U.S. patent number 3,922,378 [Application Number 05/498,302] was granted by the patent office on 1975-11-25 for fluorinated hydrocarbon coating method.
This patent grant is currently assigned to Medical Evaluation Devices & Instruments Corporation. Invention is credited to William M. Kline.
United States Patent |
3,922,378 |
Kline |
November 25, 1975 |
Fluorinated hydrocarbon coating method
Abstract
This invention is directed to a method of forming an unbroken
uniform transparent coating of a fluorinated hydrocarbon resin on a
flexible coil spring, wire or similar substrate by immersing the
substrate in a dispersion of the selected resin and removing the
dispersion coated substrate therefrom, initially drying the
disperson coated substrate, heating same to a predetermined
temperature over a predetermined period of time, and then slowly
cooling the thus heated coated substrate over a predetermined
period of time to a temperature as low as or lower than a
predetermined lower temperature.
Inventors: |
Kline; William M.
(Gloversville, NY) |
Assignee: |
Medical Evaluation Devices &
Instruments Corporation (Gloversville, NY)
|
Family
ID: |
26958901 |
Appl.
No.: |
05/498,302 |
Filed: |
August 19, 1974 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
278099 |
Aug 4, 1972 |
|
|
|
|
Current U.S.
Class: |
427/2.24;
427/379; 427/120; 427/388.4; 600/585; 427/2.28 |
Current CPC
Class: |
H01B
19/04 (20130101); B05D 5/083 (20130101); B05D
3/0209 (20130101); B05D 7/16 (20130101); H01B
13/065 (20130101); B05D 3/0254 (20130101); B05D
1/18 (20130101) |
Current International
Class: |
H01B
19/04 (20060101); H01B 13/06 (20060101); H01B
19/00 (20060101); B05D 7/20 (20060101); B05D
5/12 (20060101); B05D 3/02 (20060101); B44d
001/42 (); H01b 003/44 () |
Field of
Search: |
;117/94,128.4,132CF,113,119.2,232,119.6 ;128/348-351 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
fitz Simmons et al., Thin Films of . . . (Teflon) . . . for Metals,
Naval Research Laboratory, June 15, 1956, pp. 24-29..
|
Primary Examiner: Gwinnell; Harry J.
Attorney, Agent or Firm: Tate; Thomas E.
Parent Case Text
RELATED APPLICATION
This application is a continuation-in-part of application Ser. No.
278,099, filed Aug. 4, 1972, now abandoned.
THE INVENTION
This invention relates generally to new and useful improvements in
the application of fluorinated hydrocarbon coatings to metallic
substrates and particularly seeks to provide a novel method of
applying and firmly bonding such coatings to the exteriors of small
diameter springs of the types included in the construction of
spring guides used in surgical catheterization procedures, and to
the exteriors of extremely fine flexible conducting wires of either
circular or rectangular cross-section, such as those used in the
indwelling sensing electrodes for cardiac monitoring instruments or
in the connecting electrodes for cardiac pacemakers.
These spring guides, regardless of their internal construction,
generally include a small diameter elongated body formed as a
continuously wound helical spring with the helices thereof in
contact with each other. The exterior of the spring body should be
either sheathed within a tube of inert flexible plastic having a
low coefficient of friction or coated by a similar type of plastic.
In either case, it is desirable that the sheathing or coating be as
thin as possible, consistent with the required end use so that the
ultimate outside diameter of the completed spring guide, on a
size-for-size basis, is kept at a practicable minimum.
Furthermore, since these spring guides are to be introduced into
and advanced through the blood or other vessels of animate beings,
their outer surfaces must be flexible and of a completely uniform
character with no crazing, intermittent breaks or other types of
discontinuities, nor should the outer surfaces be such as to become
powdery or separable as discrete particles or flakes.
In the case of the above-mentioned conducting wires, the
fluorinated hydrocarbon coatings serve as flexible external
insulators having smooth unbroken surface characteristics and being
of sufficient thinness as to enable a substantial number of such
wires to be assembled into a bundle of very small total
cross-section for insertion into and retention by a correspondingly
small diameter flexible sheath formed from a tube of a similar type
of fluorinated hydrocarbon.
It is believed that, at the present time, a
hexafluoropropylene-tetrafluoroethylene copolymer resin of the type
commercially designated as "Teflon" FEP and a tetrafluoroethylene
resin of the type commercially designated as "Teflon" TFE
(sometimes PTFE) are the best available for such purposes. Although
it is known that these materials have been used in the past for
coating many different types of substrates, mostly rigid metallic
articles, observation of several different makes of spring guides
coated or sheathed with such materials, and similarly coated fine
wires, indicates that none of them have been fabricated in such a
manner as to properly meet either the end use requirements or to
avoid the problems mentioned above.
However, through the use of this invention it is possible to apply
and firmly bond such types of coatings to the exteriors of surgical
spring guides, fine wires or comparable substrates in a completely
uniform manner and as unbroken continuous films having thicknesses
ranging from a low micron measurement up to about 1 mil.
Therefore, an object of this invention is to provide a novel method
for applying a fluorinated hydrocarbon coating or sheath to the
exterior of an elongated, small diameter object such as the body of
a spring guide used for surgical catheterization procedures, or a
conducting wire to be contained within an instrument electrode.
Another object of this invention is to provide a method of the
character stated in which the object to be coated is first slowly
immersed in a dispersion or emulsion of the selected fluorinated
hydrocarbon, slowly removed therefrom, subjected to a preliminary
drying at moderate temperatures for a short time, then subjected to
a higher temperature curing for a somewhat longer time, and then
cooled slowly.
Another object of this invention is to provide a method of the
character stated in which the immersion of the object to be coated
preferably is maintained for a matter of minutes; the initial
drying preferably takes place at a temperature of about
180.degree.F for about one half hour; the higher temperature curing
takes place within a temperature range of from about 545.degree. -
700.degree.F, preferably for about 1-1/2 hours; and the final
cooling takes place preferably over a period of about 2 hours to
reduce the temperature to at least as low as about 150.degree.F,
after which the coated object may be removed to the ambient
temperature of the atmosphere.
Another object of this invention is to provide a method of the
character stated in which the resultant coating is a transparent
film.
A further object of this invention is to provide a method of the
character stated in which the temperatures and treating times are
such as to prevent any substantial degradation of the physical and
mechanical qualities of the substrate such as loss of resiliency or
major discoloration.
With these and other objects, the nature of which will become
apparent, the invention will be more fully understood from the
following detailed description and the appended claims.
A typical spring guide that may be coated in accordance with this
invention is disclosed in the U.S. Pat. No. 3,749,086, granted July
31, 1973, to William M. Kline and Charles C. Roach.
Both FEP and TFE (or PTFE) types of fluorinated hydrocarbons and
probably others, are suitable for use in the method of this
invention and are commercially available from DuPont in
dispersions, for example, as "Teflon" 120 for the FEP dispersion
and "Teflon" 30B for the TFE dispersion.
Claims
I claim:
1. A method of applying and firmly bonding a fluorinated
hydrocarbon resin coating to the exposed surface of a clean
flexible metallic substrate selected from the group consisting of a
coil spring in which the helices thereof are in mutual contact and
a fine conducting wire of small area cross-section and comprising
the steps of: supplying a liquid dispersion bath of a fluorinated
hydrocarbon resin selected from the group consisting of
hexafluoropropylene-tetrafluoroethylene copolymer and
tetrafluoroethylene; slowly immersing said substrate in said
dispersion bath under non-agitated conditions for about 2-30
minutes to effect a coating of said dispersion thereon and then
slowly removing said substrate from said dispersion bath; then
subjecting said removed dispersion coated substrate to a
preliminary heating in a non-turbulent atmosphere at a temperature
not exceeding about 180.degree.F for about 10-120 minutes; then
cooling said prelimarily heated dispersion coated substrate to
about the ambient temperature of the atmosphere; then subjecting
said preliminarily heated and cooled dispersion coated substrate to
a further heating to a temperature of about 545.degree. -
700.degree. F for about 10-180 minutes whereby to drive off any
non-resin portions of said dispersion coating and to cause the
resin thereof to form as a hot melt in contact with said substrate;
and then slowly cooling the thus further heated resin coated
substrate to a temperature at least as low as about 150.degree.F
over a period of about 30-180 minutes, whereby to cause the resin
coating thereof to become firmly bonded thereto as an unbroken
flexible transparent film.
2. The method of claim 1 in which said liquid dispersion on a 100
parts by weight basis contains about 10-40 parts by weight of said
resin.
3. The method of claim 2 in which said liquid dispersion contains
about 20 parts by weight of said resin.
4. The method of claim 1 in which said further heating of said
hexafluoropropylene-tetrafluoroethylene copolymer dispersion coated
substrate is performed over a period of about ninety minutes at a
temperature of about 545.degree.-600.degree.F.
5. The method of claim 4 in which said further heating temperature
is about 575.degree.F.
6. The method of claim 1 in which said further heating of said
tetrafluoroethylene dispersion coated substrate is performed over a
period of about ninety minutes at a temperature of about
645.degree.-700.degree.F.
7. The method of claim 6 in which said further heating temperature
is about 675.degree.F.
8. The method of claim 1 in which said substrate is a coil spring
in which the helices thereof are in mutual contact.
9. The method of claim 1 in which said substrate is a fine
conducting wire of small area cross-section.
Description
The following example describes a preferred method of this
invention:
EXAMPLE
1. A spring guide, fine wire or its equivalent, to be coated first
has its exterior subjected to a degreasing (cleaning)
operation.
2. The spring guide or fine wire is then slowly immersed in the
selected fluorinated hydrocarbon dispersion, under non-agitated
conditions, for a sufficient time to permit full coating at least
of the exterior of the spring guide or fine wire with the
dispersion, which time generally is within the range of from 2-30
minutes, preferably about 10 minutes. The dispersion (on a 100-part
basis by weight) should contain about 10-40 parts by weight,
preferably about 20, of the selected fluorinated hydrocarbon
resin.
3. The spring guide or fine wire is then slowly removed from the
dispersion and at least partly dried in a nonturbulent atmosphere
at about 180.degree.F for about 10 - 120 minutes, preferably about
1/2 hour, and removed from that drying atmosphere and cooled to an
ambient temperature not greater than about 90.degree.F.
4. The thus at least partly dried spring guide or fine wire then is
placed in an oven at the approximate 90.degree.F ambient
temperature and the temperature of the oven then is raised slowly
over a period of 10 - 180 minutes, preferably about 1-1/2 hours, to
a range of 550.degree. - 600.degree.F, preferably about
575.degree.F, for the FEP dispersion coating; or to a range of
650.degree. - 700.degree.F, preferably about 675.degree.F, for the
TFE dispersion coating. In either case, the temperature then is
slowly reduced over a period of 30 - 180 minutes, preferably about
2 hours, to at least as low as 150.degree.F in order to produce a
clear, unbroken film, after which the thus coated or sheathed
spring guide is removed to the ambient temperature of the open
atmosphere. In this manner, through the controlled applications of
heat, followed by controlled coolings, the non-resin portions of
the selected dispersion or emulsion are driven off and the
remaining resin forms a hot melt that becomes annealed and firmly
bonded to the coils of the spring substrate as an unbroken
transparent flexible and virtually colorless film. The final slow
cooling from the 550.degree. - 700.degree.F heating range (exact
temperatures are, of course, dependent upon the selected type of
resin) down to at least as low as 150.degree.F is the most critical
part of this process, since appreciably faster cooling to
150.degree.F or lower will not produce either the desired fully
bonded unbroken flexible film or a film that remains fully bonded
and unbroken when the substrate to which it is applied subsequently
is subjected to a physical distortion such as flexing.
It also should be mentioned that at a temperature below about
545.degree.F for the FEP resin or below about 645.degree.F for the
TFE resin, the applied coating will be non-uniform and will readily
powder off. Furthermore, if the temperatures exceed the stated
maximums, i.e. 600.degree.F for FEP or 700.degree.F for TFE, the
coating will char and become discontinuous as by crazing or
flaking. In neither event is the coating completely and firmly
bonded to the substrate.
Here, the film, under the stated conditions, forms a melt after the
emulsifier has been driven off by heat as the temperature
progressively rises; and the resultant unbroken clear film becomes
annealed and firmly bonded to the substrate during the above
described slow cooling. Furthermore, the temperatures and times of
heating are such that the strength and resiliency of the spring or
wire substrate are substantially unaffected nor does the substrate
become appreciably discolored.
The method described in the foregoing Example produces a coating
film or sheath whose thickness is in the low micron range; but if
it is desired to increase the ultimate thickness of the applied
film, the coating procedures may be repeated in their entirety, one
or more times until the desired ultimate coating thickness, up to
about 1 mil, has been achieved.
Although, in the appended claims, the phrase "liquid dispersion"
has been used to define the physical state of the solids-containing
liquid to be applied to the substrate, it will be understood that
this phrase also is intended to include emulsions and other types
of solids-containing liquids.
It also should be understood that while the above description
generally relates to a method of coating coil springs or single
wires of circular or rectangular cross-section, the method is
equally effective for coating small diameter wires of either
twisted or braided multi-strand construction.
* * * * *