U.S. patent number 3,904,361 [Application Number 05/252,259] was granted by the patent office on 1975-09-09 for procedure and a device for the sterilization of packaging material.
Invention is credited to Hermann Egger.
United States Patent |
3,904,361 |
Egger |
September 9, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Procedure and a device for the sterilization of packaging
material
Abstract
Sterilization of a web of packaging material is accomplished by
applying a film of sterilizing liquid to the web, passing the web
through an atmosphere saturated with steam and sterilizing liquid
while the film is maintained at a temperature just below its
boiling point and then drying the film by a flow of hot dry
sterilized air.
Inventors: |
Egger; Hermann (Ursen (FR),
CH) |
Family
ID: |
11272942 |
Appl.
No.: |
05/252,259 |
Filed: |
May 11, 1972 |
Foreign Application Priority Data
|
|
|
|
|
May 19, 1971 [IT] |
|
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50425/71 |
|
Current U.S.
Class: |
422/27; 53/167;
53/545; 118/67; 422/300; 53/426; 53/562; 118/643 |
Current CPC
Class: |
A61L
2/07 (20130101); B65B 55/103 (20130101) |
Current International
Class: |
A61L
2/07 (20060101); A61L 2/04 (20060101); B65B
55/04 (20060101); B65B 55/10 (20060101); A61l
001/00 (); A61l 003/00 (); B65b 009/12 () |
Field of
Search: |
;21/57,92,93,91,56,58
;53/180 ;117/119.8 ;118/643,67,68 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Scovronek; Joseph
Assistant Examiner: Turk; Arnold
Attorney, Agent or Firm: Browdy and Neimark
Claims
What is claimed is:
1. A process for the sterilization of the surface of a web of
packaging material which is to become the internal surface of the
container formed from the web, comprising the steps of:
applying to the web surface a film of a sterilizing liquid:
bringing said web surface, after the application of said film, past
and in contact with an atmosphere formed within an essentially
closed sterilization chamber to prevent the evaporation of said
film in said chamber;
spraying said chamber with steam and vapors of said sterilizing
liquid unitl said atmosphere is saturated therewith;
heating said liquid film immediately upon its contact with said
atmosphere to a temperature just below its boiling point;
keeping said liquid film at this temperature throughout its passage
past said atmosphere;
drying said hot liquid film with a flow of hot dry sterilized air
thereover at its issue from said saturated atmosphere.
2. A process according to claim 1, wherein the sterilizng liquid is
hydrogen peroxide and the atmosphere is saturated with steam and
hydrogen peroxide vapors.
3. A process according to claim 1, wherein said liquid film is kept
at a temperature just below its boiling point by infrared
radiations of a wavelength such as to be selectively absorbed by
said liquid film.
4. A process according to claim 3, wherein the wavelength of the
infrared radiations is in the range from 2.5 to 3 micron.
5. A device for the sterilization of the surface of a web of
packaging material which is to become the internal surface of the
container formed from the web, comprising:
means to apply a film of sterilizing liquid to said web
surface;
an essentially closed sterilization chamber, said chamber having an
inlet and an outlet end for the passage of said liquid filmed
surface in thereto and out thereof;
heating means arrayed in said chamber from its inlet towards its
outlet, those at its inlet being for heating said liquid film
quickly to a temperature just below its boiling point, the
successive ones being for keeping said liquid film at said
temperature; and
means to completely saturate the interior of said chamber with
steam and vapors of said sterilizing liquid, thereby preventing the
evaporation of said liquid film within said chamber.
6. A device according to claim 5, additionally comprising:
baffles within said chamber, interposed between said heating means
to minimize motion of said atmosphere within said sterilization
chamber.
7. A device according to claim 5, wherein the means to apply a film
of sterilizing liquid to the interior face of said web
comprises:
a directing roll to direct said web towards said sterilization
chamber and rotated by the movement of said web;
a wetting cylinder driven by said directing roll to apply a film of
said sterilizing liquid to the interior web face;
an equalizing cylinder to evenly distribute and determine the final
thickness of said liquid film.
8. A device according to claim 5, additionally comprising a drying
chamber forming a continuation of said sterilization chamber, the
inlet of said drying chamber coinciding with the outlet of said
sterilization chamber; and means in said drying chamber to apply a
current of hot sterilized gas to said liquid film.
9. A device according to claim 5, wherein said heating means
comprises a plurality of infrared radiators, their emission being
of a wavelength such as to be selectively absorbed by said liquid
film.
10. A device according to claim 9, wherein said infrared radiators
are retractable electric resistors projecting into said chamber of
sterilization.
11. A device in accordance with claim 5 further including means for
causing the web to bend in the middle and form a substantilly
semi-circular cross-sectional contour with said surface on the
inside, throughout the passage of said surface past said
sterilization chamber and wherein said sterilization chamber
comprises a plate having outwardly extending flanges on the sides
thereof and said semi-circular web the edges of which pass between
said flanges.
12. A device according to claim 11 wherein said heating means
present a curvature pararlleling the contours assumed by said web
at their level.
13. A device according to claim 11, said heating means compries a
succession of heaters and wherein said sterilization chamber is
subdivided into compartments by baffles interposed between
successive heaters and extending from said plate to the immdediate
vicinity of the interior web surface.
Description
The invention refers to a procedure and a device for the
sterilization of packaging material, both the procedure and the
device being especially applicable to the sterile packaging and
filling of precedently sterilized products, especially liquid
products, into containers formed from plastic or plastic coated
paper webs.
One of the problems affecting such packaging procedures and
equipment is the sterilization of that plastic coated face of the
web which will form the internal face of the container, i.e. that
face which, remaining in a prolonged contact with the contents, is
liable to contaminate them if it is not sterilized to a very high
degree. Sterilization by the mere application of heat to this face
would require temperatures which would destroy its plastic coating.
The choice of suitable chemical sterilizing substances is extremely
restricted by the requirement that even their traces must be
completely eliminated from said treated face of the web before it
is formed into containers and these containers are filled. The most
suitable sterilizing agent for this purpose has proved to be
hydrogen peroxide, because after its application it can be
completely evaporated at temperatures which do not endanger the
plastic coating of the paper web. However, the use of hydrogen
peroxide results in a number of problems. The sterilizing action of
cold peroxide is too slow for today's web processing rates. Warm
peroxide exerts a sterilizing action which is quicker and more
effective, but it still raises further problems. The proposal of
passsing the web through a tank containing heated peroxide resulted
in the drawback of heavy losses of peroxide due to its
decomposition by heat and its absorption on and uncoated face of
the web. Furthermore decolorization of anything printed on the
uncoated surface and discomfort and various unpleasant effects,
such as irritation of the mucosae and discoloration of the hair, to
the personnel are encountered in an atmosphere containing peroxide
vapors. It has also been suggested to apply hydrogen peroxide
vapors directly upon that coated face of the web, which will form
the interior surface of the containers. Its evaporation was
obtained by spraying the peroxide solution together with jets of
hot air, which caused the evaporation of the sprays before they hit
the coated web surface. However, tests have shown that this
procedure did not attain the same degree of sterilizing effect as
that exerted by a protracted contact with warm hydrogen peroxide.
In fact, sterilization tests performed on a dry concentration of
10.sup.6 spores/sq. cm of Bacillus Subtilis spread on a plastic
coating, have shown that at a temperature of not over 150.degree.C
and at an exposure time of not over 20 seconds, the mortality of
the bacilli caused by H.sub.2 O.sub.2 in a vapor phase is
practically nil ( 1 log. cycle max.).
Sterilization reaches an insufficient maximum of 2 log. cycles when
H.sub.2 O.sub.2 is sprayed and suddenly evaporated by hot air
circulation. Sterilization has however proved optimal, with 5 log.
cycles, with a liquid film of H.sub.2 O.sub.2 of 15 % concentration
when its temperature is raised just below its boiling point by
radiation and its evaporation is kept at a minimum for
approximately 20 seconds.
The results of such comparative tests, evidencing the efficiency of
the sterilization method of the invention are shown in the attached
table.
To realize these optimal results, in the procedure and device of
the invention, the hydrogen peroxide solution is applied as a cold
film of uniform thickness to the interior, plastic coated surface
of the web. Subsequently, the web passes through a sterilization
chamber filled with practically stationary, sterile, steam
saturated atmosphere and the peroxide film on it is subjected,
immediately upon its entrance into the chamber, to a sudden heating
to a temperature just below its boiling point. Throughout the
remaining portion of its travel through this chamber the film is
kept at this temperature, while the saturated atmosphere of the
chamber keeps its evaporation at a minimum. At the end of its
passage through said vapor filled chamber the interior web face has
attained the above indicated high degree of sterilization.
Immediately thereafter, the web passes into a second chamber,
wherein the interior web face is dried by a steam of precedently
sterilized hot dry air, and thence moves into the successive
processing stations of the packaging machine, in which it is
transformed into containers and the containers are filled and
sealed.
__________________________________________________________________________
Test conditions Exposure Tempera- H.sub.2 O.sub.2 concen- Minimum
time in ture tration survival Test method seconds (.degree.C)
(weight %) index .sup.(x)
__________________________________________________________________________
Contact of the packaging material with 20-60 120-150 11-18
10.sup.-.sup.1 vapor phase H.sub.2 O.sub.2 to H.sub.2 O.sub.2 of
the vapors H.sub.2 O.sub.2 Sudden evaporation, caused by circulated
20 120-150 11-18 10.sup.-.sup.2 hot air, of a H.sub.2 O.sub.2
solution sprayed or to hot of the sprinkled on the packaging
material air air Sudden evaporation, caused by hot air 20 120-150
11-18 10.sup.-.sup.3 circulation, of a H.sub.2 O.sub.2 solution
applied to hot of the in a continuous and uniform film upon air air
the packaging material H.sub.2 O.sub.2 solution applied in an even
and 20 80-100 11-18 10.sup.-.sup.5 continuous film to the packaging
material to radia- of the and heated by radiation under conditions
tions H.sub.2 O.sub.2 minimizing its evaporation
__________________________________________________________________________
.sup.(x) between the spores having survived the treatment and the
initia spores.
The procedure and the device of the invention will be better
understood from the following description, made with reference to
the attached drawings, of two of its possible embodiments.
In the drawings:
FIGS. 1A, 1B and 1C are a vertical section through the first
embodiment;
FIG. 2 is a schematic drawing, on a larger scale, of the web
wetting station of FIG. 1A;
FIG. 3 is a section, taken along the line III--III, of FIG. 1B;
FIGS. 4A-B are a vertical section through the second
embodiment;
FIG. 5 is a section taken along line V-V of FIG. 4B; and
FIG. 6 is a schematic drawing of an elevational view perpendicular
to the view of FIGS. 1A-C.
The web 1 is drawn by the usual (and therefore not shown) drive
rolls from an(also not shown) feed roll, thence, with its coated
face 1a downward, under a directing roll 4 and vertically upward
through the sterilization and the drying chamber.
In the web wetting station, generally indicated at 2, a wetting
cylinder 3 is partially immersed in a 15 % hydrogen peroxide
solution contained in tank 5 and kept there at a constant level by
any suitable known and therefore not shown system. The rotation
imparted by the web 1 to the directing roll 4 is transmitted
through any suitable means, such as a gear or belt drive, to
cylinder 3, which, in its rotation, transfers a hydrogen peroxide
film 5a from the tank 5 and to the plastic coated surface 1a of web
1.
Cylinder 6 presents at each end a raised rim 7 which presses
resiliently against the margins of the web 1 on cylinder 4, whereby
also roll 6 is entrained in rotation by the web. Rims 7 form a
clearance between the surface of cylinder 6 and the web face 1a,
which serves to equalize the liquid film on face 1a and determine
its thickness at the entrance of the web into the sterilization
chamber.
A wiper blade 8 serves to recover any liquid from the surface of
cylinder 6.
The sterilization chamber may be of any shape permitting the
arrangement of the heaters and the creation of a steam saturated
atmosphere according to the following description. However, since
in packaging practice, at a certain step, the paper web must anyhow
be folded in the middle and its two margins must be sealed together
in a successive stage to form the web into a tube, it is convenient
to take advantage of this provision to let the web itself form two
walls of the sterilization and the subsequent drying chamber. For
this purpose, the doubled-up web 1 is passed over a (not shown
guide roll 30 or between a pair of guide rolls mounted just over
line Z--Z of FIG. 1 or 4 as seen in FIGS. 1C and 6, whose axis or
axes respectively are at a right angle with those of the cylinders
in the wetting station 2. Consequently, the paper web issues flat
from between cylinders 4 and 6, assumes gradually the approximately
semicircular curvature shown in FIG. 3 or 5, with its coated face
turned inward, while its margins 9 and 10 gradually approach each
other, until the web is completely doubled-up, with said margins
pressed together when it reaches the guide roll 30 or guide rolls.
The space portion delimited by web 1 from a level just above
cylinders 4 and 6, where it is still flat, to the level where it is
completely doubled-up, is closed by a triangular plate 11, whose
sides present two flanges 12 and 13 (FIG. 3), which hug and guide
web margins 9 and 10 during their convergence, while its base
almost contacts face 1a at a level where it is still flat. Owing to
this arrangement, plate 11 and web 1 define together a sufficiently
well enclosed space, which forms the sterilization chamber. Plate
11 is backed by a boxlike structure 19.
In the embodiment according to FIGS. 1 to 3, the heating of the
peroxide film is effected by infrared radiators, such as infrared
lamps, the emitted wavelengths being comveniently selected in the
range from 2.5 to 3 microns so that they correspond to their
maximum absorption by the liquid film on the web. In this manner it
is possible to selectively heat to a desired temperature said
liquid film while preventing the excessive heating of the
supporting web material.
The radiators 14 and 15 are aligned in a vertical row on plate 11
and separated by horizontal baffles 16 which extend from plate 11
as near to the web surface 1a as it is possible without the danger
of damaging it, and thereby they separate the sterilization chamber
into compartments, with the purpose of keeping the atmosphere in
the chamber as stationary as possible. The baffles are made from
materials which absorb as little as possible of the radiations of
the heaters 14 and 15.
Each radiator or heater is of a shape approximately following the
contours assumed by the web at their level (see especially FIG. 3),
and its rays are directed by semicircular reflectors 17 of a
parabolic cross section in conical beams upon the web survace 1a.
This arrangement permits the heating of this surface uniformly both
in a transverse and in a longitudinal sense, because the radiators
are spaced from each other so that the edges of their conical beams
of radiation overlap.
Upon its entrance into the sterilization chamber, the peroxide film
is heated by the lowermost radiators 14 very quickly to a
temperature just below its boiling point. For this purpose,
radiators 14 are placed either nearer to web 1 or made of a greater
power than radiators 15. The task of the successive radiators 15 is
to maintain the liquid film at the temperature imparted to them by
the radiators 14 for the remaining portion of its travel through
the sterilization chamber.
To prevent or at least to minimize the evaporation of the peroxide
film during its passage through the sterilizing chamber and to
prolong thereby its contact with the web face 1a, in order to
obtain the desired optimal sterilization, the atmosphere of the
chamber is saturated with steam and hydrogen peroxide vapors of a
temperature equal to that of said heated film. The hydrogen
peroxide vapors are obtained by spraying H.sub.2 O.sub.2 nozzles 31
into the chamber, while steam is injected into it through a
distributor 32 at a pressure slightly above the external preesure.
These devices come into operation each time the packaging machine
is started and/or the steam and H.sub.2 O.sub.2 vapor concentration
drops below the level of saturation.
The sterilization chamber with its highly saturated atmosphere and
the arrangement of the heaters permit therefore a prolonged contact
of a very hot film of sterilizing liquid with the interior web
surface, to attain its best possible sterilization.
Safety systems of any known and suitable type turn the radiators
off whenever the movement of the web stops. Such systems are per se
known and therefore neither described nor illustrated.
The terminals 18 of the radiators 14 and 15 are located within a
box 19, which also contains the conductors for the connection with
the electric mains.
The drying chamber 22 forms a continuation of the sterilization
chamber since its walls are also formed by the web 1 and the plate
11. This chamber is separated from the sterilization chamber by a
diaphragm 20 which extends from plate 11 towards web 1. Slightly
above said diaphragm, plate 11 presents an opening 11a and slightly
below its upper end a second opening 11b. An upward curved
deflector plate 21 extends from the lower edge of opening 11a
towards the web and similarly a downward curved deflector plate 23
extends from the upper edge of opening 11b towards said web. In
said chamber 22 the H.sub.2 O.sub.2 film, which enters at a
temperature near its boiling point, comes into sudden contact with
a stream of hot dry pre-sterilized air entering through opening
11a, passing along web face 1a and issuing through opening 11b, or
in the contrary direction, as it seems fit. Owing to the high
temperature of the liquid film, the change from a vapor saturated
into a completely dry atmosphere and to the high temperature of the
air, the liquid film is removed, without leaving the smallest
residue, in an extremely short time. The temperature of the air
stream can be kept as low, for instance as 100.degree.C so, as not
to endanger the plastic coating of the web. As illustrated in J. H.
Perry, Chemical Engineer's Handbook, 10, 18 (1963) an exposure time
of 5 seconds is amply sufficient to totally remove an H.sub.2
O.sub.2 layer of 10 .mu. at a temperature of 90.degree.C of the
packaging material by means of a hot air stream of 100.degree.C at
a speed of over 2 meters/second.
In the embodiment of FIGS. 4A, 4B and 5, electric resistors,
instead of infrared lamps, are used as infrared radiation sources,
and the differences in structure in the sterilization chambers
between the first and this embodiment are due to the greater
thermal inertia of these radiation sources, so that means must be
provided to immediately remove them from the vicinity of the web in
the case of a break-down of the web transport mechanism or during
the starting-up time of the packaging machine, during which web 1
is still stationary.
For this purpose, the high-temperature electrical resistors 14' and
15' are not mounted directly upon plate 11', as in the former
embodiment, but on a box-like structure 25, and they project into
the sterilization chamber through a generally triangular opening
extending from the lower to the upper end of plate 11'. Similarly
to the radiators 14, also the lowermost radiators 14' of this
embodiment are either more powerful or kept nearer the liquid film
on web surface 1a than the successive radiators 15' for the purpose
already illustrated in connection with the first embodiment
Structure 25 is connected by piston rods 26 to double acting
hydraulic cylinders 28 which it is automatically retracted whenever
the web stops for any of the aforementioned causes. A casing 29 is
welded or otherwise fastened to plate 11' and forms, together with
web 1, a completely enclosed space 27.
It is clear that the invention is not limited to the embodiment
shown, and that especially the wetting station for the web, the
sterilization and the drying chambers may be given any other shape
without departing from the concept of the invention.
* * * * *