U.S. patent number 3,924,988 [Application Number 05/256,334] was granted by the patent office on 1975-12-09 for hollow filament spinneret.
This patent grant is currently assigned to E. I. Du Pont de Nemours & Co.. Invention is credited to James Dwight Hodge.
United States Patent |
3,924,988 |
Hodge |
December 9, 1975 |
HOLLOW FILAMENT SPINNERET
Abstract
A spinneret provided with a spinning nozzle having a plurality
of arcuate segments whose ends bear inner, inwardly tapered
enlargements at the outer one-third portions of the segments.
Inventors: |
Hodge; James Dwight
(Greenville, NC) |
Assignee: |
E. I. Du Pont de Nemours &
Co. (Wilmington, DE)
|
Family
ID: |
22971860 |
Appl.
No.: |
05/256,334 |
Filed: |
May 24, 1972 |
Current U.S.
Class: |
425/461;
264/177.14; 425/464 |
Current CPC
Class: |
D01D
5/24 (20130101); D01D 4/02 (20130101) |
Current International
Class: |
D01D
5/00 (20060101); D01D 5/24 (20060101); D01d
003/00 () |
Field of
Search: |
;425/461,464,466,198,382.2 ;239/601 ;264/176F,177F |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Baldwin; Robert D.
Claims
What is claimed is:
1. In a spinneret plate provided with at least one nozzle, for melt
spinning filaments from molten polymers, said nozzle being defined
by a substantially symmetrical pattern of four arcuate end-to-end
slots interrupted by webs, said nozzle forming a filament having a
single hollow core the improvement comprising, said slots having
ends bearing inner inwardly-tapered enlargements at the outer
one-third portions thereof, adjacent ends having proximate sides
straight and parallel throughout their entire lengths, said slots
having outer boundaries, said outer boundaries being the arc of a
circle, the inner one-third portion of said slot being of
substantially uniform width, the ratio of the distance c between
adjacent slots and the width b of the slots being less than unity,
said single hollow core being relatively smooth.
2. The spinneret plate as defined in claim 1, the ratio of the area
of an outer one-third portion to the area of the inner one-third
portion being in the range of from about 1.15 to about 1.40.
3. The spinneret plate as defined in claim 2, said ratio being
1.16.
4. The spinneret as defined in claim 1, said enlargements being
inwardly tapered at an angle with respect to the end of the slot of
less than 80.degree. and more than about 5.degree..
5. The spinneret as defined in claim 4, said angle being between
20.degree. to 60.degree. .
Description
BACKGROUND OF THE INVENTION
This invention relates to an improved spinneret for the production
of hollow filaments.
It is well known that spinnerets with specially arranged arc-like
slots can be used in the manufacture of synthetic filaments having
a hollow core. Molten polymer forced through a slot forms a bulge
and as a consequence of the bulging and the special arrangement,
the polymer issuing at adjacent slot ends coalesces a short
distance below the spinneret face. While spinnerets of the prior
art function to produce hollow filaments, their use has led to open
or ribbonized filaments after a relatively short period of
operation.
SUMMARY OF THE INVENTION
In a spinneret plate provided with at least one nozzle, said nozzle
being defined by a substantially symmetrical pattern of arcuate
end-to-end slots interrupted by webs, the improvement comprising,
said slots having ends bearing inner inwardly tapered enlargements
at the outer one-third portions thereof, the inner one-third
portion of said slot being of substantially uniform width.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a fragmentary, bottom view of a spinneret showing the
arcuate segments or orifices of one spinning nozzle.
FIG. 2 is a partial sectional view taken along irregular line 2--2
of FIG. 1 with the spinneret in its normal position.
FIG. 3 is a cross-sectional view of a filament produced with the
spinneret of FIG. 1.
FIG. 4 is a view similar to FIG. 1 showing another arcuate orifice
of the invention.
FIG. 5 is a cross-sectional view of a filament produced with the
spinneret of FIG. 4.
DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS
Only one of the plurality of spinning nozzles usually provided in a
spinneret plate 10 has been shown. The nozzle in FIGS. 1 and 2 has
four arcuate orifices or slots 12 which are separated by webs 14
and otherwise surround a solid center portion 16. Each of slots 12
bear inner inwardly tapered enlargements 18 at their outer ends,
these enlargements are within the area extending from the center of
the nozzle bounding the outer one-third portions 12a of the slots.
The inner one-third portion 12b of the slot is of substantially
uniform width.
FIG. 3 shows a cross section of a filament of the type produced by
the nozzles illustrated in FIG. 1. The filament has a substantially
circular core free of protuberances. The dotted lines indicate
where polymer from adjacent segments has coalesced and similarly
FIG. 5 illustrates a cross section of a filament produced by the
nozzles shown in FIG. 4.
FIG. 4 shows arcuate orifices having larger, blunt-tipped tapered
enlargements 18' with corresponding one-third portions 12a', 12b'.
The arcuate orifices in FIGS. 1 and 4 have dimensions represented
by letters a through g. Nominal values, in inches, for dimensions
indicated are: a, 0.033; b, 0.004; c, 0.003; d, 0.0065; e, 0.007;
f, 0.002 and g, 45.degree. .
The spinnerets of the present invention will preferably have
nozzles with four slots 12 since four webs 16 provide good strength
and are readily adaptable to the production of hollow filaments
with a relatively smooth, nearcircular core. However, two, three,
five or more segments may be used if desired. For example,
three-segment nozzles can be used to produce triangularly shaped
cores. In some instances, for example, when relatively
high-velocity cooling air is used to quench the molten polymer near
the spinneret face, it may be desirable to increase the amount of
polymer in the vicinity of the point of coalescence by increasing
the size of the enlargements. Such increases can lead to the
formation of squarish holes and although suitable for spirally
crimped filaments arising from nonuniform quenching, such filaments
are not desired for use in stuffer-box crimping.
The enlargements must begin at the ends of a slot and not extend
beyond one third the length L of the slot. The enlargements are
also tapered inwardly into the center portion 16 of the spinning
nozzle. Preferably, the enlargement will not protrude more than
about 35% of the distance from the inner boundary to the center of
portion 16. The tapering angle g should be less than 80.degree. and
more than about 5.degree.. Preferably, g will be 20.degree. to
60.degree.. The area ratio, o/ I, wherein 0 equals the area in
square mils, of an outer one-third portion (i.e., 12a or 12a') and
I equals the area, in square mils, of the inner one-third portion
(12b or 12b') should be at least 1.1 and preferably should not
exceed about 1.5. In addition, the total area of the slot should
not exceed 400 square mils. Preferably, the area ratio should be
from about 1.15 to about 1.40.
A spinneret having 450 nozzles similar to those of FIG. 1 but
without the enlargements, having an area ratio of about 1.0, was
used to make hollow filaments and in periodical determinations was
found to produce hollow filaments (17% void) with up to 20
improperly coalesced filaments. Under identical conditions, a
spinneret having 450 nozzles differing only in the presence of
enlargements of the type shown in FIG. 1 with an area ratio of 1.16
produced hollow filaments (14% void) and no improperly coalesced
filaments.
In the spinnerets of this invention, the tapered enlargements must
be at the inner portion of the segment. This particular structure
causes a velocity differential to occur in polymer flow through the
nozzle to set up force moments in the segments that favors
coalescence. Such polymer velocity differential is indicated by the
arrows in FIG. 2.
The orifices are generally of symmetrical shape with all orifices
in a nozzle being essentially the same. However, it is not
necessary that all orifices be identical and variations may be
introduced if desired, for instance, to produce unsymmetrical
filaments.
It is not essential that the inner boundary of the segment be the
arc of a circle. Straight or curving lines may also serve to define
the inner boundary but should not differ too greatly from a
circular boundary because of changes in polymer distribution. In
the practice of the present invention, the width of the web is
preferably less than the width of the arcuate segment but widths
less than about 0.002 inch should be avoided because of mechanical
inadequacy.
It has been found in practice that the viscosity of the molten
polymer varies more than the other factors and when the coalescence
performance is borderline, day-to-day variations in viscosity can
lead to continuing interruptions of the process. The spinnerets of
the present invention are less sensitive to fluctuations in
viscosity and have been much more effective in producing hollow
filaments having a low denier per filament.
The spinneret of the present invention may be used to produce
hollow filaments from any melt spinnable synthetic polymer
exhibiting bulging during spinning and is particularly suitable for
use with polyesters such as polyethylene terephthalate and its
copolyesters. What is claimed is: 1. In a spinneret plate provided
with at least one nozzle, for melt spinning filaments from molten
polymers, said nozzle being defined by a substantially symmetrical
pattern of four arcuate end-to-end slots interrupted by webs, said
nozzle forming a filament having a single hollow core the
improvement comprising, said slots having ends bearing inner
inwardly-tapered enlargements at the outer one-third portions
thereof, adjacent ends having proximate sides straight and parallel
throughout their entire lengths, said slots having outer
boundaries, said outer boundaries being the arc of a circle, the
inner one-third portion of said slot being of substantially uniform
width, the ratio of the distance c between adjacent slots and the
width b of the slots being less than unity, said single hollow core
being relatively smooth. 2. The spinneret plate as defined in claim
1, the ratio of the area of an outer one-third portion to the area
of the inner one-third portion being in the range of from about
1.15 to about 1.40. 3. The spinneret plate as defined in claim 2,
said ratio being 1.16. 4. The spinneret as defined in claim 1, said
enlargements being inwardly tapered at an angle with respect to the
end of the slot of less than 80.degree. and more than about
5.degree.. 5. The spinneret as defined in claim 4, said angle being
between 20.degree. to 60.degree. .
* * * * *