid up to a weight ratio of 2 : 8 to 1 : 9. The
emulsion then changes, that is, the fat forms the inner phase so
that the finished emulsion is liquid at room temperature.
One liquid is thus always used at a temperature which is
substantially lower than the temperature of the heated other
liquid, for example, by at least 25.degree.C preferably at least
50.degree.C lower. In most cases the cold liquid may be suitably
used at room temperature or tap water temperature.
In the manner described an emulsion may as a rule be produced in a
few minutes. After completion of the introduction of the second
liquid the emulsion is ready and no longer requires cooling whilst
stirring in contradistinction to the cooling times of several hours
which were frequently heretofore necessary in the manufacture of
emulsions in accordance with known methods and in known apparatus
which did not permit the use of liquids at substantially different
temperatures.
* * * * *