U.S. patent number 3,910,194 [Application Number 05/354,414] was granted by the patent office on 1975-10-07 for projectile rotating band.
This patent grant is currently assigned to Hercules Incorporated. Invention is credited to Henry C. Dehm, Burton E. Tew, Jr..
United States Patent |
3,910,194 |
Dehm , et al. |
October 7, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Projectile rotating band
Abstract
A plastic rotating band for a projectile. More particularly,
this invention relates to a projectile having a plastic rotating
band chemically bonded to the projectile.
Inventors: |
Dehm; Henry C. (Salt Lake City,
UT), Tew, Jr.; Burton E. (Salt Lake City, UT) |
Assignee: |
Hercules Incorporated
(Wilmington, DE)
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Family
ID: |
26808881 |
Appl.
No.: |
05/354,414 |
Filed: |
April 25, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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111415 |
Feb 1, 1971 |
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Current U.S.
Class: |
102/527 |
Current CPC
Class: |
F42B
14/02 (20130101) |
Current International
Class: |
F42B
14/02 (20060101); F42B 14/00 (20060101); F42B
031/00 () |
Field of
Search: |
;102/93,94,56 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Stahl; Robert F.
Attorney, Agent or Firm: Keehan; Michael B.
Parent Case Text
This is a continuation of application Ser. No. 111,415, filed Feb.
1, 1971, now abandoned.
Claims
What we claim and desire to protect by Letters Patent is:
1. A metal projectile having a high density polyethylene rotating
band secured to the surface of the metal projectile, the
intersection of the surface of the metal projectile and the
polyethylene rotating band defining an interface, said polyethylene
rotating band being secured to the metal projectile solely by a
chemical bond formed between the metal projectile and a primer and
between the primer and polyethylene rotating band at the metal
projectile-rotating band interface, said primer being prepared from
a solution comprising ethylene-acrylic acid copolymer, said
chemical bond having a strength such that the chemically bonded
polyethylene rotating band when tested to failure in tension or in
shear fails in the polyethylene rotating band rather than at the
metal projectile-rotating band interface.
2. A metal projectile having a polypropylene rotating band secured
to the surface of the metal projectile, the intersection of the
surface of the metal projectile and the polypropylene rotating band
defining an interface, said polypropylene rotating band being
secured to the metal projectile solely by a chemical bond formed
between the metal projectile and a primer and between the primer
and polypropylene at the metal projectile-rotating band interface,
said primer being prepared from a solution of a maleic anhydride
modified polymer of propylene prepared by chemically combining
solid propylene polymers with from about 0.05% to about 5% by
weight of maleic anhydride, said chemical bond having a strength
such that the chemically bonded polypropylene rotating band when
tested to failure in tension or in shear fails in the
prolypropylene rotating band rather than at the metal
projectile-rotating band interface.
Description
A rotating band is a ring of material secured to the surface of a
projectile. The exterior surface of the rotating band engages the
rifling of a gun during a firing and is engraved, thereby imparting
spin to the projectile.
Plastic rotating bands have heretofore been employed with
projectiles. Plastic rotating bands have not been universally
accepted as replacements for metal rotating bands because of
several problems associated with the use of such plastic bands. One
principal problem encountered with the plastic rotating band has
been the difficulty of maintaining the band secured to the
projectile either in firing or during flight. Many different
technical approaches have been tried to overcome this
difficulty.
With the advent of advanced, high muzzle velocity gun systems, the
necessity for improved rotating bands has become apparent. We have
now discovered that plastic rotating bands chemically bonded to a
projectile surface can withstand the complex stresses imposed on
the band in the gun during firing and in-flight. Chemical bonding
of the plastic rotating band permits use of plastic materials
having greatly reduced strength properties as rotating bands as
compared to the strength requirements for non-chemically bonded
rotating bands. Chemical bonding of plastic rotating bands to a
projectile makes possible simple projectile design and reduction or
elimination of the band seat resulting in an increased payload. A
further advantage of a plastic rotating band is that it reduces
barrel wear in the gun system.
The term "chemically bonded" used in this specification with
reference to a plastic rotating band bonded to a projectile is
defined herein to mean that the plastic bonded to a metal when
tested to failure in tension or in shear, fails in the plastic and
not at the metal-plastic interface. A simple method to evaluate
chemical bonding is to prepare a metal-plastic-metal sample such as
a metal-plastic-metal sandwich employing the same metals, plastics,
primers and procedures that are to be employed in bonding the
plastic to a projectile. After the sample has been prepared it can
be tested to failure on an Instron Testing Machine following ASTM
or modified ASTM procedures. If, in conducting these tests, the
sample fails at the metal-plastic interface, then a chemical bond,
as defined herein, has not been achieved. ASTM Tests D638-61T,
D732-46 and D1002 can be used to evaluate chemical bonding, as
defined herein, using appropriately prepared test samples.
There are numerous plastics which can be chemically bonded to
metals and employed as a chemically bonded rotating band within the
scope of this invention. Projectiles can be prepared from any metal
suitable for use in the gun system in which the projectile is being
employed. The particular plastic chosen for use as a rotating band
must, of course, be evaluated based on the overall gun system
requirements. The chief properties of the plastic material which
must be evaluated in addition to those previously defined are
bearing strength, slip properties, dimensional stability,
ductility, linear coefficient of expansion, abrasion resistance and
hardness. The plastic must have a combination of properties
permitting the plastic to engrave and obturate the projectile under
actual use conditions. Another factor to be considered in choosing
a plastic material for a rotating band for a projectile is the type
of ammunition round being manufactured. For example, plastic
rotating bands for caseless ammunition which are close to or in
direct contact with the propellant charge of the caseless round
must not absorb propellant ingredients to any significant extent
such that a change in properties of either the plastic rotating
band or propellant charge results. Cased rounds wound not
necessarily be subject to these same limitations. Also, it is
absolutely necessary that the plastic rotating band be chemically
compatible with the composition of the propellant charge.
The strength of the plastic rotating band of this invention must be
sufficient to withstand the loads imposed on the band without
breaking as the projectile passes through the gun barrel wherein
the rotating band becomes engraved in the riflings of the gun and
imparts the stabilizing spin to the projectile leaving the gun
muzzle. Plastic materials must also have sufficient tensile
strength to prevent the band from breaking in-flight.
Plastic materials which can be chemically bonded to the surface of
a projectile include both thermoplastic and thermosetting polymers.
Thermoplastic materials are preferred. Thermosetting resins which
are not highly crosslinked can be employed. Highly crosslinked
thermosetting resins have insufficient ductility to engrave and
obturate the projectile satisfactorily. The plastic material
employed as the rotating band of this invention, i.e.,
thermoplastic or thermosetting polymers, can contain fillers to
alter the properties of these plastics as necessary. A particularly
suitable filler material is fibrous glass. The plastic material can
also be foamed to alter the properties of the plastic materials.
The foamed structure can be filled with other ingredients such as
lubricants, useful in operation of the gun system.
Illustrative plastic materials which can be chemically bonded to
the surface of the projectile for use either in conventional
ammunition or caseless ammunition wherein the plastic band is in
contact with a propellant charge of the single, double or triple
base compositions include acetal resins, ethyl cellulose, epoxy
resins, polychlorotrifluoroethylene, fluorinated ethylenepropylene
resins, polyvinylidene fluoride, polyacrylonitrile, nylons;
polyolefins including, polyethylenes, polybutylenes, polypropylene,
polymethylpentenes, polyolefin copolymers such as those derived
from ethylene and propylene and the like; polyvinyl chloride,
polyvinylidene chloride, chlorinated polyvinyl chloride and
vulcanized fibers. For conventional ammunition or caseless
ammunition where the propellant charge is unplasticized
nitrocellulose, additional plastic materials which can be
chemically bonded to the projectile include polycarbonates,
polysulfones, modified polyphenylene oxide, styrene-acrylonitrile,
copolymers, acrylonitrile-butadiene-styrene terpolymers (ABS
resins), ABS modified polyvinyl chloride, ABS-polycarbonate alloys,
acrylic polymers, cellulose acetate, polyesters, and
polyvinylbutyral. The foregoing list of plastics is not all
inclusive of polymers which can be bonded to metals in preparing
the plastic rotating bands of this invention. For any particular
gun system plastics must be evaluated based on the plastic
evaluation criteria heretofore described for the conditions of
actual use.
The projectile of this invention having a plastic rotating band
chemically bonded to the surface can be prepared by several
methods. In any of the methods employed, the surface of the
projectile to which the rotating band is to be bonded, referred to
herein as the projectile band seat surface, is first cleaned very
carefully. The projectile band seat surface can be roughened such
as by sand blasting to aid in bonding of the plastic thereto. A
primer material is then applied to the clean projectile band seat
surface. The priming material employed varies with the particular
plastic material which is being used as the projectile rotating
band. The primed projectile is then heated to a temperature above
the melting point of the plastic which is to be applied. The
plastic is then applied to the hot projectile surface and fused.
The plastic coated projectile is then cooled. The heating step can
be repeated to alter the thickness of the projectile band. A
particularly suitable method for applying a plastic rotating band
to a projectile is injection molding. Other methods such as
spraying and fluidized bed methods can be employed. The plastic
rotating band can be preformed and chemically bonded to the
projectile, if desired. The chemically bonded plastic rotating band
can be machined, if necessary, to a desired configuration.
This invention is more fully illustrated in the drawings and the
examples which follow. In the drawings, like numbers are used for
like parts where applicable.
FIG. 1 is a side view of a projectile having no rotating band. FIG.
2 is a side view of a projectile partly broken away and in section
illustrating the projectile of FIG. 1 having a plastic rotating
band bonded thereto. FIG. 3 is an enlarged view illustrating the
rotating band configuration of the projectile of FIG. 2 before
firing. FIG. 4 is a side view of the projectile of FIG. 2 as it
appears after a firing. FIG. 5 illustrates another projectile
having a chemically bonded rotating band. FIG. 6 is an enlarged
view illustrating the configuration of the rotating band of FIG. 5
before firing. FIG. 7 is a side view of the projectile of FIG. 5 as
it appears after a firing. FIG. 8 illustrates another embodiment of
a chemically bonded plastic rotating band.
In FIG. 1 a projectile body 10 is shown having a rotating band seat
surface 12. The band seat depth 14 in the projectile necessitates
making the aft-end of the projectile of heavier guage steel to
withstand the forces on the projectile during firing resulting in a
decreased payload which can be carried within the envelope defined
by the exterior surface of the projectile body 10. The
configuration of a plastic rotating band 16 chemically bonded to
the rotating band seat surface 12 is shown in FIG. 2. The outermost
exterior surfaces of the rotating band referred to herein as the
rotating band ribs 18 engage the rifling in the gun in which the
projectile is fired. Groove 20, oftentimes referred to as a
cannelure, behind ribs 18 of the rotating band 16 provides space
for flow of plastic during engraving. The free volume envelope 22
aft of the forward surface of the projectile rotating band is shown
in FIG. 3 in dotted lines. FIG. 4 shows excellent engraving of the
plastic rotating band as it appears from in-flight photographs
taken from actual firings.
The projectile 23 shown in FIG. 5 has a greatly reduced band seat
depth 24 as compared to the band seat depth 14 for projectile 10
illustrated in FIGS. 1, 2 and 3. The volume shown by envelope 29
aft of the forward surface of the rotating band is the sum of the
free volume provided by the cannelures and the volume aft of the
rotating band to the aft-end of the projectile. FIG. 6 further
illustrates the band configuration of FIG. 5. The excellent
engraving of the plastic rotating band of FIG. 5 as actually seen
from high speed photographs is illustrated in FIG. 7.
FIG. 8 illustrates another embodiment of the projectile of this
invention having a plastic rotating band chemically bonded thereto.
In this embodiment, projectile 30 has no band seat whatsoever.
Plastic rotating band 32 is chemically bonded directly to the
projectile surface.
The following examples illustrate one method of preparation of the
projectile of this invention having a plastic rotating band
chemically bonded thereto, and firing results achieved with these
projectiles.
EXAMPLE 1
A 25 millimeter steel test projectile weighing 3206 grains is
sanded to remove rust and any other foreign material. After
standing, the projectile is degreased using a clean trichloroethane
dampened cloth. Surface preparation of the metal is completed by
immersing the projectile in a mixture comprising 3 parts of water
to 1 part of No. 11 deoxidizer compound which is of the phosphoric
acid type and is per MIL-M-10578B. The projectile is immersed in
the mixture for 5 minutes, is removed from the mixture, rinsed with
hot water and dried. Prior to priming of the projectile band seat
surface, the projectile is again degreased using a clean
trichloroethane dampened cloth. A primer is prepared by dissolving
an ethylene-acrylic acid copolymer, in hot xylene at 130.degree.C.
to form a 4% by weight solution of the copolymer. The
ethylene-acrylic acid copolymer employed contains 15% by weight of
acrylic acid, has a density of 0.949 grams/cc, a melt index of 50
per ASTM D-1238, a VICAT softening point of 63.degree.C., a DTA
softening point of 63.degree.C., a tensile strength of 2000 psi, an
ultimate elongation of 550% and a modulus of 8,800 psi. The priming
solution is held at 130.degree.C. at which temperature all of the
copolymer dissolves in xylene. The projectile which is at ambient
temperature is immersed in the primer solution for from about 2 to
about 3 seconds. The primer-wet projectile is then placed in an
oven at 150.degree.C. to remove xylene solvent. A high density
polyethylene having a molecular weight of between 300,000-600,000
is applied in the form of tiny pellets to the primed projectile
band seat surface. The projectile band seat surface extends for 1.0
inch along the exterior surface of the projectile. The tiny pellets
of the high molecular weight polyethylene adhere to the primed
metal surface and the projectile is placed in an oven at
150.degree.C. for about 10 minutes until the pellets are fused.
Additional polyethylene pellets are then added to fused pellets and
the projectile is returned to the 150.degree.C. oven until the
additional pellets are fused. This procedure is repeated until the
desired rotating band thickness is achieved. The projectile is then
removed from the oven and the entire projectile is quenched with
cold tap water. The plastic band is then machined to the
configuration illustrated in FIG. 2.
EXAMPLE 2
The projectile having the rotating band of high density
polyethylene prepared as described in Example 1 and having a
configuration as shown in FIG. 2 is fired in a 25 millimeter gun
having a uniform twist rifling, said rifling making an exit angle
of 8.degree. and 55 minutes with the barrel of the gun. The
projectile muzzle velocity is measured at 3360 feet per second.
High speed photographs are taken of the projectile in-flight.
Rifling marks are visible on the band and all data indicate that
the projectile was spinning properly. The photographs show that the
plastic bands engraved well and the bands were fully retained
in-flight. FIG. 4 is a drawing of the projectile in-flight as it
appears from high speed photographs.
EXAMPLE 3
Two 25 millimeter steel projectiles having the rotating band groove
depth of 0.026 and 0.052 inches, respectively, said grooves being
spaced 0.25 inches from the aft-end of the projectile are sanded to
remove rust and other foreign materials. After sanding, the
projectiles are degreased using a trichloroethane dampened cloth.
Surface preparation is completed by immersing the projectile in a
mixture comprising 3 parts of water and 1 part of No. 11 deoxidizer
compound of the phosphoric acid type per in MIL-M-10578B. The
projectile is maintained immersed within this solution for 5
minutes, is removed from the solution, rinsed with hot water, and
dried. The projectile is again degreased using a trichloroethane
dampened cloth. A priming solution is prepared by dissolving a
maleic anhydride modified polymer of propylene in xylene at
120.degree.C. to form a 2% by weight solution of the polymer. This
polymer of propylene is prepared by chemically combining solid
propylene polymers with from about 0.05 to about 5% by weight of
maleic anhydride. The projectiles are heated to 200.degree. C. and
are immersed in the priming solution for from about 2 to about 3
seconds and placed in an oven held at 200.degree.C. for about 5
minutes to remove the xylene solvent. Powdered polypropylene having
an average particle size of 35 microns is dusted on the hot primed
surface. The projectile is placed in an oven at 200.degree.C. to
fuse the polypropylene powder. Additional polypropylene is added to
the surface of the fused polypropylene and the heating and fusing
procedure is repeated until a rotating band having a thickness of
0.075 inches results. The projectile is removed from the oven and
the entire projectile is quenched using large amounts of cold tap
water which is poured over the internal and external walls of the
projectile body. The plastic band is then machined to the rotating
band configuration illustrated in FIG. 6.
EXAMPLE 4
Two projectiles having polypropylene rotating bands chemically
bonded thereto following the procedure set forth in Example 3 and
having the band configuration of FIG. 6 are fired in a 25
millimeter gun. The barrel of the gun has a uniform twist rifling
which makes an exit angle of 8.degree. and 55 minutes with the
barrel. Muzzle velocity of the projectiles is from 3600 to 3700
feet per second. High speed photographs are taken of these
projectiles in-flight. These photographs show that all the
projectiles are stable in-flight, with very small yaw angles and
yaw damping. These photographs also show that the polypropylene
rotating bands engrave well and are fully retained in-flight.
For optimum use of a projectile having a chemically bonded rotating
band, the configuration of the plastic rotating band is important.
The plastic rotating band chemically bonded to the surface of the
projectile should have sufficient free volume aft of the forward
edge of the rotating band to permit flow of the plastic into this
area during the engraving process. As the projectile travels
through the barrel of the gun, the plastic material engraves and
flows into the free volume aft of the forward surface of the
rotating band. If insufficient free volume is provided to accept
this flow of plastic material, excess pressure can build up in the
gun which can result in excessive barrel wear, unsatisfactory
ballistics, rotating band failure and possibly gun failure.
From the foregoing discussion it is obvious that the plastic
material chosen for any particular gun system must have sufficient
ductility to flow under the conditions encountered within the gun.
If there is insufficient ductility in the plastic material
employed, the plastic rotating band can crack or break-up resulting
in failure of the projectile to be stabilized in-flight, causing
failure of the projectile to be fired in the desired
trajectory.
As will be evident to those skilled in the art, various
modifications can be made or followed in view of the foregoing
disclosure and discussion without departing from the spirit or
scope of the disclosure or from the scope of the claims.
* * * * *