U.S. patent number 3,913,309 [Application Number 05/123,401] was granted by the patent office on 1975-10-21 for fibrous composition of matter.
Invention is credited to Nereo Chiarotto.
United States Patent |
3,913,309 |
Chiarotto |
October 21, 1975 |
Fibrous composition of matter
Abstract
An ignifuge or fire resistant intimate blend of fibres in the
form of a composite yarn, a woven fabric made of such composite
yarns, a non-woven fabric and textile articles obtained therefrom.
The fibres are selected among glass fibres or ceramic fibres
surrounded by at least two different kinds of fibres selected among
synthetic and/or natural fibres. One of such two fibres has a
melting point different from the other of the two fibres and both
of the two fibres have melting points lower than the melting point
of the glass or ceramic fibre wool and chlorovinyl fibres are among
the preferred fibres surrounding the glass fibres. During the
melting of the fibres surrounding the glass fibre, at least a
partial disintegration thereof takes place and a carbonous deposit
is formed on the glass fibres protecting them from heat and
increasing heat resistant properties thereof.
Inventors: |
Chiarotto; Nereo (Varese,
IT) |
Family
ID: |
27273239 |
Appl.
No.: |
05/123,401 |
Filed: |
March 11, 1971 |
Foreign Application Priority Data
|
|
|
|
|
Mar 17, 1970 [IT] |
|
|
22050/70 |
Jul 3, 1970 [IT] |
|
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26982/70 |
Nov 12, 1970 [IT] |
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31683/70 |
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Current U.S.
Class: |
57/229; 57/904;
57/256; 423/477 |
Current CPC
Class: |
D04H
1/5418 (20200501); C04B 30/02 (20130101); D04H
1/5412 (20200501); D04H 1/43 (20130101); D04H
1/4266 (20130101); D04H 1/551 (20130101); D04H
1/43828 (20200501); D04H 1/435 (20130101); D02G
3/185 (20130101); D03D 15/513 (20210101); D04H
1/4334 (20130101); D04H 1/4291 (20130101); D02G
3/443 (20130101); D04H 1/43835 (20200501); D04H
1/542 (20130101); D04H 1/4209 (20130101); D04H
1/4218 (20130101); C04B 30/02 (20130101); C04B
14/38 (20130101); C04B 16/06 (20130101); C04B
18/18 (20130101); C04B 18/24 (20130101); Y10S
57/904 (20130101); D04H 1/43838 (20200501); Y02W
30/91 (20150501) |
Current International
Class: |
C04B
30/00 (20060101); C04B 30/02 (20060101); D03D
15/12 (20060101); D04H 1/42 (20060101); D02G
3/02 (20060101); D02G 3/18 (20060101); D02g
003/36 (); D02g 003/44 () |
Field of
Search: |
;161/170,175,176,192,150
;57/14BY,14G,144 ;423/447 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Huckert; John W.
Assistant Examiner: Gorenstein; Charles
Attorney, Agent or Firm: Modiano; Guido Josif; Albert
Claims
I claim:
1. A composite yarn which exhibits fire resistant properties due to
thermal decomposition, said yarn comprising a glass-fiber core, a
carbonizable coating for said core consisting of a blend of a
natural animal fiber with a synthetic fiber, said coating
exhibiting thermal decomposition, upon being subjected to high
temperatures, and forming a substantially carbonaceous residue
rendering the yarn fire resistant.
2. The composite yarn of claim 1, wherein said glass fiber is
selected from the group consisting of beta glass fibers, common
glass fibers, ceramic fibers and mixtures thereof.
3. The composite yarn of claim 1, wherein said natural fiber is
selected from the group consisting of wool fibers, silk fibers,
artificial proteic fibers and mixtures thereof.
4. The composite yarn of claim 1, wherein said synthetic fiber is
selected from the group consisting of polyvinylchloride fibers,
polyamide fibers, modacrylic fibers, polyester fibers,
polyacrylonitrilic fibers and mixtures thereof.
5. The composite yarn of claim 1, wherein said glass fiber core
consists of a filament of beta glass and said coating consists of
an intimate blend of polyvinylchloride fibers and wool fibers.
6. The composite yarn of claim 5, wherein said glass filament is
wrapped by said polyvinylchloride fibers and wool fibers which form
a tube-like coating for said filament.
7. The composite yarn of claim 5, wherein the weight ratio glass
fibers: polyvinylchloride fibers: wool fibers is approximately
100:40:60.
8. A fabric made of composite yarn of claim 1.
Description
BACKGROUND OF THE INVENTION
The present invention relates to a fibrous composition of matter,
in particular for obtaining products with improved ignifuge
characteristics. More particularly, the present invention relates
to composite yarns having improved ignifuge characteristics, to
fabrics obtained by said yarns and to non-woven fabrics having
improved ignifuge characteristics, obtained from said fibrous
composition of matter.
By the term ignifuge is generally meant a property of a fabric
which does not permit the spreading or propagation of a flame (i.e.
fire resistant). It is known that a fabric can be ignifuge because
it is formed from ignifuge fibres or because it is formed from
fibres which, after the fabric has been made, are processed, such
as by impregnation treatment with suitable substances which confer
said ignifuge property to the fabric.
The problem facing the experts in the art during the conceiving of
a fabric having ignifuge properties, above all of a fabric to be
employed for obtaining textile goods which is applicable to the
clothing field and/or furnishing field, is represented by the
necessity of conferring the fabric in the course of its
manufacture, both with ignifuge characteristics, and with all those
properties conventionally required from a fabric to be employed in
the clothing field and/or furnishing field. It is known that, for
some time, persons skilled in the art have been constantly in
search of fibres that can satisfy and solve the problem or have
been in search of substances for impregnating fabrics, which
substances, while conferring to the fabrics the desired
fire-resistant properties, would not diminish their other
properties or characteristics. Thanks to said continual research,
there are currently available ignifuge fabrics which appear
satisfactory up to maximum temperature values in the order of
400.degree.-500.degree. C. On achieving or exceeding a temperature
of the above order, in ignifuge fabrics currently available, there
occurs a disadvantage caused by the fact that the fabric, both when
obtained from ignifuge fibres or when impregnated with ignifuge
substances, becomes easily perforated or is heat-conductive as, for
example, in the case of glass fibres.
In fact in fire accidents it is not only important to prevent the
spreading of fire over the clothes, but also to prevent eccessive
heat to reach the body of the user.
SUMMARY OF THE INVENTION
The main object of the present invention is to produce a
flameproof, heat-insulating composition of matter which can be
processed into yarns, textiles, and non-woven fabrics suitable for
application in the garment and furnishing field as well as for
industrial applications, and whose flameproof properties are such
as not only to prevent the spreading of the flame, but also to
resist perforation by a flame at temperatures higher than
400.degree.-500.degree. C which is the maximum temperature at which
flameproof fabrics at present commercially available can
resist.
It is a further object of this invention to produce a fibrous
composition of matter with properties of the above-mentioned type
that can easily be formed from materials which are normally
commercially available, employing production processes of a known
type so as to be advantageous also from the strictly economic point
of view.
These and still further objects, which will better appear from the
following, are achieved by a fibrous composition of matter
comprising a blend of glass fibres and of at least two fibres
selected from the group consisting of synthetic fibres, natural
fibres and blends thereof the synthetic and natural fibres having a
melting point below the melting point of said glass fibres and
which, when melting, form on said glass fibres a substantially
carbonous residue.
The term "melting point" as used in this specification should be
intended in the sense of a melting process which involves at least
a partial disintegration of the molecular structure of the fibre
and in which the boundaries between the pure melting process and
the pure disintegration might not be exactly defined.
In one of its aspects, the present invention relates to a composite
yarn, comprising a glass-fibre core and a coating for said core
formed from at least two fibres selected from the group consisting
of synthetic fibres, natural fibres and blends thereof having
melting points which differ from each other and are below the
melting point of said glass fibres and which, when melting, form on
said core a substantially carbonous residue, said melting involving
at least a partial decomposition.
By the term "glass fibres," as used in this specification and in
the accompanying claims, are meant common glass fibres, "beta"
glass fibres, ceramic fibres and the like fibres. "Beta" glass
fibres appear to be of particular advantage for the applications of
this invention. "Beta" fibres are manufactured by Owens-Corning
Fiberglas Corporation of U.S.A., but under the term "Beta" glass
fibres as used in this specification glas fibres having singularly
a diameter of less than 5 microns should be intended. Synthetic
and/or natural fibres having disintegrative melting points lower
than that of said glass fibres, useful in the present invention,
comprise, woollen fibres, artificial proteic fibres, naturalsilk
fibres, chlorovinyl fibres, modacrylic fibres, acrylonitrile
fibres, polyester fibres, polyamide fibres, cellulose fibres,
preventively treated with fire-resistant substances and their
blends.
Particularly advantageous, in applications of this invention are
woolen fibres and chlorovinyl fibres, in combination with said
glass fibres and in particular with beta glass fibres.
Further characteristics and advantages of the invention will better
appear from the description of examples of the fibrous composition
of matter, of yarns and non-woven fabrics obtained therefrom, which
are given hereinafter as indicative and not limitative
examples.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
EXAMPLE 1
The obtaining of a composite yarn took place by employing, as the
core of said yarn, beta glass fibres manufactured by Owens-Corning
Fiberglas Corporation and a coating formed from a blend of wool and
vinyl fibres, and more precisely a polychlorovinyl fibre,
commercially known under the trademark of "Leavin" manufactured by
the Italian Company Chatillon S.p.A. of Milan, Italy. Said
polychlorovinyl fibre melts, without flame, at a temperature of
about 250.degree. C while wool notoriously burns slowly, melting at
a temperature of over 300.degree. C. Beta glass, which forms the
thread-core of the composite yarn according to the present
invention, has a melting point of about 1,000.degree. C.
The weight proportions of the components of the yarn were as
follows: 100 parts by weight of Td 100 Beta fibre glass, 60 parts
by weight of 66.sup.s wool and 40 parts by weight of
polychlorovinyl fibre "Leavin" of 3 deniers. First a roving of wool
and Leavin fibres was made with the indicated proportions in
conventional manner and the roving and the fiber glass thread were
joined by the conventional "core spun" technique. A composite yarn
has been obtained in which a core of fibre glass was completely
surrounded by fibres of wool and Leavin forming a coating.
The composite yarn thus obtained was exposed to a Bunsen flame of
about 800.degree. C. First the melting of the Leavin fibre was
observed, which formed a deposite on the other fibres retarding the
heat action thereon. Subsequently the wool fibres begun to melt and
decompose.
It was observed that the melting residue of Leavin fibres and the
melting residue of wool fibres mixed and formed a carbonous residue
which made a protective and insulating deposite on the glass
fibres. The yarn showed a surprising heat and fire resistance. It
is believed that these surprising fire and heat resisting
properties are aided by the following mechanism.
Initially, the decomposition of the polychlorovinyl fibre takes
place with the development of acidic gas and a deposit of said
fibre on other fibres with which it is intimately mixed. At a given
point, the wool fibres which have an inflamability point of about
600.degree. C begin to melt with the development of basic gas. The
two gases developing from the melting of the polychlorovinyl and
wool fibres, partly neutralize each other, thus preventing the wool
from burning, due to lack of oxygen; the amalgam formed from the
chlorovinyl residues and of the carbon residues originating from
the wool are depositated on the beta glass fibre (the core of the
composite yarn). This glass fibre is thermically protected by such
residues deposited on it, resisting up to over 900.degree. C before
initiating the melting process.
The composite yarn according to the invention was woven, forming
textile goods having, in addition to the above mentioned surprising
ignifuge characteristics, all those properties normally required
for clothing and furnishings. The tests carried out, showed that,
when subjected to the action of fire the heat insulating properties
of the fabric remarkably increased.
EXAMPLE 2
A composite yarn was obtained according to the indications of
example 1, in which however the wool fibre was substituted by an
artificial proteic fibre, for example a caseine F fibre known
commercially under the trademark "Merinova," manufactured by the
Italian Company SNIA VISCOSA. The composite yarn thus obtained,
when subjected to the action of a flame, resisted up to
temperatures in the order of 800.degree. C.
EXAMPLE 3
A composite yarn was obtained according to indications of example
1, substituting the wool with natural silk. In this case, when
subjected to a flame, the yarn resisted up to a temperature in the
order of 700.degree. C.
EXAMPLE 4
Following the indications of example 1, a composite yarn was
obtained by employing, as the core of said yarn, beta glass fibres,
and an intimate bend of modacrylic fibre and wool fibre as a
coating. This composite yarn, when subjected to the action of the
flame, resisted up to temperatures in the order of
700.degree.-750.degree. C.
EXAMPLE 5
The procedure of Example 4 was repeated, substituting the wool
fibres with artificial proteic fibres and/or with silk fibres. The
composite yarn obtained had fire-resistant characteristics
comparable with those of the yarn of Example 4.
EXAMPLE 6
The procedure of obtaining a yarn according to Example 4 was
followed, wherein however the coating of the beta glass fibre was
obtained by first forming a thread from the rovings of
acrylonitrilic and polyester fibres and then jointing together such
thread with the thread of glass fibre by a conventional end-to-end
technique. The composite yarns obtained according to this example,
subjected to the action of the flame, resisted up to a temperature
in the order of 550.degree.-600.degree. C.
EXAMPLE 7
The procedure for obtaining a composite yarn according to example 1
was followed, substituting the chlorovinyl fibre with polyester.
When subjected to the flame, the composite yarn resisted
temperatures in the order of 550.degree.-600.degree. C.
EXAMPLE 8
The procedure as described in Example 1 was followed with the
exception that the polychlorovinyl fibre was substituted by 66
polyamide fibre, while the wool was substituted each time by other
artificial proteic fibres or by natural silk. In each case
composite yarns were always obtained which resisted high
temperatures, comparable with those against which the yarn obtained
by Example 1 resisted.
EXAMPLE 9-9A
The procedure according to that described in examples 1-8 was
followed, with the exception that a beta glass fibre was
substituted, the first time, with a common glass thread, and the
second time with a ceramic thread, thus obtaining two composite
yarns which resisted a temperature in the order of
600.degree.-650.degree. C before melting, which means that they had
altogether surprising ignifuge characteristics compared with the
fire-resistant characteristics of yarns up to now known.
The yarns obtained according to the previous examples, were woven
and shaped into textile goods having, in addition to the
above-mentioned surprising ignifuge and insulating characteristics,
all those properties normally required from fabrics which are
applicable to the fields of clothing industry, furnishings and
other known industrial applications.
It has been found that the same fibres which form the composite
yarn in examples 1-9-9A, could advantageously be used in obtaining
fabrics of the so-called non-woven type or felted fabrics, having
most marked ignifuge characteristics and practically comparable
with those of the composite yarn as in the above examples, and of
fabrics obtained from said composite yarn.
The non-woven fabric of the above-mentioned type is suitable for
numerous applications among which the most remarkable ones are the
obtaining of linings or stuffings, wall-to-wall carpets of the
"moquette" type, so-called "pressed" articles, on prior
impregnation of the non-woven fabric, with appropriate bending or
adhesive agents as additives; thses articles had the same
surprising and highly desired ignifuge and increased insulating
characteristics under the action of fire.
These non-woven fabrics can be manufactured by intimately blending
a first fibre selected from the group comprising beta glass fibres,
common glass fibres, ceramic fibres and silicious fibres, with at
least two other fibres which are selected from natural and/or
synthetic fibres, these natural and/or synthetic fibres having
different melting points, and below the melting point of said first
fibre, and forming, on melting, a substantially carbonaceous
residue on said first fibre.
Advantageously, said second fibres are selected from wool fibres,
artificial proteic fibres, natural silk fibres, chlorovinyl fibres,
modacrylic fibres, acrylonitrilic fibres, polyester fibres,
polyamide fibres, and their blends.
The following are some examples of non-woven fabrics obtained with
fibres of the above-mentioned type.
EXAMPLE 10
10 kg. of glass tuft or flock and 10 kg. of wool tuft or flock and
10 kg. of polychlorovinyl tuft were thoroughly mixed, and a
non-woven fabric of the felted type was obtained therefrom by
conventional techniques. Repeated and strictly controlled tests,
showed very high ignifuge properties, currently unavailable in the
known non-woven fabrics, and even higher than the ignifuge
properties of the single fibres composing the fabric thus obtained.
This was explained by a cooperative ignifuge action of surface and
near to surface layers of the fabric.
With the non-woven fabric of this example, paddings or stuffings in
general were easily obtained as for instance paddings for
furnishings, motor-car seats, to the obtaining of covering elements
such as for instance wall-to-wall carpets and the like, which all
had the same desired fire-resistant characteristics.
On prior impregnation with appropriate adhesive additives, as for
example chlorovinyl resins and the like resins, and subsequent
moulding, with the non-woven fabric of Example 1, shaped "pressed"
articles, having ample and different applications and the desired
ignifuge characteristics, were obtained.
EXAMPLE 11
A non-woven felted-type fabric was obtained in a conventional
manner by intimately mixing 10 kg. of ceramic fibre, 10 kg. of
modacrylic fibre and 10 kg. of wool or other artificial proteic
fibres or silk. In all cases, the non-woven fabric thus obtained
when subjected to the effect of a flame, resisted very high
temperatures in the order of 700.degree.C before the melting
process of the internal layers of the fabric started. Similarly, as
already mentioned in Example 10, this non-woven fabric was used to
obtain articles such as, for example, paddings or stuffings,
articles for covering and the like, all having high ignifuge
characteristics.
In other embodiments of the non-woven fabric of this invention,
different combinations of glass fibres, ceramic fibres, beta glass
fibres in an intimate blend with at least two other fibres of which
one was selected from the group of woollen fibres, artificial
proteic fibres, natural silk fibres and the other one was selected
from the group of chlorovinyl, modacrylic, acrylonitrilic,
polyester, polyamide and the like fibres or their blends, were
used. All the non-woven fabrics obtained from these combinations
had surprising ignifuge characteristics and were easily processable
for obtaining textile goods, such as paddings in general, covering
articles, ropes and the like. On prior impregnation with adhesive
substances of the synthetic resins type, compatible with the
employed synthetic fibres and with simple moulding operations by
pressing, it was possible to obtain shaped or pressed articles in
different forms and of different even considerable dimensions, all
having the desired ignifuge characteristics.
In a particular application of the non-woven fabric according to
the invention, a fabric formed substantially of three adjacent
layers was obtained in a single piece. Each layer was formed of
three types of fibres, selected from the above mentioned groups,
each layer having, with respect to the other adjacent layers,
either the same quantitative combination of the three fibre types
of different combinations, with one fibre type prevailing with
respect to the remaining two.
Yarns obtained as above described but inwhich instead of Leavin
fibres the following vinyl fibres were used.
Fibravyl manufactured by the French Company Soc. Rhovyl
Clevyl T manufactured by the French Company Soc. Rhovyl
Rhovyl manufactured by the French Company Soc. Rhovyl
Thermovyl manufactured by the French Company Soc. Rhovyl
Vinyon manufactured by the U.S.A. Union Carbide Corp.
showed similar surprising ignifuge characteristics.
* * * * *