U.S. patent number 3,903,890 [Application Number 05/498,892] was granted by the patent office on 1975-09-09 for disposable diaper of simple construction.
This patent grant is currently assigned to Johnson & Johnson. Invention is credited to Frederick K. Mesek, Virginia L. Repke.
United States Patent |
3,903,890 |
Mesek , et al. |
September 9, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Disposable diaper of simple construction
Abstract
A disposable diaper of economical and simple construction is
provided comprising a highly porous batt of short cellulosic fibers
and a water-impervious backing sheet adjacent one surface of the
batt. Structural integrity is provided to the batt by a binder
material applied to the surface opposite the backing sheet and
extending through the batt thickness in spaced linear areas.
Inventors: |
Mesek; Frederick K. (Downers
Grove, IL), Repke; Virginia L. (Oak Forest, IL) |
Assignee: |
Johnson & Johnson (New
Brunswick, NJ)
|
Family
ID: |
23982935 |
Appl.
No.: |
05/498,892 |
Filed: |
August 20, 1974 |
Current U.S.
Class: |
604/365; 604/366;
604/372; 604/379; 604/369; 604/373 |
Current CPC
Class: |
A61F
13/539 (20130101); A61F 13/532 (20130101); A61F
13/534 (20130101); A61F 2013/5395 (20130101); A61F
2013/53445 (20130101); A61F 2013/15821 (20130101); A61F
2013/530153 (20130101); A61F 2013/51409 (20130101); A61F
2013/530145 (20130101); A61F 2013/53908 (20130101); A61F
2013/530131 (20130101); A61F 2013/51061 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61F 013/16 () |
Field of
Search: |
;128/287,29R,29P,296
;161/128,116 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Medbery; Aldrich F.
Claims
We claim:
1. A multi-layer disposable diaper comprising (1) a highly porous
batt comprised at least primarily of short cellulosic fibers and
(2) a water-impervious backing sheet adjacent one surface of said
batt and bonded thereto in spaced areas of adhesion, the fibers of
said batt being bonded together by a resinous binder covering the
surface opposite said backing sheet to provide a smooth permable
skin as a body contacting surface of said batt, said resinous
binder extending throughout the thickness of said batt in spaced
linear areas.
2. The diaper of claim 1, wherein said batt includes a densified,
paper-like layer adjacent said impervious layer.
3. The diaper of claim 1, wherein said backing sheet is adhered to
said batt by said binder in said spaced linear areas.
4. The diaper of claim 1, wherein said backing sheet is adhered to
said batt by a separate adhesive in the marginal areas of the
region of contact between said backing sheet and said batt.
5. The diaper of claim 1, wherein said binder contains a
surfactant.
6. The diaper of claim 1, wherein said binder is a thermoset
material.
7. The diaper of claim 1, wherein said highly porous batt is
comprised entirely of short fibers.
8. The diaper of claim 1, wherein said highly porous batt is
comprised of short fibers and long fibers.
9. The diaper of claim 8 wherein said short and long fibers are
uniformly blended.
10. The diaper of claim 8 wherein said batt comprises different
proportions of short and long fibers at different thickness
portions thereof with a maximum concentration of long fibers at the
surface opposite said backing sheet.
11. A method of making a diaper comprising the steps of applying a
liquid resinous binder to a surface of a highly porous batt of
short cellulosic fibers, compressing said batt in spaced linear
areas to cause said liquid resinous binder to move through the
thickness of said batt in said area, solidifying said binder to
provide a smooth fluid permable skin as a body contacting surface
of said bott and to form spaced binder walls extending throughout
the thickness of the batt and adhering the surface of said batt
opposite said first named surface to a water-impervious backing
sheet.
12. The method of claim 11, wherein said liquid resinous binder is
applied as a foam.
13. The method of claim 11, wherein said liquid resinous binder is
an aqueous latex of a thermosetting material.
14. The method of claim 11, wherein said liquid resinous binder
contains a surfactant.
Description
BACKGROUND OF THE INVENTION
Disposable diapers provide substantial advantages in convenience
over diapers intended to be laundered and reused, particularly when
they are used away from home. In recent years, many different
disposable diapers have been proposed and some have been successful
in the marketplace.
In the usual disposable diaper there are at least two fibrous
layers and at least one impervious plastic sheet as the outermost
layer to prevent the passage of urine into the bed clothes or outer
garments when the diaper is in use. The reason for the use of at
least two fibrous layers is that the properties desired for the
layer in contact with the infant's skin are at variance, to a large
extent, with the properties desired for the portion of the diaper
which is not in direct contact with the infant's skin. In the layer
intended to be in contact with the infant's skin, generally called
th "facing" layer, the properties desired are strength, smoothness,
and freedom from shedding or dusting. In the layer of the diaper
spaced from the infant's skin the properties desired are high
absorbency and low cost. The latter properties are conveniently
found in the fibrous batts made of loosely compacted short
cellulosic fibers and such batts have very little integral strength
and have a substantial tendency to lose fibers by dusting.
From the standpoint of cost and simplicity of fabrication it would
be advantageous to have a single fibrous layer which could serve
the functions of both the facing layer and the absorbent layer.
However, prior to this invention, the satisfactory performance of
both the facing function and the absorbent function could not be
achieved in a single fibrous layer.
SUMMARY OF THE INVENTION
In accordance with the present invention, a highly porous loosely
compacted batt comprised at least primarily of short cellulosic
fibers is treated with a liquid resinous binder in certain
localized portions to provide a facing surface having the desired
strength and the smoothness, and to provide spaced reinforcement to
the loosely compacted batt. Specifically, this invention provides a
multi-layered disposable diaper having only one fibrous layer and
comprising (1) a highly porous batt comprised at least primarily of
short cellulosic fibers, and (2) a water-impervious backing sheet
adjacent one surface of said batt and bonded thereto in spaced
areas of adhesion, the fibers of said batt being bonded together by
a resinous binder covering the surface opposite said backing sheet
and extending throughout the thickness of said batt in spaced
linear areas.
It has been found that upon solidification of the liquid resinous
binder on the surface opposite the water-impervious backing sheet,
the strength and smoothness of the batt surface is enhanced. It has
also been found that upon the solidification of the liquid resinous
binder which has been forced or otherwise moved through the
thickness of the batt in the spaced linear areas the overall
strength of the batt is enhanced without materially detracting from
its absorbent capacity.
In a preferred embodiment of this invention, a paper-like,
densified, highly compacted layer, or skin, may be formed on the
loosely compacted batt on the surface adjacent the water-impervious
backing sheet and opposite the surface to which the resinous binder
is applied. The paper-like, densified, highly-compacted cellulosic
fibrous layer, or skin, is integral with the loosely compacted batt
and is made by lightly moistening the surface of the batt on which
the skin is to be formed and thereafter compressing the batt
between compression rolls. The paper-like, densified skin is of
substantially higher density than the remainder of the loosely
compacted batt and therefore tends to draw urine discharge from the
remainder of the loosely compacted batt and to spread it laterally
within the skin layer away from the point of discharge and toward
the edges of the batt. In this manner, a limited discharge of urine
is kept as far away as possible from the infants's skin. The
purpose of the paper-like densified skin and the manner of its
formation is described in more detail in our U.S. Pat. No.
3,612,055, issued Oct. 12, 1971 on application Ser. No. 6,864,
filed Jan. 29, 1970.
The fibers of the loosely compacted batt may be composed entirely
of short cellulosic fibers, or may combine short cellulosic fibers
with textile length fibers, either uniformly throughout the
thickness of the batt, or nonuniformly with different relative
proportions of short fibers and textile length fibers in different
thickness portions of the batt, as described in more detail
below.
DESCRIPTION OF THE DRAWINGS
This invention is more readily understood by reference to the
drawings, in which:
FIG. 1 is a plan view of the diaper of this invention;
FIG 2 is an enlarged fragmentary cross-sectional view of the
preferred embodiment of the diaper of this invention, taken along
plane 2--2 of FIG. 1; and
FIG. 3 is an enlarged fragmentary cross-sectional view of another
embodiment of the diaper of this invention in which a mixture of
fibers is used, the mixture varying in proportions in different
thickness portions of the fibrous batt.
DETAILED DESCRIPTION OF THE INVENTION
Referring to the drawings, the diaper assembly 10, comprises a
lowermost water-impervious sheet 11 which is rectangular in shape
and a highly water absorbent fibrous pad, or batt 12 which is also
rectangular in shape and coextensive with the impervious sheet. The
batt and the impervious sheet are adhered to each other at adhesive
areas 13 (shown as shaded areas in FIG. 1) along the side margins
of the impervious sheet and the batt.
At the surface of the batt adjacent the impervious sheet there is a
paper-like densified layer 14 which is an integral portion of the
batt and which serves to enhance its strength. In addition, the
paper-like densified skin has a greater attraction for urine
discharge than the loosely compacted remainder of the batt and
tends to draw within itself and to spread rapidly any urine
discharged into the loosely compacted portion of the batt.
At the free surface of the batt, the surface opposite the
paper-like densified skin 14, there is a smooth skin 16 formed by
the surface fibers of the batt bonded to each other by a resinous
binder. There is a series of grooves 17 in skin 16 which, in the
particular embodiment shown in the drawings, produces a diamond
shaped pattern, as shown in FIG. 1. Immediately below each groove
17 there is a wall of binder 18 extending throughout the thickness
of the batt. The binder walls are in spaced linear areas,
sufficiently close to each other to provide strength reinforcement
to the batt. Binder walls 18 are generally from about 1/2 to about
11/2 inches apart.
Batt 13 is formed of loosely compacted short cellulosic fibers,
such as wood pulp fibers, or cotton linters, or mixtures thereof.
In the major portion of the volume of the batt (the portion outside
of the densified skin 14, the binder-impregnated pattern 16 and the
binder walls 18) the cellulose fibers are primarily held together
by interfiber bonds, as is known in the art. Briefly, this batt,
outside of the paper-like skin 14 and the resin bonded portions 16
and 18 is a low bulk density coherent web of loosely compacted
cellulose fibers preferably comminuted wood pulp fibers in the form
of so-called "fluff."
The term "short fibers," as used herein, refers to fibers less than
about 1/4 inch in length, in contrast to "long fibers", or "Textile
length fibers" which are longer than about 1/4 inch in length, and
generally are between about 1/2 and 21/2 inches in length. The
former are substantially less costly than the latter. The
classification of fibers by length may be carried out by the Clark
Classification procedure described in the test manual of The
Technical Association of Pulp and Paper Industry (TAPPI-T233
SU64).
The composite density of batt 12, including its densified layer 14
and including its resin-impregnated portions 16 and 18 should be
above about 0.07 gm./cc., and preferably between about 0.10 and
0.15 gm./cc. The foregoing density values are applicable to the
diaper as produced. In storage and handling, the loft or thickness
of the batt is increased to some extent, resulting in lowered
densities.
An important aspect of this invention is the provision for
selective wettability between different portions of the fibrous
batt, such that the liquid discharge is selectively drawn from the
resin-impregnated surface 16 into the unimpregnated portions of the
batt and then from the unimpregnated, loosely compacted portions in
the body of the batt into the densified layer thereof.
The least wettable portion of the batt is the resin-impregnated
surface 16 since the resinous binder tends to be hydrophobic.
However, even in the resin-impregnated surface, the ability to be
wetted by water is desired. Water repellency in surface 16 is not
desired since it can prevent the liquid from penetrating into the
loosely compacted absorbent portion of the batt behind the surface,
just as a tent fabric can hold back the penetration of rain water.
For this reason, a wetting agent, such as an anionic surfactent, is
included in the resinous binder to moderate and reduce its water
repellency. Surface 16, after treatment with a resinous binder
containing a wetting agent, is receptive to penetration by urine
but remains less wettable than unimpregnated portions of the
batt.
When the diaper is in use and urine is passed by the infant wearing
it, the urine passes through the relatively unwettable
binder-impregnated fibers at surface 16 and into the highly
wettable fibers in the body of batt 12. The urine then passes into
the densified layer which is made of the same highly wettable
fibers as the body of batt 12, but which has enhanced wicking power
for the urine because of its higher density. The urine in the
densified layer spreads through a substantial area in the densified
layer before any substantial amount flows back into the body of the
batt and thereafter spreads through a substantial area in the body
of the batt before any substantial amount flows back through
surface 16. Thus, the diaper of this invention acts to keep urine
away from the infant's skin as long as possible in the same manner
as the more complex and more expensive diapers made from a
plurality of fibrous components.
The diaper is also strong and resistant to dusting because of the
binder at its outer surface and in the spaced linear areas.
The nature of the binder material used in accordance with this
invention is not critical. Binder materials may be either
thermoplastic or thermosetting, the latter being preferred for
diapers intended to be heat-sterilized. Preferably, the binder
material is in the form of an aqueous emulsion or latex.
One binder that has been employed successfully is a
self-cross-linking latex of a polyethylacrylate containing small
amounts of acrylonitrile and a cross-linking monomer sold under the
trademark 2600X120. The binder latex is preferably of a low
viscosity type with a viscosity less than 5 centipoises.
Application of the binder composition to the surface of the batt to
the batt interior without penetration of the binder may be in the
form of a fine spray. Preferably, the binder application is applied
in the form of a froth or foam. By its nature, the foam wets the
entire surface of the batt without spreading to the batt interior.
The foam cells break on the fibrous surface to form, after curing,
a network of bonded fibers over the entire surface of the batt.
The binder composition, as stated above, preferably contains a
surfactant to avoid water-repellency in the binder-treated fibers.
In addition, the surfactant can act as a foaming agent when the
binder composition is to be used in the form of a foam.
Suitable surfactants are the alkyl aromatic sulfonates, fatty alkyl
sulfates, sulfated oils, sulfated esters, petroleum sulfonates,
carboxylic acid soaps, quaternary ammonium compounds, amine salts,
and the like. Specific surfactants suitable for producing foam are
dodecyl benzene sulfonate, sodium stearyl sulfopropionate, lauryl
alcohol sulfonate, monostearylethylenediamine and trimethyl
ammonium methyl sulfate. A typical surfactant which has been found
to be suitable is the ionic sulfonated alkyl ester sold under the
trademark Triton GR-5. The amount of surfactant used may be varied
over relatively wide limits of from about 0.18 to about 5 percent
based on the weight of the binder, though it is preferred that from
about 0.5 percent to 21/2 percent of surfactant be used in
producing the foamed binder.
The desired binder distribution in the batt used in the diaper of
this invention is obtained by compressing the web from which the
batt is made between a smooth compression roll (on the dry side of
the batt) and a compression roll having ridges corresponding to the
spaced linear areas in which the binder is to be distributed (on
the side of the batt wet with binder). Compression in the localized
linear areas forces liquid binder material from the surface of the
web into the body of the web and through its entire
thicknesses.
Suitable apparatus for making the batt is similar to that shown in
U.S. Pat. No. 3,444,859, issued May 20, 1969 to Frank Kalwaites,
except that foam is applied to only one side of the web and the
compression rolls are of the type described above, one roll being
smooth and the other having ridges.
In the preferred embodiment in which the batt includes a densified,
paper-like layer, the layer is preferably formed on the web from
which the batt is made prior to the application of binder
thereto.
The backing sheet may be placed in juxtaposition to the web from
which the batt is made before the application of binder and the
application of localized pressure to force the binder into and
through the web. In this case, the binder, upon compression, will
come into contact with the backing sheet in the areas of
compression and will, after curing, serve to adhere the batt to the
backing sheet in the localized areas.
In another embodiment, the application of binder, the application
of localized pressure to force the binder into and through the web
and the curing of the binder takes place before the backing sheet
is applied to the web. In this case, the web and backing sheet are
adhered to each other independently of the linear areas of the web
which contain binder. The adhesion of the web to the backing sheet
may be by lines, dots or other discontinuous areas of adhesion
distributed throughout the area of contact between the web and the
backing sheet, it may be by marginal areas of adhesion either
completely around the outer edges of the diaper, or (as shown in
FIG. 1) only on the side edges.
In another embodiment of this invention, textile length fibers may
be used in combination with the short cellulosic fibers in the
loosely compacted batt to provide added strength and better feel.
The textile fibers may range in length from about 1/2 inch to about
21/2 inches and may be of either uniform or non-uniform lengths.
Suitable textile fibers are those of rayon, polyester, cellulose
acetate, nylon, etc.
The textile length fibers may be uniformly blended with the short
fibers by air laying techniques in weight proportions up to about
25 percent, as disclosed in Liloia et al, U.S. Pat. No. 3,663,348,
issued May 16, 1972, the disclosure of which is hereby incorporated
by reference.
Alternatively, and as illustrated in FIG. 3, the textile fibers may
be blended in a non-uniform manner so that the proportion of short
and long fibers varies at different thicknesses. In such
non-uniform blends, it is preferable that an enriched concentration
of textile fibers be present at face 26, opposite backing sheet 21,
so that strength and smoothness are provided at the outermost face.
Face 26 has grooves 27, similar to groves 17 of FIG. 2, and is
impregnated into resin to a short depth near face 26.
The remainder of batt 22 has a lower proportion of long fibers and
has spaced resin-impregnated areas 28, similar to areas 18 of FIG.
2. The batt is adhered to the backing sheet at areas 23 similar to
areas 13 of FIG. 2.
Batts of the nature of batt 22 may be prepared by any of several
methods. A preferred method utilizes separate feeds of short and
long fibers to each of two counter-rotating lickerins from which
the fibers are picked up in separate gas streams and thrown toward
each other so that they cross over each other before the fibers are
deposited onto a foraminous belt below the lickerins. Such methods
are described in the copending, coassigned application of Ruffo et
al, Ser. No. 108,546, filed Jan. 21, 1971, the disclosure of which
is hereby incorporated by reference. Webs of the nature of those
disclosed in said Ruffo et al application have a concentration of
long fibers in excess of the overall concentration at face 26, a
concentration of short fibers in excess of the overall
concentration at the face adjacent the backing sheet and a gradual
transition between these faces.
In still another embodiment of this invention, batt 22, instead of
being substantially uniform thickness as shown in the drawings, may
be shaped to be thicker in its mid-portion in transverse cross
section and thinner near its side edges. A batt of this type is
advantageous in that it is more conformable when wrapped around an
infant and in that it concentrates the maximum weight of absorbent
in the portion of the diaper most likely to be the site of
wetting.
Batts having a shaped transverse contour with a peak at the
mid-portion may be made in several ways. For example, the method of
the aforementioned Kalwaites U.S. Pat. No. 3,444,869 may be
modified by feeding two pulp boards to hammer mill 12 rather than
the single pulp board 11 and centrally disposed therewith.
Alternatively, the opening below the hammer mill and above the belt
may be diamond-shaped, or octagonal so that the center line of
conveyor 13 is under the opening for a longer period than the sides
of the conveyor and thus gets more of a deposit of fibers.
In the embodiment of the invention described above the resinous
binder has been applied solely to the surface of the batt opposite
the surface adjacent the backing sheet. In some cases, however, it
may be desirable to apply the resinous binder to both surfaces of
the batt before bringing the batt into contact with the backing
sheet so that the application of pressure in the localized linear
areas forces the liquid binder from both surfaces into the interior
of the batt and throughout its thickness in those localized areas.
In this embodiment, a smaller amount of binder is required on the
surface opposite the backing sheet since the binder is forced
inwardly from both surfaces; and this embodiment may be preferred
with binders tending to impart a harsh feel to the outer surface
when used thereon in greater amounts.
It will be understood by those skilled in the art that other
variations and modifications of the specific embodiments described
above may be employed without departing from the scope of the
invention as defined in the appended claims.
* * * * *