U.S. patent number 3,904,405 [Application Number 05/328,926] was granted by the patent office on 1975-09-09 for sliding seal parts and process of making.
This patent grant is currently assigned to Ametek, Inc.. Invention is credited to Irving J. Hess, Robert A. Russell.
United States Patent |
3,904,405 |
Russell , et al. |
September 9, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Sliding seal parts and process of making
Abstract
A sliding seal part and method of making by use of coated carbon
filaments or particles with aluminum, the coated particles being
subjected to heat and pressure to form the seal part.
Inventors: |
Russell; Robert A. (Rosemont,
PA), Hess; Irving J. (Philadelphia, PA) |
Assignee: |
Ametek, Inc. (New York,
NY)
|
Family
ID: |
23283073 |
Appl.
No.: |
05/328,926 |
Filed: |
February 2, 1973 |
Current U.S.
Class: |
419/11; 205/159;
418/152; 419/24; 205/137; 205/237; 418/178; 418/179 |
Current CPC
Class: |
F01C
19/005 (20130101); C22C 32/0084 (20130101) |
Current International
Class: |
C22C
32/00 (20060101); F01C 19/00 (20060101); C22C
001/04 () |
Field of
Search: |
;117/160,114C,228,DIG.11,46CC ;418/178,179,113,152 ;204/14N
;75/201,212,226 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Weiffenbach; Cameron K.
Assistant Examiner: Buffalow; Edith R.
Attorney, Agent or Firm: Smythe & Moore
Claims
What is claimed is:
1. The process of producing sliding seal part means comprising the
steps of adheringly plating discrete carbon elements with aluminum,
then consolidating said plated elements into sliding seal part
means by pressure and heat, wherein the plating is carried out by
electrodeposition from an ethereal bath containing anhydrous
aluminum chloride and a metal hydride selected from the group
consisting of lithium hydride and lithium aluminum hydride.
2. The process of producing sliding seal part means comprising the
steps of adheringly plating discrete carbon elements with aluminum,
then consolidating said plated elements into sliding seal part
means by pressure and heat, wherein the plating is carried out by
electrodeposition from an ethereal bath containing anhydrous
aluminum chloride and a metal hydride and wherein the ethereal bath
is selected from the group consisting of ethyl ether, ethyl n-butyl
ether, anisole, phenetole, diphenyl ether and mixtures of ethyl and
butyl ethers.
3. The process of producing sliding metal seal part means as
claimed in claim 1 wherein the discrete carbon elements are
vitreous carbon particles.
4. The process of producing sliding metal seal part means as
claimed in claim 1 wherein the discrete carbon elements are
calcined anthracite particles.
5. The process of producing sliding seal part means as claimed in
claim 2, wherein the discrete carbon elements are vitreous carbon
particles.
6. The process of producing sliding seal part means as claimed in
claim 2, wherein the discrete carbon elements are calcined
anthracite particles.
Description
This invention relates to sliding seal parts or the like and a
method of making the parts.
Bearing or sliding seal parts, including carbon or graphite, which
have self-lubricating properties are known in the art, but such
have been brittle with low fatigue strength and have had a tendency
to score. The impregnation of formed structures of carbon filaments
or particles with plastic resins or metals, such as silver, copper,
bronze, cadmium or babbit, have been tried, but these have not had
the required properties or strength and wear resistance. It also
has been suggested that carbon powder be pressed and the pressed
particles put into an autoclave and immersed in a molten aluminum
metal bath in said autoclave under pressure. Aluminum carbide will
form between the particles in the pressed shape. A seal so made has
not been completely satisfactory and has been uneconomical to
make.
One of the objects of the invention is to make an improved sliding
seal part or piece having the desired physical characteristics.
Another of the objects of the invention is to provide a method for
making sliding seal parts which produces seals of improved strength
and physical characteristics.
Another object of the invention is to produce sliding seal parts in
a more economical manner than previously accomplished.
In one aspect of the invention, carbon filaments or particles,
herein referred to as elements, are coated or plated with aluminum.
This is carried out preferably by electrodeposition. Other plating
methods such as electroless or chemical plating can be used. The
plating process can be carried out at room temperature. The metal
coated or plated elements are then formed under pressure and heat
to the desired seal and sliding part form. The forming can be
carried out in various manners as described hereafter. It has been
found that the products of the present invention have been
particularly efficacious for uses such as the apex seals for the
rotor of Wankel-type engines.
These and other objects, advantages and features of the invention
will become apparent from the following description and drawings
which are merely exemplary.
In the drawings:
FIG. 1 is a schematic diagram of the steps involved in the
invention;
FIG. 2 is a representation of a photomicrograph (500X) of a part
made in accordance with Example I described hereafter;
FIG. 3 is an example of one use of the invention which is in a
"Wankel" engine;
FIG. 4 is a broken perspective view of a seal as used in FIG. 3;
and
FIG. 5 is a representation of a photomicrograph of a part made in
accordance with Example II described hereafter.
Referring to the flow diagram of FIG. 1, the carbon or graphite
fibers or particles are represented in box 10 which are plated at
11 and then consolidated under heat and pressure at 12 to the form
of a sliding seal part or bearing.
The carbon or graphite filaments or fibers can be the desired
dimensions as set forth hereafter. If particles of carbon or
graphite are used, then these can be sized as described
hereafter.
The carbon elements, discrete fibers or particles, are adheringly
plated with aluminum by electrodeposition or by electroless
deposition.
In the case of electrodeposition, such can be carried out, for
example, as described in U.S. Pat. No. 2,651,608 to Brenner in a
bath as set forth therein. The bath can consist of an ether, such
as ethyl ether, ethyl n-butyl ether, a mixture of ethyl and butyl
ethers, anisole, phenetole or diphenyl ether; a metal hydride such
as lithium hydride or lithium aluminum hydride; and anhydrous
aluminum chloride.
Following are examples of manners in which the invention can be
practiced.
EXAMPLE I
The graphite yarn used was "Thornel 400," the trademark of Union
Carbide Corp. for its brand of high strength, high modulus graphite
yarn, such a yarn being comprised of 1,000 filaments, approximately
7.6 microns in diameter, twisted to form a yarn.
Aluminum was electrodeposited on 12-inch lengths of graphite yarn
using the methods described in the aforementioned Brenner patent.
Sufficient aluminum was deposited to form an aluminum plated yarn
having approximately 60 weight percent aluminum and 40 weight
percent graphite fiber. Sections of aluminum plated yarn
approximately two inches long were plied together in a rectangular
die and subjected to heat and pressure. The temperature was
maintained at 900.degree.F. and the pressure at 4,000 p.s.i. for 30
minutes. The plated aluminum coating on the individual filaments of
the graphite yarn consolidates to form a homogeneous distribution
of graphite fibers in an aluminum matrix. FIG. 2 of the drawing
represents a 500X magnification of the cross section of the
resultant composite as viewed in a direction perpendicular
(90.degree.) to the orientation of the graphite fiber axis. The
tensile strength of the part so made was 38,000 p.s.i. as measured
in a direction parallel to the axis of the graphite fibers. The
tensile strength of a comparable aluminum part of the same
dimensions but not containing any graphite fiber is 10,000
p.s.i.
EXAMPLE II
The carbon powder used was "M351" vitreous carbon, as sold by
Beckwith Carbon Co.
Aluminum was electrodeposited on a specific size of M351 vitreous
carbon (-200 mesh + 325 mesh) using the methods described in the
aforementioned Brenner patent. Sufficient aluminum was deposited to
yield a plated powder containing 30 weight percent of aluminum and
70 weight percent of vitreous carbon powder.
Sliding seal parts were formed from the aluminum plated vitreous
carbon powder as follows:
1. The plated powder was blended with sufficient aluminum alloy
powder, designated as Al32, made by Aluminum Company of America, to
yield a mixture containing 50 percent vitreous carbon by
weight.
2. The blend was cold compacted at a pressure of 40,000 p.s.i. to
yield a form having sufficient green strength to be subjected to
subsequent processing.
3. The form made in step 2 was heated without pressure to a
temperature of 1,100.degree.F. in a furnace containing N.sub.2 or
an inert atmosphere for a period of 15 minutes.
4. Upon completion of step 3, the form while still hot was placed
in a die whose dimensions conformed to the finished dimensions of
the sliding seal part and was subjected to a pressure of
approximately 150,000 p.s.i. and was maintained at this pressure
for 5 minutes.
The part made in the above example was subjected to a wear test.
Results of the wear test are described in Table I.
EXAMPLE III
Example III is the same as Example II except that calcined
anthracite or carbon powder sold under the trademark "A-Carb," a
trademark of U.S. Graphite Co., was used.
Tests were performed on articles made in accordance with prior art
as described hereafter.
______________________________________ SAMPLE DESCRIPTION
______________________________________ 1 Commercially available
carbon-aluminum apex seal used in the Wankel-type engine and
manufactured by the molten aluminum metal infiltration process. 2
Seal made according to the method described in Example II. Sample
Size A retangular bar 0.5 inch in length by 0.24 inch in width and
0.34 inch in height. The bar had a radius of 5/32 inch on the face
subjected to wear testing.
______________________________________
TEST METHOD
The test seal was held against the rotating surface of a hard
chrome plated aluminum alloy disc. The disc was rotated at a
peripheral speed of 5,400 feet per minute. The test seal was
mounted on a lever arm which extends 6 inches beyond the point at
which the seal touched the rotating disc. A load of 5 pounds was
placed on the end of the lever arm. The disc surface was lubricated
with SAE20 oil, and the disc was rotated for each of the test
samples for the same period of time. The wear rate of the samples
was determined by measuring the difference between original height
of the test sample and the height after the wear test and dividing
this difference in height by the length of time the test was run so
as to obtain wear rates in inches of wear per hour. The results are
reported in Table I.
TABLE I ______________________________________ Test Sample Wear
Rate ______________________________________ 1 .00145 inches/hour 2
.00019 inches/hour ______________________________________
The plating also can be performed by electroless or chemical
plating such as chemical vapor deposition or vacuum deposition.
The heat and pressure or consolidation step can be carried out in
various manners. The plated filaments or particles can be heated in
a mold which has pressure applied. Also, powder metallurgy
techniques can be employed compacting under high pressure the
coated elements without heat. The pressure of the aluminum on the
carbon provides sufficient green strength to handle the part for
subsequent processing. Such is not the case when uncoated carbon
powder and aluminum powder are mixed. The second step is the
sintering of the formed green shape. The third step, optional, is
coining, pressing or otherwise treating the sintered part.
One example of use of the invention is seen in FIG. 3 wherein the
seal 13 is shown in conjunction with rotor 12a of the Wankel engine
15. The combination is the subject of copending application Ser.
No. 328927, filed Feb. 2, 1973.
It should be apparent that variations can be made in details hereof
without departing from the spirit of the invention except as
defined in the appended claims.
* * * * *