U.S. patent number 3,909,431 [Application Number 05/080,200] was granted by the patent office on 1975-09-30 for coolant-lubricant composition comprising fluorocarbon-cyclohexanone mixtures.
This patent grant is currently assigned to Allied Chemical Corporation. Invention is credited to Francis J. Figiel.
United States Patent |
3,909,431 |
Figiel |
September 30, 1975 |
Coolant-lubricant composition comprising fluorocarbon-cyclohexanone
mixtures
Abstract
Certain fluorocarbons, particularly
1,1,2-trichloro-1,2,2-trifluoroethane in admixture with
cyclohexanone are useful as evaporative coolant-lubricant
compositions. These mixtures are useful in the machining of metals
because of their stability, chemical inertness, non-flammability
and non-toxicity.
Inventors: |
Figiel; Francis J. (Boonton,
NJ) |
Assignee: |
Allied Chemical Corporation
(New York, NY)
|
Family
ID: |
22155891 |
Appl.
No.: |
05/080,200 |
Filed: |
October 12, 1970 |
Current U.S.
Class: |
508/577; 508/590;
252/68; 252/78.1 |
Current CPC
Class: |
C10M
3/00 (20130101); C10M 2207/08 (20130101); C10M
2211/022 (20130101); C10N 2040/22 (20130101); C10M
2211/06 (20130101) |
Current International
Class: |
C10M 001/30 ();
C10M 003/24 () |
Field of
Search: |
;252/11,15,52,54,58 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Metz; Andrew H.
Attorney, Agent or Firm: Stewart; Anthony J. Friedenson; Jay
P.
Claims
I claim:
1. Mixtures comprising a fluorocarbon which is
trichloromonofluoromethane, dichloromonofluoromethane,
monochloromonofluoromethane, dichlorotetrafluoroethane,
tetrachlorodifluoroethane, 1,1,1-trichloro-2,2,2-trifluoroethane,
1,1,2-trichloro-1,2,2-trifluoroethane, dibromotetrafluoroethane,
dichlorotrifluoroethane, monochlorotrifluoroethane, or
dichlorohexafluorocyclobutane, and cyclohexanone in which mixtures
the weight percent of cyclohexanone does not exceed about 2.
2. Mixtures according to claim 1 containing
1,1,2-trichloro-1,2,2-trifluoroethane.
3. Mixtures consisting essentially of a fluorocarbon which is
trichloromonofluoromethane, dichloromonofluoromethane,
monochloromonofluoromethane, dichlorotetrafluoroethane,
tetrachlorodifluoroethane, 1,1,1-trichloro-2,2,2-trifluorothane,
1,1,2-trichloro-1,2,2-trifluoroethane, dibromotetrafluoroethane,
dichlorotrifluoroethane, monochlorotrifluoroethane, or
dichlorohexafluorocyclobutane, and cyclohexanone in which mixtures
the weight percent of cyclohexanone does not exceed about 2.
4. Mixtures according to claim 3 in which the weight percent of
cyclohexanone is within the range of about one-half to about 2.
5. Mixtures according to claim 3 in which the fluorocarbon is
1,1,2-trichloro-1,2,2-trifluoroethane.
6. Mixtures according to claim 1 containing a propellant.
7. Mixtures according to claim 6 in which the propellant is a
fluorocarbon having a vapor pressure between about 0-71 p.s.i.g. at
70.degree.F.
8. Mixtures according to claim 7 in which the fluorocarbon having a
boiling point from 0.degree.-100.degree.C./760 mm is
1,1,2-trichloro-1,2,2-trifluoroethane.
9. Mixtures according to claim 8 in which the propellant is
dichlorodifluoromethane.
10. Mixtures according to claim 9 in which the weight percent of
the propellant based on the weight of the mixture does not exceed
about 40.
Description
BACKGROUND OF THE INVENTION
The fabrication, and more specifically the machining or cutting of
metals and metal alloy parts of lathes, planers, threaders, and the
like, is a well known and common operation in the metal-forming
industry. The operations involving the cutting and shaping of metal
and alloys such as titanium, stainless steels, aluminum and
beryllium, are extremely difficult and give rise to many problems
such as work-hardening during light cuts, short tool life and slow
machining speeds, due primarily to the generation of heat at the
point of contact of the cutting tool and the work piece.
It is known to improve the life of the cutting tool by cooling the
surfaces of the cutting tool and work-piece by employing lubricants
containing relatively large amounts of an evaporative coolant. The
usual coolant-lubricants or cutting oils, generally contain a
petroleum-derived substance such as mineral oil, kerosene, mineral
lard oil, sulfurized-chlorinated mineral oil, and sulfurized
mineral lard oil. Synthetic coolant-lubricants are also in common
use and such include polyglycols, esters, polycarbonates, imines,
amines, amides, silicones, halogenated hydrocarbons and mixtures
thereof.
Many coolant-lubricants used in the art or tested for use in the
prior art suffer from one or more of the following disadvantages.
For example most petroleum derived lubricants leave residues which
form coatings on the work-piece so that markings on the work-piece
or cutting tools are obliterated. The residues or coatings are
often difficult to remove and when removed, by use of abrasive
substances, can result in marring of the surfaces of the object
being machined. Other lubricants, such as kerosene and light
mineral oil fractions, are extremely flammable and thus present
hazards. Amines and nitrogenous oils are toxic and may present
health hazards to the operating personnel. Silicone oils often
leave residues which are difficult to remove. It is essential that
a work-piece, after the maching operation, be free of contaminants
which might affect the adhesion or appearance of paints or sealants
to be applied subsequently to the work-piece.
It is a major object of this invention to provide novel solvent
compositions which cool and lubricate metal work-pieces during the
machining thereof.
It is another object to provide coolant-lubricant solvent
compositions which are non-flammable, non-toxic and which do not
discolor the work-piece nor leave difficult to remove residues
thereon.
A particular object of this invention is to provide novel solvent
mixtures possessing the non-flammable and non-toxic characteristics
of 1,1,2-trichloro-1,2,2-trifluoroethane and providing
significantly better lubricating and cooling properties while in
use during the machining of metals than previously used
lubricants.
Other objects and advantages of the invention will be apparent from
the following description.
SUMMARY OF INVENTION
In accordance with the present invention, it has been found that
mixtures comprising a fluorocarbon coolant having a boiling point
from 0.degree.-100.degree.C./760 mm and cyclohexanone (C.sub.6
H.sub.10 O) as lubricant, in which mixture the weight percent of
the cyclohexanone does not exceed about 2, provide excellent
evaporative coolant and lubricating characteristics when applied to
metal parts during machining operations, and do not leave hard to
remove residues on the work-pieces or cutting tools.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Examples of suitable fluorocarbon coolant lubricants are
trichloromonofluoromethane, dichloromonofluoromethane,
monochloromonofluoromethane, dichlorotetrafluoroethane (sym- or
asym-), tetrachlorodifluoroethane (sym- or asym-),
1,1,1-trichloro-2,2,2-trifluoroethane,
1,1,2-trichloro-1,2,2-trifluoroethane, dibromotetrafluoroethane,
dichlorotrifluoroethane, monochlorotrifluoroethane, and
dichlorohexafluorocyclobutane. Mixtures of these coolants may also
be employed.
The preferred coolant is 1,1,2-trichloro-1,2,2-trifluoroethane.
Mixtures according to the invention in which the weight percent of
cyclohexanone is within the range of from about one-half to about 2
are preferred.
The compositions of this invention are essentially free of
inorganic contaminants, light in color, inert to chemical reactants
and stable.
The coolant-lubricant compositions of my invention may be applied
to the work-piece in any convenient manner as will be apparent to
those skilled in the art. One illustrative method is by gravity
flow, that is the compositions may be applied dropwise or in a
steady stream to the area around the point of contact of the
cutting tool and work-piece. Preferably, the novel compositions are
mixed with a conventional propellant in the amount of from about 5
to about 40% by weight of the composition, preferably 15-25% by
weight of the composition, and the resultant mixture applied to the
point of contact of the cutting tool with the work-piece, using
conventional aerosol equipment. Propellants such as fluorocarbons,
carbon dioxide, nitrogen, and mixtures thereof are typical of
suitable propellants which can be used. The preferred propellants
are fluorocarbons which have vapor pressures between about 0-71
p.s.i.g. at 70.degree.F. Illustrative are dichlorotetrafluoroethane
(sym- and asym-), monochlorodifluorethane and
dichlorodifluoromethane. The latter is the preferred propellant. As
can be seen, the propellant may be the same or different than the
coolant compound.
We have found that the presence of relatively small, i.e., up to
about 2% by weight, of cyclohexanone in the compositions of this
invention, provides sufficient lubrication character to extend the
tool-life and provides excellent work-piece finish. The propellants
serve not only to facilitate the application of the cyclohexanone
CCl.sub.2 F--CClF.sub.2 mixture to the work-piece but also may
improve the coolant properties of the mixture. Moreover the
presence of a propellant in amounts of up to about 40 weight
percent does not noticeably affect the lubricant properties of the
mixtures. Preferably the weight percent of propellant used is
within the range of about 15 to 25.
The following examples illustrate the principles and practice of my
invention. Parts and percentages are by weight unless otherwise
specified.
EXAMPLE 1
Cascade steel coupons, annealed to 32-35 Rockwell hardness, and
containing 4.1% nickel were machined on a 14 inch Sheldon Engine
Lathe, having a standard feed of 0.003 in. and a cut dept of 0.01
in. The lathe was operated at various speeds, from 45 rpm to 200
rpm.
Various coolants and/or lubricant compositions were applied through
a nozzle mounted at a point above the lathe so as to direct a spray
of coolant and/or lubricant against the work-piece at the point of
contact of the cutting tool and the work-piece. The duration of
each test was five minutes. The lathe speed, composition of the
coolant and/or lubricant under test, and the results of the test
are set out in tabular form in Table I, below.
TABLE 1 ______________________________________ Speed
Coolant/lubricant Results ______________________________________ 45
rpm Cutting Oil.sup.5 Good.sup.1 45 rpm Genetron 113/12.sup.2 4
Good 120 rpm Cutting Oil.sup.5 Turnings hot 120 rpm Genetron
113/12.sup.4 Turnings hot 160 rpm Cutting Oil.sup.5 Smog,
discolora- tion of turnings 160 rpm Genetron 113/12.sup.4
Discoloration or turnings 160 rpm 1% C.sub.6 H.sub.10 O, Genetron
Good-surface clean 113/13.sup.3 4 160 rpm 2% C.sub.6 H.sub.10 O,
Genetron Good-some lubri- 113/12.sup.3 4 cant visible on work-piece
200 rpm Cutting Oil.sup.5 Much discoloration of turnings. Tool
attacked. 200 rpm 1% C.sub.6 H.sub.10 O, Genetron Good 113/12.sup.3
4 ______________________________________ Legend:
Genetron-Registered trademark of Allied Chemical Corp. for
halogenated hydrocarbons. .sup.1 Good result indicated by clean
appearance of surface and turnings, no residue or one which is
easily wiped clean. .sup.2 Genetron 113 =
1,1,2-trichloro-1,2,2-trifluoroethane Genetron 12 =
Dichlorodifluoromethane (Propellant) (ratio 75%/25%, Genetron
113/12) .sup.3 Ratio 75% Cyclohexanone, Genetron 113 mixture, 25%
Genetron 12 .sup.4 About 180 parts of the mixture used. .sup.5
About 75 parts of cutting oil, Grade BR-112, product of American
Oil and Supply Co., Newark, N.J.
These results indicate that the turning of cascade steel coupons,
presents little or no problem at slow speeds but does at the
higher, i.e., 120 rpm and higher. The turning can be readily
accomplished at high speeds without damage to the cutting tool
and/or work-piece by use of a composition of this invention to
provide cooling and lubrication of the work-piece and cutting
tool.
EXAMPLE 2
When, instead of the cascade steel coupons machined in Example I
above, aluminum (AL 6061TG) coupons were used with the same
equipment and conditions, the lathe could be efficiently operated
at speeds up to 1,250 rpm. As was the case in Example 1, the finish
of the work-piece was the cleanest and free from residue only when
a coolant-lubricant composition containing 1 to 2% cyclohexanone
and 1,1,2-trichloro-1,2,2-trifluoroethane with
dichlorodifluoromethane as propellant was employed. Use of oil or
fluorocarbon (without cyclohexanone) resulted in a finish which was
slightly marred by residue or heat distortion effects. Use of
cyclohexanone (without oil or fluorocarbons) results in a
work-piece contaminated with residue.
EXAMPLE 3
One inch thick cascade steel coupons, annealed to 32-35 Rockwell
hardness and containing 4.1% nickel, were drilled in about 2
minutes with a 1/4 inch drill at a feed rate of 0.004
inch/revolution, and a speed of 1500 rpm. When using 12 parts of
1,1,2-trichloro-1,2,2-trifluoroethane as the coolant, the bit was
rapidly attacked. However, when a mixture of 3 parts of a 1%
solution of cyclohexanone in 1,1,2-trichloro-1,2,2-trifluoroethane
and 1 part of dichlorodifluoromethane was used to cool and
lubricate the bit and work-piece, the performance of the drill was
excellent, that is the chips were not discolored nor was any tool
build-up noted, and the surface of the work-piece was smooth.
EXAMPLE 4
Repetition of the above drilling test, but using a 1/2 inch drill
rotating at 810 rpm gave the following results:
a. When 14 parts of a 3:1 mixture of
1,1,2-trichloro-1,2,2-trifluoroethane and dichlorodifluoromethane
were used to cool the piece and drill, there was considerable
discoloration of the chips and extensive tool build-up was
noted.
b. When the coupon and drill were lubricated with a commercially
available cutting oil, an unsatisfactory result similar to that
obtained in (a) above was obtained.
c. When 15 parts of a 3:1 mixture of a solution of 1% cyclohexanone
in 1,1,2-trichloro-1,2,2-trifluoroethane and
dichlorodifluoromethane was used to cool and lubricate the coupon
and drill, no discoloration of the chips or tool build-up was
noted.
d. When 14 parts of a 3:1 mixture of a solution of 1.5% of
cyclohexanone and 1,1,2-trichloro-1,2,2-trifluoroethane and
dichlorodifluoromethane were used as the coolant-lubricant no
discoloration of the chips or tool build up was evident.
EXAMPLE 5
Cascade steel coupons, annealed to 32-35 Rockwell hardness and
containing 4.1% nickel were milled on a Bridgeport Milling Machine
using a feed rate of nine-sixteenth inch per minute, a depth of
0.02 inch, spindel speed of 80 to 210 rpm. The area around the
point of contact of the spindle and work-piece was cooled and
lubricated with 40 parts/minute of operation of coolant-lubricant
composition.
When a solution of 1.5% cyclohexanone in
1,1,2-trichloro-1,2,2-trifluoroethane was used as coolant-lubricant
an exceptionally good finish was achieved, that is no discoloration
of, or residue was left on the surface of the piece even at the
high spindle speed of 210 rpm. Cutting oil, when used at that high
speed, rapidly decomposed and left a hard residue on the piece.
When 1,1,2-trichloro-1,2,2-trifluoroethane alone was used, a very
coarse finish developed on the work-piece.
It will be apparent to those skilled in this art that for
specialized purposes, various additives could be incorporated with
the compositions of the invention, for example, co-lubricants,
antioxidants, co-propellants and the like. Such additives will be
chosen so as not to adversely affect the essential properties of
the basic composition for a given purpose.
The invention therefore is not intended to be limited by any
specific embodiments dislosed herein, but only by the scope of the
claims appended hereto.
* * * * *