U.S. patent number 3,915,833 [Application Number 05/437,150] was granted by the patent office on 1975-10-28 for electrolytic cell with improved bipolar electrode connection.
Invention is credited to Steven A. Michalek, Richard L. Sampson.
United States Patent |
3,915,833 |
Michalek , et al. |
October 28, 1975 |
Electrolytic cell with improved bipolar electrode connection
Abstract
In a bi-polar filter press electrodialysis cell the adjacent
electrode pair is provided with attached bosses positioned to allow
the pressure receiving area of each boss to mate with each other
and surround the threaded bolt engaging means. An improved
electrical contact is made between the mating surfaces of the anode
and cathode bosses by coating the valve metal anode boss surface
with platinum and the ferrous metal or a nickel cathode boss
surface with a soft metal such as copper. A soft metal gasket is
placed between the bolt head and the pressure receiving shoulder of
the boss through which the bolt passes.
Inventors: |
Michalek; Steven A. (Hamilton,
MA), Sampson; Richard L. (Sudbury, MA) |
Family
ID: |
23735287 |
Appl.
No.: |
05/437,150 |
Filed: |
January 28, 1974 |
Current U.S.
Class: |
204/254; 204/268;
204/256; 204/279 |
Current CPC
Class: |
C25B
11/02 (20130101); C25B 9/77 (20210101) |
Current International
Class: |
C25B
9/20 (20060101); C25B 11/00 (20060101); C25B
11/02 (20060101); C25B 9/18 (20060101); C25B
009/00 () |
Field of
Search: |
;204/254,256,268,279,29F,286,266 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Mack; John H.
Assistant Examiner: Solomon; W. I.
Attorney, Agent or Firm: Saliba; Norman E.
Claims
The embodiments of the invention in which an exclusive property or
privelege is claimed are defined as follows:
1. In a bi-polar electrolytic filter press cell wherein a metal
cathode and a valve metal anode of each electrolysis cell is
separated by a cation selective ion-exchange membrane and wherein
the anode and cathode of the adjoining or contiguous cells are
maintained in space relationship by an electrically non-conductive
barrier sheet between them; the anode and cathode being in direct
electrical connection with each other through said barrier sheet by
attaching metal bosses on one side of each of said anode and
cathode, said bosses being positioned to allow the pressure
receiving area of each anode and cathode boss to mate with each
other to surround thread engaging means, the composition of the
bosses being substantially the same as the respective electrode to
which it is attached, one boss having female thread engaging means
for receiving a threaded bolt which bolt passes through the
adjacently disposed other boss and into the said one boss, said
bolt having a composition substantially the same as the boss
through which it passes, the said other boss having a pressure
receiving shoulder which mates with the pressure receiving shoulder
of the bolt head, the improvement comprising having the pressure
receiving and mating area of the said cathode boss plated with a
highly conductive and easily reduced metal selected from the group
consisting of copper, silver and gold and the said pressure
receiving and mating area of the said valve metal anode boss plated
with a platinum group metal and further having metal gasket means
for providing a leak proof seal and electrical contact between the
said bolt head pressure receiving shoulder and the pressure
receiving shoulder of the said other boss whereby under mechanical
pressure from the bolt thread engaging means the two highly
conductive soft mating surfaces of the said bosses and the said
mating shoulders of the said bolt head and other boss are squeezed
into intimate contact with each other to form an improved
electrical connection and a leak proof seal thereby.
2. The electrolytic cell of claim 1 wherein the metal cathode and
attached boss are selected from the group consisting of iron, steel
and nickel and a plating of copper is on the pressure receiving and
mating area of said boss.
3. The electrolytic cell of claim 1 wherein the female thread
engaging means of one boss are also plated with substantially the
same coating composition as that of the pressure receiving and
mating area of the said one boss.
4. The electrolytic cell of claim 1 wherein at least the thread
portion of the said bolt are also plated with a metal coating
substantially the same as the coating on the pressure receiving and
mating area of the boss through which the said bolt passes.
5. The electrolytic cell of claim 1 wherein the metal of said
gasket means is selected from the group consisting of copper and
lead.
6. The electrolytic cell of claim 1 wherein the pressure receiving
and mating area of the said cathode boss is coated with a highly
conductive silver epoxy thixotropic compound.
Description
This invention relates to bi-polar electrodialysis cells for
caustic-chlorine production and particularly to cation selective
membrane or diaphragm filter press type cells employing improved
means for electrically and mechanically inter connecting the
adjacent pair of metal anode and cathode bi-polar electrodes.
Bi-polar electrolytic filter press diaphragm cells for
caustic-chlorine production employing dimensionally stable metal
anodes require an internal electrical connection between the metal
bi-polar electrodes. Such a connection is disclosed in U.S. Pat.
No. 3,752,757 wherein the metal anode and cathode of adjoining
cells are electrically connected with each other by thread engaging
means with the anode and cathode maintained in space relationship
to each other by a non-conductive plastic barrier sheet
therebetween. The use of internal electrical connections of the
bi-polar electrodes through the barrier sheet subjects the
connection to a corrosive environment thereby necessitating the
need for improved and better protected electrical and mechanical
connections.
In accordance with the present invention there is provided a
bi-polar electrolytic filter press cell wherein a valve metal anode
and a ferrous metal or nickel cathode of each electrolysis cell is
separated by an ion selective membrane of the cation type and
wherein the anode and cathode of the adjoining or contiguous cells
are maintained in space relationship by an electrically
non-conductive sheet between them; the anode and cathode being in
direct electrical connection with each other through said sheet by
attaching metal bosses or lugs on one side of each of said anode
and cathode, said bosses positioned to allow the pressure receiving
area of each adjacently disposed anode and cathode boss to mate
with each other to surround thread engaging means, the metal
composition of the bosses being substantially the same as the
respective electrode to which it is attached, one boss having a
female thread engaging means for receiving a threaded bolt which
bolt passes through the other boss into the said one boss, said
bolt having a composition substantially the same as the boss
through which it passes, the said other boss having a pressure
receiving shoulder which mates with the pressure receiving shoulder
of the bolt head, the improvement comprising having the pressure
receiving and mating area of the said (cathode) boss plated with a
highly conductive and easily reduced metal selected from the group
consisting of copper, silver and gold and the said pressure
receiving and mating area of the said valve metal (anode) boss
plated with a platinum group metal whereby under mechanical
pressure from the bolt thread engaging means the two highly
conductive soft mating surfaces of the said bosses are squeezed
into intimate contact with each other to form an improved
electrical connection thereby.
The drawing is a fragmented cutaway view of the improved bi-polar
electrode joint taken at the middle of and along the length of the
threaded bolt joining the metal electrodes together according to
this invention.
In this invention as shown in the drawing is a typical bi-polar
metal electrode connection provided with a metal anode (1) and an
adjacently disposed metal cathode (3). The anode is preferably
foraminous in structure such as an expanded sheet of a valve metal
material such as titanium. The cathode is fabricated of a ferrous
metal such as iron or nickel and as with the anode is preferably of
the expanded mesh type. The plastic barrier or separator sheet
which is located between the electrodes to form the adjacent cell
walls in a filter press type membrane cell is not shown since it is
not concerned with the present invention. The use of such
separators in bi-polar electrode cells is fully disclosed in U.S.
Pat. No. 3,752,757 and need not further be described herein. To
facilitate the bolting of the anode 1 with the cathode 3 an anode
boss or button 4 is attached to the anode 1 and a corresponding
cathode boss or button 5 is attached to the cathode 3 as by welding
or other means. The anode boss 4 contains a hole 18 having thread
engaging means 11 and acts as the female receiving boss for
engaging threaded male bolt 20. The threaded bolt hole 18 of the
anode boss 4, the cathode boss bolt hole 22 and the cathode 3 are
in alignment with one another so that the bolt 20 can be inserted
and engaged readily. The mechanical and electrical connection is
made by inserting the bolt 20 through an electrode such as the
cathode 3 and cathode boss 5 and into the adjacent other boss or
anode boss 4 which as illustrated is the female bolt receiving
boss. The bolt 20 is turned until there is tight contact exerted by
the bolt head pressure receiving shoulder 9 against the cathode
boss pressure receiving shoulder 10 and further by the anode boss
pressure receiving area 12 against the cathode boss pressure
receiving area 13. To insure good contact and a leak proof seal
between the surfaces of the bolt head pressure receiving shoulder 9
and the cathode pressure receiving shoulder 10, it becomes
advantageous to place a soft metal gasket or washer 7 therebetween
made of a material such as copper or lead The pressure receiving
shoulders and areas 9, 10, 11 and 12 respectively are preferably
flat but may be of other shapes, the main consideration being the
proper mating engagement with firm contact to provide both a strong
mechanical joint and solid electrical contact.
In accordance with this invention an improved electrical contact is
provided especially in the mating engagement between the pressure
receiving areas 13, 12 of the anode boss 4 and the cathode boss 5
by coating the said engaging or mating surfaces or by applying
therebetween a highly conductive material which will withstand the
conditions encountered in caustic-chlorine production. The anode 1
and anode boss 4 attached together by appropriate means are
fabricated from the same valve metal or an alloy thereof which
metal is preferably titanium. The anode boss pressure receiving
area or mating surface 12 is coated or plated with at least one
platinum group metal or metal compound. The coating is preferably
platinum and is applied by any of several methods well known in the
art. The platinum coating may also be extended to cover the thread
engaging means 11 of the anode boss hole 18 if so desired but such
coating of the treads is not critical to the present invention
since the much larger butting area covered by the mating surfaces
of the anode and cathode bosses is the major source of good
electrical contact. Thread engaging means generally have
insufficient cooperating mating surfaces for the required contact
area. The cathode 3, cathode boss 5 and bolt 20 are preferably made
of the same or similar metal; a ferrous metal such as steel or iron
being preferred. The cathode boss pressure receiving area of mating
surface 13 can also be coated or plated with a continuous coating
of copper, silver or gold which coating can be further coated over
with platinum if so desired. It may also be advantageous to coat
the thread engaging means 8 of the bolt 20 in a similar manner
although this is not critical in the present invention for reasons
stated hereinabove. The manner of coating ferrous metals with the
aforesaid metals is well known in the art and is not within the
scope of the present invention. U.S. Pat. No. 3,627,561 discloses a
process for metallurgically bonding platinum to iron by first
plating the iron with a layer of easily reduced metal such as
copper and thereafter depositing the platinum, ideally by
flame-spray or plasma jet spray.
Where the mating surfaces of both the cathode and anode boss
pressure receiving areas contain a coating or layer of a metal
which is softer than that metal of which the base surface is
composed, it then becomes possible to join the plated parts
together into an improved electrical joint connection. Under
mechanical pressure, a strong electrical connection is made when
the softer metals on the mating surface of the anode and cathode
boss are squeezed or driven into intimate contact with each
other.
Other means of providing good electrical contact between the
pressure or mating surface of the anode and cathode boss is to
plate the valve metal surface with a platinum group metal as
described above while maintaining the iron or nickel surface
intact. Prior to bringing the two mating surfaces together, an
electrically conductive epoxy compound is applied there between.
Such a compound is commercially available from Epoxy Technology
Inc. of Watertown, Massachusetts under the designation Epo-Tek
415G. This compound is described as a two component (part A and B)
pure silver epoxy thixotropic paste. Part A the silver epoxy and
part B the silver hardener may each be employed above or mixed in
approximately equal parts and allowed to cure at room temperature.
Another electrically conductive preparation usable in the same
manner is designated as Catalog No. 21059 obtainable from the
Thomas & Beth Company of Elizabeth, New Jersey. This compound
is a mixture of fine metallic zinc particles suspended in a high
temperature grease. This compound also seals out corrosive liquids
from surface joints and additionally lowers the electrical
resistance therebetween.
Based on the disclosure herein, various modifications will be
suggested to those skilled in the present art. Such modifications
are to be understood to be within the scope of the present
invention.
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