U.S. patent number 3,914,468 [Application Number 05/392,531] was granted by the patent office on 1975-10-21 for method for marking paved surfaces.
This patent grant is currently assigned to Minnesota Mining and Manufacturing Company. Invention is credited to John B. Condon, Thomas L. Harrington.
United States Patent |
3,914,468 |
Condon , et al. |
October 21, 1975 |
Method for marking paved surfaces
Abstract
An improved method for marking paved surfaces by methods as
taught in Harrington, U.S. Pat. No. 3,410,185, using solid
particulate thermosoftening marking material. A bonding layer is
first formed by coating onto the paved surface a liquid,
low-viscosity coating composition that comprises a film-forming
organic binder material. After formation of the bonding layer the
particulate marking material is projected onto the bonding layer in
the presence of heat.
Inventors: |
Condon; John B. (Stillwater,
MN), Harrington; Thomas L. (St. Paul, MN) |
Assignee: |
Minnesota Mining and Manufacturing
Company (St. Paul, MN)
|
Family
ID: |
23550944 |
Appl.
No.: |
05/392,531 |
Filed: |
August 29, 1973 |
Current U.S.
Class: |
427/137; 404/77;
427/202; 427/224; 427/375; 427/422 |
Current CPC
Class: |
E01F
9/506 (20160201); E01F 9/518 (20160201) |
Current International
Class: |
E01F
9/04 (20060101); B05D 005/10 (); E01C 005/00 ();
E01C 011/24 () |
Field of
Search: |
;117/26,33,72 ;1/72
;94/1.5,22 ;404/77 ;427/137,202,376,422 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Childs; Sadie L.
Attorney, Agent or Firm: Alexander, Sell, Steldt &
Delahunt
Claims
What is claimed is:
1. An improved method for marking a paved roadway surface without
first severely cleaning the surface comprising
A. coating onto the paved roadway surface a thin bonding layer of
liquid coating composition that has a viscosity less than about
1000 centipoises, comprises a film-forming organic bonding
material, and (1) readily wets the paved roadway surface, (2) then
advances within about 30 seconds to a non-spreading form that is
sufficiently free of flammable solvents so that when briefly
exposed to an elevated temperature between 150.degree.F and
500.degree.F, it does not char or burn but softens to a tacky
condition, and (3) ultimately advances to a tough film that adheres
well to the paved surface;
then, within about one hour after completion of step (A),
B. momentarily heating the paved surface and the bonding layer to
an elevated temperature;
C. projecting toward the thus-heated bonding layer a marking
material that comprises a continuous stream of solid individual
organic-based particles that
1. are capable of passing a screen of about 20 mesh, with at least
80 weight percent being retained on a screen of about 200 mesh;
2. are non-tacky, non-blocking, free-flowing, and solid at
temperatures up to about 120.degree.F, and
3. comprise (a) a coloring agent in an amount sufficient to color a
marking formed from the marking material and (b) an organic
thermoplastic phase that accounts on the average for at least about
25 volume-percent of the marking material and that rapidly melts to
a low-viscosity condition such that its melt-viscosity is less than
about 4000 centipoises at 300.degree.F and less than about 15,000
centipoises at 250.degree.F; and
D. heating the individual particles as they proceed toward the
bonding layer to a temperature above 150.degree.F sufficient to at
least soften a major portion of the organic thermoplastic phase of
the particles before they reach the bonding layer;
the heated condition of the bonding layer and the particles being
such that the particles wet and bond to the surface of the bonding
layer and coalesce into a film, which subsequently becomes solid,
non-tacky, and capable of bearing wheeled road traffic without
tracking.
2. A method of claim 1 in which the organic phase of the particles
of marking material principally comprises a polyamide resin.
3. A method of claim 1 in which said liquid coating composition
material comprises a composition of acrylonitrile-butadiene
copolymer and a heat-reactive phenol-formaldehyde resin; a
composition of polychloroprene and heat-reactive
phenol-formaldehyde resin; an alkyd resin; a water-insoluble
isocyanate-terminated polyurethane prepolymer; or an
epoxy-resin-based composition.
4. A method of claim 1 in which the coating composition has a
viscosity less than about 100 centipoises.
Description
BACKGROUND OF THE INVENTION
Harrington, U.S. Pat. No. 3,410,185, and Harrington and Jorgensen,
U.S. Pat. No. 3,664,242, teach methods by which solid particulate
thermosoftening marking materials are applied to paved surfaces in
the presence of heat to form continuous markings. These methods
made possible for the first time the formation of markings on paved
surfaces that were ready to bear traffic within seconds after
application. This rapid traffic-bearing ability meant that
traffic-control markings could be applied to roadways with almost
no interruption of traffic. The methods and materials described in
U.S. Pat. Nos. 3,410,185 and 3,664,242 have found good acceptance
in the pavement-marking industry, especially for forming markings
at roadway intersections.
Another long-standing goal in the pavement-marking industry is to
find marking methods and marking materials that will form markings
capable of a long useful life on the roadway. Many traffic-control
markings last only a few months or less, especially at the heavily
traveled intersections for which the methods described above are
especially used. Early failure of markings is particularly
prevalent in geographic areas that experience severe winters, which
subject roadways and applied markings to internal stresses such as
freeze-thaw cycles that tend to weaken the marking or separate it
from the roadway, and which require roadway cleaning operations
involving application of sand and salt to the roadway and plowing
of the roadway. Early failure of the traffic-control markings means
that roadway-marking costs are greatly increased; and for portions
of the year there may be no traffic-control markings on the
roadway.
Achieving longer life in traffic-control markings formed from solid
particulate marking materials is a special challenge because of the
difficult conditions under which the marking operation is
performed. The roadway surface is an unclean surface covered with a
film of accumulated road oils as well as particles of dirt or sand.
Yet it is impractical to subject such a surface to anything more
than a superficial cleaning, such as sweeping the surface, during a
roadway-marking operation. Further, a paved roadway and the
substrate underlying the roadway provide a large heat sink, so that
to successfully perform the marking operation, the roadway surface
and marking material should be directly heated to a rather high
temperature, as with a flame. Even so, the thermally softened
particulate marking materials must wet the roadway surface and form
a continuous adherent film almost instantly after application. That
means that for an organic polymeric material to be useful in a
solid particulate marking material for roadways, the organic
polymeric material should have a rather sharp melting point and a
low melt-viscosity; but such materials tend to be brittle and more
susceptible to the effects of wear that prevent long life. Another
limiting condition of roadway marking is the fact that, for a
roadway marking operation to be practical, the marking must be
achieved by single passes of the marking equipment.
These limitations have made it difficult to improve the life of
traffic-control markings prepared from solid particulate
thermosoftening marking materials. While the
instant-traffic-bearing capabilities of the markings formed from
such materials gives them an important utility, their utility would
be greatly increased if a way could be found to lengthen the life
of the markings.
SUMMARY OF THE INVENTION
The present invention is based on the discovery that the useful
life of markings prepared from solid particulate thermosoftening
marking materials can be significantly extended by forming a thin
adherent bonding layer on the roadway with a liquid coating
composition prior to application of the solid particulate marking
material. Despite the adverse conditions listed above, markings of
significantly improved durability result.
Briefly, a method of the invention comprises the steps of
A. coating onto a paved roadway surface a thin bonding layer of
liquid coating composition that has a viscosity less than about
1,000 centipoises, comprises a film-forming organic binder
material, and (1) readily wets the paved roadway surface, (2) then
advances within about 30 seconds to a non-spreading form that is
sufficiently free of flammable solvents so that when briefly
exposed to an elevated temperature between 150.degree. and
500.degree.F, it does not char or burn but softens to a tacky
condition, and (3) ultimately advances to a tough film that adheres
well to the paved surface;
then, within about one hour after completion of step (A),
B. momentarily heating the paved roadway surface and the bonding
layer to an elevated temperature;
C. projecting toward the thus-heated bonding layer a marking
material that comprises a continuous stream of solid individual
organic-based particles that
1. are capable of passing a screen of about 20 mesh, with at least
80 weight-percent being retained on a screen of about 200 mesh;
2. are non-tacky, non-blocking, free-flowing, and solid at
temperatures up to about 120.degree.F; and
3. comprise (a) a coloring agent in an amount sufficient to color a
marking formed from the marking material and (b) an organic
thermoplastic phase that accounts on the average for at least about
25 volume-percent of the marking material and that rapidly melts to
a low-viscosity condition such that its melt-viscosity is less than
about 4,000 centipoises at 300.degree.F and less than about 15,000
centipoises at 250.degree.F; and
D. heating the individual particles as they proceed toward the
bonding layer to a temperature sufficiently above 150.degree.F to
at least soften a major portion of the organic thermoplastic phase
of the particles before they reach the bonding layer.
The heated condition of the bonding layer and the particles is such
that the particles wet and bond to the surface of the bonding layer
and coalesce into a film, which subsequently becomes solid,
non-tacky, and capable of bearing wheeled road traffic without
tracking.
PRIOR ART
The application of a liquid coating composition to a substrate
prior to application of a second marking material to the substrate
is akin to a "priming" operation. And such priming operations have
been previously performed prior to application of solid particulate
thermosoftening marking materials; see U.S. Pat. Nos. 2,716,075 and
3,264,131, for example. But the use of a preliminary bonding layer
in a roadway marking operation is a novel extension of "priming"
operations. Prior priming operations call for a severe cleaning of
the surface that is to be coated and a careful application of the
priming and final coating materials. Such operations contrast with
roadway-marking operations, which are performed under conditions
that would be thought to prevent a productive use of priming: the
unclean and diverse nature of the roadway surface; the need to use
single-pass marking operations; the need to permit traffic to
travel over the applied bonding layer prior to application of the
particulate marking material so as to avoid interruption of
traffic; the need to apply the particulate marking material more
quickly after application of the bonding layer than is normally
used for drying a primer; the direct application of high
temperatures to the bonding layer, as with a flame; the use of
rather brittle, low-melt-viscosity marking materials to achieve
instant traffic-bearing ability; and exposure of the markings to
severe winter conditions. The improvement in durability achieved by
the present invention under such conditions was not suggested by
the prior art.
DETAILED DESCRIPTION
A wide variety of film-forming binder materials are useful to form
bonding layers according to the invention. Some exemplary binder
materials are compositions of acrylonitrilebutadiene copolymers and
heat-reactive phenol-formaldehyde resins; compositions of
polychloroprene and heat-reactive phenol-formaldehyde resins;
drying-oil-modified alkyd resins; water-insoluble,
isocyanate-terminated polyurethane prepolymers; and
epoxy-resin-based compositions. Bonding layers consisting of the
listed binder materials generally have sufficient toughness and
film integrity, even when exposed to moisture and other normal
environmental roadway conditions, so as to hold the marking layer
onto the roadway; they are readily wetted by the molten marking
material (meaning that their surface energy is generally about the
same as or greater than the surface energy of the molten marking
material); they adhere well to the roadway; and they adhere well to
the marking material.
Film-forming binder materials that have adhesion-promoting groups
like those contained in the compositions above are usually
especially suited to use as binder materials in the invention. And
the best adhesion between the bonding layer and the marking layer
generally occurs when an intermixture of the two develops during
application. Such an intermixture generally is obtained if the
bonding layer softens sufficiently to become tacky in the presence
of the heat applied prior to and during application of the marking
material.
Reaction between the bonding layer and the marking materials is
also desirable. In general, binder materials that cure or
crosslink--as by a reaction between two parts of a binder material
or as a result of exposure of the bonding layer to oxygen or
moisture--after the bonding layer has been applied form the most
tough films, and such binder materials are preferred.
The binder material is usually dissolved in an organic solvent to
form a liquid low-viscosity coating composition that will wet the
paved surface. The coating composition may or may not be colored by
a coloring agent. Generally the desired wetting occurs with coating
compositions that have a viscosity at application of less than
about 1000 centipoises, and preferably the coating composition has
a viscosity less than about 500 centipoises and more preferably
less than about 100 centipoises at application (viscosities given
herein are as measured on a Model RVT Brookfield viscometer, using
a number 3 spindle at 100 revolutions per minute). Such
low-viscosity coating compositions not only wet the paved surface
well (generally penetrating 50-75 percent or more of the
interstices of the paved surface), but also form a thin layer from
which solvents rapidly escape. In the ultimate form of the bonding
layer, after elimination of solvent, etc., the average thickness of
the layer over its whole width is preferably less than about 3
mils, and more preferably is less than about 1 mil.
Once the coating composition has been applied to the paved roadway
surface, it rapidly advances (preferably in less than 30 seconds)
to a non-spreading form that is sufficiently free of flammable
solvents so that, when briefly exposed to an elevated temperature
between 150.degree. and 500.degree.F, or a flame, it will not char
or burn. At the same time, the bonding layer preferably becomes
nontacky, preferably within 30 seconds after application of the
coating liquid.
After the bonding layer has been formed on the roadway, usually
within a few minutes after application of the coating composition,
the solid particulate marking material is applied to the bonding
layer. The marking material is applied by procedures generally
described in the above-identified U.S. Pat. Nos. 3,410,185 and
3,664,242, both of which are incorporated herein by reference. One
typical apparatus for applying marking material by these procedures
is described in Micheln, U.S. Pat. N0. 3,393,615. That apparatus
uses a flame (as fed by a gaseous or atomized fossil fuel) that
strikes the roadway and extends somewhat in front of the apparatus,
where it preheats surface portions of the roadway and the bonding
layer on the roadway. Generally, the surface portions of the
roadway and bonding layer are heated to a temperature between about
150.degree. and 500.degree.F (as measured, for example, by a
heat-sensitive crayon marked on the roadway). The marking material
is sprayed through the flame onto the bonding layer, and in
traveling through the flame, the marking material is softened so
that at least a major portion of the organic thermoplastic phase of
the particles is softened before they reach the bonding layer.
Preferred marking materials for use in this method are also
described in the above-identified U.S. Pat. Nos. 3,410,185 and
3,664,242. These marking materials include organic-based particles,
as well preferably as an inert nonmelting particulate material,
such as transparent glass beads. In the preferred marking
materials, the organic phase of the organic-based particles
principally comprises a polyamide condensation product of
polycarboxylic acid and polyamine (generally accounting for at
least about 50 weight-percent of the organic phase), and in the
most preferred embodiments also includes a low-molecular-weight
viscosity reductant. Another useful marking material comprises
epoxy resin and a low-molecular weight viscosity reductant such as
phthalic anhydride. As previously noted, the organic phase of the
particles melts quickly to a low-viscosity condition when heated
but achieves a solid non-tacky condition within seconds up to one
minute when cooled to about 75.degree.F. Generally the
melt-viscosity of the organic phase should be less than about 4,000
centipoises at 300.degree.F, and less than about 15,000 centipoises
at 250.degree.F; preferably it is less than 3,000 centipoises and
10,000 centipoises at 300.degree.F and 250.degree.F,
respectively.
As also previously noted, the organic-based particles of marking
material are generally capable of passing a screen of about 20
mesh, with at least about 80 weight-percent being retained on a
screen of about 200 mesh. Preferably the particles pass a screen of
40 mesh, with at least about 80 weight-percent being retained on a
screen of about 100 mesh. The particles should be nontacky,
nonblocking, free-flowing, and solid at normal ambient temperature
up to about 120.degree.F to permit them to be handled practicably
in marking equipment. A coloring agent is generally included in the
particles in an amount sufficient to color a marking formed from
the marking material.
The invention is further illustrated by the following examples.
EXAMPLES 1 - 5
A set of test markings was prepared using different bonding layers
formed from different coating compositions. Each coating
composition was first roller-coated onto a concrete city street.
After about 15 minutes, a polyamide-based marking material as
described in Example 2 of U.S. Pat. No. 3,664,242 was applied to
each of the resulting bonding layers through an applicator as
described in U.S. Pat. No. 3,393,615. A control marking was also
formed by applying the same marking material directly to the
concrete roadway next to the set of test markings. The markings
were applied in very early spring so that the markings would
experience freeze-thaw cycles, etc. that would accelerate failure
of the markings.
The coating compositions for the bonding layers of the different
test markings were as follows. For the first test marking, labeled
Example 1, the coating composition comprised 11.3 parts of
polychloroprene (Neoprene AC and WHR made by duPont in a ratio of
one part to three parts), 5 parts of a heat-reactive
phenol-formaldehyde resin (Bakelite CKR 1634 made by Union
Carbide), 2.2 parts of magnesium oxide, 0.5 part of zinc oxide,
43.8 parts of petroleum solvent, 27.4 parts acetone, and 9.1 parts
toluol, and had a viscosity of about 60 centipoises. The coating
composition of Example 2 comprised an alkyd resin that included 35
weight-percent soya oil and 31 weight-percent phthalic anhydride
and was dissolved in xylol to give a 30 weight-percent solution
having a viscosity of about 25 centipoises (diluted Syntex 3638
made by Celanese). The coating composition of Example 3 comprised
10.6 parts of acrylonitrile-butadiene elastomer (Paracril BS made
by Uniroyal), 10.7 parts of heat-reactive phenol-formaldehyde resin
(5.4 parts Bakelite 1003 and 5.3 parts of Varcum 5485 made by
Reichhold), 1.1 part of zinc oxide, 1.5 salicylic acid, and 0.2
part antioxidant, all dissolved in ketone solvents to prepare a 10
weight-percent-solids solution having a viscosity of about 30
centipoises. The coating composition of Example 4 comprised a
water-insoluble isocyanate-terminated polyurethane which in turn
comprised a polyethylene oxide having an average molecular weight
of 200 terminated at both ends with isocyanate groups formed by
reaction of the polyethyleneoxide with toluene diisocyanate,
dissolved in acetone to give a 30 weight-percent-solids solution at
250 centipoises. The coating composition of Example 5 also
comprised a water-insoluble isocyanate-terminated polyurethane as
described, but was formed from a polyethyleneoxide having a
molecular weight of 400.
The markings were rated periodically for chipping in the manner
described in ASTM D-913-51 until the control marking had totally
failed so as to have a zero rating in the test. At this time all of
the test markings usually bonding layers still had 10 ratings.
EXAMPLE 6
Markings were formed on a concrete roadway by the procedure
described for Examples 1-5 above. One marking was prepared using a
bonding layer formed from the liquid coating composition of Example
1, and another control marking was prepared without using a bonding
layer. The markings were applied in the spring of the year (May 8)
and rated for chipping periodically during the summer and fall.
______________________________________ Marking Marking Date of with
without rating bonding layer bonding layer
______________________________________ May 8 10 10 May 18 10 9 May
26 10 8 May 31 10 4 July 28 10 0 September 15 9 0 October 20 7 0
______________________________________
From the foregoing it will be seen that one problem in the
application of a primer coating to a roadway surface involves the
need for such primed surface to bear traffic prior to the
application thereon of a suitable marking material. Particularly
when the priming composition contains a flammable solvent, it is
necessary to avoid elevated temperature or flame exposure of the
primed surface until essentially all of the flammable solvent is
removed, because of the obvious fire hazard which might result.
However, in the interval during which the solvent is removed from
the primed surface before the marking composition is applied, it is
extremely desirable to minimize any traffic restriction over the
roadway surface, and it is therefore one unique feature of the
present invention that the priming composition does not lose its
priming capability during its exposure to normal traffic in this
interval.
* * * * *