U.S. patent number 3,902,868 [Application Number 05/303,970] was granted by the patent office on 1975-09-02 for fuel additive and method for improving combustion.
This patent grant is currently assigned to Enercon Corporation International. Invention is credited to Robert M. Zoch, Jr..
United States Patent |
3,902,868 |
Zoch, Jr. |
September 2, 1975 |
Fuel additive and method for improving combustion
Abstract
A fuel additive for addition in a vapor phase to a fuel such as
gasoline in the air/fuel mixing zone of an internal combustion
engine for increasing combustion efficiency in the engine while
reducing the amount of gaseous pollutant emissions. BACKGROUND OF
THE INVENTION The field of this invention is fuel additives for
fuels used in internal combustion engines. It has been recognized
in the past that liquid fuels for internal combustion engines, such
as gasoline, can be improved by the inclusion in the liquid fuel of
an alcohol with water and also other additives, examples of which
are found in U.S. Pat. Nos. 1,412,233; 1,469,053; 1,474,983;
1,504,837; and 1,622,572. In more recent years, it was suggested in
U.S. Pat. No. 2,789,891 that a gasoline fuel system conditioner
should contain an alcohol without water but with a lubricating oil
and other additives, which conditioner would be impossible to
vaporize properly for vapor phase addition, and is added to the
fuel in liquid form. SUMMARY OF THE INVENTION The present invention
relates to a new and improved fuel additive which is added as a
vapor to a fuel such as gasoline in the air/fuel mixing chamber of
an internal combustion engine. The fuel additive includes an
alcohol and water and preferably other selected additives, all of
which are vaporizable in a blend for vapor phase addition to the
engine fuel intake system. In the preferred embodiment, the fuel
additive of this invention in a concentration of from 0.2 to 1.2
volume percent of the fuel, which amount is significantly small as
compared to the amount of fuel while obtaining the advantages over
the prior art of improved combustion efficiency, reduced gaseous
pollutant emissions and volatility.
Inventors: |
Zoch, Jr.; Robert M.
(Dickinson, TX) |
Assignee: |
Enercon Corporation
International (N/A)
|
Family
ID: |
23174484 |
Appl.
No.: |
05/303,970 |
Filed: |
November 6, 1972 |
Current U.S.
Class: |
44/438 |
Current CPC
Class: |
C10L
10/02 (20130101); C10L 1/10 (20130101); C10L
1/125 (20130101); C10L 1/1857 (20130101); C10L
1/1824 (20130101) |
Current International
Class: |
C10L
1/10 (20060101); C10L 1/18 (20060101); C10L
1/12 (20060101); C10l 001/32 () |
Field of
Search: |
;44/51,52,56 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
"Handbook of Chemistry and Physics", College Edition, 45th Edition,
Chemical Rubber Company, 1964, p. C-408.
|
Primary Examiner: Garvin; Patrick P.
Assistant Examiner: Metz; Andrew H.
Attorney, Agent or Firm: Pravel & Wilson
Claims
I claim:
1. A fuel additive for adding in a vapor phase to fuel at the fuel
intake to an internal combustion engine, consisting essentially of
a homogeneous mixture of:
about 20 to about 65 percent by volume at 60.degree.F. of a low
molecular weight aliphatic alcohol;
with the balance being water and additional additives compatible
with said alcohol and vaporizable at approximately the same
temperature in the mixture therewith;
said alcohol being methanol present in an amount of from about 30
to about 65 percent by volume of the additive; and
said balance consists of:
about 10 to about 20% by volume of isopropanol;
about 12 to 18 percent by volume of methyl ethyl ketone;
about 4 to about 12 percent by volume of an aromatic selected from
the group consisting of toluene, xylene, benzene and phenol;
and
with the rest being water.
2. A method of improving fuel combustion in an internal combustion
engine wherein fuel, air and a vapor additive are mixed for
combustion, comprising the steps of:
vaporizing a fuel additive using air to serve as a carrier for said
additive in the vapor phase;
introducing said vapor to fuel and air mixed in the air-fuel mixing
zone of the internal combustion engine; and
said fuel additive consisting essentially of:
about 20 to about 65 percent by volume at 60.degree.F. of a low
molecular weight alcohol;
with the balance being water and additional additives compatible
with said alcohol and vaporizable at approximately the same
temperature in mixture therewith;
said alcohol being methanol present in an amount of from about 30
to about 65 percent by volume of the additive; and
said balance consists of:
about 10 to about 20 percent by volume of isopropanol;
about 12 to 18 percent by volume of methyl ethyl ketone;
about 4 to about 12 percent by volume of an aromatic selected from
the group consisting of toluene, xylene, benzene and phenol;
and
with the rest being water.
3. The method set forth in claim 2, wherein:
the fuel additive is added in a vapor phase in an amount of about
0.2 to about 1.2 percent by volume of the total of the fuel.
Description
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The fuel additive of this invention is a chemical blend which is
injected as a homogeneous vapor into the fuel intake system of an
internal combustion engine using air as a carrier gas. It has been
discovered that by the addition of the fuel additive of this
invention as such vapor mixture to the air/fuel mixing zone of the
internal combustion engine, many advantages are produced, among
which are increased combustion efficiency in the engine, reduced
gaseous pollutant emissions and volatility of the fuel additive.
The quantity of the fuel additive required using the method of this
invention is extremely low and therefore such additive is
economical. In the preferred form of the invention, the additive of
this invention is added as a vapor in an amount of about 8 to about
45 cubic centimeters per gallon of fuel. Stated differently, the
concentration of the fuel additive of this invention with respect
to the gasoline or other primary fuel is from 0.2 to about 1.2% by
volume.
The principal components of the fuel additive of this invention are
an alcohol, preferably methanol, and water. When the alcohol and
water are the only components of the fuel additive of this
invention, the alcohol is present in an amount from about 20 to
about 60% by volume (at 60.degree.F.), and the water is present in
an amount of from about 80 to about 40% by volume. More precisely,
the preferred volume percentages of the fuel additive are about 40%
alcohol and aboout 60% water by volume.
The fuel additive is added to the fuel/air mixture as previously
explained and the optimum amount which is added is about 20 cubic
centimeters per gallon of the gasoline or other internal combustion
fuel. With such method of this invention, employing the fuel
additive of this invention, the combustion efficiency is increased
approximately 12% and hydrocarbon pollutant emissions are reduced
about 70%.
To further optimize the fuel additive of this invention, on the
basis of ignition temperature, limits of flammability, flash point,
latent heat of vaporization, molar heat release, and volatility,
the fuel additive preferably includes other components such as
aliphatic ketones, higher molecular weight alcohols, and aromatic
solvents, in the preferred mixture set forth below:
Component Volume % (60.degree.F) Preferred Range
______________________________________ Methanol 53.8 30 - 65
Isopropanol 16.9 10 - 20 Methyl Ethyl Ketone 14.9 12 - 18 Toluene
6.9 4 - 12 Water 7.5 0 - 45
______________________________________
Instead of methanol as the alcohol in the above composition,
ethanol may be used with substantially the same results with
respect to combustion efficiency, but with a reduced decrease in
the pollutant emissions. Other higher molecular weight alcohols
such as n-butanol, isobutanol, and the pentanols could be used in
place of the isopropanol but with a decreased vaporization of the
water constituents. Several aromatics such as zylene, benzene, or
phenol could be used in place of toluene listed in the above
example. However, the toluene is preferred because of its limits of
flammability and flash point being more satisfactory in the blend.
Other aliphatic ketones such as acetone, methyl proplyl ketone, or
diethyl ketone could be used instead of the methyl ethyl ketone in
the above example of the fuel additive of this invention.
It should be noted that all of the above additives are capable of
being readily vaporized with the alcohol and the water. Such
volatility is extremely important in producing the vapor of the
fuel additive of this invention for use in carrying out the method
of this invention by introducing same into the fuel/air mixing zone
of the internal combustion engine. Additionally, the preferred
mixture of this invention is capable of being vaporized at a
constant vapor composition, which means that the mol fraction ratio
of the components remain essentially constant. This is also
important in providing consistently improved engine operation as
the additive is being used.
* * * * *