U.S. patent number 3,902,946 [Application Number 05/380,738] was granted by the patent office on 1975-09-02 for photoflash lamp and method of coating same.
This patent grant is currently assigned to GTE Sylvania Incorporated. Invention is credited to Emery G. Audesse, Harold L. Hough.
United States Patent |
3,902,946 |
Audesse , et al. |
September 2, 1975 |
Photoflash lamp and method of coating same
Abstract
In a photoflash lamp having a vacuum-formed thermoplastic
coating over its glass envelope for providing reinforcement, a
silicone mold release agent is disposed between the plastic coating
and glass envelope to relieve high localized stresses and provide a
more uniform compressive loading on the glass. In a method for
applying the thermoplastic coating, the silicone release agent is
sprayed onto the glass envelope of the lamp before it is located in
a preformed sleeve of the thermoplastic material, which is
subsequently vacuum-formed onto the glass envelope.
Inventors: |
Audesse; Emery G. (Salem,
MA), Hough; Harold L. (Beverly, MA) |
Assignee: |
GTE Sylvania Incorporated
(Danvers, MA)
|
Family
ID: |
26964623 |
Appl.
No.: |
05/380,738 |
Filed: |
July 19, 1973 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
287724 |
Sep 11, 1972 |
3770366 |
|
|
|
Current U.S.
Class: |
156/198; 156/267;
156/287; 156/294; 264/571; 431/360; 156/213; 156/286; 156/289;
264/516; 427/106 |
Current CPC
Class: |
F21K
5/02 (20130101); Y10T 156/1005 (20150115); Y10T
156/108 (20150115); Y10T 156/103 (20150115) |
Current International
Class: |
F21K
5/08 (20060101); F21K 5/00 (20060101); B65B
031/02 () |
Field of
Search: |
;156/84-86,213,229,285,289,294,267,286,287 ;206/316,418
;431/94,95,92,93 ;65/270,110 ;117/72 ;215/12R,12A,11E
;264/90,92,264 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Van Horn; Charles E.
Assistant Examiner: Frisenda, Jr.; F.
Attorney, Agent or Firm: Coleman; Edward J.
Parent Case Text
This is a division, of application Ser. No. 287,724, filed Sept.
11, 1972 now U.S. Pat. No. 3770366.
Claims
What we claim is:
1. A method of coating the glass envelope of a photoflash lamp with
a light-transmitting thermoplastic material, said method
comprising:
applying a thin film coating of a lubricating release agent on the
exterior surface of said glass envelope, said release agent being
clear and substantially inert with respect to said glass and
thermoplastic,
placing said film coated glass envelope within a preformed sleeve
of said thermoplastic material, and
drawing a vacuum in the space between said thermoplastic sleeve and
said film coated glass envelope, while simultaneously
heating said sleeve and envelope assembly incrementally along the
length thereof, whereby the temperature and vacuum cause said
thermoplastic sleeve to be incrementally formed onto said film
coated glass envelope.
2. The method of claim 1 wherein heat is applied uniformly about
said sleeve and envelope assembly by one or more localized sources
of heat encircling said assembly, and said assembly is indexed
through a plurality of heating stations, each of which has said one
or more localized sources of heat positioned at successively higher
elevations.
3. The method of claim 1 including the further step of prebaking
said thermoplastic sleeve to remove the mositure therefrom prior to
assembling said sleeve with said film coated glass envelope.
4. The method of claim 1 including the further steps of
constricting and tipping off said vacuum formed sleeve at the
conclusion of said incremental heating process.
5. The method of claim 1 wherein said release agent is a silicone
mold release agent.
6. The method of claim 1 wherein said release agent is applied by
spraying it onto the exterior surface of said glass envelope.
7. A method of coating the glass envelope of a photoflash lamp with
a light transmitting thermoplastic material, said method
comprising:
applying a thin film coating of a lubricating release agent on the
interior surface of a preformed sleeve of said thermoplastic
material, said release agent being clear and substantially inert
with respect to said glass and thermoplastic,
placing said glass envelope within said interiorly coated sleeve of
thermoplastic material,
and drawing a vacuum in the space between said interiorly coated
thermoplastic sleeve and said glass envelope, while
simultaneously
heating said sleeve and envelope assembly incrementally along the
length thereof, whereby the temperature and vacuum cause said
interiorly coated thermoplastic sleeve to be incrementally formed
onto said glass envelope.
8. The method of claim 7 including the further step of prebaking
said thermoplastic sleeve to remove the moisture thereof prior to
applying said coating of mold release agent thereon.
9. The method of claim 7 wherein said release agent is a silicone
mold release agent.
10. The method of claim 7 wherein said release agent is applied by
spraying it onto the interior of said preformed sleeve of
thermoplastic material.
Description
BACKGROUND OF THE INVENTION
This invention relates to photoflash lamps and, more particularly,
to an improved protective coating for flashlamps and a method for
applying such a coating.
A typical photoflash lamp comprises an hermetically sealed glass
envelope, a quantity of combustible material located in the
envelope, such as shredded zirconium or hafnium foil, and a
combustion supporting gas, such as oxygen, at a pressure well above
one atmosphere. The lamp also includes an electrically or
percussively activated primer for igniting the combustible to flash
the lamp. During lamp flashing, the glass envelope is subject to
severe thermal shock due to hot globules of metal oxide impinging
on the walls of the lamp. As a result, cracks and crazes occur in
the glass and, at higher internal pressures, containment becomes
impossible. In order to reinforce the glass envelope and improve
its containment capability, it has been common practice to apply a
protective lacquer coating on the lamp envelope by means of a dip
process. To build up the desired coating thickness, the glass
envelope is generally dipped a number of times into a lacquer
solution containing a solvent and a selected resin, typically
cellulose acetate. After each dip, the lamp is dried to evaporate
the solvent and leave the desired coating of cellulose acetate, or
whatever other plastic resin is employed.
In the continuing effort to improve light output, higher
performance flashlamps have been developed which contain higher
combustible fill weights per unit of internal envelope volume,
along with higher fill gas pressures. In addition, the combustible
material may be one of the more volatile types, such as hafnium.
Such lamps, upon flashing, appear to subject to glass envelopes to
more intense thermal shock effects, and thus require stronger
containment vessels. One approach to this problem has been to
employ a hard glass envelope, such as the borosilicate glass
envelope described in U.S. Pat. No. 3,506,385, along with a
protective dip coating. Although providing some degree of
improvement in the containment capability of lamp envelopes, the
use of dip coatings and hard glass present significant
disadvantages in the areas of manufacturing cost and safety.
To overcome these disadvantages, a more economical and
significantly improved containment vessel for flashlamps is
described in a copending application Ser. No. 268,576, filed July
3, 1972 and assigned to the assignee of the present application.
According to this previously filed application, a thermoplastic
coating, such as polycarbonate, is vacuum formed onto the exterior
surface of the glass envelope. The method of applying the coating
comprises: placing the glass envelope within a preformed sleeve of
the thermoplastic material; drawing a vacuum in the space between
the thermoplastic sleeve and the glass envelope; and,
simultaneously heating the assembly incrementally along its length,
whereby the temperature and vacuum cause the thermoplastic to be
incrementally formed onto the glass envelope with the interface
substantially free of voids, inclusions and the like. This method
provides an optically clear protective coating by means of a
significantly faster, safer and more economical manufacturing
process, which may be easily integrated on automated production
machinery. The process permits use of the stronger, more
temperature resistant thermplastics, and the resulting coating
maintains the glass substrate under a compressive load, thereby
making the glass envelope itself more resistant to failures. As a
result, this coating reduces the cost of materials by permitting
the use of soft glass to meet high containment requirements.
The thermoplastic material is selected to have a coefficient of
thermal expansion several times greater than the coefficient of
thermal expansion of the glass envelope. Hence, as the
thermoplastic coating cools from the softening temperature
subsequent to vacuum forming, it will exert a compressive load on
the envelope to thereby in effect strengthen the glass. For
example, the thermoplastic coating may exert a compressive load of
from 1000 to about 4000 pounds per square inch on the glass
envelope. Although the glass becomes stronger with a higher
compressive load, an increase in the compressive loading on the
glass results in a corresponding increase in the tensile loading on
the coating. Typically, these tension stresses in the coating may
be approximately 2000 to 3000 pounds per square inch. In itself,
this loading appears acceptable if uniform throughout the coating.
In actual practice, however, higher localized stresses appear to
develop, probably due to irregularities in the glass, friction
between the plastic and glass, and irregularities on the inner
surface of the plastic.
SUMMARY OF THE INVENTION
In view of the foregoing, a principal object of this invention is
to provide a photoflash lamp having a vacuumformed thermoplastic
coating to reinforce the glass envelope wherein high localized
stresses in the coating are relieved and a more uniform compressive
loading on the glass is provided.
Another object is to provide an improved containment vessel for a
flashlamp.
A further object is to provide an improved method for coating the
glass envelope of a photoflash lamp with a thermoplastic
material.
These and other objects, advantages and features are attained, in
accordance with the invention, by disposing a lubricating release
agent between the vacuum-formed thermoplastic coating and the glass
envelope. The improved method comprises; applying a thin film
coating of mold release agent on the exterior surface of the glass
envelope; placing the film coated glass envelope within the
preformed sleeve of thermoplastic material; drawing a vacuum in the
space between the thermoplastic sleeve and the film coated glass
envelope; and, simultaneously heating the assembly incrementally
along its length, whereby the temperature and vacuum cause the
thermoplastic to be incrementally formed onto the film coated glass
envelope.
Alternatively, the mold release agent may be coated on the interior
surface of the preformed thermoplastic sleeve prior to assembly
with the glass envelope.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention will be more fully described hereinafter in
conjunction with the accompanying drawings, in which:
FIG. 1 is an enlarged sectional elevation of a percussive-type
photoflash lamp having a protective coating in accordance with the
invention;
FIG. 2 is an enlarged sectional elevation of a preformed sleeve of
thermoplastic adapted for assembly and vacuum forming onto the film
coated glass envelope of a percussivetype photoflash lamp;
FIG. 3 illustrates the step of aerosol spraying a thin film coating
of mold release agent on the exterior surface of the lamp envelope,
in accordance with the invention;
FIG. 4 is an enlarged elevation, partly in section, showing a
percussive flashlamp assembled in the thermoplastic sleeve of FIG.
2 prior to vacuum forming;
FIG. 5 is a simplified fragmentary elevation, partly in section, of
the vacuum forming apparatus, this view illustrating the
simultaneous vacuum drawing and heating steps;
FIG. 6 illustrates the constricting step carried out by the
apparatus of FIG. 5; and
FIG. 7 illustrates the tipping off step carried out by the
apparatus of FIG. 5.
DESCRIPTION OF PREFERRED EMBODIMENT
The present invention comprises an improvement over the lamp and
method described in the aforementioned copending application Ser.
No. 268,576, and in like manner, its teachings are applicable to
either percussive or electrically ignited photoflash lamps of a
wide variety of sizes and shapes. For purposes of example, FIG. 1
illustrates a percussive-type photoflash lamp embodying the
principles of the invention.
Referring to FIG. 1, the percussive lamp comprises a length of
glass tubing defining an hermetically sealed lamp envelope 22
constricted at one end to define an exhaust tip 24 and shaped to
define a seal 26 about a primer 28 at the other end thereof. The
primer 28 comprises a metal tube 30, a wire anvil 32, and a charge
of fulminating material 34. A combustible 36, such as filamentary
zirconium or hafnium, and a combustion supporting gas, such as
oxygen, are disposed within the lamp envelope, with the fill gas
being at a pressure of greater than one atmosphere. As will be
detailed hereinafter, the exterior surface of glass envelope 22 is
covered by a vacuum-formed thermoplastic coating 46, with a
lubricating release agent 47 disposed between the thermoplastic
coating and glass envelope in accordance with the invention.
The wire anvil 32 is centered within the tube 30 and is held in
place by a circumferential indenture 38 of the tube 30 which loops
over the head 40, or other suitable protuberance, at the lower
extremity of the wire anvil. Additional means, such as lobes 42 on
wire anvil 32 for example, may also be used in stabilizing the wire
anvil supporting it substantially coaxial within the primer tube 30
and insuring clearance between the fulminating material 34 and the
inside wall of tube 30. A refractory bead 44 is fused to the wire
anvil 32 just above the inner mouth of the primer tube 30 to
eliminate burn-through and function as a deflector to deflect and
control the ejection of hot particles of fulminating material from
the primer.
Typically, the lamp envelope 22 has an internal diameter of less
than 1/2 inch, and an internal volume of less than 1 cc., although
the present invention is equally suitable for application to larger
lamp sizes.
Operation of the percussive-type lamp of FIG. 1 is initiated by an
impact onto tube 30 to cause deflagration of the fulminating
material 34 up through the tube 30 to ignite the combustible 36
disposed within the lamp envelope.
The improved coating method will now be described with reference to
FIGS. 2-7. For purposes of example, the method will be described
with reference to vacuum forming a thermoplastic coating on the
percussive lamp of FIG. 1, although it will be understood that a
similar method may be employed with an electrically ignited lamp.
Referring first to FIG. 2, the thermoplastic material to be coated
on the exterior surface of the lamp envelope is initially provided
as a preformed sleeve 48 having the shape of a test tube. To
facilitate passage of the coaxially projecting primer tube 30,
sleeve 48 is provided with a single coaxially disposed hole 50.
Sleeve 48 may be formed by a molding process, and to minimize
possible checks and crazes in the plastic upon being vacuum formed
to the glass envelope, the preformed sleeve 48 should be prebaked
at about 125.degree.C for at least 15 minutes to drive away
residual moisture prior to assembly with the glass envelope.
In accordance with the present invention, before assembling the
sleeve on the envelope, a thin film coating of a clear mold release
agent 47 is applied on the exterior surface of the glass envelope
22. Preferably, the release agent 47 is applied by means of an
aerosol spray 51, as illustrated in FIG. 3, although other methods
of application, such as by dipping in a solvent solution or by
agitating in a dry release agent powder may be employed. The
material 47 may comprise any lubricating release agent which is
clear and substantially inert with respect to the glass envelope 22
and the thermoplastic sleeve 48. A silicone mold release agent has
been found to be particularly suitable for this application.
In the next step, shown in FIG. 4, the film coated glass envelope
22 of the percussive lamp is placed within the preformed
thermoplastic sleeve 48, with the primer tube 30 projecting through
hole 50. It will be noted that both the sleeve 48 and the lamp
envelope 22 have generally tubular sidewalls. To facilitate the
vacuum forming process, the fit should be as close as possible.
Accordingly, the outside diameter of the tubular envelope 22 and
the inside diameter of the tubular sleeve 48 are dimensioned so
that, when the envelope is placed within the sleeve, there exists a
clearance x of from 0.001 to 0.015 inch between the tubular
sidewalls thereof prior to heating and vacuum forming.
The next step, heating and vacuum forming, is illustrated in FIG.
5. The envelope and sleeve assembly 22, 48 is held during the
evacuating and heating processes by means of a chuck 50 gripping
the primer tube 30. Another chuck 52, having an evacuating tube 54,
grips the open end of the thermoplastic sleeve 48. One or more
localized sources of heat, represented by heaters 56, encircle the
envelope and sleeve assembly for uniformly applying heat about the
tubular sleeve in a substantially localized elevational plane. In
operation, the process comprises drawing a vacuum in the space
between the sleeve 48 and envelope 22, while simultaneously heating
the envelope and sleeve assembly incrementally along its length.
More specifically, the vacuum is drawn through the tube 54, in the
direction of the arrow, at the open end of sleeve 48. At the same
time, the heaters 56 are controlled to heat the sleeve to
approximately the softening temperature of the thermoplastic
material. A relative incremental axial movement is effected between
the envelope-sleeve assembly and the heaters, so that incremental
heating in a localized elevational plane starts at the end of the
sleeve 48 through which the primer tube 30 projects, and then
proceeds toward the open end of the sleeve from which the vacuum is
being drawn. In this manner, the temperature and vacuum cause the
thermoplastic sleeve 48 to be formed onto the film coated glass
envelope 22 with the interface therebetween substantially free of
air voids, inclusions and the like.
Referring to FIG. 5, this incremental heating process may be
accomplished at one station by either moving chucks 50 and 52
downward with respect to a set of stationary heaters 56, or by
moving heaters 56 upward with respect to a set of stationary chucks
50 and 52. A preferred method of effecting the incremental heating,
however, is to index the envelope-sleeve assembly through a
plurality of heating stations, with the heaters at each station
positioned at successively higher elevations.
At the conclusion of the incremental heating process, the sleeve 48
is constricted at portion 58, as shown in FIG. 6, by slowly pulling
chucks 50 and 52 away from each other, while continuing to apply
heat and draw a vacuum. Finally, as shown in FIG. 7, the vacuum
formed sleeve 48 on the lamp is separated from the portion 60 of
the sleeve held in chuck 52 and tipped off at point 62, thereby
completing the encapsulation of glass envelope 22 in the
thermoplastic coating 46.
The composition of sleeve 48, and thus coating 46, may be of any
vacuum formable light-transmitting thermoplastic material having a
reasonably high impact strength and softening temperature. Suitable
materials include acrylic, acylonitrile-butadiene-styrene,
cellulose acetate, ionomers, methylpentene polymer, nylon,
polycarbonate, polystyrene, polysulfone, or alloys thereof. In the
case of some of the harder materials, it may also be desirable to
add a small amount (10-20%) of compatible plasticizer to the
composition. Further, commercial blue dyes can be used in the
sleeve for color corrections desirable with various photographic
color film.
As described in the aforementioned copending application, the
thermoplastic material preferably is selected to have a coefficient
of thermal expansion several times greater than the coefficient of
thermal expansion of the glass envelope. In this manner, the
coating 46, provided by the above described vacuum forming process,
will exert a compressive load on the glass envelope 22 to thereby
in effect strengthen the glass and make it more resistant to the
effects of thermal shock and impact. For example, with a
coefficient of thermal expansion at least six times greater than
that for the glass, the thermoplastic coating may exert a
compressive load of from about 1000 to about 4000 pounds per square
inch on the glass envelope.
The added containment strength provided by this compressive loading
may be better understood by briefly considering the effects of the
combustion process. Upon flashing the lamp and igniting the shreds
of combustible, the inner surface of the glass envelope is
subjected to severe thermal shock in the form of impact from hot
globules of metal oxide; for example, zirconium oxide has a melting
point of 2715.degree.C. Each thermal impact against the internal
glass surface produces a thermal stress gradient through the wall
of the glass envelope, which serves as an insulator to the
conducted heat, and causes expansion of the glass. Any
thermoplastic coating on the glass will be under tension (T.sub.D)
and there will be a localized tensile stress (T.sub.x) at the
interface of the coating and glass, opposite the point of globule
impact. The build up of the localized tensile stress T.sub.x by the
thermal stress gradient is what can eventually cause a crack
through the glass wall. On the other hand, the compression loading
(C) which is exerted on the glass envelope by the coating functions
to counteract the tensile loading of T.sub.D and T.sub.x by
delaying the thermal stress gradient through the glass wall; this
may be illustrated as T.sub.D + T.sub.x - C. Accordingly, the
higher the compressive loading, the stronger the glass. Also,
however, an increase in the compressive loading on the glass
results in a corresponding increase in the tensile loading on the
coating. Hence, a compressive load that is too high can be
detrimental to the thermoplastic. Where necessary, the compressive
loading can be relieved by the inclusion of a small amount of
plasticizer in the coating composition and/or filters that alter
the thermal expansion coefficient.
Further, in accordance with the present invention, we have found
that by using a thin film layer 47 of silicone mold release between
the glass and thermoplastic, as described above, the problem of
undesirably high localized stress points in the coating 46 can be
alleviated or substantially minimized. These high localilzed
stresses are believed to be due to interface irregularities and
friction; hence, we feel that the thin film of silicone mold
release acts as a lubricant in the glass-plastic interface, thereby
allowing for slippage between the materials and having the net
effect of reducing high stress points.
Verification of this improvement has been seen by placing the
finished lamp in a 17% solution of ethyl acetate and methanol for 3
minutes. This solvent-stress test simulates the effects of
accelerated aging. The parts without silicone mold release show
multiple checks and crazes, while the parts with mold release are
nearly free of cracks and crazes. A long term test of 100 hours at
150.degree.F in a dry oven shows similar results.
In one typical embodiment of the invention, a percussive flashlamp
of the type shown in FIG. 1 was provided with a clear vacuum-formed
coating 46 of polycarbonate resin having a wall thickness of about
0.020 inch. The lamp contained a combustible fill 36 comprising
19.5 mgs. of shredded zirconium foil and oxygen at a fill pressure
of 8 atmospheres. The tubular envelope 22 was formed of G-1 type
soft glass and had a nominal outside diameter of 0.325 inch. In the
process of coating the lamp, an injection molded sleeve 48 of clear
polycarbonate resin having a nominal inside diameter of 0.340 inch
and a wall thickness of 0.020 was employed. Before placing the lamp
in the sleeve, the glass envelope 22 was sprayed with a silicone
mold release agent. During vacuum forming, the molded sleeve was
incrementally heated to a temperature of about 400.degree.F by a
nitrogen flow serpentine heater. The coefficient of thermal
expansion of soft glass of this type ranges from 85 to 95 .times.
10.sup.-.sup.7 in./in./.degree.C between 20.degree. and 300.degree.
C, whereas the coefficient of thermal expansion of unfilled
polycarbonate between 25.degree. and 140.degree.C is about 660
.times. 10.sup.-.sup.7 in./in./.degree.C. Upon measuring several
sections of lamps made as described above, the average compressive
stress exerted by the coating 46 upon the glass envelope 22 was
found to be about 1300 pounds per square inch. Flashing of a number
of these lamps in both the vertical and horizontal position
exhibited no containment failures.
Although the invention has been described with respect to specific
embodiments, it will be appreciated that modifications and changes
may be made by those skilled in the art without departing from the
true spirit and scope of the invention. For example, instead of
applying the silicone mold release agent 47 to the exterior surface
of the lamp envelope 22, the same results can be achieved by
spraying or otherwise applying the mold release agent on the
interior surface of the preformed thermoplastic sleeve 48. This
step would occur after the step of prebaking the sleeve, but before
assembling the glass envelope within the sleeve.
* * * * *