U.S. patent number 3,904,726 [Application Number 05/378,899] was granted by the patent office on 1975-09-09 for methods of manufacturing fibrous granulates.
This patent grant is currently assigned to Societe d'Exploitation des Brevets Granofibre Sebreg. Invention is credited to Jean Fournet, Guy Jacquelin.
United States Patent |
3,904,726 |
Jacquelin , et al. |
September 9, 1975 |
Methods of manufacturing fibrous granulates
Abstract
This invention relates to methods of manufacturing fibrous
granulates. Various fibers of animal, vegetable, mineral or
synthetic origin can be granulated by a method in accordance with
the invention in which the fibers are first intertangled or felted
in a dry state and then tightened relative to each other by
treatment with a liquid followed by drying. The liquid is used in
an amount which is sufficient to form menisci between the fibres.
Additional bonding between the fibers can also be effected using
bonding agents etc. The present invention enables fibrous
granulates to be produced which are coherent, substantially
spherical, light, flexible and resilient.
Inventors: |
Jacquelin; Guy (Grenoble,
FR), Fournet; Jean (Saint-Romain-en-Gal,
FR) |
Assignee: |
Societe d'Exploitation des Brevets
Granofibre Sebreg (Ampuis, FR)
|
Family
ID: |
9102206 |
Appl.
No.: |
05/378,899 |
Filed: |
July 13, 1973 |
Foreign Application Priority Data
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|
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Jul 21, 1972 [FR] |
|
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72.26426 |
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Current U.S.
Class: |
264/117;
264/37.11 |
Current CPC
Class: |
B01J
2/12 (20130101) |
Current International
Class: |
B01J
2/12 (20060101); B01J 002/12 (); D21C 009/00 () |
Field of
Search: |
;264/117,113,112,37
;162/9 |
References Cited
[Referenced By]
U.S. Patent Documents
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|
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2483406 |
October 1949 |
Francis, Jr. |
3229008 |
January 1966 |
Harrington, Jr. et al. |
3564083 |
February 1971 |
Fournet et al. |
3589977 |
June 1971 |
Fournet et al. |
|
Primary Examiner: Goldstein; Melvin
Assistant Examiner: De Benedictis; Thomas
Attorney, Agent or Firm: Eslinger; Lewis H. Sinderbrand;
Alvin
Claims
We claim:
1. A method of manufacturing a fibrous granulate, which method
comprises the steps of agitating resilient fibers which are dry on
their surfaces and which have a moisture content of not mre than
55% of the total weight of the fibers under dry conditions, to
initiate imbrication of the fibers in groups and form fibrous
aggregates having relatively low cohesion; thereafter depositing on
the surface of the fibrous aggregates a suitable liquid selected,
in accordance with the fibers being treated, to form liquid menisci
on the fibers; said depositing step comprising the step of spraying
only a limited amount of liquid onto the fibrous aggregates which
limited amount of liquid is just sufficient to form liquid menisci
between the surfaces of the fibers of each aggregate at the
crossing points of the fibers, thereby to deform the fibers and
cause mechanical tightening and increased mechanical
interengagement and cohesion of the fibers; and thence evaporating
the liquid to intensify the tightening and increase the mechanical
interengagement and cohesion of the fibers.
2. A method according to claim 1, wherein said agitating step
comprises agitating the fibers in a rotary tunnel having a
substantially horizontal axis, the tunnel being filled with fibers
to between two thirds and four fifths of its volume.
3. A method according to claim 1, including the steps of grading
the fibrous mass resulting from the dry agitating step before said
depositing step to separate fibrous aggregates of a predetermined
size from pulverulent products, fibers that have remained free,
loose fiber groups and fiber groups of less than a predetermined
size, thereafter disintegrating the fiber groups to free the fibers
that constitute them, collecting the free fibers removed during the
grading step and the free fibers obtained by said disintegrating
step and mixing the collected free fibers with fresh fibers and
subjecting them to the dry agitating step, and depositing said
liquid solely on the fibrous aggregates of predetermined size
separated during the grading step.
4. A method according to claim 1, wherein said depositing step
comprises atomizing the liquid on the fibrous aggregates.
5. A method according to claim 3 including the steps of spreading
the separated fibrous aggregates in a layer of substantially
uniform thickness and vibrating the aggregates during distribution
of the liquid.
6. A method according to claim 1, including the step of drying the
fibrous aggregates after distribution of the liquid.
7. A method according to claim 1, wherein the liquid deposited on
the fibrous aggregates is water and the mean moisture content
thereof after deposition is from 50 to 85%, based on the total
weight of the moist aggregates.
8. a method according to claim 1, including the step of forming
additional connections between the fibers to reinforce the physical
and mechanical action of tightening of the fibers due to dampening
with the liquid.
9. A method according to claim 8, wherein the fibers are
thermoplastic and additional connections are obtained by subjecting
fibers tightened by the liquid to a thermal treatment which
produces local welding between the fibers.
10. A method according to claim 8, wherein the fibers are
thermocontractile and the additional connections are obtained by
subjecting the granulates tightened by the liquid to a thermal
treatment which intensifies this tightening.
11. A method according to claim 8, wherein the damping liquid
contains a binding agent which causes localised gluing between the
fibers when the granulates tightened by this liquid are dried and
additional connections are thereby produced.
Description
This invention relates to methods of manufacturing fibrous
granulates.
It has hitherto been proposed to manufacture fibrous granulates in
two stages, firstly by subjecting the fibres to a dry treatment in
which individual fibers assembled loosely in a tunnel having a
horizontal axis are stirred by rotation of the tunnel so as to
start imbrication of the fibers into groups and to form fibrous
aggregates having little cohesion, and then to treat the aggregates
with a liquid carrier during which the aggregates are suspended in
a liquid and agitated with this liquid either by simple rotation or
rotation combined with pulsation to consolidate the fibrous
aggregates and transform them into granulates having desired
properties.
The products of such a method are desirably coherent, substantially
spherical, light, flexible and resilient fibrous granulates which
are sufficiently solid not to come apart easily, and are relatively
inexpensive to produce from the base fibers.
According to the present invention there is provided a method of
manufacturing a fibrous granulate which method comprises agitating
natural or synthetic fibers which are dry on their surface and have
a moisture content of not more than 55% of the total weight of the
fibers under dry conditions in order to initiate their imbrication
in groups and form fibrous aggregates having little cohesion;
depositing a liquid on the surface of the aggregates so as to form
liquid menisci between the surfaces of the fibers of each aggregate
and cause tightening of the fibers; and evaporating the liquid to
intensify the tightening.
The fibers may be of natural origin, for example vegetable fibers
such as wood fibers, annual plant fibers e.g. straw, cotton linters
or the like; animal fibers such as wool or various hairs; or
mineral fibers such as asbestos or various fibrous crystals. The
fibers may also be of artificial origin, for example organic fibers
such as viscoses or rayons; or mineral fibers such as spun glass or
stone or the like. The fibers in addition may be of synthetic
origin such as polyvinyl chloride, a polyolefin, a polycarbonate,
or one of various copolymers.
As used herein, the word "aggregate" refers to organised groups of
fibers obtained by dry treatment and the word "granulate" refers to
spherules obtained by consolidation of such aggregates.
Using a method in accordance with the present invention it is
possible to reduce the duration of the wet treatment of the
aggregates compared with hitherto, the energy consumed in effecting
this treatment and the energy in extracting water from the
granulates. The cost of the resulting granulates can thereby be
reduced considerably.
Apparatus for effecting a method in accordance with the invention
can be simpler than that used for hitherto proposed methods and
this makes it possible to reduce the amount of capital investment
in the apparatus and this influences the cost of the granulates.
Furthermore, it is possible to establish profitable small capacity
installations near to places where the fibrous granulates are
produced.
Where the product is to consist only of fibrous granulates, the
fibrous mass resulting from the dry treatment will generally be
graded in order to separate the fibrous aggregates of desired size
from other components. These other components can be pulverulent
products, fibers that have remained free, and fibrous groups that
are loose or are of unsuitable size. The fibrous groups tend to
disintegrate and completely free the fibers that consitute them.
The free fibers removed during separation and the free fibers
produced by disintegration, can be mixed with fresh fibers and
subjected to a dry treatment. The liquid is then only deposited on
fibrous aggregates which have been graded.
Fibrous aggregates extracted from the fibrous mass resulting from
the dry treatment are preferably spread in a layer of substantially
uniform thickness and the liquid atomized on to this layer while
the aggregate is being vibrated.
The liquid may be water which may, if desired, contain a surfactant
and/or a binder.
The fibrous granulates are advantageously dried after
moistening.
In a practical embodiment of the present invention, the fibers used
were distinct from one another, although in the case of vegetable
fibers, the mass of fibers treated contained a few slivers, that is
to say thick bundles of fibers in which numerous parallel fibers
are connected to one another and constitute a group that does not
have the form of a fiber.
Irrespective of the origin of the fibers, which may be animal,
vegetable, mineral or synthetic, the fibers were dry. The fibers
were not moist on their surfaces at this stage but they could have
internal moisture. Thus, in the case of wood fibers, the moisture
content could be from 3 to 55% of the total weight of the fibers
but it should not make them appear damp to the touch.
For the dry treatment, the individual dry fibers were assembled in
a tunnel in the form of a body with a horizontal axis of
revolution. The tunnel may have partitions. The tunnel was arranged
to be driven in rotation about its horizontal axis. The tunnel was
filled to more than half its internal volume. Moreover, no liquid
was distributed in this tunnel, so that the treatment of the fibers
was carried out under really dry conditions.
The fibers were subjected to mechanical felting interactions during
rotation of the tunnel. The fibers were slightly deformed
resiliently and their interlacing was consolidated by the stresses
developed by these resilient forces. Fibrous aggregates were thus
formed in the moving mass of fibers undergoing treatment.
Most of the resulting cohesive aggregates, which were in the form
of spherules, had dimensions which corresponded substantially to
the mean length of the fibers and these dimensions varied little
even when the treatment was prolonged. Moreover, the fibrous
structures that were formed were cohesive only in so far as their
dimensions did not greatly exceed the mean length of the fibers.
Larger structures had a tendency to break during sliding of the
layers of fibers relative to one another, and when falling.
The effectiveness of the dry treatment generally depends on the
extent to which the tunnel is filled, since the active driving
surface must be small with respect to the volume treated, and on
the speed of rotation of the tunnel.
Particularly good results were obtained when the extent of filling
of the tunnel was between two thirds and four fifths of the volume
of the tunnel.
For example, when 850 kg. of wood fibers are subjected to the dry
treatment in a tunnel 2.5 m in diameter and 8m long, the extent of
filling is 65%. After 2 hours rotation at a peripheral speed of
about 80 m/min, 80% of the fibrous mass had been transformed into
aggregates.
When the grain size of the aggregates had been stabilized, the dry
treatment was complete and the wet treatment could begin.
Although not always necessary, it may be found desirable to grade
the treated fibrous mass before it is subjected to the wet
treatment in order to separate fibrous aggregates of appropriate
sizes, fibers that have remained free, fibrous groups that are
loose or are of unsuitable size, and pulverulent products and the
like.
This grading may be effected by screening, which also makes it
possible to eliminate fibrous aggregates of appropriate size which
have insufficient cohesion. These latter aggregates tend to fail to
withstand the various stresses imposed by the screens, and they
break up.
The groups that are loose, or are of unsuitable size, and the
remains of aggregates destroyed during screening, are
disintegrated, for instance by carding, so that the fibers of which
they are made are freed from one another. These fibers, and those
that remained free, can be mixed with fibers being used for the
first time and subjected to a fresh dry treatment so that fibers
that are not aggregated or are badly aggregated are recycled.
The graded fibrous aggregates cannot be used in such a state
because their internal cohesion is insufficient.
It is therefore essential to consolidate the aggregates and the wet
treatment hereinafter described enables this to be effected.
The wet treatment is preferably applied to fibrous aggregates which
have been separated from the rest of the mass that has been
subjected to the dry treatment. However, the wet treatment can be
applied to the whole of the mass, provided that the product
containing the granulate can contain free fibers or loose groups of
fibers, and also provided that the proportion of fibrous aggregates
in the mass is sufficiently high.
The wet treatment consists of depositing a quantity of a liquid on
the surface of the fibrous aggregates which is just sufficient to
form liquid menisci between the surfaces of the fibers. These
menisci cause tightening of the fibers and this tightening is
intensified by evaporation of the liquid.
Advantageously the fibrous aggregates are spread in a layer of
substantially uniform thickness on a moving surface and the liquid
distributed by atomization. In order to provide uniform moistening,
the moving surface is preferably vibrated. The moving surface,
which may be horizontal, rising or falling, and may be flat,
cylindrical, helical or of some other shape, guides the suitably
moistened fibrous aggregates towards a dryer so that the liquid
forming the menisci is completely and rapidly removed.
In most cases, and more particularly when the base fibers are of
natural origin, the liquid can be water. The mean moisture content
of the whole mass is then preferably between 50 and 85% based on
the total weight of the moist aggregates.
In certain cases, however, other liquids can be sprayed on. For
example, if the base fibers are polyethylene the liquid may be a
hydrocarbon or a solvent which moistens the fibers.
To show clearly the transformation which results from the wet
treatment, and by which the fibrous aggregates having little
cohesion become fibrous granulates having better cohesion, two
types of tests have been effected.
A first series of tests was designed to measure the diametrical
contraction of the fibrous aggregates subjected to wet treatment.
Aggregates based on wood fibers were disposed on a motionless
plate, and the variation in the diameter of a large number of
aggregates was measured by means of a cathetometer.
Atomization of water was found to be accompanied by a contraction
varying from 5 to 10%, according to the aggregates, and drying was
accompanied by a further contraction of about 1%.
A second series of tests was designed to measure the cohesion of
the fibrous granulates. Two needles were inserted diametrally into
each granulate. Then, by means of a dynamometer, a force tending to
move the needles apart was exerted until the granulate subjected to
the test disintegrated. The value of the breaking force,
arbitrarily called the cohesion, is significant and was given as a
criterion of estimation. The example described hereinafter refers
to the results of several tests.
Fibers of conifers such as those which make up "wood pulp" paste
were subjected to a dry treatment in accordance with the invention.
The fibrous aggregates obtained had weak cohesion because the
cohesion was between 10 and 12 g for a diameter of 8mm.
The aggregates were moistened to 80% with water, and then dried.
The cohesion of the fibrous granulates obtained was then between 25
and 30g.
It may be advantageous to reinforce the effect of moistening, which
results in producing a physical and mechanical effect in which the
fibers of the aggregates are tightened, by combining the effect of
moistening with that of another kind of connection between the
fibers.
Reinforcing connections can be produced by moistening with the
liquid. In this case the liquid serves to swell the surface fibers,
and if these fibers have been brought sufficiently close together
under the action of the surface tensional forces, connections
between fibers appear and these further consolidate the
granulates.
For example, if polymer fibers are to be treated, a swelling agent
which permits bonding by evaporation may be used in the moistening
liquid.
With certain thermoplastic fibers, the granulates can be subjected
to a thermal treatment which makes it possible to accelerate
evaporation of the moistening liquid and the drying of the
granulates. Furthermore, it is thereby possible to soften the
surface of the fibers and produce on their surfaces a pasty state
similar to that obtained using a swelling agent. The interfacial
tension forces than produce local welding by bringing the fibers
close together.
For example, 5 to 8mm diameter polyvinyl chloride granulates having
a cohesion of a few grammes between needles may attain a cohesion
of more than 800g when subjected to thermal treatment for a few
minutes at 100.degree. to 110.degree.C.
Fibers which are "thermocontractile", and react to an increase in
temperature by changing their dimensions, can be subjected to a
thermal treatment in the form of a granulate which also makes it
possible to accelerate evaporation of the moistening liquid and the
drying of the granulate, to produce intensified imbrication and
tightening of the fibers.
In general, the moistening liquid used with any type of fiber can
include a substance capable of consolidating the approach of the
fibers towards one another by glued connections. It is possible for
this purpose to use various amylaceous materials, various polymers
and more generally any product capable of producing a glued
connection between the fibers by drying and/or thermal treatment.
For example, fibrous aggregates obtained by dry treatment of
conifer fibers can be moistened with a 20g/l suspension of
pre-gelled starch in water so that their weight is doubled.
After drying, the cohesion of the fibrous granulates thus obtained
can reach a value between 80 and 100g.
A method in accordance with the invention may be used in most cases
in which the fibrous granulates are required to be economical and
are not subjected to tensile stresses or are only subjected to weak
tensile stresses.
Particularly important applications are the manufacture of light,
porous insulating fillers and the manufacture of base products for
the production of moulded or extruded parts forming sub-layers of
various coatings.
* * * * *