U.S. patent number 3,912,579 [Application Number 05/099,850] was granted by the patent office on 1975-10-14 for reverse cleaning and de-inking of paper stock.
This patent grant is currently assigned to Bergstrom Paper Company. Invention is credited to Harry J. Braun.
United States Patent |
3,912,579 |
Braun |
October 14, 1975 |
Reverse cleaning and de-inking of paper stock
Abstract
A slurry consisting of water, fibers and contaminants is fed
tangentially into the top of a centrifugal cleaner having bottom
and top outlets, thereby creating a vortex in the cleaner. The
outer part of the vortex moves downwardly and most of the inner
part of the vortex moves upwardly. Large percentages of
contaminants are thrown into the inner part of the vortex and
exhausted from the top of the cleaner, while most of the fibers and
small percentages of the contaminants move to the outer part of the
vortex and are exhausted through the bottom outlet.
Inventors: |
Braun; Harry J. (Neenah,
WI) |
Assignee: |
Bergstrom Paper Company
(Neenah, WI)
|
Family
ID: |
26796546 |
Appl.
No.: |
05/099,850 |
Filed: |
December 21, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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830395 |
Jun 4, 1969 |
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Current U.S.
Class: |
162/4; 162/55;
209/727; 210/512.1 |
Current CPC
Class: |
D21D
5/18 (20130101); D21B 1/325 (20130101); Y02W
30/64 (20150501) |
Current International
Class: |
D21D
5/00 (20060101); D21D 5/18 (20060101); D21B
1/32 (20060101); D21B 1/00 (20060101); B04C
003/06 (); B01D 003/00 () |
Field of
Search: |
;162/4-8,55 ;209/211
;210/512R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lindsay, Jr.; Robert L.
Parent Case Text
RELATED APPLICATION
This application is a continuation-in-part of application Ser. No.
830,395 filed June 4, 1969 now abandoned by Harry J. Braun for
REVERSE CLEANING AND DE-INKING OF RECLAIMED PAPER STOCK.
Claims
I claim:
1. In the recovery of paper fibers for reuse from waste paper
material, the process of separating the reusable paper fibers from
certain contaminants, a first type of which have specific gravities
lower than that of water, and a second type including ink peppers,
clays, pigment and fillers, which have specific gravities
substantially greater than that of water but which, because of
size, shape or size and shape, have a high hydraulic drag
coefficient, which comprises;
a. supplying said slurry to a closed cylindricalconical vessel
having a tangentially arranged inlet port adjacent the base thereof
and having an outlet port in the base thereof and an outlet port in
the apex thereof,
b. maintaining the slurry flow through the vessel at a
substantially higher rate than that which is normal for the vessel
operating in normal fashion at nominal capacity, which normal rate
is determined by the equation
Q .apprxeq. 0.741 d.sub.c.sup.3
where
Q = through flow in gpm
D.sub.c = diameter of cone base in inches
while maintaining in said outlet ports a flow relation wherein the
flow through the apical outlet port is at least as great as the
flow through the base outlet port to develope centrifugal force
conditions causing vortical separation of said slurry with
increased concentration of fibers in an outer fraction of the
vortex which moves towards the apical outlet thereby increasing in
an inner fraction of the vortex which moves towards the base outlet
the ratio of the second type of contaminants to fiber above that
which prevails with normal through flow and while increasing in
said inner fraction the concentration of the first type of
contaminants above that which prevails with normal through flow
c. exhausting through the base outlet the contents of the inner
fraction consisting essentially of water, said contaminants and a
minor portion of said fibers, and
d. exhausting through the apical outlet the contents of the outer
fraction consisting essentially of water, the great predominance of
said fibers, and a minor portion of said contaminants.
2. The process recited in claim 1, wherein the through flow rate
through the vessel is maintained at about one and one-half times
the rate which is normal for the vessel.
3. The process recited in claim 1 wherein the specific gravities of
the second type of contaminants range from about two to four times
that of water.
Description
FIELD OF INVENTION
Classifying, Separating And Assorting Solids; Grading Deposition,
Vortical.
PATENT BACKGROUND
Fontein U.S. Pat. Nos. 2,550,341 and 2,649,963; Hirsh U.S. Pat. No.
2,975,896; Grundelius U.S. Pat. No. 3,486,619.
SUMMARY OF THE INVENTION
The invention is directed to a method of liberating an aqueous
fibrous suspension from shives and/or other undesirable particles
which, due to shape and density or shape, density and size, are
difficult to separate. The other undesirable particles are regarded
as lightweight particles since they normally appear with the
desired fibers when these fibers are removed from a centricleaner
as the light fraction, as opposed to the heavier rejects.
The method comprises feeding the suspension to a cyclone separator
(centricleaner) having two outlets for separating the suspension
into a first fraction containing a preponderance of shives and/or
other undesirable lightweight particles and a minimum of acceptable
fibers and a second fraction containing a preponderance of
acceptable fibers and a minimum of shives and other undesirable
lightweight particles. Of the two outlets, one is a light fraction
outlet and the other is a heavy fraction outlet, the preponderance
of acceptable fibers (second fraction) being discharged through the
heavy fraction outlet and the preponderance of undesirable
lightweight particles (first fraction) being discharged through the
light fraction outlet.
Relative flow conditions are maintained in the outlets so that the
suspension separates into the first and second fractions while
maintaining a through-flow volume ranging from one which is
substantially normal for the separator to one which is materially
greater.
OBJECTS
In the field of papermaking, wastepapers constitute a valuable
source of fibers, provided they can be decontaminated or de-inked.
Up until comparatively recent times, the contaminants, which
consisted largely of carbon black inks and clay and pigment
fillers, could be removed reasonably well by conventional methods
of defibering, solvating, washing, screening and other cleaning
processes, including conventional centrifugal cleaning. The
specific gravities of many of the contaminants ranged from about
2.5 to 8.0, and the specific gravities of the fibers ranged from
about 0.9 to 1.4.
Centrifugal cleaning, as heretofore practiced, was reasonably
successful for removing various particulate contaminants which lent
themselves, because of their specific gravity, to rejection as
so-called "heavies". Examples of useful types of centrifugal
cleaners, so-called "cyclone separators", are those various sized
devices manufactured by Bauer Brothers, Bird Machinery Company,
Nichols Engineering, and others, and which consisted essentially in
a cylindrical and/or cone shape vessel having a tangential inlet at
the top, and axial outlet at the top and bottom. A slurry, of about
0.5 percent consistency, was fed in under pressure through the
inlet to form a vortex, having an outer, downwardly spiraling
portion (hereafter called "outer vortex") and an inner upwardly
spiraling portion (hereinafter called "inner vortex"). Generally
speaking, the heavy particles, i.e., those with radially outward
settling velocities substantially greater than the radially outward
settling velocities of fibers and "light" contaminants moved to the
outer vortex and exhausted, as "rejects", through the bottom
outlet; and the fibers, having radially outward settling velocities
less than the radially outward settling velocities of the heavy
contaminants were carried to the inner vortex and were exhausted as
" accepts" through the top outlet.
While specific gravity is an important factor in centrifugal
separation, other factors which militated against normal separation
by centrifugation, as previously practiced, come into play. It was
known that particle size and shape, and the effect of hydraulic
drag thereon are significant. In conventional centrifugal cleaner
operation, fibers failed to migrate to the outer vortex, apparently
because the hydraulic drag coefficient thereof results in a
negligible settling velocity. Unfortunately, a substantial amount
of high density contaminants such as clay or pigment filler which
would have been expected to go to the outer vortex also went to the
inner vortex and out through the upper accept outlet despite their
specific gravity being generally greater than the medium,
apparently because of their size and shape which affects the
hydraulic drag coefficient. So also with what is known as "ink
pepper", i.e., extremely small particles of ink which had escaped
preceding washing and screening processes.
Difficult as these problems were when conventional centrifugal
separation was practiced, they became intolerable with the advent
of a new class of contaminants, i.e., materials of plastic,
polymeric, adhesive, rubbery, asphaltic or synthetic nature, now
used in coating, printing, laminating and binding. Papers having
one or more of these contaminants find their way into the
wastepaper markets, and, since their specific gravities are
generally close to and less than that of water, they, too, tend to
migrate to the inner vortex of a conventionally operated
centrifugal cleaner and are exhausted through the upper outlet
along with the fiber accepts.
The object now is to provide a centrifugal separation process for
de-inking and otherwise de-contaminating reclaimed paper stock,
wherein the former centrifugal process is completely reversed,
wherein the accept material, consisting predominantly of water and
fiber, is taken off from the outer vortex and discharged through
the heavy fraction bottom outlet of a centrifugal cleaner, and the
reject material, consisting predominantly of water and contaminants
of both heavy and light varieties, are taken from the inner vortex
and out from the top of the cleaner. Among the contaminants so
taken off from the inner vortex and discharged through the light
fraction top outlet are ink pepper, clays and pigment fillers,
fiber fines, and other minute solids, in aggregate, those which
have densities greater than that of water, but which, because of
size, shape or size and shape, are retained in the inner vortex,
and also among the contaminants which are taken off via the top
outlet are those of plastic, polymeric, adhesive, rubber, asphaltic
or synthetic nature, in aggregate, those which have densities less
than the density of water, and shives, whose densities are about
the same as the desired fibers, but whose shapes are generally more
extensive in one or more dimension than those of fiber.
These and other objects will be apparent from the following
specification and drawing, in which the sole FIGURE is a
diagrammatic representation of a typical centrifugal cleaner
reversely operated according to the subject process.
Referring now to the drawing, which diagrammatically illustrates a
typical centrifugal cleaner 2, which, for specific example, may be
a standard Bauer Brothers 3-inch type with a conical side wall 4, a
bottom nozzle 6, a top nozzle 8, a closed top 9, and a tangential
inlet pipe 10 adjacent the top. In a cleaner of given size, the
relative diameters of the top and bottom nozzles determine the flow
splits, and, in part, the solids splits, which are critical to the
improved results of the subject process, as will be discussed
later.
In describing both the new "reverse" method and the old "normal"
method, it will be understood that at this stage of the de-inking
and decontaminating process, the stock has been defibered and
solvated, washed, screened or otherwise de-inked by conventional
methods, but that it is still contaminated with one or more of a
variety of contaminants of greater density than water, such as clay
or pigment, ink pepper, and contaminants of lesser density than
water, such as adhesive, plastic, etc., materials. However, at any
given time of an operation of the centricleaner, the contaminants
may tend to consist of one variety, while at another time they may
tend to consist of the other variety.
As the stock enters the top of vessel 4, an outer
downwardly-spiraling portion OV of the vortex is formed, and the
liquid and solids therein are exhausted out bottom nozzle 6. Within
the outer portion of the vortex, an inner, upwardly spiraling
portion IV of the vortex forms, and the liquid and solids therein
are exhausted out the top nozzle 8. As previously normally
operated, the liquid and solids exhausted via bottom nozzle 6 were
the rejects, i.e., water and some of the heavy contaminants, and
the liquid and solids exhausted out the top nozzle 8 were the
accepts, i.e., water and fibers, but also the light contaminants,
and some of the contaminants having densities greater than water
which were present because of small size or shape and attendant
large hydraulic drag coefficients. Because no separation is
perfect, some fibers also went out the bottom nozzle 6 with the
rejects.
The stock input through input pipe 10 should have a consistency of
about 0.50 percent, consisting of water, fibers and contaminants,
although the consistency may range from 0.10 to 1.50 percent. The
most desired pressure of the stock fed to the cleaner according to
the present process should be about 90 lbs. psig, but may range
from 40 lbs. to 100 lbs., and preferably without back pressure. The
input pressure of feed stock into the cleaner may thus range from
that which is about normal for the separator to that which is
considerably greater than normal; and, hence, the through flow may
range from that which is about normal to that which is considerably
greater than normal. Separation improves with increase in pressure,
but in decreasing degree towards the higher end of the range, with
diminishing return due to higher costs of pumping at the higher
pressures.
The specific data for the necessary effective area and/or pressure
relations can be easily determined for each type of separator with
which the method of the invention is to be carried out as the
calculation necessary for the purpose are well known to men skilled
in the art. It is common practice to regulate the concentrations of
the fractions obtained from cyclone separators by varying the area
and/or pressure relations at the outlets as is described, for
instance, in U.S. Pat. Nos. 2,550,341 and 2,649,963.
Among the unexpected results of the subject process wherein the
fiber solids are exhausted with the underflow and the contaminants
are exhausted with the overflow is that the temperature seems to
make little appreciable difference in the fiber solids splits.
However, when the fiber solids were exhausted with the overflow,
significantly more fiber solids were rejected in the underflow with
increase in water temperature. This was apparently due to decrease
of water viscosity as it increased in temperature, with resultant
decrease in hydraulic drag on the fiber solids, thereby permitting
them to migrate towards the cleaner wall in the outer vortex so
that more fibers were exhausted with the underflow rejects. The
significant implication of temperature effects, however, is that
the subject process is less temperature-sensitive than was the
conventional operation of the cleaner.
The following is a compilation of two runs, denoting in the column
entitled "Reverse" the cleaning operation of the subject process,
and in the column entitled "Normal" a cleaning operation according
to prior art practices. Both runs were made with the same
conventional 3-inch Bauer Brothers centrifugal cleaner, with the
slurries at approximately the same room temperature, i.e.,
unheated. In both runs, the cleaner had a five-eighths inch
overflow nozzle. In the Normal run the cleaner had a one-eighth
inch underflow nozzle, whereas in the Reverse run the cleaner had a
one-half inch underflow nozzle. "Total Solids" means fiber and ash.
"Ash Solids" means those solids, primarily clay and pigment, which
remained after placing a sample of Total Solids in a muffle furnace
and burning off all or substantially all the organic matter,
including the fibers. Unrepresented in these figures was a small
quantity of red rubbery natural latex adhesive which was added to
the feed stock in both runs. This adhesive was prepared for these
tests as follows: a sandwich of adhesive between two sheets of
fiber, as commonly found in flying splices, was fed to a
hydropulper and reduced to size representative of mill operation.
This sandwiched adhesive was selected as representative of a light
contaminant which normally has been particularly difficult to
separate from fibers, and because of its easy identification in
hand sheets made from the solids in the overflow and underflow
exhausts. Its specific gravity is about 0.9 to 1.1, as compared
with from about 0.9 to 1.4 fibers. In the Reverse run, about 99
percent of the adhesive was exhausted with the overflow reject,
whereas in the Normal run about 99 percent of the adhesive was
exhausted with the overflow accept.
In production runs, many contaminants have been identified in hand
sheets made from the solids content of the overflow. These vary
according to the make-up of the feed stock, and include rubbery
adhesive particles of various colors, plastic film ranging from
clear to various deep shades, strings from re-inforcing tape, large
ink balls, finely divided ink pepper, chips of various sizes and
colors, wood shives, fluorescence coating chips and plastic, and
other extraneous material. The sizes of the contaminants ranged
from 0.03 sq. mm (TAPPI Standard T-213m and T-347m) upward for the
rubbery or adhesive contaminants to 1 inch .times. 1 inch for
plastic films, and varied in specific gravity from somewhat less
than that of the fibers in the feed stock to somewhat greater than
that of the fibers. Some, such as the shives, were of about the
same specific gravity as the desired fibers.
______________________________________ NORMAL REVERSE Feed Total
Gallons 846 1189 Total Soliids 33.69 50.80 Ash % 18.64 20.40 Ash
Solids Lbs. 6.28 10.20 Flow G.P.M. 21.84 33.5 Consistency % 0.481
0.512 Underflow total Gallons 29.0 611 Total Solids 4.67 42.70 Ash
% 10.9 13.2 Ash Solids Lbs. 0.51 5.64 Flow G.P.M. 0.745 17.2
Consistency % 1.929 0.838 Overflow Total Gallons 817 578 Total
Solids 29.02 8.10 Ash % 19.9 56.3 Ash Solids Lbs 5.77 4.56 Flow
Gg.P.M. 20.9 16.3 Consistency % 0.426 0.168 Flow Split Underflow %
3.43 51.39 Overflow % 96.57 48.61 Solids Split Underflow % 13.86
84.05 Overflow % 86.14 15.95 Ash Split Underflow % 8.12 55.29
Overflow % 91.88 44.71 Fiber Split Underflow % 15.18 (Reject) 91.51
(Accept Overflow % 84.82 (Accept 8.49 (Reject) Psig Lbs. Inlet 45
90 Overflow Nozzle 5/8" 5/8" Underflow Nozzle 1/8" 1/2"
______________________________________
In addition to the almost total rejection of the light contaminant
trace, the rejection of 44.71 percent of the ash by the Reverse
process, as contrasted with rejection of 8.12 percent of the ash by
the Normal process is significant. Also significant is the
underflow acceptance of 91.51 percent of the fibers in the Reverse
process, as compared with the overflow acceptance of only 84.82
percent of the fibers in the normal process.
As to the explanation of why the contaminants, with densities
greater than that of water, such as clay and pigment and ink
pepper, with specific gravities of about 2.6, 3.0 and 2.0,
respectively, are found in the overflow, it is believed that they,
because of their extremely minute particle size and possibly their
platelet shape, and their concommitment much higher coefficients of
hydraulic drag, as compared with the fibers, therefore hold back in
greater degree than do the fibers from their natural tendency to
migrate to the outer portion of the vortex.
In the foregoing examples, the "Flow G.P.M. 21.84" and "Psig Lbs.
Inlet 45" approximate the normal (20 gpm and 40 Psig Lbs. Inlet)
through-flow and inlet pressure recommended by the manufacturer for
the 3-inch cleaner to obtain optimal separation results, and from
which derives the following formula for determining normal
through-flow for different-size centricleaners operating in normal
mode and at the same efficiencies:
Q .apprxeq. 0.741 d.sub.c.sup.3 where
Q = through flow in gpm, and
D.sub.c = diameter of cone base in inches
The above process results in marked improvement in the separation
of contaminants from fiber solids, recognizing that there still
remains some undesirable overlap of contaminants in the fiber
exhausted from one end of the cleaner, and of fiber in the
contaminants exhausted from the other end of the cleaner.
As to the contaminants which because of their size, shape and
specific gravity, exhibit normal behavior and therefore are
exhausted through the bottom outlet with the fibers, these are
subsequently separated from the fibers by passing them and the
fibers through a cleaner which is normally operated according to
prior practices.
* * * * *