U.S. patent number 3,917,784 [Application Number 05/387,945] was granted by the patent office on 1975-11-04 for method for producing pile fabrics having excellent appearance and properties.
This patent grant is currently assigned to Kanebo, Ltd.. Invention is credited to Takeshi Nishida.
United States Patent |
3,917,784 |
Nishida |
November 4, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Method for producing pile fabrics having excellent appearance and
properties
Abstract
A pile fabric having excellent appearance and properties is
produced by conjugate spinning a polyamide and a polyester in a
side-by-side relation, applying to the resulting filaments firstly
a non-aqueous oil composition and then an aqueous oil composition,
drawing the thus treated filaments and taking them up on a bobbin,
unwinding the filaments from the bobbin and allowing them to stand
under a relaxed state to develop spontaneous crimps, compressing
the crimp-developed filaments to a filling density of 150 - 380 g/l
and then immersing them in water at a temperature of lower than
50.degree.C and raising the temperature to higher than 80.degree.C
to set the spontaneous crimps and simultaneously splitting the
filament into the two components and forming the resulting
filaments in the pile fabric or by forming directly the drawn
filaments obtained in the same manner as described above into a
pile fabric to develop spontaneous crimps, jetting steam on the
pile fabric surface to set the spontaneous crimps and immersing the
pile fabric in water at a temperature of lower than 50.degree.C and
raising the temperature to higher than 80.degree.C to split the
filaments into the two components.
Inventors: |
Nishida; Takeshi (Kobe,
JA) |
Assignee: |
Kanebo, Ltd. (Tokyo,
JA)
|
Family
ID: |
26422739 |
Appl.
No.: |
05/387,945 |
Filed: |
August 13, 1973 |
Foreign Application Priority Data
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|
|
|
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Aug 15, 1972 [JA] |
|
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47-81740 |
Aug 15, 1972 [JA] |
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47-81741 |
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Current U.S.
Class: |
264/103; 264/147;
264/210.3; 264/DIG.47; 264/168; 264/289.6; 264/172.11; 264/172.14;
264/172.18; 264/172.17 |
Current CPC
Class: |
D06M
7/00 (20130101); D06C 11/00 (20130101); D01F
8/14 (20130101); F04C 2210/26 (20130101); Y10S
264/47 (20130101); D06M 2200/40 (20130101) |
Current International
Class: |
D01F
8/14 (20060101); D06C 11/00 (20060101); D02G
001/20 (); B29H 007/18 () |
Field of
Search: |
;264/171,21F,168,147,103,DIG.47 ;28/DIG.1 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Woo; Jay H.
Attorney, Agent or Firm: Woodhams, Blanchard and Flynn
Claims
What is claimed is:
1. A method of producing a pile fabric, which comprises the steps
of:
1. conjugate spinning a fiber-forming polyamide and a fiber-forming
polyester in side-by-side relation at a conjugation ratio of from
1/3 to 3/1 to form bicomponent filaments;
2. applying to the bicompoment filaments of step 1 after they exit
from the spinneret, first
a. from 0.5 to 2.0 wt. % of a spinning oil composition containing
less than 10 wt. % of water, and then
b. from 0.3 to 1.5 wt. % of a spinning oil composition containing
more than 40 wt. % of water;
the foregoing steps 2(a) and 2(b) being carried out without drawing
the filaments;
3. drawing the bicomponent filaments of step (2) at a temperature
of from 70.degree. to 130.degree.C, and then taking up the
bicomponent filaments on a bobbin, the filaments at this time being
substantially unsplit and uncrimped and possessing the inherent
properties of a spontaneous crimp percentage of more than 40%, a
split percentage of more than 70% and a shrinkage difference of
from 2 to 12%;
4. unwinding the filaments from the bobbin, and permitting the
filaments to relax in air to develop spontaneous crimps in the
filaments;
5. placing the crimped filaments in a vessel at a filling density
of from 150 to 380 grams of filament per liter of vessel volume,
and therein immersing the crimped filaments in water having a
temperature of less than 50.degree.C and then raising the
temperature of the water to more than 80.degree.C to set the crimps
and simultaneously to split the components of the filaments;
and
6. forming the split filaments of step (5) into a pile fabric.
2. A method as claimed in claim 1, in which in step (4) after the
filaments are unwound from the bobbin, they are wound in a relaxed
package and the filaments in the relaxed package are permitted to
relax in air to develop spontaneous crimps and, in step (5), the
relaxed package is placed in the vessel and is immersed in
water.
3. A method as claimed in claim 1, in which the pile fabric is a
carpet and the filaments in the carpet have a denier of from 10 to
50.
4. A method for producing a pile fabric, which comprises the steps
of:
1. conjugate spinning a fiber-forming polyamide and a fiber-forming
polyester in side-by-side relation at a conjugation ratio of from
1/3 to 3/1 to form bicomponent filaments;
2. applying to the bicomponent filaments of step (1 ) after they
exit from the spinneret, first
a. from 0.5 to 2.0 wt. % of a spinning oil composition containing
less than 10 wt. % of water, and then
b. from 0.3 to 1.5 wt. % of a spinning oil composition containing
more than 40 wt. % of water;
3. drawing the bicomponent filaments of step (2) at a temperature
of from 70.degree. to 130.degree.C, and then taking up the
foregoing steps 2(a) and 2(b) being carried out without drawing the
filaments; the bicompoment filaments on a bobbin, the filaments at
this time being substantially unsplit and un-crimped and possessing
the inherent properties of a spontaneous crimp percentage of more
than 40%, a split percentage of more than 70% and a shrinkage
difference of from 2 to 12%;
4. forming the filaments of step (4) into a pile fabric;
5. permitting said pile fabric to stand in air to develop
spontaneous crimps in the filaments in the pile fabric;
6. contacting the pile fabric with steam jets directed against the
pile surface so as to strongly compress the pile and to set the
spontaneous crimps in the filaments; and
7. immersing the pile fabric of step (6) in water having a
temperature of less than 50.degree.C and then raising the
temperature of the water to more than 80.degree.C to split the
components of the filaments.
5. A method as claimed in claim 4, in which the pile fabric is a
carpet and the filaments in the carpet have a denier of 10 to
50.
6. The method as claimed in claim 1, wherein said conjugate ratio
of the polyamide to the polyester is 5/3 - 5/2.
7. The method as claimed in claim 1, wherein the filling density in
step (5), is 200 - 350 g/l.
8. The method as claimed in claim 1, wherein said spontaneous crimp
percentage is 60 to 95%.
9. The method as claimed in claim 1, wherein in step (5), the
heated water treatment is effected as part of scouring or dyeing
steps.
10. The method as claimed in claim 1, wherein the crimp developed
filaments are immersed in water at a temperature of lower than
40.degree.C and the temperature is raised to higher than
90.degree.c and said temperature is maintained for more than 30
minutes.
11. the method as claimed in claim 1, wherein said non-aqueous oil
composition comprises a lubricating oil together with surface
active agent and an antistatic agent diluted with an organic
solvent and containing less than 10% of water.
12. The method as claimed in claim 1, wherein said aqueous oil
composition is a lubricating oil together with a surface active
agent and an antistatic agent dissolved or emulsified in water and
containing 50 to 90% of water.
13. The method as claimed in claim 1, wherein the total amount of
the two oil compositions applied on the filaments is 0.8 to 2.5% by
weight.
14. The method as claimed in claim 4, wherein said conjugate ratio
of the polyamide to the polyester is 5/3 - 5/2.
15. The method as claimed in claim 4, wherein said spontaneous
crimp percentage is 60 - 95%.
16. The method as claimed in claim 4, wherein in step (7), the
heated water treatment is effected as part of scouring or dyeing
steps.
17. The method as claimed in claim 4, wherein in step (7), the pile
fabric is immersed in water at a temperature of lower than
40.degree.C and the temperature is raised to higher than
90.degree.C and said temperature is maintained for more than 30
minutes.
18. The method as claimed in claim 4, wherein said non-aqueous oil
composition comprises a lubricating oil together with a surface
active agent and an antistatic agent diluted with an organic
solvent and containing less than 10% of water.
19. The method as claimed in claim 4, wherin said aqueous oil
composition is a lubricating oil together with a surface active
agent and an antistatic agent dissolved or emulsified in water and
containing 50 to 90% of water.
20. The method as claimed in claim 4, wherein the total amount of
the two oil compositions applied on the filaments is 0.8 to 2.5% by
weight.
21. The method as claimed in claim 4, wherein the steam is jetted
on the pile fabric from a distance of less than 1 cm.
Description
The present invention relates to a method for producing pile
fabrics having excellent appearance and properties and more
particularly to a method for producing pile fabrics, particularly
pile carpets having excellent appearance and properties from
composite filaments in which polyamide and polyester are bonded in
a side-by-side relation.
Recently, the tufting machines have been developed and the demand
for pile carpets composed of synthetic fibers has rapidly increased
and particularly the demand for the pile carpets composed of
filaments has rapidly increased owing to their high durability.
Heretofore, in almost all of the filaments to be used for pile
carpets, bulkiness is provided to straight filaments by a crimping
process, such as stuffer box method, false twisting method and the
like. Becuase if straight filaments per se are piled to form a
carpet, the filaments forming the pile are gathered and the
substrate (backing cloth) is seen between the piles and the
appearance is quite poor and if the piles composed of straight
filaments are densely tufted so that the substrate is not seen, the
amount of filaments thus tufted is very large and such a means is
disadvantageous in view of cost and the carpet becomes hard and the
walking feel is very poor.
On the other hand, recently it has been attempted to produce pile
carpets composed of filaments having selfcrimpability in which two
polymers are bonded eccentrically along the longitudinal direction
of the filament but in this case it is necessary to effect
previously a crimp developing and setting treatment in the filament
state. If piles are formed by omitting these treatments and the
scouring and dyeing are performed, the monofilaments constituting
the piles concentrate and are crimped in the same shape and the
piles are distorted and excess crimps are formed, consequently the
covering, appearance, walking feel and the like of the resulting
pile fabric are very poor.
As mentioned above, heretofore the filaments to be used for the
pile carpet are subjected to a crimping proces but the crimping
process needs a complicated and expensive apparatus and therefore
the cost of the filaments is high. Furthermore, in the filaments
unevenness of mechanical and thermal treatment is liable to be
caused during said process and this unevenness results in defects
of pile unevenness, streaks and the like.
For solving these defects, the inventor has diligently studied and
found that pile carpets having excellent appearance and properties
can be produced without effecting the above described crimping
process by utilizing filaments having specific properties and
composed of polyamide and polyester and the present invention has
been accomplished.
The specific properties of the filaments of the present invention
are firstly formation of spontaneous crimps in said filament and
secondly the splitability of the two components.
The term "spontaneous crimp" used herein means the crimps developed
due to the difference of elastic shrinkage of the two components
when a filament obtained by eccentric conjugate spinning of two
components having a difference in their elongation elasticity, such
as polyester and polyamide, is drawn, the tension is removed and
the filament is relaxed in air.
The term "splitability of two components" used herein means the
property that the two components bonded along the longitudinal
direction of the filament are split into the respective components.
It has been well known that a filament obtained by conjugate
spinning two components in a side-by-side relation develops crimps
due to the difference of shrinkage of the two components and a
stretchable fibrous structure and a bulky fibrous structure are
formed by utilizing the crimpability. This concerns the filament
composed of two components having mutual adhesion and in the
previously utilized crimps, the shrinkage difference between the
two components is positively caused by heating in a relaxed state
and the formed crimps are set by heating and the concept of the
spontaneous crimp used herein has never been seen.
In addition, the utility of the composite filaments composed of two
splitable components has been well known and this has been
disclosed in U.S. Pat. Nos. 3,350,488 and 3,117,906 and French Pat.
No. 1495835 and all of these patents relate to a process for
producing fine filaments and aim at the production of silky
filaments and are different in the function, effect and object from
the present invention and of course, the concept of the spontaneous
crimp according to the present invention has never been found.
Polyamide and polyester have no adhesion and particularly when the
fineness of the monofilament is very large as in carpet filaments,
the side-by-side type composite filaments of these two components
undergo splitting in an undrawn state and the drawing can not
substantially be effected. However, according to the present
invention it has been found that by selecting oil compositions to
be applied in the spinning step, the adhesion is controlled and the
filaments having spontaneous crimpability, which can be split into
two components by a very simple process, can be produced and the
present invention has been accomplished by utilizing these specific
properties.
In the previous carpets composed of synthetic filaments, static
electricity is accumulated on a human body when he walks on the
carpet and when he touches a door handle, the electricity is
discharged and a stimulation is given and an unpleasant feeling is
caused but the present invention improves this point. Namely, the
present invention provides a pile fabric composed of filaments in
which the polyamide monofilaments which are charged positively and
the polyester monofilaments which are charged negatively are
complicatedly entangled and therefore the static electricities
generated by the friction include both positive and negative
charges which cancel each other and the carpet of the present
invention is very low in static electrification.
The object of the present invention will be apparent from the above
described explanation and it is to provide a method for producing a
pile fabric having excellent appearance and properties at a low
cost. Namely, the present invention provides a method for producing
a pile fabric without needing the crimping step using a particular
apparatus and step.
Another object of the present invention is to provide a method for
producing a pile fabric of a very low electrification.
An aspect of the present invention is a method for producing a pile
fabric in which a polyamide and a polyester are conjugate spun in a
side-by-side relation at a cross-sectional area ratio of 1/3 - 3/1,
the resulting filaments are applied firstly with a non-aqueous oil
composition and then with an aqueous oil composition, the thus
treated filaments are drawn and taken up on a bobbin, from the
bobbin the filaments are unwound and left to stand under a relaxed
state to develop spontaneous crimps, the crimp developed filaments
are compressed under a filling density of 150 - 380 g/l and then
immersed in water at a temperature of lower than 50.degree.C and
the temperature is raised to higher than 80.degree.C to set the
spontaneous crimps and simultaneously split the filaments into the
two components and the resulting filaments are formed into the pile
fabric.
Another aspect of the present invention is a method for producing a
pile fabric in which a polyamide and a polyester are conjugate spun
in a side-by-side relation at a cross-sectional area ratio of 1/3 -
3/1, the resulting filaments are applied firstly with a non-aqueous
oil composition and then with an aqueous oil composition, the thus
treated filaments are drawn and taken up on a bobbin, the filaments
are formed into a pile fabric and then spontaneous crimps are
developed, steam is jetted onto the pile fabric surface to set the
spontaneous crimps and then the pile fabric is immersed in water at
a temperature of lower than 50.degree.C and the temperature is
raised to higher than 80.degree.C to split the filaments into the
two components.
The polyamides suitable for the present invention are nylon-4,
nylon-6 nylon-7, nylon-11, nylon-12, nylon-66, nylon-610,
polymethaxylyleneadipamide, polyparaxylylenedecaneamide,
polybiscyclohexylmethanedecaneamide and copolyamides consisting
mainly of these polymers.
As the comonomer in the copolyamides, mention may be made of
lactams, such as caprolactam, enanthlactam, laurolactam and the
like; aminocarboxylic acids, such as aminocaproic acid,
aminodecanoic acid, p-aminomethyl-benzoic acid and the like; nylon
salts of diamines, such as hexamethylenediamine,
nonamethylenediamine, undecamethylenediamine, m-xylylenediamine,
p-xylylenediamine and piperazine with dibasic acids, such as adipic
acid, sebacic acid, isophthalic acid, terephthalic acid and the
like.
The polyesters are polyethylene terephthalate, polytetramethylene
terephthalate, polyethylene oxybenzoate,
poly-1,4-dimethylcyclohexane terephthalate, polypivalolactone and
copolyesters consisting mainly of these polymers.
As the monomers in the polyesters, mention may be made of lactones,
such as pivalolactone, .epsilon.-caprolactone and the like;
aliphatic diols, such as ethylene glycol, trimethylene glycol,
tetramethylene glycol, diethylene glycol, polyethylene glycol and
the like; alicyclic diols, such as 1,4-cyclohexanedimethanol,
1,4-cyclohexanediol and the like; aromatic dicarboxylic acids, such
as terephthalic acid, isophthalic acid, sodium sulfo-iso-phthalate,
naphthalenedicarboxylic acid and the like; aliphatic dicarboxylic
acids, such as adipic acid, sebacic acid, 1,10-decanedicarboxylic
acid; alicyclic dicarboxylic acids, such as hexahydroterephthalic
acid, hexahydroisophthalic acid and the like. When the dicarboxylic
acids or diols are copolymerized, it is necessary to copolymerize
the dicarboxylic acids and diols.
When the copolyamides and copolyesters are used, if the
copolymerization ratio is too high, the adhesion of the two
components becomes high and the two components are hardly split by
the heat treatment of the present invention and the effect of the
present invention cannot be obtained and the mechanical properties
of the resulting pile fabric is deteriorated and accordingly the
copolymerization ratio is preferred to be less than 15 mol% based
on the main component.
The conjugate ratio of the two components according to the present
invention is a very important factor in view of the following two
points.
One among them is the spontaneous crimp, one characteristic of the
present invention is to utilize the spontaneous crimp generated
when the filament is relaxed in air and therefore the effect of the
present invention depends upon whether the filament has a high
spontaneous crimpability or not. When the conjugate ratio of
polyamide to polyester is outside the range of 1/3 - 3/1, the
filament cannot have the required spontaneous crimpability and the
effect of the present invention cannot be obtained.
The spontaneous crimp percentage of the filaments utilized in the
present invention is desirable to be more than 40% when determined
by the following process and when said percentage is 60 - 95%, the
more preferable result can be obtained.
Process for determining the spontaneous crimp percentage (C.sub.S)
is as follows.
The length of the filament after the filament is left to stand in
air at a humidity of 65% RH and a temperature of 25.degree.C for 1
hour under a load of 0.1 mg/d, is l.sub.S and the length when said
filament is left to stand for 1 minute under a load of 0.1 g/d
instead of the above load is l.sub.T. ##EQU1##
It is considered that the spontaneous crimps are generated due to
the difference of elastic shrinkage of the polyamide and polyester
components constituting the filament in a side-by-side relation and
the fact that a filament has a high spontaneous crimp percentage
means that both the components are satisfactorily bonded in the
monofilament.
Another important point of the conjugate ratio is the problem of
electrification of the resulting pile fabric. As mentioned above,
the electrification of the pile fabric of the present invention is
very low but when the conjugate ratio is beyond the range of 1/3 -
3/1, the balance of the positively charged polyamide and the
negatively charged polyester is lost and one or the other of the
positive and negative charges becomes excessive and an undesirable
result is obtained.
A more detailed explanation will be made with respect to the
conjugate ratio. When the conjugate ratio is within the range of
1/3 - 3/1, the effect of the present invention can be attained but
in view of the durability of the resulting pile fabric, it is
preferable that the amount of polyamide is larger than that of
polyester and when the ratio of polyamide/polyester is 3/1 - 1/1,
more particularly 5/2 - 3/2, a pile fabric having very excellent
properties can be obtained, because polyamide is higher than
polyester in the abrasion resistance and impact resistance.
For a better understanding of the invention, reference is taken to
the accompanying drawings, wherein:
FIGS. 1 - 5 show cross-sectional views of the composite filaments
to be used in the present invention;
FIGS. 6A, 6B, 7A, 7B, 8A and 8B show embodiments of steam jetting
devices to be used in the method of the present invention. FIGS.
6A, 7A and 8A show cross-sectional views of the devices and FIGS.
6B, 7B and 8B show front views of the jet nozzles;
FIG. 9 is a perspective view of an embodiment for carrying out the
steam jet treatment of the present invention;
FIG. 10 is a cross-sectional view of the steam jet treatment of the
present invention;
FIG. 11 is a cross-sectional view of another embodiment for
carrying out the steam jet treatment of the present invention;
FIGS. 12 and 13 are photographs for showing the appearance of the
surfaces of the tufted carpets obtained by the method of the
present invention; and
FIGS. 14 and 15 are photographs for showing the appearance of the
surfaces of the tufted carpets made of splittable filaments of
polyamide and polyester, which are not treated with the method of
the present invention.
The side-by-side type composite filaments used in the present
invention mean filaments wherein the two components are bonded in a
parallel relation along the longitudinal direction of the
monofilament and the cross-section is the shapes as shown in FIGS.
1 - 5. In view of the properties of the resulting carpet,
particularly durability, the shapes in which the two components
after splitting have a substantially triangular shape as shown in
FIGS. 2 - 4, are preferable.
The important point in the production of the filaments according to
the present invention consists in that the the extruded filaments
are applied firstly with a non-aqueous oil composition and then
with an aqueous oil composition.
The most essential point of the technical idea of the present
invention consists in that the spontaneous crimps are set and the
composite filaments are split into two components and this can be
attained only by improvement of the adhesion of the two components
to a required extent and control of the adhesion in such a manner
that the filaments are split into two components by a simple heat
treatment. As mentioned above, polyamide and polyester are
essentially poor in the adhesion and therefore the composite
filament of polyamide and polyester in a side-by-side relation is
difficult to produce on an industrial scale but the present
invention can solve this difficulty by selection of the spinning
oil compositions.
It is not clearly understood why the process for applying the
spinning oil compositions to be used in the method of the present
invention is effective for attaining the object of the present
invention but an assumption concerning this will be explained as
follows. It has been found that the adhesion of the side-by-side
type filament of polyamide and polyester is highly influenced by
the water content in the oil composition to be applied in the
spinning. Namely, when the water content in the spinning oil
composition is high, the two components are readily split, whereas
when the water content is decreased, the two components are
difficult to split. This is because under an undrawn condition,
polyamide filament absorbs water and swells considerably, while
polyester filament does not substantially absorb water and does not
swell. The polymers spun in the melted condition are near an
absolutely dry condition and when an oil composition having a high
water content is applied to the solidifying filament, the
difference of the water absorbing property and swelling property of
the polyamide and polyester appears considerably and the divergency
of the bonding surface of both the components generates rapidly and
highly and the filament is readily split into the two
components.
On the other hand, when a non-aqueous oil composition having a low
water content is applied, the above phenomenon does not occur and
therefore the adhesion is improved. By the above explanation the
reason why the non-aqueous oil composition is applied in the method
of the present invention, will be understood. The reason why an
aqueous oil composition is subsequently applied, is based on the
following two points.
The first point consists in that when only the non-aqueous oil
composition is applied, the winding of the filament is difficult.
When the undrawn filament applied with only the non-aqueous oil
composition is wound on a bobbin, the polyamide component absorbs
gradually moisture in air and swells and the winding is readily
destroyed and it is impossible to take-up a large amount of
filament. In general, a non-aqueous oil composition is low in the
affinity of mutual filaments and consequently when the drawn
filament is taken-up, the filament is liable to disturb the wound
form and when the denier of monofilament is large as more than 10
deniers, this defect readily occurs.
Accordingly, it is necessary to supplement this defect by applying
an aqueous oil composition after the non-aqueous oil composition is
applied. The spinning rate of synthetic fibers is usually more than
several hundred meters per minute and therefore the non-aqueous oil
composition and the aqueous oil composition are applied
substantially simultaneously, but only by determining the sequence
of applying of these oil compositions as described above, the
production of the side-by-side type filament of polyamide and
polyester is feasible. This is surprising and the reason is not
clear.
The second point consists in that the adhesion of the two
components is improved too much if only the non-aqueous oil
composition is applied.
The inventor has found that the filament obtained by applying only
the non-aqueous oil composition is too much improved in the
adhesion of the two components and it is difficult in the following
step to split the filament into the two components and therefore it
is necessary to adopt the process for applying the two oil
compositions in sequence according to the present invention.
In general, as the spinning oil compositions, a lubricating oil,
such as mineral oils or fatty acid esters, is diluted together with
a surface active agent and an anti-static agent with water or an
organic solvent.
The term "non-aqueous oil composition" used herein means the
spinning oil compositions having a low water content and the water
content is preferred to be as low as possible and if the water
content is less than 15%, the object of the present invention can
be accomplished and if said content is less than 10%, a more
preferable result can be obtained.
The term "aqueous oil compositions" used herein means the oil
compositions wherein a lubricating oil is dissolved or emulsified
toogether with a surface active agent and an antistatic agent in
water and when the water content is more than 40%, such an oil
composition is effective and the use of the oil composition
containing a water content of 50 - 90% gives amore preferable
result.
The lubricating oils including mineral oils; fatty acid esters such
as methyl oleate, ethyl palmitate, propyl palmitate, n-butyl
palmitate, n-butyl stearate, lauryl laurate, oleyl oleate; higher
alcohols such as lauryl alcohol, oleyl alcohol.
The surface active agents and the antistatic agents cannot be
distinguished distinctly and anionic, nonionic, cationic and
amphoteric surface active agents are usable. As the surface active
agents (emulsifiers), nonionic active agents, such as
polyoxyethylene castor oil ether, polyoxyethylene oleyl ether,
polyoxyethylene trimethylolpropane tristearate are preferable. As
the antistatic agents, anionic active agents, such as potassium
polyoxyethylenelauryl sulfate, potassium polyoxyethyleneoleyl
phosphate, sodium dodecylbenzenesulfonate, sodium cetylsulfonate
and the like are preferable.
As the diluting agents in the non-aqueous oil compositions, use may
be made of aromatic hydrocarbons, such as benzene, toluene, xylene;
halogenated hydrocarbons, such as trichloroethylene,
perchloroetehylene, carbon tetrachloride, low boiling fractions of
petroleum, such as gasoline, light oil, kerosene, ligroin and the
like.
The amounts of the oil compositions deposited on the undrawn
filament (excluding the volatile component) are 0.5 - 2.0% by
weight in the non-aqueous oil composition and 0.3 - 1.5% by weight
in the aqueous oil composition and the total amount of the oil
compositions is preferred to be 0.8 - 2.5% by weight.
The undrawn filaments applied with the oil compositions in the
above described manner may be drawn by any process but in order to
prevent the splitting of the two components, it is preferable to
use a hot pin (surface: satin, diameter: 30 - 20 mm) or a hot
roller. The hot roller process by which the heat is sufficiently
given by winding a few turns, is most preferable. When the drawing
temperature is too low, yarn breakage and splitting occur, while
when the temperature is too high, the adhesion is too much improved
and the preferable temperature is 70.degree. - 130.degree.C, more
particularly 80.degree. - 100.degree.C. The heat setting of the
drawn filament may be either effected or not, but as mentioned
hereinafter the difference of heat shrinkage between polyester and
polyamide influences highly upon the production step of the pile
fabric and the appearance and properties of the resulting pile
fabric. Accordingly, the heat setting must be carefully carried
out. Said temperature is usually preferred to be 100.degree. -
160.degree.C. If said temperature is too high, the shrinkage of
polyester which is readily set, becomes low and the difference of
shrinkage becomes too large and such a temperature is not
preferable.
Namely, when the difference of length of the polyester monofilament
and the polyamide after the splitting, which is caused due to
shrinkage difference, is too small, the resulting pile structure is
poor in the bulkiness and is not preferable, while when the
difference is too large, loose filaments are formed on the
structure surface and the appearance and properties are
deteriorated and further when the above described first aspect
process is carried out, the loose filaments get caught by a guide
and the production of the pile fabric is very difficult.
In the production of the pile fabric according to the present
invention, it is very valuable for obtaining the good pile fabric
that the following tests are conducted with respect to the
composite filaments.
One of them is a measurement of the above described spontaneous
crimp percentage and said percentage is desirable to be more than
40% as described above.
Another is the split percentage of the two components of the
filament owing to the heated water treatment and the shrinkage
difference of the split polyamide monofilament and the split
polyester monofilament after said treatment.
These measurements are referred to as "the heated water treatment
measurements" hereinafter and they are as follows.
The monofilament prior to the heated water treatment is referred to
as "monofilament" and each monofilament obtained by splitting into
the two components is referred to as "fibril monofilament".
Heated water treatment measurement:
10 monofilaments are taken in a loop (total length of loop: 1 m)
and this loop is immersed in water at a temperature of lower than
50.degree.C and then the temperature of water is raised until the
water is boiled, in 30 minutes and the boiling is continued for 10
minutes, after which the thus treated filaments are taken out and
dried in air in a chamber having a humidity of 65% RH and a
temperature of 25.degree.C and then the split percentage and the
shrinkage difference are determined.
Split percentage:
The total number of the "monofilaments" and the "fibril
monofilaments" is read and this number is n. ##EQU2##
The split percentage must be more than 70% and if said percentage
is more than 90%, the more excellent result can be obtained.
Shrinkage difference:
Each of the fibril monofilaments is applied with a load of 0.2 g/d
and the length is read. The length of the filament having the
maximum length is l.sub.a and the length of the filament having the
minimum length is l.sub.b. ##EQU3##
When this value is 2 - 12%, the production of the pile structure is
smooth and the appearance and properties of the resulting pile
structure are good and when this value is 5 - 10%, the more
favorable result can be obtained.
An explanation will be made with respect to the process for setting
the spontaneous crimps and splitting the monofilament into the two
components.
A process by which prior to the formation of the pile fabric the
spontaneous crimps are set and the monofilaments are split into the
two components is as follows.
The filaments obtained according to the above described process are
relaxed in air to develop the spontaneous crimps and then
compressed in a filling density of 150 - 380 g/l, after which the
filaments are immersed in a warm water at a temperature of lower
than 50.degree.C and the temperature of water is raised to higher
than 80.degree.C to set the spontaneous crimps and simultaneously
split the filaments into the two components, whereby filaments
suitable for the production of the pile structure are obtained.
In order to relax the filament in air to develop the spontaneous
crimps, the filament taken out from a bobbin is wound into a form
in which the filament can be relaxed freely (referred to as
"relaxed package"), for example, into a hank form, muff form or
knit form. Of course, the relaxed package is preferably covered
with a stretchable cover in such an extent that the development of
the spontaneous crimps is not prevented and the filament is
protected in the following steps. Then, the relaxed package is
filled in a vessel and heat treated. Namely, the above described
relaxed package is compressed and filled in a filling density of
150 - 380 g/l and subjected to the above described heated water
treatment. This step will be explained with reference to an
embodiment. That is, a plurality of filament packages wound in muff
forms are charged in an Over-maier dyeing machine and on the
packages a cover is put and the above described pressure is applied
thereon and then water at a temperature of lower than 50.degree.C
is poured into the dyeing machine so as to immerse the packages,
after which the temperature of water is raised to higher than
80.degree.C. In this case the rate of raising temperature is not
particularly defined. By this process the spontaneous crimps are
set and this will be explained as follows.
Since the filament to be used in the present invention has a high
spontaneous crimpability, when the filament is formed into a
relaxed package, at once the crimps are developed. Then, the
crimped filament is charged in a vessel in a high filling density
of more than 150 g/l and heat treated, whereby the developed
spontaneous crimps are set.
Thus the crimped yarns can be obtained without carrying out a
specific crimping process.
In this heated water treatment, the temperature of the water when
the treatment is started, is lower than 50.degree.C and the
temperature of the final hot water treatment is higher than
80.degree.C and by this heated water treatment the filaments are
split into the two components because of the specific property
possessed by the filaments. The phenomenon that the filaments are
split into the two components is very important and if the two
components are not split by this heat treatment, the crimped form
is varied prior to and after the treatment by the heat shrinkage
difference between the two components.
If the heated water treatment is effected in a lower filling
density than 150 g/l, the filaments are split into the two
components under such a condition that the filaments readily move,
consequently at the same time when the filaments are split, the
crimps disappear, so that the filling density must be more than 150
g/l. While, when the filling density is extremely high, the
spontaneous crimps are not only set by the heat treatment, but also
there is formed the portion where the crimps owing to the
compression of the mutual filaments are provided and the resulting
filaments are very uneven in the crimp. Accordingly, the
excessively high filling density of more than 380 g/l must be
avoided. The filling density is preferred to be 200 - 350 g/l in
order to set the crimps satisfactorily and to obtain more uniform
crimped filaments.
In the heated water treatment, it is preferable in order to split
the filaments fully and set the crimps more satisfactorily that the
filaments are immersed in water at a temperature of lower than
40.degree.C and the temperature is raised to higher than
90.degree.C and said temperature is kept for a time of more than 30
minutes.
Next, the method wherein the filaments not subjected to the heated
water treatment are formed into a pile fabric and then the formed
spontaneous crimps are set and the filaments are split into the two
components, will be explained.
This method comprises that the untreated filaments are formed into
a pile fabric, for example, by tufting and then said pile fabric is
left to stand in air to develop the spontaneous crimps in the
filaments constituting the pile fabric, a steam jetting treatment
is effected on the pile fabric surface and then the pile fabric is
immersed in warm water at a temperature of lower than 50.degree.C
and the temperature is raised to a temperature of higher than
80.degree.C to split the filaments into the two components.
The term "steam jetting treatment" used herein means that a steam
is jetted onto the pile surface and does not mean that the pile is
heat treated under a steam atmosphere. The jet of steam should be
conducted in such an extent that the pile is vigorously compressed
by the jet.
FIGS. 6 - 8 show embodiments of the steam jetting devices and in
these drawings each A is the cross-sectional view and each B is a
front view of the jet nozzle. In FIGS. 6 and 7, a large number of
nozzles are opened in a circular tube and in FIG. 8 the nozzles are
opened in a given flat surface.
In these drawings, 1 represents a steam introducing tube, 2
represents a steam reservoir, 3 represents jet nozzles and the
arrow represents the steam flow.
FIG. 9 shows an embodiment of operation of the present invention
and the pile structure 5 moves immediately below the jetting device
4, whereby the steam jetting treatment is effected.
FIG. 10 shows an embodiment for carrying out the steam jetting
treatment, in which the pile structure 5 running immediately below
the jetting device 4 is treated with the jetting device. 6
represents a support.
The shorter the distance (d) between the jet nozzle and the pile
surface, the better the effect is and the distance is usually less
than 1 cm. Furthermore, it is effective that d is minus, that is
the jet treatment is effected while the pile is somewhat compressed
and when the pile length is uneven, there is such an effect that
the pile length is made uniform and such a method is rather
preferable.
The object can be attained by effecting the jet of steam from above
the pile but the jet may be effected from above and below the pile
as shown in FIG. 11.
This method is characterized in that the pile structure is
subjected to the steam jetting treatment to set the spontaneous
crimps and then the filaments are split into the two
components.
When the filaments are split into the two components without
effecting said treatment, the crimps disappear and a pile fabric
having a low bulkiness and poor appearance and properties are
obtained. The heat treatment other than the steam jetting treatment
can not substantially effect the setting of the spontaneous
crimps.
The inventor has found that in order to set the spontaneous crimps
it is necessary to supply a large amount of heat to the filaments
instantaneously and in this point, a satisfactory process other
than the steam jetting treatment can not be found.
The adhesion of polyamide and polyester in the composite filament
to be used in tthe present invention has been controlled in a given
extent as mentioned above and as the result, the filaments are
readily split by a heat treatment or a mechanical treatment and
when the pile structure is heat treated relatively gradually under
a dry heated atmosphere or a steam atmosphere, the heat treatment
is effected while the splitting between the two components is
advancing, consequently the preferable pile structure can not be
obtained.
Another object of the steam jetting treatment consists in that the
entaglement of mutual filaments constituting the pile is promoted
by the jet and the bulkiness and properties of the resulting pile
structure are improved.
The heated water treatment may be carried out by Wince dyeing
machine, beam dyeing machine, Jiggar dyeing machine but in the pile
structure the use of beam dyeing machine and Jiggar dyeing machine
is somewhat difficult and Wince dyeing machine is the most
preferable.
The conditions for the heated water treatment was already mentioned
in detail with respect to the process wherein in the filament form,
the spontaneous crimps are set and the filaments are split.
Therefore, the explanation is omitted herein.
The reason why the filaments are split into the two components by
the heated water treatment, is not clear but as mentioned above,
the filaments to be used in the present invention are controlled in
the adhesion of the two components properly and therefore the
filaments are split into the two components by a simple heat
treatment. The inventor has found that when the filaments are
directly immersed in hot water at a temperature of higher than
80.degree.C, the filaments are relatively difficult to split, while
when the filaments are firstly immersed in water at a temperature
of lower than 50.degree.C and the temperature is raised, the
filaments are readily split. Presumably this is because the water
at a temperature of lower than 50.degree.C penetrates into the
bonded interface of the two components and the temperature of water
is raised, whereby the molecular movement becomes vigorous
resulting into that the filaments are readily split into the two
components by the heated water treatment.
However, when the filaments are directly immersed in hot water at a
temperature of higher than 80.degree.C, the setting of crimps and
the thermal variation of polymers constituting the filament proceed
earlier than the penetration of water between the two components
and the splitting of the two components is difficult.
The advantage that the filaments are split into the two components
by the heated water treatment consists in that the temperature
condition of this treatment is substantially the same as the
temperature conditions of scouring and dyeing usually
conducted.
That is, the scouring and dyeing are usually conducted as follows.
THe scouring solution or dyeing solution is contacted with a
fibrous structure at a temperature of lower than 50.degree.C and
then the temperature of the solution is continuously raised to
higher than 80.degree.C. Accordingly, in the method of the present
invention, the heated water treatment can be substituted with the
scouring or dyeing step and the pile structure having excellent
appearance and properties can be obtained without effecting a
specific heat step.
An additional effect obtained in the present invention is as
follows. The pile fabric obtained by the method of the present
invention is very low in the electric charge and even if a human
body walks on the pile structure, the accumulation of electric
charge on the human body is very low. The reason has already been
mentioned but the propriety will be understood from the fact that
the filaments in the pile fabric according to the present invention
are fully entangled.
FIGS. 12 and 13 are photographs showing surfaces of the tufted
carpets obtained by the method of the present invention, which show
that the filaments constituting the pile are complicatedly
entangled and the bulkiness is high.
FIGS. 14 and 15 show photographs of tufted carpets formed of
splitable filaments composed of polyester and polyamide, which are
not produced according to the present invention. In these carpets,
the direction of the filaments constituting the pile is uniform and
the bulkiness is poor. When the direction of the filaments
constituting the pile is uniform as in these piles, the fibril
monofilaments having lower shrinkability gather on the surface,
consequently such a carpet is not desirable in view of the
electrification.
A further effect of the present invention consists in the following
point. Since the pile fabric obtained by the method of the present
invention is composed of two components of polyamide and polyester
having quite different dyeabilities, a beautiful carpet having a
high grade in which two colored filaments are mixed, can be easily
obtained by a device of dyeing process.
Such a carpet has never been obtained by the conventional process
using the conventional filaments and in this point the present
invention is very advantageous.
The present invention is particularly effective for production of
pile fabrics, that is a carpet composed of filaments of a large
denier and the denier of filaments when applying to carpet is 10 -
50, preferably 20 - 40.
The following examples are given for the purpose of illustration of
this invention and are not intended as limitations thereof.
In the preceding description and the following working examples,
the method for producing the pile fabric is explained with respect
to tufting process in order to make understanding easy but the
present invention is not limited to this process and knitting
process, weaving process and the like may be applied for production
of the pile fabric.
Impact resistance and electric charge voltage on a human body of
the pile fabric in the following Examples are determined as
follows.
Impact resistance (retaining percentage of thickness %):
An impact piece composed of a synthetic rubber having an impact
area of 3 cm.sup.2 and a weight of 1 Kg is dropped on the pile
fabric from a height of 10 cm repeatedly a given number of times at
a rate of 30 times/min and the heights of the pile are determined
prior to and after such a test and are H.sub.a and H.sub.b,
respectively. ##EQU4##
The measurement of the height of the pile is effected under a load
of 20 g/cm.sup.2.
Electric charge voltage on a human body:
A sample to be tested is adjusted in temperature and humidity in
air at 20.degree.C and 30% RH for more than 48 hours and then a
human body walks on the sample more than 60 steps at a rate of 2
steps/sec, after which the electric charge voltage on the human
body is determined while continuing the walking in the same manner
as described above. The determined value varies with the walking
but the average value is determined.
Example 1 (Preparation of filaments)
Using nylon-6having an intrinsic viscosity of 1.14 measured at
30.degree.C in m-cresol and polyethylene terephthalate (abbreviated
as PET hereinafter) having an intrinsic viscosity of 0.64 measured
at 30.degree.C in o-chlorophenol, various composite filaments were
prepared as follows.
The molten nylon-6 and molten PET were separately pumped into a
spinneret maintained at 280.degree.C and joined in a side-by-side
relation in various conjugate ratios as shown in the following
Table 2, and then extruded through a circular or cross orifice of
the spinneret. The resulting undrawn filaments were cooled and
wound at a take-up velocity of 300 m/min while applying various oil
compositions of different water content as shown in the following
Table 1 by means of two step oiling rollers. In this case, the
number of rotations of the oiling rollers was adjusted in such a
manner that the amount of the oil composition adhered on the
undrawn filament is 0.5 - 1.5% by weight in the first oiling step
and 0.3 - 1.2% by weight in the second oiling step. The results of
the thus obtained undrawn filaments are shown in the following
Table 2. As seen from the results of Table 2, the operation was
impossible when only the nonaqueous oil composition was applied on
the filament.
Then, the undrawn filaments shown in Table 2 were drawn by
contacting with a hot roller and a hot plate (length: 400 mm) at
various setting temperatures as shown in the following Table 3 to
obtain drawn composite filaments of 900 d/30 f. The drawing ratio
was 3.75 - 3.82 times. The drawing treatment was not effected with
respect to the undrawn filaments No. 1, 2, 5, 6 and 8 of Table
2.
The following Table 3 shows a number of the thus obtained drawn
filament, the number of the undrawn filament, the temperature of
the hot roller, the temperature of the hot plate, spontaneous crimp
percentage, and split percentage and shrinkage difference in the
heated water treatment. From the results of Table 3, it can be seen
that the drawing of filaments cannot be satisfactorily effected,
when the oil compositions are applied in the manner other than the
present invention.
Table 1
__________________________________________________________________________
Non-ionic Oil Lubricat- surface Anti- compo- Class ing oil active
static Kerosene Water sition (%) agent agent (%) (%) No. (%) (%)
__________________________________________________________________________
1 non- 30 17.5 2.5 45 5 aqueous 2 " 30 17.5 2.5 40 10 3 " 25 19 3
39 14 4 other 20 15 2 40 23 5 " 18 10 2 38 32 6 aqueous 18 13 2 22
45 7 " 18 13 2 7 60 8 " 10 7 2 0 81
__________________________________________________________________________
Table 2 ______________________________________ Oil com- Oil com-
Undrawn Shape of Conjugate position position Wind- filament cross
ratio No. at No. at ing No. section (nylon- first second opera-
6/PET) roller roller tion ______________________________________ 1
FIG. 1 1/1 1 not A applied 2 " " 1 5 " 3 " " 1 6 good 4 " " 1 8 " 5
" " 2 2 A 6 " " 2 4 " 7 " " 2 7 good 8 " " 3 4 A 9 " " 3 6 good 10
" " 4 7 " 11 " " 7 not " applied 12 FIG. 2 1/4 1 8 " 13 " 1/3 1 8 "
14 " 1/1 1 8 " 15 " 2/1 1 8 " 16 " 3/1 1 8 " 17 " 4/1 1 8 "
______________________________________ A: Wound filament is
disturbed and the taking up on a bobbin is impossible.
Table 3
__________________________________________________________________________
Temperature Heated water for drawing Sponta- treatment Drawn
Undrawn setting .degree.C neous measurement filament filament crimp
No. No. per- Split Shrinkage Hot Hot centage percentage difference
roller plate (%) (%) (%)
__________________________________________________________________________
3-1 3 85 120 55 100 7 4-1 4 " " 70 100 7 7-1 7 " " 58 100 6 9-1 9 "
" 57 100 6 The filament is split into 10-1 10 " " two components
under undrawn condition, and loose 11-1 11 " " filament is formed
and drawing is impossible 12-1 12 " " 30 80 6 13-1 13 " " 43 90 4
14-1 14 " " 75 100 6 15-1 15 " " 72 100 7 16-1 16 " " 61 90 7 17-1
17 " " 38 70 7 15-2 15 80 not 78 100 2 set 15-3 15 85 180 53 80 13
15-4 15 85 160 61 90 10 15-5 15 100 not 66 80 8 set 15-6 15 135 not
59 60 8 set
__________________________________________________________________________
EXAMPLE 2
The drawn filaments shown in Table 3 were wound up in the form of a
muff (1 Kg winding), respectively. As soon as this muff was relaxed
in air, the filament shrunk to develop spontaneous crimps. The
muffs were charged in a filling density of 300 g/l into Over-maier
dyeing machine of 30 capacity and warm water of 50.degree.C was
filled therein and thereafter the temperature was raised up to
80.degree.C in 30 minutes. Then, the muffs were heated at
80.degree.C for 30 minutes and allowed to cool and taken out from
the dyeing machine. Next, the thus treated muffs were dehydrated by
a centrifuge and dried (at 115.degree.C0 to obtain crimped
filaments composed of fibril monofilaments. The number of crimps
per 1 inch of the crimped fibril monofilament was measured to
obtain a result as shown in the following Table 4. In this case,
the number of crimps was measured according to JIS-L-1074-1935.
Table 4 ______________________________________ Spontaneous Crimped
Drawn crimp Number of filament filament percentage crimps No. No.
(%) ______________________________________ 3-1 3-1 55 8.8 4-1 4-1
70 10.7 7-1 7-1 58 8.9 9-1 9-1 57 8.7 12-1 12-1 30 4.6 13-1 13-1 43
7.9 14-1 14-1 75 11.0 15-1 15-1 72 10.5 16-1 16-1 61 10.1 17-1 17-1
38 5.1 15-2 15-2 78 11.3 15-3 15-3 53 8.4 15-4 15-4 61 9.8 15-5
15-5 66 10.3 15-6 15-6 59 9.2
______________________________________
From the results of Table 4, it can be seen that good crimped
filaments are obtained when the spontaneous crimp percentage is
more than 40%.
EXAMPLE 3
Each of the drawn filaments used in Example 2 was subjected to
scouring and dyeing in the Over-maier dyeing machine according to
the following recipes to obtain beautiful dyed filaments wherein
PET fibril monofilament was dyed in yellow and nylon-6 fibril
monofilament was dyed in red.
The number of crimps of the dyed filaments was substantially equal
to that of Example 2.
1. Scouring
Scouring bath: soap content 1 g/l, soda ash 1 g/l, sodium
tripolyphosphate 2 g/l Bath ratio: 1 : 100 Temperature condition:
The bath temperature was raised from 40 to 80.degree.C in 30
minutes and the scouring was effected at 80.degree.C for 20
minutes.
2. Dyeing
Acid dye (red) 2% owf Disperse dye (yellow) 3% owf Carrier 3 g/l
Bath ratio: 1 : 100 Temperature condition: The bath temperature was
raised from 40 to 98.degree.C in 30 minutes and the dyeing was
effected at 98.degree.C for 60 minutes.
3. Reduction cleaning
Sodium hydroxide 1 g/l Hydrosulfide 1 g/l Activator 0.5 g/l
Temperature condition: 80.degree.C, 20 minutes
The thus obtained four dyed filaments were doubled while each of
the filaments was twisted in a S direction at 60 T/M, and then
tufted into a carpet under the following conditions.
______________________________________ Gauge 5/32 inch, Stitch
8/inch, Length of pile 5 mm
______________________________________
The appearance, impact resistance and electric charge voltage on
human body of the thus obtained carpet were observed and measured
to obtain results as shown in the following Table 5.
Table 5
__________________________________________________________________________
Impact Electric Drawn Conjugate resistance charge Carpet filament
ratio Appearance (%, on human No. No. (nylon-6/PET) 1000 times)
body (KV)
__________________________________________________________________________
3-1 3-1 1/1 uniform, high 65 2.3 bulkiness 4-1 4-1 " uniform, very
71 1.9 high bulkiness 7-1 7-1 " uniform, high 68 2.5 bulkiness 9-1
9-1 " uniform, high 67 2.1 bulkiness 12-1 12-1 1/4 uniform, poor 52
5.0 bulkiness, substrate is seen 13-1 13-1 1/3 uniform, high 65 2.8
bulkiness 14-1 14-1 1/1 uniform, very 73 1.7 high bulkiness 15-1
15-1 2/1 uniform, very 78 1.9 high bulkiness 16-1 16-1 3/1 uniform,
very 74 2.5 high bulkiness 17-1 17-1 4/1 uniform, poor 56 4.8
bulkiness, substrate is seen 15-2 15-2 2/1 uniform, high 77 1.5
bulkiness 15-3 15-3 " some uneven- 76 3.5 ness in pile, high
bulkiness 15-4 15-4 " uniform, very 79 2.6 high bulkiness 15-5 15-5
" uniform, very 78 1.9 high bulkiness 15-6 15-6 " uneveness 71 2.0
in pile
__________________________________________________________________________
The tufting operation was stable except the case of the drawn
filament No. 15-3. In case of the filament No. 15-3, the operation
was frequently stopped, because the dyed filament twined around the
guide and needle, so that it should be adjusted.
It is generally said that the shock due to discharge of static
electricity accumulated in human body takes place when the electric
charge exceeds 3 KV. The carpet composed only of nylon shows a
value of more than 10 KV when the electric charge on human body is
measured according to the method of the present invention.
Therefore, it is obvious from the results of Table 5 that the
electric charge of the carpet obtained by the present invention is
considerably low as compared with that of the carpet composed only
of nylon and the discharge shock is not caused.
On the other hand, the carpets No. 12-1 and 17-1 beyond the scope
of the present invention are lower in electric charge than the
carpet composed only of nylon, but are insufficient to prevent the
discharge shock. Furthermore, these carpets are poor in the
appearance and impact resistance.
EXAMPLE 4
The drawn filament No. 15-1 of Example 1 was wound in the form of a
muff in the same manner as described in Example 2 and charged in a
filling density as shown in the following Table 6 into an
Over-maier dyeing machine and then dyed in the substantially same
manner as described in Example 3 to obtain a dyed crimped filament.
The number of crimps of the thus obtained crimped filament is also
shown in Tbale 6.
Table 6 ______________________________________ Crimped Filling
density Number of filament No. (g/l) crimps
______________________________________ 15-7 390 10.8 15-8 380 10.6
15-9 330 10.5 15-10 280 10.2 15-11 210 9.0 15-12 150 7.8 15-13 135
4.3 ______________________________________
From the results of Table 6, it can be seen that when the filling
density is less than 150 g/l, the number of crimps becomes
considerably small so that the filling density is necessary to be
more than 150 g/l.
Then, each of the crimped filaments No. 15-7 to 15-13 was tufted
into a carpet in the same manner as described in Example 3. The
appearance, impact resistance and electric charge voltage on human
body of the thus obtained carpets were observed and measured to
obtain results as shown in the following Table 7.
Table 7
__________________________________________________________________________
Electric Crimped Filling Impact charge on Carpet filament density
Appearance resistance human body No. No. (g/l) (%, 100 times) (KV)
__________________________________________________________________________
15-7 15-7 390 noticeable 68 2.1 streaks, high bulkiness 15-8 15-8
380 uniform, high 70 2.3 bulkiness 15-9 15-9 330 uniform, very 75
1.9 high bulkiness 15-10 15-10 280 uniform, very 78 1.8 high
bulkiness 15-11 15-11 210 uniform, very 76 2.0 high bulkiness 15-12
15-12 150 uniform, high 69 2.4 bulkiness 15-13 15-13 135 low
bulkiness, 59 3.3 substrate is seen, poor
__________________________________________________________________________
When the filling density of the crimped filament is more than 380
g/l in the dyeing, noticeable streaks appears in the obtained
carpet, which is considered due to the dyeing uneveness and the
crimping unevenness, and also the appearance is poor. When the
filling density ranges in 150 - 380 g/l, good carpets can be
obtained.
EXAMPLE 5
The drawn filament No. 15-1 of Example 1 was knitted into a
cylindrical knitted goods by means of a cylinder needle machine
having a cylinder diameter of 31/2 inch and 40 needles. The
resulting cylindrical knitted goods, as soon as relaxed, shrunk to
develop spontaneous crimps. Then, the cylindrical knitted goods was
charged in a filling density as shown in the following Table 8 into
an Over-maier dyeing machine and dyed in the same manner as
described in Example 3 and then dried and deknitted to obtain the
dyed crimped filament. The number of crimps of the crimped filament
is also shown in Table 8.
Table 8 ______________________________________ Crimped Filling
density Number of filament No. (g/l) crimps
______________________________________ 15-14 390 11.8 15-16 380
11.7 15-17 300 11.9 15-18 150 8.2 15-19 135 4.6
______________________________________
From the results of Table 8, it can be seen that when the filling
density is less than 150 g/l, the number of crimps becomes
considerably small, so that the filling density is necessary to be
more than 150 g/l.
The crimped filaments No. 15-14 to 15-19, respectively, were tufted
into a carpet in the same manner as described in example 3. The
appearance, impact resistance and electric charge voltage on human
body of the thus obtained carpets were observed and measured to
obtain results as shown in the following Table 9.
Table 9
__________________________________________________________________________
Electric Crimped Filling Impact charge on Carpet filament density
Appearance resistance human body No. No. (g/l) (%, 100 times) (KV)
__________________________________________________________________________
15-14 15-14 390 noticeable 65 2.5 streaks, high bulkiness 15-16
15-16 380 uniform, high 71 2.3 bulkiness 15-17 15-17 300 uniform,
very 75 1.9 high bulkiness 15-18 15-18 150 uniform, high 68 2.1
bulkiness 15-19 15-19 135 low bulkiness, 53 3.2 substrate is seen,
poor
__________________________________________________________________________
When the filling density is more than 300 g/l in the dyeing,
noticeable streaks appears in the obtained carpet, which is
considered due to the dyeing unevenness and the crimping
unevenness, and the appearance is poor. When the filling density
ranges in 150 - 380 g/l, good carpets can be obtained.
COMPARATIVE EXAMPLE 1
The drawn filament No. 15-1 of Example 1 was wound on a perforated
bobbin (made of stainless steel) having a diameter of 100 mm (1 Kg
winding) and dyed under the same conditions as described in Example
3 except that the dyeing solution was jetted through holes of the
perforated bobbin. The thus dyed filament had a number of crimps of
2.6.
The dyed filament was tufted into a carpet in the same manner as
described in Example 3. However, the substrate was seen because the
fibril monofilaments constituting the pile were uniformly directed,
and further the bulkiness and appearance were poor.
In order to improve surface covering property and not to see the
substrate, it is necessary to tuft double yarns of five filaments
into carpet.
FIG. 14 is a photograph showing the surface of the thus obtained
carpet not following to the method of the present invention, while
FIG. 12 is a photograph showing the surface of the carpet No. 15-1
of Example 3 according to the present invention. When both the
carpets are compared with each other, the fibril monofilaments
constituting pile in the carpet of the present invention (FIG. 12)
have satisfactory crimps and are entangled to each other, while in
the carpet obtained by the method not following to the present
invention (FIG. 14) the fibril monofilaments are uniformly directed
and are not satisfactorily entangled.
The impact resistance and electric charge voltage of the carpet
shown in this comparative example (composed of double yarns of five
filaments) were 58% and 4.9 KV, respectively, which are
considerably inferior to the carpet according to the present
invention.
From this result it can be seen that unless the filaments are
treated in a relaxed package in which the filaments are wound so
that they can freely shrink, a good carpet can not be obtained.
COMPARATIVE EXAMPLE 2
The filament No. 15-1 of Example 1 was wound in the form of a muff
in the same manner as described in example 2. The resulting muffs
were charged into an Over-maier dyeing machine and hot water was
poured therein so as to develop spontaneous crimps. After the hot
water was poured, the temperature in the dyeing machine lowered to
70.degree.C, and then was raised up to 95.degree.C in 15 minutes
while heating and maintained at 95.degree.C for 30 minutes.
Thereafter, the filament was allowed to cool, taken out from the
dyeing machine, dehydrated by a centrifuge and dried to obtain a
crimped filament. However, this crimped filament was not
substantially split into two components and had considerably
crimping unevenness and was poor.
EXAMPLE 6
The four filaments of each filament Nos. 12-1, 13-1, 14-1, 15-1,
16-1 and 17-1 were twisted in a S direction at 60 T/M to obtain
twisted filaments of 3600 d/120 f, and the thus twisted filaments
were tufted under the following conditions to obtain a white
carpet. In the carpet, the filaments developed spontaneous
crimps.
______________________________________ Gauge 5/32 inch, Stitch
9/inch, Length of pile 6 mm
______________________________________
The obtained carpet was moved just under a steam jet apparatus in
which three jetting devices as shown in FIG. 7 are provided in
parallel at a rate of 1 m/min as shown in FIG. 9 to effect a steam
jet treatment.
The diameter of tube of the steam jetting device was 20 mm, the
diameter of the get nozzle was 2 mm and the nozzles were arranged
in zigazg at a distance of 5 mm. The steam pressure was 3.5
Kg/cm.sup.2 and the height of the jet nozzle was set so as to
contact with the pile (d=0). During the steam jet treatment, the
surface temperature of the pile was 99.degree.C.
After the steam jet treatment, each carpet was dyed by means of a
Wince dyeing machine under the substantially same conditions as
described in Example 3.
The following Table 10 shows the number of the dyed carpet,
appearance, impact resistance and electric charge voltage on human
body.
Table 10
__________________________________________________________________________
Conjugate Impact Electric Drawn ratio resistance charge on Carpet
filament (nylon-6/ Appearance (%, human body No. No. PET) 1000
times) (KV)
__________________________________________________________________________
12-2 12-1 1/4 low bulkiness, 55 4.7 poor 13-2 13-1 1/3 split two
com- 64 2.7 ponents are satisfactorily entangled, high bulkiness
14-2 14-1 1/1 split two com- 71 1.8 ponents are satisfactorily
entangled, very high bulkiness 15-20 15-1 2/1 split two com- 81 2.3
ponents are satisfactorily entangled, very high bulkiness 16-2 16-1
3/1 split two com- 69 2.7 ponents are satisfactorily entangled,
high bulkiness 17-2 17-1 4/1 poor 59 4.1 bulkiness
__________________________________________________________________________
From the results of Table 10, it can be seen that good carpets are
obtained by the method of the present invention. When the conjugate
ratio (nylon-6/PET) is out of the range of the present invention,
i.e., 1/4 or 4/1, only carpets having poor bulkiness, low impact
resistance and high electric charge are obained.
COMPARATIVE EXAMPLE 3
Three carpets No. 15-21, 15-22 and 15-23 were provided, i.e., the
carpet 15-21 obtained by dyeing the white carpet composed of the
filament No. 15-1 of Example 6 in the same manner as described in
Example 6 without subjecting to a steam jet treatment, the carpet
15-22 obtained by heating the same white carpet in a steam
atmosphere at 100.degree.C for 1 minute and then dyeing it as
described above, and the carpet 15-23 obtained by immersing the
same white carpet in hot water at 95.degree.C for 1 minute and then
dyeing it as described above. Then, the appearance, impact
resistance and electric charge voltage of three carpets were
measured.
In any case, the appearance was poor and the bulkiness was low.
Furthermore, the impact resistance was 56 - 60% and the electric
charge voltage was 4.3 - 5.1 KV.
FIG. 15 is a photograph showing the surface of the carpet No. 15-22
beyond the scope of the present invention, while FIG. 13 is a
photograph showing the surface of the carpet No. 15-20 of Example 6
according to the present invention. In FIG. 15, the fibril
monofilaments constituting the pile were uniformly directed and are
not fully entangled. In FIG. 13, the fibril monofilaments
constituting the pile had crimps and were satisfactorily entangled
to each other.
* * * * *