U.S. patent number 3,906,617 [Application Number 05/141,351] was granted by the patent office on 1975-09-23 for method of preventing braze and diffusion flow.
This patent grant is currently assigned to GTE Sylvania Incorporated. Invention is credited to Cecil Behringer, George J. Kamin.
United States Patent |
3,906,617 |
Behringer , et al. |
September 23, 1975 |
Method of preventing braze and diffusion flow
Abstract
A solid material containing a rare earth compound suspended in a
fugitive carrier is useful in preventing braze and diffusion flow
by applying the slurried compound to the material to be brazed or
diffusion coated in a continuous layer by conventional methods.
Alternative compositions are suspensions of rare earth compounds in
a fugitive carrier and refractory metal oxides, admixed with rare
earth compounds and mixtures thereof suspended in a fugitive
carrier.
Inventors: |
Behringer; Cecil (Edina,
MN), Kamin; George J. (Towanda, PA) |
Assignee: |
GTE Sylvania Incorporated
(Stamford, CT)
|
Family
ID: |
26688799 |
Appl.
No.: |
05/141,351 |
Filed: |
May 7, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
16583 |
Mar 4, 1970 |
3623921 |
Nov 30, 1971 |
|
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Current U.S.
Class: |
228/118;
228/215 |
Current CPC
Class: |
B23K
35/224 (20130101); C23C 10/04 (20130101); B05D
1/32 (20130101) |
Current International
Class: |
C23C
10/04 (20060101); C23C 10/00 (20060101); B05D
1/32 (20060101); B23K 35/22 (20060101); B23k
001/04 () |
Field of
Search: |
;29/470.9 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Husar; Francis S.
Assistant Examiner: Rowold; Carl A.
Attorney, Agent or Firm: O'Malley; Norman J. Castle; Donald
R. McNeill; William H.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATION
This application is a divisional application of Ser. No. 16,583,
filed Mar. 4, 1970 and now U.S. Pat. No. 3,623,921, which is
assigned to the assignee of the present invention.
Claims
We claim:
1. In the process of brazing, wherein a first part and a second
part to be brazed are assembled with a filler alloy between said
parts to form a joint and are then heated above the liquidus of the
filler alloy, the improvement comprising applying a substantially
uninterrupted layer of a brazing stopoff composition to said joint
and to a portion of said parts adjacent to said joint, before being
brazed, said composition consisting essentially of a suspension of
a solid material in a fugitive carrier in weight ratios of about
15:85 to about 60:40 respectively, said solid material comprising
from about 40 to about 100 weight percent based on the total weight
of said solid material of a rare earth compound selected from the
group consisting of rare earth oxides, rare earth salts of lower
aliphatic acids, rare earth salts of mineral acids and mixtures
thereof and from about 0 to about 60 weight percent based upon the
total weight of said solid material of a refractory metal
oxide.
2. An improvement according to claim 1 wherein said braze stopoff
composition is applied by brushing.
Description
BACKGROUND OF THE INVENTION
This invention relates to a composition and method for preventing
braze and diffusion coating flow. More specifically it relates to a
suspension of a rare earth or mixed rare earth compound suspended
alone in a fugitive carrier or admixed with refractory metal oxides
suspended in a fugitive carrier and applied by conventional methods
to the material to be brazed or diffusion coated.
In brazing applications it is usually necessary to apply a material
to the joint and adjacent portion of the work piece to be brazed to
prevent the filler alloy from flowing over the entire work piece.
The most commonly used materials in this application are composed
of highly refractory oxide such as alumina (Al.sub.2 O.sub.3),
titania (TiO.sub.2) and magnesia (MgO). These materials have shown
varying degrees of utility with the aluminum-silica, copper-gold,
nickel-chromium, and copper-zinc filler alloys used in brazing.
However, in brazing with the newer filler alloys such as
palladium-nickel-gold and silver-copper palladium, the existent
stopoffs do not protect the surfaces and varying degrees of creep,
break through, and undesired adhesion occur. Also, in the newer
applications the inefficiency of the presently available stopoffs
necessitate grinding of the joined surfaces to remove the undesired
bonding agent and to produce a clear sharp junction. Overcoming
these problems necessitate additional steps and expense.
Generally the same highly refractory oxides are used in diffusion
coating applications. In this case, the refractory oxides are used
to control the size of the area to be coated and have had only
limited success in diffusion coating process such as carburizing,
nitriding, and aluminizing. For example, in the diffusion coating
of turbine parts such as nozzles, blades, and the like, the
existent stopoffs do not protect the surfaces and the coatings are
able to penetrate the stopoff. Also, many of the stopoffs
themselves have a residual coating which must be removed by fine
grinding to produce a marketable finished piece. Overcoming both
problems necessitate additional steps and expense.
It is believed, therefore, that a brazing and diffusion coating
stopoff which prevents brazing and diffusion coating flow that is
easily and readily removed without having an appreciable amount of
residue or necessitating costly additional steps is an advancement
in the art.
SUMMARY OF THE INVENTION
In accordance with one aspect of this invention, there is provided
a composition useful for stopping braze and diffusion coating flow.
The composition consists essentially of a solid material and a
fugitive carrier in weight ratios of from about 15:85 to about
60:40 wherein said solid material comprises from about 40 to about
100 weight percent of a rare earth compound selected from the group
consisting of oxides, salts of lower aliphatic and salts of mineral
acids and from about 0 to about 60 weight percent of a refractory
metal oxide.
In accordance with another aspect of this invention, there is
provided an improved process for brazing. The parts to be brazed
are assembled with a filler alloy between the joint; and the joint
and a portion of the parts adjacent to the joint are coated, before
being brazed, with a substantially uninterrupted layer of a rare
earth compound slurry composition as described above.
In accordance with still another aspect of this invention, there is
provided an improved process for diffusion coating wherein a
continuous substantially uninterrupted layer of the composition is
applied to a portion of the parts that are not to be diffusion
coated.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a side elevational view of one embodiment of the present
invention.
FIG. 2 is a view of the embodiment of FIG. 1 as taken along the
lines 2--2.
Referring to FIG. 1 and FIG. 2 in more particularity, the first
part 10 and second part 12 have a filler alloy 13 disposed between
the two parts to form a joint. A layer 14 of brazing stop-off
composition is applied over the joint and a portion of each of part
10 and part 12 adjacent to the joint. When the filler alloy 13 is
heated above its liquidus, the layer of brazing stop-off
composition 14 prevents the flow of filler alloy. After the brazing
the stop-off composition can be rinsed off of the brazed parts.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
For a better understanding of the present invention together with
other and further objects, advantages and capabilities thereof,
reference is made to the following disclosure and appended claims
in connection with the above description of some of the aspects of
the invention.
The present invention relates to a rare earth compound slurry
composition and a method for preventing braze and diffusion coating
flow. Surprisingly, it has been found that when the aforementioned
composition is prepared and applied to parts to be brazed and/or
diffusion coated the flow of the filler alloy and/or coatings is
controlled, and that the stop-off is easily and readily removed
after the brazing and/or coating without any appreciable amount of
residue.
Referring now to the invention with greater particularity, yttrium,
for purposes of this invention, is to be considered one of the rare
earth elements and included in the lanthanide series. The useful
rare earth compounds are the rare earth oxides and heat
decomposable rare earth compounds that decompose to form rare earth
oxide. Useful heat decomposable compounds include the rare earth
salts of lower aliphatic acids and mineral acids. As used herein
lower aliphatic acids include those having from 1 to about 5 carbon
atoms. Preferred compounds are the rare earth oxides, oxalates,
carbonates, and mixtures thereof. Preferred rare earths are yttrium
and the heavy rare earths, that is, those having atomic numbers of
64 through 71, namely, gadolinium, terbium, dysprosium, holmium,
erbium, thulium, ytterbium, lutetium and mixtures thereof. Of these
yttrium oxide and yttrium carbonate are especially preferred.
Yttrium and any of the heavy rare earths can be the sole component
in the solid material that is suspended in the fugitive carrier,
however, mixtures of these compounds can be used if desired. For
example, yttrium oxide is one of the especially preferred rare
earth compounds and beneficial results have been achieved when
yttrium oxide is used in the solid material from about 60 to about
70% by weight along with from about 30 to about 40% of a heavy rare
earth oxide.
As previously mentioned the solid material can include refractory
metal oxides in conjunction with the rare earth compounds. The
solid material can contain from about 40% to 100% by weight of the
rare earth compound and from about 0% to about 60% by weight of a
refractory metal oxide such as alumina (Al.sub.2 O.sub.3), titania
(TiO.sub.2), magnesia (MgO) and the like. Solid materials
comprising from about 40% to about 90% by weight of a rare earth
compound and from about 10% to about 60% by weight of a refractory
metal oxide are preferred for some applications. Especially
preferred is a solid material comprising from about 80 to about 90%
by weight of yttrium oxide, from about 5 to about 10% of titanium
oxide and from about 5 to about 10% of aluminum oxide.
The solid material can be suspended in a fugitive carrier by any of
the methods generally used for suspending pigments in paints. In
practice, ball milling of the solids into the fugitive carrier and
physical agitation to suspend the solids into the fugitive carrier
are usually used. As used herein, a fugitive or volatile carrier is
one that will either volatize or decompose to form volatile
decomposition products when heated in air to a temperature of about
150.degree. C. Examples of fugitive carriers that can be employed
are polyacrylamides, polyvinylacetates, polyvinyl pyrrolidone,
homopolymers and copolymers of the lower alkyl acrylates and
methacrylates (e.g. C.sub.1 through C.sub.5). Especially preferred
are polyvinyl acetates such as Lacquer L-18 as supplied by Raffi
and Swanson, Inc.
The concentration of the rare earth compound in the carrier is
varied as desired, depending on such factors such as the particular
method of applying the coating, such as, for example, brushing,
spraying, dipping and extruding the desired thickness of the
individual coating, the number of coatings to be applied, the
viscosity of the carrier, the desired covering power of the
stopoff, the desired viscosity of the slurry, and other influencing
factors. Typically, the solid material is present in the
composition in an amount corresponding to about 175 to about 1,500
grams per 100 gms of the carrier.
The composition is applied to the desired areas of the parts to be
brazed or diffusion coated by the methods well known to one skilled
in the art -- for example, brushing, spraying, extruding, etc. In
brazing the aforementioned composition is generally applied to the
joint and a portion of the parts next to the joint so as to prevent
the filler alloy from running and covering the entire work piece
when the work piece is brazed. Whereas in diffusion coating, the
composition is generally applied to the areas of the work piece not
to be coated and which will be subjected to an atmosphere of the
coating material.
After the work piece is brazed or diffusion coated, the powder-like
residue can be readily removed such as for example by wiping the
residue off with a damp cloth, washing the work piece with water,
and air blasting the work piece.
To more fully illustrate the present invention, the following
detailed examples are presented. All parts, proportions, and
percentages are by weight, unless otherwise given.
EXAMPLE 1
About 500 parts of yttrium oxide is ball milled for about 24 hours
using alumina balls. The oxide is dried for about 12 hours at about
130.degree. C and hammermilled. About 300 parts of the dried oxide
is suspended in 200 parts of a 10 wt. percent solution of polyvinyl
pyrrolidone in water by means of mechanical stirring for 24 hours.
The resultant suspension (braze stopoff) is applied by brush to a
joint and adjacent area of a metal to be brazed and which has a
silver-copper-palladium filler alloy, so that the joint and
adjacent area are coated. The metal is heated to above about
1742.degree. C. After coating the braze stopoff is washed off the
metal piece with water. The filler alloy is contained within the
joint with no overflow.
EXAMPLE 2
About 200 parts of yttrium oxide is added to about 250 parts of
lacquer L-18, a low residue polyvinylacetate supplied by Raffi and
Swanson, Inc. is ball milled for about 24 hours using alumina
balls. The resultant suspension (diffusion coating stopoff) is
applied by brush to parts of a turbine blade prior to aluminzing
the blade. After coating the diffusion coating stopoff is wiped off
with a damp cloth and the parts of the blade coated with the
stopoff are not aluminized.
EXAMPLE 3
About 45 parts yttrium oxide, about 2.5 parts alumina and about 2.5
parts titania are added to about 250 parts of lacquer L-18, a low
residue polyvinylacetate supplied by Raffi and Swanson, Inc. is
ball milled for about 24 hours using alumina balls. The resultant
suspension (diffusion coating stopoff) is poured into the holes of
a honeycomb piece of metal prior to diffusion coating it. After
cooling the diffusion coating stopoff is wiped off with a cloth and
the filled crevices are not coated.
EXAMPLE 4
About 50 parts are mixed rare earth oxides, containing about 70%
yttrium, about 15% ytterbium, about 7% dysprosium, about 6% erbium,
about 0.01% gadolinium, about 1.0% holmium, about 0.01% lanthanium,
about 1.0% lutetium, about 0.1% terbium, and about 0.1% thulium,
are added to about 250 parts lacquer L-18, a low residue
polyvinylacetate supplied by Raffi and Swanson, Inc. is ball milled
for about 12 hours using alumina balls. The resultant suspension
(diffusion coating stopoff) is applied by brush to parts of a
turbine blade prior to aluminizing the blade. After coating the
diffusion coating stopoff is wiped off with a cloth and the parts
of the blade coated with the stopoff are not aluminized.
Substantially the same results are obtained when the brazing and
diffusion coating stopoffs are prepared using yttrium carbonate,
yttrium oxalate, yttrium oxide admixed with gadolinium oxide,
yttrium oxide admixed with terbium oxide and dysprosium oxide and
yttrium oxide admixed with alumina in substantially equivalent
amounts to yield a composition having substantially the same solids
content.
While there has been shown and described what are at present
considered the preferred embodiments of the invention, it will be
obvious to those skilled in the art that various changes and
modifications may be made therein without departing from the scope
of the invention as defined by the appended claims.
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