U.S. patent number 3,924,680 [Application Number 05/570,714] was granted by the patent office on 1975-12-09 for method of pyrolysis of coal in situ.
This patent grant is currently assigned to In Situ Technology, Inc.. Invention is credited to Ruel C. Terry.
United States Patent |
3,924,680 |
Terry |
December 9, 1975 |
Method of pyrolysis of coal in situ
Abstract
A method of pyrolysis of coal in situ includes the steps of
establishing a pair of passages between a sub-surface coal
formation and the surface with the coal passages being adapted to
separately remove liquids and gases from the coal formation,
establishing a sump at the bottom of the passages which extends at
least partially below the coal formation to receive liquid volatile
material released from the formation, and heating the coal
formation so that initially tars in the formation will migrate
radially until they go beyond the heated area whereupon they will
solidify and form a hermetic barrier around the zone to be
pyrolyzed to confine gaseous liquid volatile materials released
from the coal as a result of the pyrolysis. The released gaseous
materials can then flow to the surface through one of the passages
and the liquid volatile material can flow into the sump and be
pumped to the surface through the other passage.
Inventors: |
Terry; Ruel C. (Denver,
CO) |
Assignee: |
In Situ Technology, Inc.
(Denver, CO)
|
Family
ID: |
24280750 |
Appl.
No.: |
05/570,714 |
Filed: |
April 23, 1975 |
Current U.S.
Class: |
166/258; 166/259;
166/295 |
Current CPC
Class: |
E21B
43/247 (20130101) |
Current International
Class: |
E21B
43/16 (20060101); E21B 43/247 (20060101); E21B
033/138 (); E21B 043/24 (); E21B 043/26 () |
Field of
Search: |
;166/256,258,259,272,288,295,302 ;299/3,6,14 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Novosad; Stephen J.
Assistant Examiner: Suckfield; George A.
Attorney, Agent or Firm: Burton, Crandell & Polumbus
Claims
What is claimed is:
1. A method of pyrolysis of coal in situ comprising the steps
of:
establishing a hermetically sealed passage between a subsurface
coal formation and a surface location wherein said passage includes
means for removing both liquids and gases from the coal
formation,
heating at least a portion of the coal formation,
driving fluid tars in the coal which are mobilized by the heat
outwardly from the heated portion and allowing them to solidify in
lower temperature portions of the coal formation to define a fluid
impervious barrier around the heated portion, and
allowing volatile material released from the heated coal to be
removed through said passage and flow to a surface location.
2. The method of claim 1 further including the steps of:
establishing a cavity in the coal formation in fluid communication
with said passage, said cavity extending at least partially below
the coal formation, and
pumping liquid volatile material released from the heated coal
which has flowed into said cavity out of said cavity to a surface
location.
3. The method of claim 2 further including the step of establishing
two distinct passages between the coal formation and the surface
whereby liquids and gases can be transferred separately from the
coal formation to the surface.
4. The method of claim 3 further including the step of establishing
fluid permeable channels in the coal formation to facilitate the
flow of gaseous and liquid fluids released from the coal during
pyrolysis.
5. The method of claim 2 wherein said cavity is established so as
to be of a larger cross-sectional area than said passage.
6. The method of claim 1 wherein the coal formation is heated by
burning a second coal formation beneath said first mentioned coal
formation to supply heat to the first mentioned coal formation.
7. The method of claim 6 wherein the pressure in the coal formation
zone defined by said barrier is controlled by relieving the
pressure at the surface end of said passage.
8. A method of pyrolysis of coal in situ comprising the steps
of:
establishing a hermetically sealed passage between a subsurface
coal formation and a surface location wherein said passage includes
means for removing both liquids and gases from the coal
formation,
heating at least a portion of the coal formation,
injecting a thermo-setting sealant material into the formation
through said passage and allowing the sealant to flow radially from
the passage until it sets up to form a barrier around said portion
of the formation, and
allowing gaseous volatile material released from the heated coal to
be removed through said passage and flow to a surface location.
Description
BACKGROUND OF THE INVENTION
Coal is a complex material made up of hardy residuals from
vegetation that grew and died in ancient times. With the
multiplicity of vegetation sources, coupled with ensuing variations
in physical and chemical environments, coal is far from being a
uniform material. In the evolution of coal through geological time,
each deposit has been subjected to chemical action, submergence,
pressure from the over burden, and heat. As a result, the physical
and chemical characteristics show wide variations from deposit to
deposit.
Generally the composition and characteristics of coal can be
described as relative amounts of moisture, volatiles, fixed carbon
and ash. For the most part, the moisture and ash contents are
considered to be nuisances while the volatiles and fixed carbons
are considered to be useful materials.
Coal has been produced for many centuries for the benefit of
mankind. Almost without exception, coal has been removed from its
underground site and then transported to various points of use. In
the removal process, both nuisance components and useful components
are extracted together and are transported together to the points
of use. While it is highly desirable to leave moisture and ash
contents behind, commercial techniques for doing so are, at best,
successful only to a minor degree. Further, extraction techniques
beginning with the principle of the primitive pick and shovel have
not been improved upon, although significant improvements have been
made in mechanization of the pick and shovel concept.
With the wide variations in the characteristics of coal from
deposit to deposit, it becomes necessary to begin with the planned
end use for the coal in order to determine which deposit is a
suitable candidate for mining. For example, if the planned end use
is to make coke for the smelting of iron ore, then the virgin coal
must have desired coking characteristics. That is to say, the
virgin coal, when heated to high temperature with air excluded,
must give up its moisture content and a substantial amount of its
volatile content, and still retain sufficient mechanical strength
to withstand the rough handling inherent in the smelting process.
Further, a ready market must be available at the coking site for
the valuable coal chemicals that are present in the volatiles that
are removed in the coking process. The problem of selecting a
suitable coal for coking is further complicated by the fact that
one of the nuisances, the ash or mineral content of the coal, is
retained in the coke which later becomes an additive to waste slag
in the blast furnace. It is obvious that the selected coal deposits
should be in reasonable proximity of the end use facilities because
the cost of transporting the nuisance components can place a
significant cost disadvantage against the overall project.
Some coals are unusually rich in volatile content and thus are
attractive for the extraction of valuable coal chemicals. After
mining the coal and removal to proper facilities, the volatiles can
be removed by the application of heat in an environment that
excludes air, resulting in extraction of volatiles in liquid and
gaseous forms. The residue is coke (or for non-coking coal, char)
and the retained ash content. Since the residue is a substantial
portion of the original coal, commercial practices dictate that a
suitable market be found for the coke or char. The problem of
disposal of the nuisance ash then is passed on to the user of the
coke or char. Again, the mine, coal chemical extraction plant, and
the market for coke or char must be in reasonable proximity of each
other to offset the cost of transportation and disposal of the ash.
In this case, the second nuisance, moisture content, is largely
extracted at the time the coal chemicals are removed.
Heretofore, most pyrolysis of coal has required mining the coal,
using strip mining or underground mining techniques. The coal is
then processed above ground to remove as much debris as practical
and to crush the coal to appropriate sizes. The coal is then
transported to and placed in a suitable retorting vessel so that
heat may be applied in the absence of air to drive off the volatile
matter in gaseous and liquid form. After the volatiles are
substantially removed, the retort chamber and the residual coke or
char is removed. Since the residual coke or char is well above the
ignition temperature, care must be taken to cool the residual coke
or char rapidly to keep it from bursting into flame upon being
exposed to air. Such a process of necessity, is composed of many
costly steps of handling, requires many different items of
equipment and facilities, and requires substantial numbers of
employees (some of whom are located underground) to conduct and
control operations. Each of the steps in the process, tend to be a
batch operation in itself, resulting in numerous start-stop
operations. It is for these reasons that coal chemicals have had
difficulties in competing with chemicals from petroleum because
chemicals from petroleum can be produced in a series of continuous
processes from the crude oil reservoir to finished products.
As will be appreciated from the description of the invention
hereinafter, the processes for producing chemicals from coal in
accordance with the present invention are continuous in principle,
are competitive with chemicals from petroleum, require no man power
underground, and require substantially less costly equipment at the
surface than is required for conventional pyrolysis of coal.
Chemicals to be recovered from coal in situ in accordance with the
invention include Benzene (C.sub.6 H.sub.6), Toluene (C.sub.7
H.sub.8), Xylene (C.sub.8 H.sub.10), Naphthalene (C.sub.10
H.sub.8), Anthracene (C.sub.14 H.sub.10), Phenol (C.sub.6 H.sub.5
OH), Cresols (C.sub.7 H.sub.7 OH), Pyridene (C.sub.5 H.sub.5 N),
Methanol (CH.sub.3 OH), and others.
The processes to be described hereinafter result in the production
of coal somewhat analogous to the primary production of petroleum.
If the coal to be produced contains 30 percent volatile matter, for
example, than approximately 20 percent of the coal in place will be
produced as a fluid using the processes of the invention. Such
production compares favorably with normal primary production of
crude oil. Upon completion of production using the processes
described herein, the residual carbonized coal can be further
produced using one or more of the processes taught in my copending
patent applications Ser. Nos. 510,409 and 531,453.
OBJECTS OF THE INVENTION
It is an object of the present invention to provide a new and
improved process for removing coal chemicals from coal in situ,
thereby eliminating mining of the coal itself in the conventional
sense and eliminating costly surface facilities for the handling of
coal through a pyrolysis process.
It is another object of the present invention to provide a new and
improved process for removing coal chemicals from coal in situ
whereby the coke or char as well as the ash is left in situ.
It is another object of the present invention to provide a new and
improved process for pyrolyzing coal in situ which includes the
step of defining an underground pyrolyzing zone with a barrier of
fluid impervious material.
SUMMARY OF THE INVENTION
All coal has some degree of permeability and thus will permit the
passage of fluids along channels of permeability. If the fluid is a
gas, the fluid can be made to migrate under the influence of
differential pressure within the coal. Such a gas will move from a
higher pressure zone to a lower pressure zone and if the lower
pressure zone is connected to a conduit to the surface, the gas can
be delivered to the surface for processing. If the fluid is a
liquid, likewise the liquid can be made to migrate under the
influence of differential pressure or by gravity or by a lower
pressure zone or lower gravitational zone. If the zone of lower
pressure or lower gravitation, such as a sump, is connected to a
conduit to the surface, the liquid can be delivered to the surface
by differential pressure, gas lift or by pumps for further
processing or use.
Pyrolyzing or applying heat to coal results in the separation of
the volatile matter from the carbonized coal. Beginning at ambient
temperature, and with the application of heat in the absence of
air, the coal begins to expand, and entrained gases are expelled,
and at a temperature range above 100.degree.C (212.degree.F), the
coal gives up its entrained moisture content by evaporation or by
flashing to steam, resulting in the build up of formation pressure.
A conduit or conduits to the surface can relieve this pressure and
deliver steam to the surface. Initially the steam will encounter
cooler zones in the coal stratum and will condense into water. When
the total coal stratum is heated to a temperature above the boiling
point of water, released moisture may be removed to the surface as
steam.
Further application of heat to the coal stratum, for example up to
200.degree.C (392.degree.F) will result in the oozing of tars from
the coal which initially are quite viscous and for all practical
purposes, immobile. As more heat is added to the coal stratum, the
oozing tars become less and less viscous and will flow under the
influence of gravity and differential mine pressure. Further
applications of heat, for example up to 300.degree.C (572.degree.F)
cause some of the volatiles to vaporize into condensable gases.
Still further applications of heat will induce thermal cracking of
the volatiles resulting in both condensable and noncondensable
gases as measured at normal atmospheric temperatures. Without
relief, considerable internal pressure will be generated in the
coal strata. A suitable conduit to the surface, of course, can
release the pressure in the pyrolysis zone to the desired pressure
level and serve as a passage for the flow of produced fluids.
In order to facilitate a better understanding of the present
invention, it will be described in connection with a multilayered
coal deposit, such as commonly found in the western part of the
United States. These deposits are a series of coal strata separated
from each other by relatively thin sections of shale. The stratum
of coal affected by the present invention is immediately above a
thin shale stratum which overlies another coal stratum that is
being gasified. The gasification may be carried out in accordance
with one or more of the processes set forth in my copending
applications, Ser. Nos. 510,409 and 531,453. Waste heat from the
lower stratum being gasified is slowly released through the
overlying shale to the upper coal stratum resting on the shale.
Much of the waste heat lost from the gasification project is
captured in the processes described herein for further useful
work.
In a commercial project employing the processes described herein,
the areal extent of the coal stratum affected can encompass several
acres, for example 20 acres, that generally correspond to the areal
extent of the heat source which can be an underlying coal formation
subjected to in situ gasification. On the periphery of the coal
stratum to be subject to pyrolysis, there is a transistion zone
between the coal that has been heated and the outlying coal that is
at ambient temperature. In the initial stages of pyrolysis,
released fluids will escape from the affected zone into the
outlying stratum of coal. Hot tars migrating radially will enter
the transition zone, become cooled and immobile, will plug the
natural permeability of the coal that is being invaded, and will
form a pressure tight barrier in the transition zone. If there are
insufficient tars to provide a good seal, then a hot thermosetting
sealant can be injected from the surface into the coal stratum to
establish the barrier. This barrier seals an area of several acres
that may now be subjected to further pyrolysis, with production
efficiencies approaching, and sometimes exceeding, that of retorts
above ground. Attributes that are particularly advantageous to
production efficiencies include use of waste heat and the
substantially lower capital investment required.
Two factors are of particular importance in the early stages of a
pyrolysis project underground. These are the water content and the
permeability patterns of the underground coal stratum. If the coal
stratum is an aquifer it may be highly desirable to provide
facilities to dewater the coal and to control the ingress of
additional water. Upon application of heat to the formation, the
change of water to steam through the latent heat of vaporization is
highly endothermic, and thus will absorb enormous quantities of
heat for no useful purpose other than to make steam. The problem of
water encroachment is eliminated when the transition zone barrier
is established.
It is advantageous to know the patterns of underground permeability
in order to locate a pattern of conduits to the surface for
efficient production. Patterns of permeability can be determined
satisfactorily by taking a series of oriented cores through the
coal stratum. In cases where permeability is poor, additional
permeability can be obtained using fracturing techniques well known
in the petroleum industry.
Another method of increasing permeability is the technique of
electrolinking. Coal is a reasonably good conductor of electricity
with a resistance on the order of 1 ohm for each 10 lineal feet. By
placing two electrodes in the coal stratum, some distance apart,
for example 200 feet, and passing an electric current between the
two electrodes, electrolinking will occur. The electric current
will flow along the path of least resistance between the two
electrodes. This path will be something other than a straight line
and a continuing flow of an electrical current will increase the
temperature of the coal along this path. When the temperature in
the path reaches a sufficient level, for example 750.degree.F, the
coal begins to release gases and a permeable channel is established
for the flow of fluids. Repetition of this technique between
numerous points in the coal deposit can open a significant number
of permeable fluid channels.
After the coal formation to be pyrolyzed has been conditioned as by
the removal of water and the preliminary heating of the formation
resulting in the establishment of a suitable fluid impervious
barrier around the pyrolysis zone, the heat such as may be supplied
by an underlying burning coal formation is allowed to separate the
volatile materials in the coal from the carbonized coal with the
gaseous volatiles being allowed to escape to the surface through a
passage provided therefor and the liquid volatiles being allowed to
flow into a sump from which a pump can convey the liquid volatiles
to the surface.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a diagrammatic vertical section taken through a portion
of the earth illustrating the geologic relationship of the coal
zone to be pyrolyzed with a lower coal zone being gasified.
FIG. 2 is a diagrammatic plan view illustrating a possible well
pattern for use in practicing the method of the present
invention.
FIG. 3 is a diagrammatic vertical section taken through a well and
surrounding subsurface formation, the well being designed for use
in the method of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring first to FIG. 1, a geologic condition ideal for
practicing the method of the present invention is illustrated. It
will there be seen that the coal stratum or formation 10 to be
pyrolyzed is situated beneath a thin shale zone 12 which lies
immediately beneath what will be termed the overburden 14 and above
a second thin shale zone 16 which overlies a second or lower coal
stratum 18. The lower coal stratum 18 overlies a bed of clay 20 or
the like defining the lower limit of the lower coal stratum. Also
illustrated in FIG. 1 are a pair of wells 22 which establish
passages of communication between the surface of the ground and the
lower coal formation 18. These wells are used for the injection of
gasifying agents and the removal of gases for in situ gasification
of the lower coal stratum which may be carried out in accordance
with the teachings in my copending United States patent
applications Ser. Nos. 510,409 and 531,453.
The heat generated by the burning coal in the lower stratum or
formation 18 during the gasification process is transmitted through
the shale layer 16 separating the coal stratums and supplies the
heat for pyrolysis of the upper coal stratum 10.
Prior to the start of production activities, several wells 24
(FIGS. 2 and 3) may be drilled from the surface to the upper coal
stratum and oriented cores taken through the coal to determine the
permeability pattern. With permeability information thus derived, a
proper pattern of production wells can be established to make
maximum use of available permeability channels. If greater
permeability is desired, it can be obtained by conventional oil
field practices such as hydrofracking, explosive fracking, etc. or
by electrolinking as described in the Summary of the Invention.
Production of volatile liquids and gases through pyrolysis may be
obtained with a single production well 24, such as shown in FIG. 3,
or with a multiplicity of wells located, possibly as shown in FIG.
2, on channels of maximum permeability in the coal stratum 10.
A further pre-production step would include testing the coal
stratum 10 for its free water content. If the coal stratum 10 is an
aquifer, then an outer group of service wells 26 may be drilled
outside the pyrolysis zone 28 into the upper coal stratum to remove
excess water. The water removal phase can be expedited by
installing pumps in the service wells 26 and in the production
wells 24 provided in the pyrolysis zone.
Removal of water is continued while the upper coal stratum 10 is
heated by the underlying burning coal formation causing the liquid
volatiles, such as tars, to migrate radially outwardly until they
are slightly beyond the pyrolysis zone 28. Typically, the tars will
begin to soften at about 500.degree.F and will begin to migrate at
about 800.degree.F. The migration of tars can be effected by
raising the formation pressure as occurs normally with the
application of heat in the pyrolysis zone and/or lowering the
pressure in the surrounding areas in a conventional manner via the
service wells 26. Once the tars have migrated beyond the heated
pyrolysis zone, the cooler temperatures, approximately 60.degree.F
to 80.degree.F in a transition zone 30 allow the tars to solidify
and form a fluid impervious barrier 32 around the pyrolysis zone.
After the barrier 32 is established, the removal of water can be
terminated as the pyrolysis zone will then be sealed off from
encroaching water. A fluid impervious barrier could also be formed
by injecting a thermo-setting sealant material into the formation
and allowing it to radiate outwardly until it sets up in the
formation.
A preferred embodiment of a production well 24 is illustrated in
FIG. 3 and is established by drilling a bore 34 through the
overburden 14, the upper shale layer 12 and the upper coal stratum
10. An hermetically sealed casing 36 is set in the well bore with
the cement 38 from the top of the upper coal formation 10 to the
surface 40. At the top of the casing, an exit conduit 42 is
provided through which gases produced from pyrolysis can flow and
valve means (not shown) are provided to control the flow of gases
therethrough. A string of tubing 44 is positioned inside the casing
36 defining an annulus 46 in communication with the exit conduit 42
and a pump 48 is installed at the lower end of the tubing for the
production of liquids from the pyrolysis zone. An enlarged cavity
50 is provided at the bottom of the well bore so as to extend at
least partially into the shale formation 16 separating the upper
and lower coal formation. This cavity may be formed by underreaming
the well bore in a manner conventionally practiced in the petroleum
industry. The cavity, which may extend for example, one foot into
the shale, forms a sump for the collection of liquids. It is
important that the sump be located in a hot area so that liquids
will be kept hot and fluid for removal by the pump 48.
With the fluid impervious barrier 32 circumscribing the pyrolysis
zone 28 and with at least one production well 24 established, the
pyrolyzed upper coal formation 10 is ready for production. As more
and more heat is applied to the shale stratum 16 by the underlying
burning coal formation 18, the coal in the upper coal formation 10
continues to ooze tars which may be referred to as liquid
volatiles. The liquid volatiles drain into the sump or cavity 50
where they are pumped to the surface by the pump 48. When the
temperature in the sump reaches thermal cracking temperatures, for
example 1,800.degree.F., some of the liquid volatiles will be
cracked to gases and may be removed through the annulus 46 and be
produced with gaseous volatiles released during pyrolysis through
the exit conduit 42 provided in the casing 36. Gaseous volatiles,
such as methane, are of course released from the coal by the
pyrolysis and flow directly through the annulus 46 to the exit
conduit 42. The rate at which the gaseous volatiles are released,
which is controlled by the valve (not shown) in the exit conduit
42, determines the pressure in the formation, thus allowing the
pressure to be maintained at desired levels.
Produced fluids, both liquids and gas, may be processed at the
surface after recovery in facilities (not shown) similar to those
used conventionally in connection with above ground pyrolysis
retorts with the valuable coal chemicals being separated into
useful components such as benzene, anthracene, cresol, and the
like. Production may be continued as described so long as the
volatile matter is released in volumes of commercial value.
Although the present invention has been described with a certain
degree of particularity, it is understood that the present
disclosure has been made by way of example and that changes in
details of structure may be made without departing from the spirit
thereof.
* * * * *