U.S. patent number 3,923,970 [Application Number 05/456,236] was granted by the patent office on 1975-12-02 for stable aerosol shaving foams containing mineral oil.
This patent grant is currently assigned to Carter-Wallace, Inc.. Invention is credited to Hans Breuer.
United States Patent |
3,923,970 |
Breuer |
December 2, 1975 |
Stable aerosol shaving foams containing mineral oil
Abstract
A shaving cream composition packaged in a pressure container
comprising an emulsion system characterized by good foam stability
when discharged from the container said emulsion comprising from 4
to 16% by weight of sodium, potassium and/or alkylolamine soaps of
fatty acids, 1 to 6% by weight of emulsifiers of the class of
sorbitan esters of fatty acids, 0 to 4% by weight of an amide, 5 to
25% by weight of mineral oil and the balance composed of auxiliary
emulsifiers, stabilizers, surfactants, perfume and water.
Inventors: |
Breuer; Hans (Somerville,
NJ) |
Assignee: |
Carter-Wallace, Inc. (New York,
NY)
|
Family
ID: |
23812005 |
Appl.
No.: |
05/456,236 |
Filed: |
March 29, 1974 |
Current U.S.
Class: |
424/47; 514/554;
424/73; 514/558; 510/406; 510/421; 510/437; 510/417 |
Current CPC
Class: |
A61K
8/361 (20130101); A61Q 9/02 (20130101); A61K
8/046 (20130101) |
Current International
Class: |
A61K 007/06 ();
A61K 007/15 () |
Field of
Search: |
;424/47,73,170,172,70
;252/90 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Goldberg; Jerome D.
Assistant Examiner: Clarke; Vera C.
Attorney, Agent or Firm: Clarke; Kevin B.
Claims
What is claimed is:
1. An aqueous soap emulsion suitable for aerosolization comprising
about 4 to about 16% by weight of a water-soluble soap selected
from the group consisting of sodium, potassium, ammonium, an
alkylolamine soap of a fatty acid and mixtures thereof, from 3 to
6% by weight of an emulsifier selected from the group consisting of
a sorbitan ester of a fatty acid and a polyoxyethylene oleyl ether
having an HLB of 1-9 and from 5 to about 25% by weight mineral
oil.
2. The soap emulsion in accordance with claim 1 which also includes
up to about 4% by weight of an amide of lauric acid with
diethanolamine.
3. The soap emulsion in accordance with claim 1 wherein said
emulsifier is a sorbitan ester having an HLB of 1-9.
4. The soap emulsion in accordance with claim 3 wherein said
sorbitan ester is a srobitan ester of oleic acid having an HLB of
1.8 to 5.0.
5. An aerosol shave cream package comprising a valve-controlled
pressure-tight container containing from 1 to 15% of a liquefied
propellant gas and the balance being the soap emulsion of claim
1.
6. The aerosol shave cream package in accordance with claim 5
wherein said emulsion includes from 1 to 6% by weight of said
sorbitan ester.
7. The shave cream package of claim 6 wherein said sorbitan ester
is present in an amount of from 4 to 5% by weight.
8. The shave cream package of claim 7 wherein said sorbitan ester
is sorbitan sesquioleate.
9. The shave cream package of claim 7 wherein said sorbitan ester
is sorbitan monolaurate.
Description
BACKGROUND OF THE INVENTION
This invention relates to pressurized shaving cream compositions
which provide relatively stable aerosol shaving foams having
improved lubricating properties. More particularly, this invention
relates to a foam concentrate in a pressure container which
concentrate when discharged produces stable, rigid shaving foams
characterized by good lubricating properties as well as persisting
throughout the shaving operation.
While aerosol shaving creams having been popular for the past
twenty years, these compositions have been the subject of
continuing research in order to improve their characteristics,
particularly foam characteristics, and overcome consumer
dissatisfactions. For example, much effort has been expended on
improving the lubricating properties of the lathers so as to
protect the face and speed the shaving operation. In the course of
these efforts, a wide variety of additives for the shaving cream
compositions have been proposed and tested. For instance,
polysiloxanes have been added in amounts of up to 5% by weight to
enhance lubricity. Similarly, up to 5% of water-soluble polymeric
materials such as polyvinylpyrrolidone, polyacrylamide,
carboxymethylcellulose, polyethylene oxide, and copolymers of
acrylic acid and polyallyl sucrose have been employed for the same
purpose. Additionally, oily materials such as lanolin, lanolin
fractions, petrolatum, mineral oil, fatty acids, fatty alcohols,
etc. have been added to shaving creams in varying amounts from
about 0.5% up to about 20% by weight for a variety of reasons
including lubrication.
In the preparation of the prior art emulsions as heretofore
described, it is the preferred practice in preparing concentrate
emulsions to add lipophilic emulsifiers to the oil phase and
hydrophilic emulsifiers to the water phase. The water phase is then
added to the oil phase such procedures as described by W. C.
Girffin in Sagarin, Cosmetic Science and Technology p. 1025 (1957)
as well as in Sanders, P. Aerosol Emulsion Foams J. Soc. Cos. Chem.
Vol. 24, No. 10, P. 637, September, 1973.
Alternatively, the oil phase may be added to the water phase, but
in all cases, a lipophilic emulsifier is added to the oil phase and
a hydrophilic emulsifier is added to the water phase.
In preparing the compositions of the prior art following the
conventional compounding methods, the foams obtained upon extrusion
of the emulsion from the aerosol container are generally
characterized by a soft watery consistency. It is often necessary
to subject the container to vigorous and prolonged shaking in order
to obtain a suitable foam for shaving. This has been found to be
particularly true in the case of concentrates containing mineral
oil. The latter not only tend to yield weak and unstable foams when
extruded from the container, but in addition when propellant is
being added during the filling operation the emulsions tend to
separate, giving different lather properties depending on how hard
the container is shaken before use.
It has now been found that pressurized shaving cream compositions,
containing emollient materials, and which have improved lubricating
qualities and relatively good emulsion stability are obtained when
such shaving cream compositions include as emulsifiers sorbitan
esters of fatty acids having an HLB of 1-9. In addition ethers of
oleyl alcohol and ethylene oxide which have a similar HLB are also
suitable.
DESCRIPTION OF THE INVENTION
The shaving cream compositions of the present invention comprise
from about 4 to 16% by weight of a water-soluble soap selected from
the group comprising sodium, potassium, ammonium and alkylolamine
soaps of fatty acids containing 8 to 24 carbon atoms; from about 1
to 6% by weight of a sorbitan emulsifier of the class of sorbitan
esters of fatty acids and ethers of oleyl alcohol and ethylene
oxide having an HLB of 1-9; and from about 10 to 20% of an
emollient material such as mineral oil.
The preferred compositions of the present invention are a blend
of:
a. Sodium and/or potassium and alkylolamine soaps of fatty acids
varying in chain length from 8-22 carbon atoms. The total soap
level may vary from 4 to 16% by weight. The ratio of alkali to
triethanolamine bases is not critical to this invention.
b. Emulsifiers of the class of sorbitan esters of fatty acids
having an HLB of 1-9. Particularly sorbitan esters of oleic acid
having an HLB of 1.8-5.0 are suitable. Ethers of oleyl alcohol and
ethylene oxide which have similar HLB are also suitable. The
sorbitan emulsifiers are present in amounts of from 1 to 6% by
weight, preferably 4 to 5% by weight.
c. Amides of lauric acid with diethanolamine made according to the
Kritschevsky process or by reacting methyl laurate with
diethanolamine. The amides are present in amounts of from 0 to 4%
by weight.
d. Mineral oil of Saybolt viscosities of 48-364 universal seconds
at 100.degree.F. The mineral oil, which is present in amounts of
from 5 to 25% by weight, must be of cosmetic, NF or USP grade.
e. The balance of the formulations is composed of auxiliary
emulsifiers such as gums, polyvinylpyrrolidone or similar
stabilizers of other surface active agents of the class of
ethoxylated fatty acid esters or ethers and ethoxylates of sorbitan
fatty acid esters, perfume and water.
Table 1 which follows sets out ten specific examples of the novel
compositions of the present invention.
Additional ingredients which are compatible with the described
shaving cream compositions can also be added to modify or enhance
the properties thereof as desired. For example, up to about 4% of
an amide of a C.sub.8 -C.sub.18 fatty acid as well as minor
proportions of 0.5 to 3% by weight of water-soluble synthetic
anionic, amphoteric or nonionic wetting agents such as lauryl
sulfate salts, higher alkyl substituted imidazolinium salts can be
included to further modify lather characteristics. In addition
small amounts of water-soluble polymeric materials such as
polyvinylpyrrolidone, polyacrylamide, carboxymethyl cellulose etc.
and humectants such as glycerin, propylene glycol, sorbitol and
polyethylene glycols can be added. Also, minor amounts of various
adjuvants such as water-soluble and water-insoluble germicides,
coloring agents, sequestering agents, menthol, and corrosion
inhibitors such as silicates, phosphates, etc. may be incorporated
in the compositions.
The propellant used in the inventive compositions can be any
liquefied, normally gaseous, hydrocarbon or halogenated hydrocarbon
or mixture thereof which is effective to provide a pressure in the
range of about 30 to 70 p.s.i.g., preferable 40 to 55 p.s.i.g., in
the ultimate container.
TABLE 1
__________________________________________________________________________
EXAMPLES 1-10
__________________________________________________________________________
INGREDIENT 1 2 3 4 5 6 7 8 9 10
__________________________________________________________________________
Stearic Acid, Triple Pressed, Flake OR 7.63 7.63 7.63 7.63 7.63
7.63 8.63 7.63 7.63 7.63 Stearic Acid, Emersol 132 Lily, Flake
Stripped Coconut Fatty Acid 0.85 0.85 0.85 0.85 0.85 0.85 0.85 0.85
0.85 -- Potassium Hydroxide (45%) 2.32 2.32 2.32 2.32 2.32 2.32
2.32 2.32 2.32 2.32 Sodium Hydroxide, Beads 0.25 0.25 0.25 0.25
0.25 0.25 0.25 0.25 0.25 0.25 Glycerin, U.S.P. 3.99 3.99 3.99 3.99
3.99 3.99 3.99 3.99 3.99 3.99 Triethanolamine, N.F., (85%) 1.17
1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 Light Mineral Oil,
N.F. 13-16 centi- stokes 14.00 14.00 14.00 14.00 14.00 -- 14.00
14.00 14.00 14.00 Lauramide DEA 2.00 2.00 2.00 2.00 -- 2.00 2.00 --
2.00 2.00 Polyvinylpyrrolidone (PVP-K-30) 0.15 0.15 0.15 0.15 0.15
0.15 0.15 0.15 0.15 0.15 Perfume 33.269/B/NY 0.46 0.46 0.46 0.46
0.46 0.46 0.46 0.46 0.46 0.46 Sorbitan Sesquioleate (Arlacel 83)ICI
4.64 -- -- -- 4.64 4.64 4.64 -- 4.64 4.64 Deionized Water 55.39
55.39 55.39 55.39 55.39 55.39 55.39 55.39 55.39 55.39 Propellant
Mix "0" (P12/P22:90.8%/9.2%) 7.15 7.15 7.15 7.15 7.15 7.15 7.15
7.15 -- -- Sorbitan Monolaurate -- 4.64 -- -- -- -- -- -- -- --
Sorbitan Monopalmitate -- -- 4.64 -- -- -- -- -- -- -- Sorbitan
Monostearate -- -- -- 4.64 -- -- -- -- -- -- Superamide L-9C (Onyx
Oil and Chem.) -- -- -- -- 2.00 -- -- -- -- -- Mineral Oil, USP
38-41 centistokes -- -- -- -- -- 14.00 -- -- -- -- Polyoxyethylene
(2) oleyl ether -- -- -- -- -- -- -- 4.64 -- -- n-propane -- -- --
-- -- -- -- -- 7.15 7.15 Lauric Acid (95% min. purity) -- -- -- --
-- -- -- -- -- 0.85 TOTAL 100.00 100.00 100.00 100.00 100.00 100.00
100.00 100.00 100.00 100.00
__________________________________________________________________________
The well known C.sub.3 -C.sub.4 hydrocarbons as well as the
chlorofluorinated C.sub.1 -C.sub.2 hydrocarbons are suitable
propellants because they are odorless, non-toxic and exhibit
minimal skin irritation tendencies. The propellant may also be
formed of a mixture of two or more such compounds. Suitable
propellants include dichlorodifluoromethane (CCl.sub.3 F),
dichlorotetrafluoroethane (CClF.sub.2 CClE.sub.2),
monochloropentafluoroethane (CClF.sub.2 CF.sub.3),
dichloromonofluoromethane (CHCl.sub.2 F), monochlorodifluoromethane
(CHClF.sub.2), monochlorodifluoroethane (CH.sub.3 CClF.sub.2),
trichlorotrifluoroethane (C.sub.2 Cl.sub.3 F.sub.3), and
difluoroethane (CH.sub.3 CHF.sub.2). Preferred propellants are
propane, dichlorodifluoromethane and mixtures of
dichlorodifluoromethane and dichlorotetrafluoroethane.
As indicated above, the proportion of propellant must be sufficient
to provide the desired pressure within the container. Generally,
the propellant will be present in an amount of from 1 to 15% by
weight of the composition, and preferable about 2.5 to 8% by
weight. After giving effect to the known vapor-reducing effects of
the oily material such as mineral oil, the proportion of propellant
or propellant mixture can be readily ascertained by calculation.
Moreover, the propellant level depends greatly upon the molecular
weight and density of the particular gas used.
Further improvements in the handling properties of the emulsions
present in the invention are attained when the novel method of
formulation disclosed in copending application Ser. No. 456,237
filed concurrently herewith is employed. This process allows the
formulations, such as exemplified by Examples 1-10 to remain
reasonably fluid (200-2,000 cps.) at the point of aerosolization
and at room temperature. Thus, the emulsions are easy to handle
during manufacturing and filling as well as during pressuring.
Normally the concentrates of the present invention are prepared by
adding lipophilic emulsifiers to the oil phase and hydrophilic
emulsifiers to the aqueous phase. The water phase is then added to
the oil phase. It has been found that by following the process of
said copending application when the mineral oil phase is added as
the last essential ingredient, at the end of the soap formation,
just before cooling and before adding the perfume, a much thinner
lotion is obtained which can be easily handled during processing
and aerosolization.
The novel compositions of the present invention as exemplified by
Examples 1-10 are prepared as follows:
The polymeric material such as polyvinylpyrrolidone is admixed with
deionized water in a processing kettle equipped with a large and
small mixer both operated at high speed, after the
polyvinylpyrrolidone is completely dispersed and the mixture lump
free, the mixers are slowed and the following ingredients added in
the order indicated:
1. Humectant i.e. glycerin -- if required
2. Potassium hydroxide and/or sodium hydroxide
3. Triethanolamine
The mixers are again operated at high speed and stearic acid is
slowly added at a rate designed to easily disperse the acid and
prevent clumping, upon complete dispersion of the stearic acid the
batch is heated to 60.degree. .+-. 2.degree.C and additional water
is added when the batch temperature reaches approximately
60.degree.C the following ingredients are added in the order
indicated:
1. Coconut fatty acid or equivalent
2. Lauric diethanolamide if required
The batch is then heated to 80.degree. .+-. 2.degree.C and held at
this temperature for a period of time sufficient to melt all waxes.
While the batch is mixed. A sorbitan oleate is then added and the
batch mixed for an additional 5 minutes maintaining the temperature
at 80.degree. .+-. 2.degree.C. While maintaining the temperature of
the mixture, mineral oil is then added at a uniform rate over a 5
minute period. After all of the mineral oil has been added the
batch is held at 80.degree. .+-. 2.degree.C for approximately 10
minutes and the batch is then pumped from the kettle and cooled to
23.degree. .+-. 3.degree.C, perfume is added and the entire batch
mixed until of a uniform consistency being careful not to aerate
the batch.
In some of the examples, notably No. 4 all or part of the sorbitan
oleate may be premixed with the mineral oil. This component is then
added at the point where mineral oil would normally be incorporated
as described above.
The compositions of the present invention prepared in the manner as
hereinabove described are readily adapted for use in conventional
aerosol dispensers now in use in a manner well known to those
skilled in the art.
The foams obtained from the concentrates of the present invention
exhibit desired wetting action while at the same time lubricating
the face so that a minimal razor drag is experienced. Additionally,
the lather serves to deposit an oil film on the skn and thus leaves
the face smooth and in non-irritated condition.
* * * * *