U.S. patent number 3,902,939 [Application Number 05/312,118] was granted by the patent office on 1975-09-02 for method for forming traffic regulating signs on road surfaces.
Invention is credited to Ludwig Eigenmann.
United States Patent |
3,902,939 |
Eigenmann |
September 2, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Method for forming traffic regulating signs on road surfaces
Abstract
The specification describes a method and a tape material for
adhesively securing a traffic regulating sign or mark on a road
surface, provided by laying on and pressing against a primer layer,
preliminarily provided on a road surface, a tape material having a
lower face designed to be juxtaposed on said primer layer, wherein
said tape material lower face is provided with a lower layer of a
compound which is not sticky at ambient temperature and comprises
at least one component adapted to be modified and impart
adhesiveness to said lower face, upon a thermal or physical or
chemical action exerted by said primer layer upon actual contact of
the tape material therewith by means of a resulting interfacial
inter-exchange relationship.
Inventors: |
Eigenmann; Ludwig (Vacallo,
Canton Ticino, CH) |
Family
ID: |
11234547 |
Appl.
No.: |
05/312,118 |
Filed: |
December 4, 1972 |
Foreign Application Priority Data
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Dec 2, 1971 [IT] |
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31966/71 |
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Current U.S.
Class: |
156/71; 156/320;
156/337; 404/77; 404/79; 404/94; 523/172; 524/71 |
Current CPC
Class: |
E01F
9/578 (20160201) |
Current International
Class: |
E01F
9/08 (20060101); E01F 9/04 (20060101); E01F
009/04 () |
Field of
Search: |
;404/77,79,82,92,94,95
;260/2R ;156/71,523,320,337,526,575 ;117/32,54,37R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Whitby; Edward G.
Attorney, Agent or Firm: Striker; Michael S.
Claims
I claim:
1. A method of forming a traffic-regulating indicium on a road
surface, comprising the steps of applying a primer layer to the
road surface; and effecting direct contact between said primer
layer and a substantially non-adhesive surface of a marking strip,
said primer layer and said strip surface cooperating in a manner
such that a transformation effecting bonding between said primer
layer and said strip surface without interposition of a
bond-forming substance between the same, and which transformation
is absent in the absence of said direct contact, occurs in response
to said direct contact.
2. A method as defined in claim 1, wherein said primer layer
comprises at least a substantial proportion of bitumen.
3. A method as defined in claim 1, said primer layer being in a
heated condition when applied to the road surface; and wherein said
direct contact is effected while said primer layer is still in a
heated condition, said transformation occurring due to the heat of
said primer layer and comprising a change in said strip surface
from a substantially non-adhesive condition to an adhesive
condition.
4. A method as defined in claim 1, said primer layer comprising a
solvent for said strip surface; and wherein said transformation
comprises at least partial dissolution of said strip surface.
5. A method as defined in claim 4, wherein said strip surface
comprises a resinous component and said solvent at least partially
dissolves said resinous component.
6. A method as defined in claim 1, wherein said strip surface
comprises a resinous component which is capable of undergoing
cross-linking with at least one component of said primer layer, and
said transformation comprises cross-linking of said one and
resinous components.
7. A method as defined in claim 6, wherein the interface between
said primer layer and said strip surface is in heated condition so
as to promote cross-linking of said one and resinous
components.
8. A method as defined in claim 6, wherein said primer layer
comprises an agent for promoting cross-linking of said one and
resinous components.
9. A method of forming a traffic-regulating indicium on a road
surface, comprising the steps of applying a primer layer to the
road surface, said primer layer including at least one component
which is capable of undergoing cross-linking, and said primer layer
including an agent which promotes cross-linking of said one
component; and effecting direct contact between said primer layer
and a substantially non-adhesive surface of a marking strip, said
strip surface including a resinous component which is capable of
undergoing cross-linking with said one component so that bonding of
said marking strip to said primer layer upon contact between said
strip surface and said primer layer occurs without interposition of
a bond-forming substance between said strip surface and said primer
layer, and the interface between said primer layer and said strip
surface being in heated condition so as to promote cross-linking of
said one and resinous components.
10. A method as defined in claim 9, wherein said primer layer
comprises a minimum of substantially 50 percent by weight of
bitumen.
Description
BACKGROUND OF THE INVENTION
a. The Field of the Invention
This invention is concerned with methods and means for providing a
road surface with traffic regulating signs, generally but not
exclusively consisting of continuous or interrupted lane dividing
or laterally defining lines. More particularly, this invention is
concerned with the art of forming said traffic regulating lines or
signs by laying on and adhesively securing to a preliminarily
prepared road a strip material having a lower face adapted for
juxtaposition and adhesive connection to a prepared and essentially
smoothed area of the road blanket and an upper face for forming the
sign and possessing suitable properties for good visibility, wear
resistance and so on.
B. The Prior Art
These methods are well known in the art and widely published. The
use of factory made strip materials, which can be stocked in coiled
bobbins, carried to the locations where the traffic regulating sign
is to be formed on a road surface and then un-wound to
progressively lay the material on such surface, is very
advantageous. The road surface preparation and the laying down of
the materials can be mechanically made with a minimum of traffic
disturbance.
For most complete details of such art, with relation to the
laying-down machines, the strip material and the road surface
preparation, reference is made to several of Applicant's prior
patents such as U.S. Pat. Nos. 3,007,838, No. 3,155,564, No.
3,235,436, No. 3,262,375 and No. 3,399,607.
The strip material is essentially of elasto-plastic nature and its
body may be formed from a variety of compositions. Examples of such
compositions have been described, among other publications, in the
Applicant's prior U.S. Pat. No. 3,587,415, where the compositions
for forming the "base strip" have been described. In this latter
patent specification there has been described also how the upper
face of the strip material can be advantageously provided with
means for improving its anti-skid properties and its nightime
visibility. Other means for further improving the above and other
properties have been made open to public inspection and knowledge
by the French Pat. Publications No. 2,085,900, No. 2,086,257 and
No. 2,097,941.
In view of the above extensive publications relating to the prior
art of the invention, any further discussion of is superfluous.
The methods and means heretofore proposed and made known are
however subject to certain objections and limitations; such
objections are principally concerned with the provision of an
extremely tacky surface layer at the lower face of the strip
material and/or at the upper layer of the prepared area of the road
blanket, for ensuring a firm adhesive connection. This sticky
surface layer can be factory provided on the lower face of the
strip material and then protected by a paper or plastic film for
preventing the coils of the wound bobbin of the material from
adhering to each other and for facilitating the manipulation of the
material prior to the laying-down thereof, and means are provided
for removing such protective film just prior to laying the material
on the road.
The prior art includes preferably the provision of means for
applying to the upper face of the prepared road blanket or
preferably to the lower face of the strip material a thin layer of
highly viscous adhesive. This provision requires rather costly and
complicated means and devices and a very careful control and
operation of such devices and of the means provided for applying
and spreading the adhesive on such face in measured amount. It has
been also heretofore proposed to provide the layer of the compound,
preliminarily applied on the road blanket for preparing the road
surface prior to laying-down the strip material thereon (such layer
is currently referred to as "primer layer" in the art, and thus
defined as this description proceeds and in the appended claims)
with a tacky upper surface. This method is also seriously
objectionable both because this surface is extremely receptive to
dirt, sand, powder and so on, and because the primer layer, the
width of which is necessarily larger than the sign forming strip or
tape material, will form on the road surface sticky portions at
either side of the applied tape material.
BRIEF SUMMARY OF THE INVENTION
It is therefore a principal object of this invention to provide new
and improved methods, steps, means and materials by which the above
and other objections and limitations of the prior art can be
eliminated or at least greatly reduced.
Essentially, according to the invention, the sign forming tape
material is provided, at its face designed to be contacted with,
juxtaposed and pressed on the upper face of the prepared road
surface, with a layer of a compound which is not sticky at least at
ambient temperature, but capable of providing an adhesive bond with
the upper surface of the primer layer on the road, upon a physical
and/or a chemical modification occurring in the compound adjacent
to the tape material - primer layer interface and promoted by
actual contact and pressure of said sign forming tape material on
said primer layer, said modification occurring by an inter-exchange
originated by said actual contact and occurring through said
interface.
It is therefore a specific object of this invention to provide a
new and advantageous tape material, adapted to be laid on and
adhesively secured to the upper face of a primer layer coating a
selected area of a road surface to form a traffic regulating sign
thereon, the said tape material having a visible sign actuating
upper face, a body of known elasto-plastic nature and a lower face
forming a potentially adhesive lower layer which is not sticky at
ambient temperature and including at least one component capable of
being modified so as to promote a physical bond with said primer
layer when contacted with and pressed on the upper face of said
primer layer.
According to an embodiment of the invention, the said potentially
adhesive lower layer comprises a thermoplastic resinous component
capable of acquiring adhesive properties if thermally plastified,
and the tape material is laid on and pressed over a preliminarily
heated primer layer to promote a heat exchange at said interface,
leading to an adhesive bond between said lower layer of the tape
material and the primer layer on the road surface. The preliminary
heating of the primer layer is preferably provided by forming said
primer layer of a meltable compound and laying the molten compound
on the road surface blanket and then laying the tape material on
the still hot primer layer.
According to another embodiment of the invention, the said
potentially adhesive lower layer comprises a resinous component
capable of chemically reacting in particular to cross-link with
another component present in the primer layer composition to
provide the desired physical bond at said interface. In such
occurrence a heat inter-exchange at said interface can be
preferably provided for promoting and/or accelerating the chemical
reaction.
According to a further embodiment of the invention, the said
potentially adhesive lower layer comprises a resinous component
capable of acquiring sticky properties when partially dissolved by
compatible solvents, and the tape material is laid on and pressed
against a primer layer including an excess of at least one of said
compatible solvents.
Further embodiments of the invention comprise combinations of the
above indicated modes for providing a bond forming inter-exchange
at the interface provided by the actual juxtaposition and pressure
of the potentially adhesive lower layer preliminarily and factory
provided at the lower face of the tape material on the upper face
of a primer layer preliminarily provided on the selected area of
the road surface to be marked.
These and other features and advantages of the invention will be
now made apparent in and by the following description of exemplary
modes of making use of the invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
EXAMPLE 1
Thermally promoted bond.
According to this example, the potentially adhesive lower layer
consists of a rather thin, such as from 0.2 to 0.8 mm, film
applied, during the manufacture of the tape material (or of the
sheet stock material from which the tape material is cut, according
to current art) to the lower face of a sign forming article, the
body and the upper layer of which are in turn made according to the
known art, such as described in any of the prior patents and patent
publications referred to above. The said lower layer is made of a
compound including preferably a synthetic rubber.
The primer layer is made, according to current art, of a compound
prevailingly consisting of bitumen and it is applied on and
smoothed over the road blanket, also according to current art, in
its molten or fluidified state, and the tape material is laid
thereon when the said primer layer is still hot. In some
occurrences, it might be expedient to apply the primer layer well
in advance to the laying down of the tape material; in such
occurrence such primer layer may be re-heated by means of a gas
burner, for example.
The said primer layer has preferably the following composition, in
parts by weight:
Bitumen parts 160 "Chemigum No. 600" (Goodyear) (1) parts 5 Resin
"Eskorez 1101" (Esso) (2) parts 10 Coumarone-indene resin parts 10
Methylene chloride parts 10
The said potentially adhesive layer has preferably the following
composition, in parts by weight also:
EXAMPLE 2
Bond promoted by combined chemico-physical action
In this occurrence, the interfacial bond is prevailingly provided
by a chemical cross-linking promoted between resinous components
appertaining to the potentially adhesive lower layer and
respectively to the primer layer. Such components consist of like
resins or of resins of similar nature and capable of cross-linkage.
Preferably, the resinous component in the said lower layer is
selected from those wherein a suitable hardener (provided in the
compound of the primer layer) is highly soluble. As a consequence
of such provision, when the tape material is contacted with and
pressed on the primer layer, the said hardener is at least partly
transferred through the interface and promotes the cross-linking of
such resinous component, leading to the desired physical bond of
the tape on the primer layer, upon a chemical action.
Of course, more than one reaction promoter can be made use of, such
promoters being chosen from those capable of co-reacting and
operating synergically, said promoters (catalysts, accelerators)
being individually present in the said potentially adhesive layer
and primer layer, so that their co-action and synergy can be
originated by the actual contact between the tape material and the
primer layer only.
By preliminarily heating the primer layer, such as described in
Example 1, a deeper and more intimate bond can be provided at
either side of the interface, upon the thermally promoted
plasticization and softening of the juxtaposed compounds.
The potentially adhesive lower layer of the tape material is
preferably compounded as follows, in parts by weight:
"Chemigum No. 600" parts 60 "Neoprene AD" (DuPont) or "Bayprene"
(Bayer) parts 70 Magnesium oxide parts 4 Resin "Durez 12603"
(Hocker Chem.) (3) parts 60 Zinc oxide parts 5 Baryta parts 60 (3)
as an example of a phenolic resin.
In turn, the primer layer is preferably compounded as follows, in
parts by weight:
Bitumen 40/50 parts 140 Resin "Eskorez 1101" parts 40 "Oronite 128"
(Chevron) (a plasticizer) parts 20 "Desmodur R" (Mayer) (an
isocyanate resin) parts 15 Methylene chloride parts 65
EXAMPLE 3
Bond promoted by use of solvents
The potentially adhesive lower layer of the tape material can be
provided by making use of either of the compounds described in the
Examples 1 or 2. The layer is factory applied to the lower face of
tape (or stock sheet) body, upon plasticization of the compound by
means of suitable solvents, according to current art. These
solvents are eliminated until the lower face of the tape is no
longer tacky, preliminarily to winding the tape onto bobbins for
storage, transportation and application on the road surface.
The ability to adhesively connect itself to the primer layer, by
part of the tape lower layer, is restored by adding to said lower
layer a certain amount of solvent equal or equivalent to those used
for plasticizing the compound, said solvent being present, as an
excess of solvent, in the primer layer. For example, methylene
chloride can be made use of as a plasticizing solvent for the
potentially adhesive lower layer of Example 1, such chloride being
itself the solvent for the primer layer of same Example 1. In this
occurrence, however, the solvent is provided in a greater amount,
that is in excess, in the primer layer compound, for providing the
excess which will be transferred, through the interface, from the
primer layer to the lower face of the tape material laid on and
pressed upon said primer layer, the compound of which comprising,
in this occurrence, from 50 to 60 parts by weight of methylene
chloride.
The most suitable amount of excess solvent can be easily found by
experiments. In general, a greater excess of solvent will be
convenient when operating in summertime or in general at an ambient
temperature of at least 15.degree.C or preferably 20.degree.C. When
the road marking is being made at lower temperature, the use of
more easily volatile solvents, such as a suitable "Freon" (a series
of well known fluorine compounds) is preferred.
The use of solvents for imparting adhesiveness to the lower face of
the tape material, upon contacting it with a road surface, is
extremely simple and, while such use might require a longer time
for having the bond completed and the road sign set for traffic
passage, this specific method can be sometimes preferred in view of
its simplicity, the road marking being possible even by purely
manual operations or by means of the simplest tools.
* * * * *