U.S. patent number 3,924,031 [Application Number 05/343,806] was granted by the patent office on 1975-12-02 for method for metal coating diamonds so as to improve the interfacial bond strength.
This patent grant is currently assigned to De Beers Industrial Diamond Division Limited. Invention is credited to Bruce I. Dewar, Michael G. Nicholas, Peter M. Scott.
United States Patent |
3,924,031 |
Nicholas , et al. |
December 2, 1975 |
Method for metal coating diamonds so as to improve the interfacial
bond strength
Abstract
A method of producing metal coated diamond particles in which
the coatings are strongly bonded to the diamond particles
characterised in that a layer of an alloy consisting of a major
proportion of a metal such as copper, nickel or iron and a minor
proportion of a carbide-forming metal such as titanium, chromium or
vanadium is applied to the uncoated particles and then the coated
particles are heat treated to a temperature of between 500.degree.C
and a temperature just below the melting point of the alloy for a
time sufficient to enable a bonding carbide layer to form at the
alloy/diamond interface, the steps being carried out in a
non-oxidising atmosphere. The invention further provides diamond
particles having bonded thereto an alloy comprising a major
proportion of nickel and a minor proportion of a carbide-forming
metal such as titanium, chromium or vanadium, the bonding being
achieved by means of a carbide layer, which is preferably
continuous, at the alloy/diamond interface.
Inventors: |
Nicholas; Michael G. (Wantage,
EN), Scott; Peter M. (Newbury, EN), Dewar;
Bruce I. (Johannesburg, ZA) |
Assignee: |
De Beers Industrial Diamond
Division Limited (Johannesburg, ZA)
|
Family
ID: |
26249768 |
Appl.
No.: |
05/343,806 |
Filed: |
March 22, 1973 |
Foreign Application Priority Data
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|
|
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Mar 22, 1972 [UK] |
|
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13426/72 |
Mar 22, 1972 [UK] |
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13427/72 |
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Current U.S.
Class: |
427/217; 51/295;
427/250; 427/294; 427/383.3; 427/399 |
Current CPC
Class: |
C09K
3/1445 (20130101) |
Current International
Class: |
C09K
3/14 (20060101); B05D 007/00 () |
Field of
Search: |
;117/1B,DIG.11,228,118,71R ;51/295 ;427/217,250,294,383,399 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Konopacki; Dennis C.
Attorney, Agent or Firm: Young & Thompson
Claims
We claim:
1. A method of producing a metal coated diamond particle including
the steps of applying to an uncoated diamond particle a layer which
in the as-applied condition is an alloy comprising a major
proportion of a metal selected from copper, nickel and iron and a
minor proportion of a carbide-forming metal selected from titanium,
chromium and vanadium sufficient to form a continuous carbide layer
around the diamond particle, and heat treating the particle to a
temperature in the range of from 500.degree.C. to a temperature
just below the melting point of the alloy for a time sufficient to
produce a continuous bonding carbide layer at the alloy/diamond
interface and an interface bond strength in excess of 10
kg/mm.sup.2, the steps being carried out in a non-oxidizing
atmosphere.
Description
This invention relates to the metal coating of diamond.
Very extensive use is made of diamond in abrasive tools such as
crowns, single point tools, resin and metal bond wheels, saws and
compacts. Considerable amount of research has gone into improving
the bonding properties of the diamond to the matrices of these
tools as a poor bond at the diamond/matrix interface leads to
dislodgment of the diamond from the matrix during the abrading
operation. This research has led to the development of metal coated
diamond particles which find application particularly in resin bond
wheels. Such metal coated particles have been found to have
retention properties in resin bond wheels which are superior to
uncoated diamond particles. However, research continues in an
effort to improve the bond strength of the metal/diamond interface,
thereby to improve the retention properties of diamond in the
matrices of abrasive tools.
It is an object of this invention to provide a method of bonding an
alloy to diamond which provides a strong interfacial bond between
the alloy and the diamond.
It is a further object of the invention to provide a novel metal
coated diamond particle.
According to the invention, there is provided a method of producing
a metal coated diamond particle including the steps of applying a
layer of an alloy comprising a major proportion of a first metal
and a minor proportion of a carbide-forming metal to an uncoated
particle and heat treating the particle at a temperature in the
range of from 500.degree.C to a temperature just below the melting
point of the alloy for a time sufficient to enable a bonding
carbide layer to form at the alloy/diamond interface, the steps
being carried out in a non-oxidising atmosphere.
It has been found that the bond strength of the alloy/diamond
interface is a function of the temperature of heat treatment, the
period of heat treatment and the concentration of carbide-forming
metal in the alloy and that by suitably controlling these factors
the bond strength can be maximised. Bond strengths in excess of 10
kg/mm.sup.2 can be achieved.
In order to achieve maximum bond strength it is preferred to
provide sufficient carbide-forming metal in the alloy for a
continuous carbide layer to be formed at the diamond/alloy
interface. The amount necessary to achieve this will vary with the
depth of the alloy layer. For example it has been found that for
alloy depths of about 1000 A, a carbide-forming metal content of
between 10 and 30 percent by weight of the alloy produces a
continuous layer of carbide at the diamond/alloy interface after
the heat treatment.
The first metal may be any suitable metal for coating diamonds, for
example copper, nickel or iron.
The carbide-forming metal is preferably a transition metal and
preferably one selected from the group of titanium, vanadium and
chromium.
The amount of alloy layer which is applied to the diamond particle
will vary according to the particle and the application to which
the coated particle is to be put. The choice of a particular amount
for a particular situation is, however, well within the knowledge
of one skilled in the art.
The particles may be in the form of large particles or grit such as
RD, SD, or MD grit. The coated grit is particularly suited for use
in resin bond and metal bond wheels, saws and compacts. The coated
larger particles find application in crowns and single point
tools.
The non-oxidising atmosphere may be provided by helium, argon,
hydrogen, nitrogen or a vacuum of the order of 10.sup.-.sup.2
mm.Hg.
The layer of alloy may be applied to the diamond particles using
known deposition techniques such as vacuum evaporation or
sputtering techniques. These techniques are well known in the art
and descriptions of them can be found in such references as "Vacuum
Deposition of Thin Films" by L. Holland, Chapman and Hall, 1st
Edition 1956.
Any temperature in the above described range can be used. The upper
limit of the range of preferably about 50.degree. C below the
melting point of the alloy. However, where high melting alloys are
used, the temperature is preferably maintained below the
graphitization temperature of diamond.
According to another aspect of the invention, there is provided a
diamond particle having bonded thereto a layer of an alloy
comprising a major proportion of nickel and a minor proportion of a
carbide-forming metal, the bonding being achieved by means of a
carbide layer at the alloy/diamond interface. The bonding carbide
layer is preferably a continuous layer.
The carbide forming metal is preferably chosen from those described
above.
An outer layer of nickel or metal capable of alloying with nickel
will preferably be provided on the outer surface of the alloy
layer. The choice of metal and the amount of it in the outer layer
will depend on the application to which the coated particle will be
put. One skilled in this art can, however, readily make these
choices. The outer layer can be deposited on the alloy-coated
particle using known deposition techniques such as electrolytic or
electroless deposition techniques or the vacuum deposition
techniques described above.
The invention will be illustrated by the following nonlimitative
examples.
EXAMPLE 1
In order to illustrate the maximisation of the bond strengths at
the diamond/alloy interface certain experiments were carried out on
diamond plaques.
Nickel and copper based alloys were bonded to the diamond plaques.
In each case, the relevant alloy was made in a conventional manner
and then swaged into an ingot of a desired diameter, e.g. 1.5 mm.
The ingot was then cut into required lengths and a length placed on
the diamond which in turn rested on a graphite anvil in a chamber
consisting of a quartz tube clamped between water cooled top and
bottom brass plates. The chamber was evacuated by a rotary pump to
10.sup.-.sup.2 mm Hg or better pressure and maintained at this
pressure during heating. A silica piston entered the vacuum chamber
through a Wilson seal in the top plate and was used to apply
pressure to the samples on the anvils. The pressure applied was
sufficient to provide intimate contact between the alloy and the
diamond equivalent to coating. The pressures used varied between
about 3 to about 7.5 kg/mm.sup.2. Induction heating was then used
to raise the temperature of the chamber to the desired temperature
i.e., 700.degree. or 800.degree.C. Excellent solid phase bonding
between the alloy and the diamond resulted in each case.
Using this method optimum conditions have been determined for a
number of nickel and copper based alloys.
In all cases, the temperature was 800.degree.C, save for the Cu-Ti
alloy in which the temperature was 700.degree.C.
1. cu-Ti: 0.54 wt % Ti. Optimum time about 5 hours. Bond strength
24.2 kg/mm.sup.2.
2. Cu-Cr: 0.22 wt % Cr. Optimum time about 1.5 to 2.0 hours. Bond
strength 21.4 kg/mm.sup.2.
3. Nichrome V (80% by weight nickel and 20% by weight chromium):
Optimum time about 2 hours. Bond strength 14.2 kg/mm.sup.2.
4. Ni-Ti: 1 wt % Ti. Optimum time about 0.5 hours. Bond strength
28.3 kg/mm.sup.2.
5. Ni-V: 0.83 wt % V. Optimum time about 2 hours. Bond strength
26.2 kg/mm.sup.2.
The bond strengths i.e. interfacial tensile strengths, were
measured in a standard manner using a shearing jig to which was
attached a Hounsfield tensometer.
EXAMPLE 2
40-50 mesh MD diamond grit was coated with a layer of
nickeltitanium alloy (1 percent by weight titanium) using known
vacuum sputtering techniques described in the Holland reference
mentioned above. A layer amounting to 1 to 2 percent by weight of
the uncoated particle was deposited. The coated particles were heat
treated at a temperature of 800.degree.C for half an hour in a
vacuum furnace (10.sup.-.sup.2 mm/Hg).
A layer of nickel was then deposited on the treated grit using
known electroless deposition techniques. The nickel layer amounted
to 20 percent by weight of the alloy-coated particle.
For purposes of comparison, pure nickel coated grit of the same
size was prepared using the same electroless deposition techniques.
The nickel coating amounted to 20 percent by weight of the uncoated
grit.
The two types of coated grit were incorporated in saws and sawing
tests carried out. It was found that the saw containing the grit
having the alloy layer showed twelve percent less wear than the
other saw.
EXAMPLE 3
RD diamond grit was coated with a nickel-titanium alloy (1 percent
by weight titanium) and a nickel outer coat using the same method
as in Example 2, except that the nickel layer amounted to a 55
percent by weight of the alloy-coated grit.
Similarly, RD grit was coated with a 55 percent pure nickel
coating. The two types of grit were incorporated in resin bond
wheels. During grinding tests it was observed that the diamond grit
was never pulled out of its coating in the case of the alloy
coatings, whereas this did occur with the pure nickel coated
particles. This test illustrates the strength of the diamond/alloy
interfacial bond.
EXAMPLE 4
A layer of nickel-chromium alloy (10 percent by weight nickel) was
deposited on diamond plaques using sputtering techniques. The
coated plaques were heat treated at 800.degree.C for 2 hours. A
nickel overlayer was electrolytically deposited on the alloy
layer.
The diamond/alloy interfacial tensile strength or bond strength was
found to be 10 kg/mm.sup.2 using the same apparatus as that
described in Example 1.
* * * * *