U.S. patent number 3,910,798 [Application Number 05/296,138] was granted by the patent office on 1975-10-07 for moulding process.
This patent grant is currently assigned to Imperial Chemical Industries Limited. Invention is credited to Michael John Shires, John Edwin White.
United States Patent |
3,910,798 |
Shires , et al. |
October 7, 1975 |
Moulding process
Abstract
A process for the manufacture of an investment casting mold
which comprises coating an expendable pattern in a thixotropic dip
slurry, drying the coating, removing the pattern and firing the
mold.
Inventors: |
Shires; Michael John (Reading,
EN), White; John Edwin (Reading, EN) |
Assignee: |
Imperial Chemical Industries
Limited (London, EN)
|
Family
ID: |
10449100 |
Appl.
No.: |
05/296,138 |
Filed: |
October 10, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Oct 19, 1971 [GB] |
|
|
48575/71 |
|
Current U.S.
Class: |
106/38.3;
106/38.9; 106/38.35; 164/37 |
Current CPC
Class: |
B22C
1/183 (20130101); B22C 1/165 (20130101) |
Current International
Class: |
B22C
1/18 (20060101); B22C 1/16 (20060101); B28B
007/34 () |
Field of
Search: |
;106/38.3,38.35,38.22,38.23,38.24,38.27,38.9 ;164/37 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Hayes; Lorenzo B.
Attorney, Agent or Firm: Cushman, Darby & Cushman
Claims
What we claim is:
1. In a process for the manufacture of an investment casting mould
which comprises the steps of coating an expendable pattern by
immersion in a fluid mixture comprising a refractory material, a
binder, and a liquid dispersant; drying the coating; removing the
pattern and firing the mold; the improvement comprising adding to
said mixture a thickening agent in an amount sufficient to render
the mixture thixotropic, and requiring a shear stress of at least
1000 dynes/cm.sup.2 to break its structure from a solid to
liquid.
2. A process according to claim 1 in which the thixotropic mixture
requires a shear stress of at least 3000 dynes/cm.sup.2 to break
its structure from a solid to liquid.
3. A process according to any of claim 1, in which the thixotropic
mixture is subjected to shear conditions at least in the region of
the pattern for a least a portion of the time for which the pattern
is immersed in the mixture.
4. A process according to claim 3 in which the mixture is subjected
to shear such that its viscosity in the immediate vicinity of the
pattern is within the range 10-25 poises.
5. A process as claimed in claim 1 wherein the pattern is coated
with a primer coating before application of the thixotropic
mixture.
6. A process as claimed in claim 1 wherein a single coating of the
thixotropic mixture is applied.
7. A process as claimed in claim 1 wherein the thixotropic mixture
contains a treated clay as thickening agent.
8. A process as claimed in claim 7 wherein the treated clay is a
modified magnesium silicate clay.
9. A process as claimed in claim 1 wherein the thixotropic mixture
contains 0.1 to 10% by weight of the thickening agent.
10. An investment casting mould produced by the process as claimed
in claim 1.
Description
This invention relates to a process and composition for the
production of investment casting moulds.
In the known process of investment casting a shell is built up
around an expendable pattern by dipping the pattern into a slurry
of a binder and a refractory material and drying the resulting
adherent coating. This operation is repeated a number of times
until a shell of desired thickness is formed on the pattern.
Generally there are at least five dips, usually with the
application of intermediate coats of refractory powder between each
dip. The expendable pattern is subsequently removed and the mould
fired before use.
We have now found that by using a thixotropic slurry the moulds can
be formed with a reduced number of processing steps.
Accordingly, the present invention provides a process for the
manufacture of an investment casting mould comprising the step of
coating a pattern with a thixotropic mixture comprising a
refractory material, a binder, a liquid dispersant for the binders
and a thickening agent which renders the mixture thixotropic.
A thixotropic mixture, of course, is a mixture whose viscosity is
reduced when the mixture is subjected to shear conditions but which
returns to substantially its original value after the shear
conditions are removed. In the process of the invention therefore,
it is necessary to subject the mixture to shear conditions, at
least in the region of the pattern for at least a portion of the
time during which the pattern is immersed in the mixture. It is
also important that the rate at which the thixotropic mixture
sets-up or regains its non-fluid condition after shearing is
sufficiently rapid that after removal of the pattern from the
mixture excessive flow-off of the mixture from the pattern does not
occur.
We have found that it is convenient to employ a thixotropic mixture
of such a consistency that a shear stress of at least 1000,
preferably at least 3000 and more preferably at least 5000
dynes/cm.sup.2 (as measured on a Contraves Rheomat-15 rheometer
fitted with a D cup and bob) is required to break the structure of
the material from a solid to a liquid. The upper limit obviously
will be fixed by the necessity of the material to be useful as
described.
Shearing of the mixture may be effected by agitating the mixture
directly, for example, by stirring the mixture or vibrating the
vessel containing the mixture, and/or by moving the pattern within
the mixture. Thus, for example, the pattern may be oscillated
within the mixture; if desired, such movement of the pattern may be
continued whilst the pattern is being withdrawn from the mixture,
so that the oscillatory motion is superimposed on the withdrawing
motion. It will be apparent that movement of the pattern during
withdrawal from the mixture should not be so violent that the
adhering mixture is displaced; preferably such displacement is
avoided by careful removal of the pattern from the mixture. The
frequency of vibration of the thixotropic mixture is not critical;
the degree of agitation required in any particular case will depend
upon the viscosity and degree of thixotropy of the mixture and the
complexity of the pattern. Agitation such that the viscosity of the
mixture in the immediate vicinity of the pattern is of the order of
10-25 poises, preferably about 15-20 poises is usually
adequate.
It is particularly important that the thixotropic mixture be
subjected to these conditions if the pattern is of a complex shape
and/or the mixture is highly thixotropic since accurate
reproduction of the finer details in the pattern is thereby
facilitated.
It is usually desirable before applying the thixotropic mixture, to
invest the pattern first with a primer coating of comparatively low
viscosity, for example a conventional primer containing a
refractory, binder and a dispersing liquid. The purpose of such
coatings is inter alia the provision of a fine grain lining layer
to the mould. To this end the primer coat often contains a
particularly finely divided refractory which may be of chemically
resistant material since it is this layer in particular which must
withstand the chemical degradative effects of contact of molten
metal with the mould.
Subsequent coat(s) of the mould are derived from the thixotropic
mix according to the invention and suitable refractory materials
for use therein include silica; alumina, e.g. tabular alumina and
bauxite; magnesium, calcium and titanium oxides; zinc and tin
oxides; magnesite; mag-chrome grog, zirconium silicate; zirconia;
zircon; aluminium silicates, e.g. sillimanite, and alusite,
kyanite, mullite and molochite; porcelain and china clays;
carbides, e.g., silicon and tungsten carbide; nitrides, e.g.,
silicon and boron nitride; boron; asbestos; ferric oxide; chromium
oxide; chromite; mica; aluminium phosphate and mixtures
thereof.
Generally the refractory material is in the form of a powder. It is
preferred to use a refractory powder at least 50% by weight of
which has particle size of less than 0.15mm.
A wide variety of binders may be used, although the binder chosen
should be one which will set satisfactorily in a thick layer. We
have found that air-drying binders (which do not form an
impermeable skin on curing) are very effective; if desired, a
mixture of two or more compatible binders may be used. Examples of
suitable binders include silicates, e.g., alkyl silicates, such as
ethyl or isopropyl silicate, alkali metal silicates such as sodium
and/or potassium silicate, silica sols, aluminium oxychloride,
aluminium phosphate, gypsum/silica mixes and cements such as
aluminous or Portland cement.
The liquid dispersant for the binder is preferably a solvent for
the binder. The choice of a solvent clearly depends on the type of
binder to be used; examples of solvents which may be used include
polar solvents, for example, water; mineral acids; alcohols, e.g.,
aliphatic alcohols, especially methanol, ethanol, isopropanol and
butanol; glycols and glycol ethers, e.g. ethylene glycol, monoethyl
ether. Mixtures of two or more solvents may be used. In practice
the commercially available binder is commonly in the form of a
solution or suspension and the solvent of this solution may be
sufficient to form the thioxtropic mixture without the addition of
further solvent.
The thickening agent can be any which will give a thixotropic
mixture of the desired properties. Suitable thickening agents
include fumed silica, for example the fumed silica available in
commerce under the trade name Cab-o-Sil, treated clays, for example
highly beneficiated hydrous magnesium silicate, for example that
sold under the trade name Ben-a-gel and Benaqua and the organically
modified magnesium silicate clays, for example those sold under the
trade name Bentone of which the grades LT; 18C; 34;38 and 27 are
particularly suitable.
In some cases we have found it advantageous to include a small
amount of a dispersing agent, for example diethanolamine or the
thixotropic mixture.
The relative proportions of the components of the thixotropic
mixture can vary over a wide range. Suitable percentages by weight
of the components in the mixture may be as follows:
Refractory material 10-90% preferably 50-80% Binder (dry solids
1-15% preferably 5-15% content) Dispersant 5-50% preferably 10-30%
Thickening agent 0.1-10% preferably 0.5-5% Dispersing agent 0.1-5%
preferably 0.5 to 2% (optional)
As noted above, binders are commonly marketed in solution form and
it may therefore be unnecessary to add separate solvent as
dispersant.
The green mould may be dried before firing in a stream of air or by
heating at a moderate temperature, for example up to 50.degree.C.
Since a thick shell is generally formed in only one or two
operations, it is usually desirable to dry slowly, e.g., for 4
hours to 3 days, at temperatures of 10.degree. to 30.degree.C.
If an expendable pattern of sufficiently low melting point, is used
it may be drained in its molten state from the mould when this is
quite hard. Removal of the pattern may be also achieved by shock
heating the mould, e.g., to a temperature of at least 750.degree.C
preferably 900.degree. to 1200.degree.C. (Such heating may be
continued to cure the mould). Alternatively the mould may be
treated with steam, preferably dry steam, at above atmospheric
pressure, e.g., from 2 to 10 atmospheres and then fired. Firing of
the mould is continued until it is quite hard- usually 5-60 minutes
at about 1000.degree.C.
The invention is illustrated in the following examples in which
percentages are by weight. In the examples, ACPE refers to the
complex aluminium phosphate of formula AlPClC.sub.8 H.sub.25
O.sub.8 obtained by the procedure of Example 1 of UK Application
No. 29862/69 (Dutch Application No. 7008594).
EXAMPLE 1
The following mixture was formulated: ACPE 6.2 gm. Water 35 ml.
Molochite, having an average particle size 100 gm. less than
0.044mm Bentone LT 1.5 gm. Teepol 0.1 ml. Octanol 0.3 ml.
A similar mixture as formulated with the Bentone omitted, as a
primer dip.
A wax pattern was dipped in the primer dip, a stucco coat of
Molochite 60 mesh was then applied and the coating allowed to dry.
The coated pattern was then dipped in the first mixture which was
vibrated at 200 cycles/sec., by applying an oscilator to the base
of the vessel in which the mixture was placed.
The pattern was withdrawn coated with a shell having a thickness of
0.5 cm, which was allowed to dry at 30.degree.C for 4 hours. The
wax pattern was then removed by dewaxing in trichloroethylene
vapour. The resulting green mould was then sufficiently strong to
be handled and fired at 800.degree.C.
EXAMPLE 2
Example 1 was repeated using the following mixture for the
coating:
ACPE 3.1 gm Ethyl Silicate solution in isopropanol contain- 3.2 gm.
ing 25% solids based on SiO.sub.2 Water 0.8 ml. Isopropanol 41.5
ml. Molochite having an average particle size 100 gm. less than
0.044 mm Bentone 27 3 gm. Toluene 9 gm. Teepol 0.1 ml.
A primer dip consisting of the aforementioned mixture minus Bentone
27 and toluene was applied in Example 1.
The wax pattern was removed by flash dewaxing at 1000.degree.C for
about 30 seconds. The resulting mould was strong and suitable for
casting after firing.
EXAMPLE 3-7
The following mixtures were formulated:
Silica sol N 1030 1 litre (Ex-Nalfloc) Molochite 120 (Ex-English
China 2000 gm. Clays) Benagel EW 30 gm. Water 200 ml. Lissapol NDB
20 ml. Octanol 40 ml.
EXAMPLE 4
The composition as Example 3 was prepared except that the Molochite
used was Molochite 200.
EXAMPLE 5
The composition of Example 3 was prepared except that Benaqua was
used instead of Benagel.
EXAMPLE 6
The composition was as Example 1, with the addition of 35 ml. of
diethanolamine.
EXAMPLE 7
A composition was formulated as follows:
ACPE (80 w/w aqueous 100 ml solution) Water 500 ml Benagel EW 40 gm
Octanol 20 ml Molochite 120 1000 gm Lissapol NDB 10 ml
The above compositions 3 to 7, were used in a similar manner to
those of Examples 1 and 2, after an initial coating of a primer
coat to the pattern.
Extra thick moulds were obtained by employing a second immersion in
the thixotropic mix to build up the coating.
In preparing the compositions it is usual to mix all the
inepedients and then to subject the mixture to high shear stirring
for, say, 5 minutes or low shear stirring for, say 20 minutes until
a smooth creamy consistence is attained. These slurries we have
found are usually immediately usable in the process of the
invention, although their full non-sheared consistency was not
reached until about 12 hours after mixing.
* * * * *