U.S. patent number 3,908,604 [Application Number 05/481,478] was granted by the patent office on 1975-09-30 for method of and apparatus for the heating of a heat-transfer medium.
This patent grant is currently assigned to Mineralol- und Filtertechnik GmbH. Invention is credited to Peter Vocklinghaus.
United States Patent |
3,908,604 |
Vocklinghaus |
September 30, 1975 |
Method of and apparatus for the heating of a heat-transfer
medium
Abstract
A liquid medium having a high boiling point, e.g. oil, serves as
a heat-transfer medium or a recirculating centrally heated system
having a heat exchanger disposed in a combustion chamber. The
medium is recirculated through the heat exchanger. At least one
burner is provided for the combustion of a fuel composition
producing large quantities of corrosive compounds and the system is
operated such that the temperature of the combustion gases and the
wall of the heat exchanger in contact therewith is always above the
dewpoint of the corrosive components of the combustion gases.
Preferably the system is operated so that the temperature of the
heat-exchange medium is always above 200.degree. C.
Inventors: |
Vocklinghaus; Peter (Essen,
DT) |
Assignee: |
Mineralol- und Filtertechnik
GmbH (Essen, DT)
|
Family
ID: |
5884536 |
Appl.
No.: |
05/481,478 |
Filed: |
June 20, 1974 |
Foreign Application Priority Data
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Jun 20, 1973 [DT] |
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2331363 |
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Current U.S.
Class: |
122/250R;
110/260; 122/421; 110/190; 110/343 |
Current CPC
Class: |
F23C
99/00 (20130101); F23C 1/00 (20130101); F23C
2700/04 (20130101) |
Current International
Class: |
F23C
1/00 (20060101); F23C 99/00 (20060101); F22B
027/08 () |
Field of
Search: |
;110/1H,1S,1K
;122/4,25R,356,421 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sprague; Kenneth W.
Attorney, Agent or Firm: Ross; Karl F. Dubno; Herbert
Claims
I claim:
1. A method of centrally heating a heat-transfer fluid comprising
the steps of:
circulating said fluid through a heat exchanger;
generating a hot combustion gas contacting said heat exchanger by
combustion of at least one fuel composition generating large
quantities of gaseous corrosive components upon combustion; and
controlling said combustion by selectively burning a fuel and said
composition so that said combustion gas contacts said heat
exchanger only at a temperature above the dewpoint of said
corrosive components in the combustion gas.
2. The method defined in claim 1 wherein said combustion gas
contacts said heat exchanger always at a temperature of said fluid
of at least 200.degree. C.
3. The method defined in claim 1 wherein said fluid is oil.
4. The method defined in claim 1 wherein said fuel and said fuel
composition are mixed before combustion.
5. The method defined in claim 1 wherein said fuel and said fuel
composition are independently burnt in a common combustion
chamber.
6. The method defined in claim 1 wherein the temperature at a
surface of said heat exchanger is detected and used to control the
proportions of said fuel and said fuel composition which are
burnt.
7. An apparatus for the heating of a recirculated heat-transfer
fluid in a central heating station comprising:
means defining a combustion chamber;
at least one heat exchanger traversed by said fluid in said
combustion chamber;
at least one burner opening into said combustion chamber for
generating combustion gases therein passing into contact with said
heat exchanger;
means forming a combustion gas outlet from said chamber; and
control means for maintaining the temperature at which said
combustion gas contacts said heat exchanger at least in the region
of said outlet above the dewpoint of corrosive components of the
combustion gas, said control means including means for the
selective combustion of a fuel and of a fuel composition producing
large quantities of corrosive components upon combustion.
8. The apparatus defined in claim 7 wherein said control means
includes a temperature sensor on said heat exchanger, a controller
connected to said temperature sensor, and a switchover device for
selecting between combustion of fuel and said fuel composition.
9. The apparatus defined in claim 8 wherein two burners are
provided for selective operation by said switchover means, one of
said burners burning said fuel and the other burner burning said
composition.
10. The apparatus defined in claim 8 wherein a single burner is
provided with inlets for said fuel and said composition, said
switchover means selectively communicating between said inlets and
said burner.
11. The apparatus defined in claim 8 wherein said fluid is oil.
12. The apparatus defined in claim 8 wherein said temperature
sensor is disposed on said heat exchanger adjacent said outlet.
13. The apparatus defined in claim 8 wherein said heat exchanger
defines a combustion chamber coaxial with said burner, a
flow-direction-changing chamber ahead of said burner, and a
combustion gas discharge chamber coaxial with said combustion
chamber and communicating with said outlet.
Description
FIELD OF THE INVENTION
The present invention relates to a method of and an apparatus for
the combustion of fuel compositions containing sulfur and chlorine
compounds and giving rise to gaseous components which normally are
corrosive to the walls of a heat exchanger and, more particularly,
to a system for heating a heat-transfer fluid displaced in a
circulating path through a heat exchanger.
BACKGROUND OF THE INVENTION
If is, of course, known to provide a heating cycle in which a
heat-transfer fluid, e.g. a liquid, is recirculated along a closed
path and is heated at a central-heating plant or station at one
location along this path and dissipates heat to another medium, to
a load, etc. at a further location spaced from the heating
apparatus. Such systems may be used for the generation of electric
power in which the heat-transfer medium is vaporized or used to
heat a vaporizable fluid, in central heating systems for buildings
and industrial plants or any place at which remote utilization of
the thermal energy carried by the heat-transfer fluid is
possible.
The heating of such fluids is normally carried out in a boiler or
heat exchanger fired by one or more burners using as fuel
conventional fuel oil, consumer gas, natural gas or coal.
It has been proposed heretofore (see Brennstoff-Warme-Kraft, Band,
16, 1964, No. 8, pages 397-399) to use as fuel components or
compositions, used oil, aqueous and toxic sludges,
phenol-containing water and the like so as to destroy these liquids
which are environmental pollutants and are hazardous to the health.
These components can have their heating value increased by the
addition of fuel oil or can be burnt together with fuel oil, the
heat being recovered in waste-heat boilers or the like.
Such techniques have been found to be economically feasible as long
as the combustion gases, e.g. the hot gases formed on combustion
(referred to as exhaust gases after heat has been extracted
therefrom) contain practically no corrosive compounds. When
corrosive compounds are present, however, the use of the process is
rendered impractical since the heat-exchanger surfaces deteriorate
rapidly.
OBJECTS OF THE INVENTION
It is the principal object of the present invention to provide a
method of and an apparatus for the heating of a recirculating
heat-transfer fluid whereby the aforementioned disadvantages are
obviated.
It is another object of the invention to provide a method of
burning fuel compositions which produce large quantities of
corrosive gaseous components whereby the system can nevertheless be
economicalay utilized for the heating of a heat-transfer
medium.
It is a further object of the invention to provide an improved
apparatus for carrying out the last-mentioned method.
SUMMARY OF THE INVENTION
The present invention is based upon my discovery that fuel
compositions containing toxic, poisonous and like compounds can be
burnt effectively, in spite of the fact that they give rise to
corrosive components in the vapor state, and the heat generated by
such compositions can be utilized, when the temperature along the
surfaces of the heat exchanger traversed by the recirculating
heat-transfer medium, and the combustion gases is maintained above
the dewpoint of the corrosive components in the combustion gases
and preferably above 200.degree.C.
More particularly, I have found that it is possible to provide a
process for the combustion fuel compositions consisting at least in
large part of compounds producing large quantities of gaseous
corrosive compounds or such compositions in combination with
conventional fuels, without any of the disadvantages enumarated
above.
For the present purposes, fuel compositions are intended to means
compositions containing liquid or gaseous fuels or combinations
thereof which have a heat value of at least 4000 kcal/gh and
exclusively or partially give rise to liquid or gaseous combustion
or decomposition products with a high water content (10 to 50% by
weight) and contain chlorine, sulfur and like corrosive agents.
According to the method aspect of the invention, the combustion
gases are generated by the burning of large quantities of liquid or
gaseous fuel compositions producing large quantities of gaseous
corrosive compounds, only at a temperature above the dewpoint of
the corrosive compounds in the combustion gases. According to a
preferred technique, the heat exchange is carried out at a
temperature of the heat-transfer medium of at least 200.degree. C.
Surprisingly, the corrosive effect only is found when the
temperature of combustion, in the combustion chamber or the wall of
the heat exchanger in contact with the combustion gases, takes
place at or below the dewpoint temperature of the gaseous corrosive
compounds.
According to the apparatus aspects of the present invention, a
system for the heating of a recirculated heat-transfer medium
comprises a central heating system having a combustion chamber in
which at least one burner arrangement opens, and a heat exchanger
disposed between the burner and the exhaust gas outlet. According
to the invention, means is provided for the selective combustion of
liquid or gaseous fuel compositions capable of generating large
quantities of gaseous corrosive compounds and for the combustion of
conventional or gaseous fuels having minimal corrosive combustion
products, the selection or control means responding to a
temperature sensor on the heat exchanger surface proximal to the
exhaust gas outlet. When the temperature sensor indicates a
decrease in the heat-exchanger surface temperature to substantially
the dewpoint (preferably to substantially 200.degree. C) a signal
is supplied to the switchover means which operates the latter to
preferentially burn the fuel with the higher heat value, namely,
the normal fuel with low corrosive characteristics, either by
metering more of this fuel into the composition or by operating a
separate burner for this fuel for a greater duration than the
burner operating with the composition rich in corrosive combustion
products.
BRIEF DESCRIPTION OF THE DRAWING
The above and other objects, features and advantages of the present
invention will become more readily apparent from the following
description, reference being made to the accompanying drawing in
which:
FIG. 1 is a vertical section through a central heating plant for a
recirculating heat-transfer medium;
FIG. 2 is a section taken along line II----II of FIG. 1; and
FIG. 3 is a view of a double-burner arrangement which can be
substituted for the burner of FIG. 1.
SPECIFIC DESCRIPTION
In the drawing, I show a central heating station 1 for the heating
of a heat-transfer medium, especially oil having a boiling point
above 200.degree. C, which is recirculated through a system
represented generally at 2 and having an inlet 2a to the heat
exchangers of the central heating station and an outlet 2b
returning to a heat-consuming load.
The central heating station comprises a combustion chamber 3 which
is defined by a first cylindrical heat exchanger 12a communicating
with the inlet 2a and coaxially surrounding a burner 7.
The combustion chamber 3 communicates, at its axial end remote from
the burner 7, with a flow-reversing chamber 4 which lies
transversely to the axis of the combustion chamber and communicates
with an exhaust-gas outlet chamber 5 opening at 6 into a stack or
flue.
Chamber 5 is defined by a cylindrical heat exchanger 12b coaxial
with heat exchanger 12a and spacedly surrounding same. The
flow-direction changing chamber 4 is defined in part by a
spiral-tube heat exchanger 12c spaced from the end of heat
exchanger 12a. As illustrated, the heat exchangers 12a --12c are
connected in series to permit the oil to flow therethrough.
The exhaust-gas outlet 6 may be connected with an exhaust-gas
cleaning apparatus not shown.
The burner arrangement 7 comprises an atomizing burner 8 designed
to burn high-water fuel compositions to which conventional fuels
may be added. A valve 9 communicates selectively between two supply
lines 10 and 11, respectively delivering conventional fuel oil and
a waste liquid containing large quantities of water, chlorine and
sulfur compounds producing corrosive components upon combustion.
Respective pumps and reservoirs for the two liquids may be
provided.
The valve 9 may also be constituted as a mixing valve, when the
heat valve of the fuel falls, thereby indicating a reduction in the
combustion gas temperature at contact with the heat exchanger 12
close to the outlet 6, such that as the dewpoint is approached, the
temperature sensor 14 provides a signal for the controller 13 which
actuates the valve operator 15.
At startup, the oil serving as the heat-transfer medium is
recirculated in the cycle 2 through the heat exchanger and may have
a temperature below 200.degree. C or, say, room temperature as
detected by the sensor 14. The controller 13 actuates the valve
operator 15 so that the valve 9 delivers only pure fuel oil to the
burner 7, 8, whereby combustion gases of low corrosivity and high
temperature are produced.
Once the temperature of the recirculating oil is heated to
200.degree.C or above, the temperature sensor through controller 15
meters quantities of the high corrosion fuel composition to the
burner. Should the temperature detected by sensor 14 drop, the
quantity of this high-corrosion fuel composition is reduced or
terminated so that the temperature at the surface of the heat
exchanger at least at the outlet and the temperature of the
combustion gases within the heat exchanger is at all times
maintained above 200.degree.C and, therefore, above the dewpoint of
the corrosive components of the combustion gases.
Any solids produced by the combustion process may be collected on
the floor of the combustion chamber and removed by conventional
scraping or conveying devices.
The arrangement shown in FIG. 3 comprises a pair of burners 7a and
7b, the first for the combustion of pure fuel oil and the other for
combustion of the fuel composition of high corrosivity which may be
operated jointly or independently by the controller 13 to
accomplish the same results.
* * * * *