U.S. patent number 3,897,356 [Application Number 05/336,771] was granted by the patent office on 1975-07-29 for windshield wipers containing nonionic surfactant.
This patent grant is currently assigned to Scott Paper Company. Invention is credited to Alex Pociluyko.
United States Patent |
3,897,356 |
Pociluyko |
July 29, 1975 |
Windshield wipers containing nonionic surfactant
Abstract
Paper towels especially towels having wet strength derived from
cationic wet-strength resins are useful for wiping glass surfaces
such as windshields of motor vehicles and this usefulness is
significantly improved by the incorporation onto the paper towel of
a non-ionic surfactant especially ethoxylates of linear secondary
alcohols. Preferably the linear alkyl hydrophobe portion of a
mixture of secondary alcohols having 11 to 15 carbon atoms and the
hydrophylic portion is a polyethylene oxide chain randomly attached
to the linear aliphatic chain and having approximately 15 ethylene
oxide units.
Inventors: |
Pociluyko; Alex (Glen Mills,
PA) |
Assignee: |
Scott Paper Company
(Philadelphia, PA)
|
Family
ID: |
23317588 |
Appl.
No.: |
05/336,771 |
Filed: |
February 28, 1973 |
Current U.S.
Class: |
15/104.93;
510/180; 510/506 |
Current CPC
Class: |
C11D
1/72 (20130101); C11D 17/049 (20130101); A47L
1/15 (20130101); A47L 13/16 (20130101) |
Current International
Class: |
A47L
1/15 (20060101); A47L 1/00 (20060101); A47L
13/16 (20060101); C11D 1/72 (20060101); C11D
17/04 (20060101); C11d 017/04 (); C11d
001/72 () |
Field of
Search: |
;252/91,DIG.1,89 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
McCutcheon's Detergents and Emulsifiers, 1971 Annual, page 183,
Allured Publishing Corporation (1971) Ridgewood, N.J., TP
990.D4..
|
Primary Examiner: Sebastian; Leland A.
Assistant Examiner: Miller; E. A.
Attorney, Agent or Firm: DeBenedictis; Nicholas J. Kane;
John W.
Claims
What is claimed:
1. A wiper for glass surfaces consisting essentially of a
wet-strengthened paper sheet containing an active amount of a
nonionic detergent surfactant of the following general formula:
##EQU5## wherein x and y are integers each having a value of from 0
to 14 and the sum of x plus y is from 10 to 14.
2. The paper sheet of claim 1 wherein the activating amount of
detergent surfactant is from about 0.01 to about 2.0%, based upon
the dry weight of the paper.
3. A wiper for glass surfaces consisting essentially of
wet-strengtened paper sheet containing an active amount of a
non-ionic detergent surfactant wherein the non-ionic detergent
surfactant is an ethoxylated secondary alcohol produced by
ethoxylating a mixture of linear secondary alcohols containing from
11 carbon atoms to 15 carbon atoms with a hydrophylic moiety
containing 15 ethylene oxide groups.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to nonionic detergents surfactants on wet
strength paper towels in particularly to ethoxylated secondary
alcohols on paper towels having cationic wet strength resins.
2. Description of the Prior Art
Prior art paper towels designed for wiping purposes have been
altered usually both chemically and physically to improve the
wiping action. For example, wet strength chemicals (resins) have
been added to the towels to retain their strength under the wet or
moist conditions encountered during washing and wiping surfaces
especially glass surfaces. Also chemical detergents and surfactants
have been added to the paper towels to assist in the cleaning
function. Most detergent surfactants can be divided into three
subclasses that is anionic, cationic, and non-ionic detergents. As
the division suggests, these detergents have certain chemical
properties and thus are useful in certain applications because of
their properties. Therefore these detergents are generally selected
on the basis of their chemical nature.
In developing an acceptable wiping towel for glass surfaces and
more particularly, glass surfaces of moving vehicles, the following
requirements are important: the products must be of the throw-away
variety, i.e., reasonably inexpensive; the detergent must foam with
water on the glass to aid in removing visibility-obstructing dirt
and grim, and the foam must break down within a short period after
foaming. The detergent surfactant must be readily absorbable into
the towel so that it can be substantially removed from the
windshield during wiping. Moreover, the chemical must not leave a
visible or light-defracting film obstructing the driver's
visibility. Also, the film should resist condensation or fine
droplet formation (i.e. fogging) of the windshield. It was
previously believed that most non-ionic detergents were unsuitable
because they leave a distinct layer of film on the windshield (see
U.S. Pat. No. 3,354,089). The cationic detergents were eliminated
because they are substantive to cellulose and relatively
unavailable. Specific anionic detergents were discovered to be
suitable and compatible with usual wet strength resins. See U.S.
Pat. No. 3,354,089 and U.S. Pat. No. 3,335,449.
SUMMARY OF THE INVENTION
A paper sheet having wet strength and containing a ethoylated
secondary alcohol non-ionic surfactant is suitable for wiping glass
surfaces. The suitable nonionic ethoxylates of linear secondary
alcohols are those having the following formula. ##EQU1## wherein x
and y are integers each having a value from 0 to 14 and the sum of
x plus y is from 10 to 14. Wet strengthened paper stock suitable
for windshield wiper or toweling use is impregnated either by
spraying, by size-press application, or by any other standard
coating application technique with an active amount of the
above-disclosed nonionic surfactant. Such a paper towel impregnated
with the nonionic surfactant when used with moisture to wipe glass
surfaces exhibit moderate sudsing to facilitate cleaning of the
glass surface and wipes clean without leaving a light-defracting
film, that is no haziness is left on the glass surface.
DETAIL DESCRIPTION OF THE INVENTION
The one class of nonionic detergents surfactants discovered to be
suitable for use on paper windshield wipers is ethoxylated linear
secondary alcohols of the following general formula: ##EQU2##
wherein x and y are integers each having a value of from 0 to 14
and the sum of x plus y is from 10 to 14.
Wet-strength resin containing paper stock (cellulosic sheet
material) is suitable as the base sheet for practicing this
invention. Typical wet strength resins which are employed in making
such paper stock are urea-formaldehyde, polyureaformaldehyde,
melamine-formaldehyde, glyoxalacrylamide and similar known wet
strength resins for papermaking. The specific wet strength resin
employed is not critical to the practice of this invention since
the nonionic detergent surfactant is compatible with conventional
wet-strength resins. The nonionic surfactant can be applied to the
paper either before or after the application of the wet strength
resin to the paper and either before or after the curing of the wet
strength resin. Furthermore, formed wet strength paper products can
be rewet with a solution of the nonionic surfactant to impart an
activating amount of the surfactant to the paper.
It has been found that the present non-ionic detergent surfactant
when applied to wet-strengthen paper cleans glass surfaces and does
not leave a visible film upon the glass surface while it loosens
dirt by easily foaming up in small quantities of water without
producing excessive amounts of suds. The non-ionic detergent
surfactants can be sprayed onto paper products under usual
production line conditions without causing significant eye
irritation to the workers in the evirons of the spraying
activity.
An active amount of a nonionic detergent surfactant of the present
invention on paper towels depends upon the contemplated end use of
the towel especially the type and amount of soil that may be
encountered on the glass surface. Usually from about 0.01 to about
2.0% of the surfactant based upon the weight of the dry
wet-strengthen paper stock is suitable with from about 0.5 to about
0.75% preferred.
The nonionic detergent surfactants used in the present invention
are produced by ethoxylating a mixture of linear secondary alcohols
containing from 11 carbon atoms to 15 carbons atoms with a
hydrophylic moiety containing about 15 ethylene oxide groups. Such
ethoxylated secondary alcohols comprise a mixture of compounds of
the above general formula wherein n is from 11 to 15. Such
detergent surfactants are available commercially under the
tradename TERGITOL 15 S 15.
The following examples are illustrative and further describe this
invention. Included are examples employing a representative
sampling of other non-ionic surfactants which demonstrate the
surprising functionality of only one non-ionic detergent surfactant
namely those of the above general formula which function
satisfactorily as a detergent surfactant for windshield wipers.
Obviously the functionality of these specific non-ionic detergents
surfactant employed in this invention could not be predicted on a
basis of their being a member of the class of non-ionic surfactants
in view of the demostrated inoperability of representative members
of the class of nonionic detergent surfactants shown in the
following examples and table and in view of the negative teachings
in U.S. Pat. No. 3,354,089 in column 2, lines 7 to 11.
EXAMPLE I
Detergents surfactants listed in Table I were each sprayed in a
regular pattern onto a clean windshield that had been previously
washed and then rinsed with distilled water. An ordinary
commercially available paper towel having some wet strength but
having no detergent or surfactant was then used to wipe the area of
the windshields that had been sprayed with the detergent surfactant
being tested. During moderate handwiping of the windshield with the
paper towel, the sudsing characteristics of the test solution were
observed. The moderate wiping of the windshield in a regular
pattern was continued for approximately one minute thereby
duplicating the usual effort of a service station attendant
cleaning a motor vehicle windshield. The first observation during
initial wiping was whether any sudsing developed. The quantity and
duration of the sudsing was observed and those which gave a large
quantity of suds which could not be substantially removed during
the one minute wiping action were rated as no good as were those
which gave no suds. Those surfactants that sudsed and whose suds
were essentially removed during the wiping test were rated as
having good sudsing characteristics.
After the one minute of wiping a moist film remained on the
windshield which was allowed to dry. The windshield was then
visually observed with an unaided eye for any detectable haze or
visible film residue. These observations were recorded as either
leaving a visible residue (yes) or not leaving a visible residue
(no). The above test was performed for all of the detergent
surfactants listed in Table I and from the results reported it is
obvious that the non-ionic detergent surfactant employed in the
present invention has unique properties not attributable to the
general class of non-ionic detergents surfactants even the closely
related detergent surfactants sold under the trade name TERGITOL 15
S.
Igepal is a series of non-ionic surfactants available from GAF
Corporation. Igepal CO-630 and Igepal CO-880 are nonylphenoxpoly
(ethyleneoxy) ethanols having 9 and 30 moles of ethylene oxide in
their respective molecular structure. Igepal RC 520 is
Dodecylphenoxy (ethyleneoxy) ethanol having 6 moles of ethylene
oxide in its molecular structure. Igepal DM 430, DM 710 and DM 880
are Dialkylphenoxypoly (ethyleneoxy) ethanol having 9, 10-11 and 30
moles of ethylene oxide in their respective molecular
structure.
TERGITOL 15-S is a series of non-ionic sufactants available from
Union Carbide and are ethoxylates of secondary linear alcohols of
the formula: ##EQU3## wherein x and y are integers each having a
value of from 0 to 14, x plus y is from 10 to 14 and n is 3 for
TERGITOL 15 S 3, 5 for 15 S5, 7 for 15S7, 9 for 15S9, 12 for 15 S12
and 15 for 15 S15.
Pluronic is a series of non-ionic surfactants available from
Wyandotte Chemical Company formed by the condensation of propylene
oxide with propylene glycol and have the general formula: ##EQU4##
The characteristics of the specific Pluronic surfactant in Table I
are listed in Table II.
TABLE I ______________________________________ SUDSING VISIBLE
SURFACTANT CHARACTERISTICS FILM
______________________________________ Polyethoxylethyl- Good Yes
aliphatic Aliphatic polyester " Yes IGEPAL CO-630 " Yes IGEPAL
CO-880 " Yes IGEPAL RC-520 No good Yes IGEPAL DM 430 Good Yes
IGEPAL DM 710 " Yes IGEPAL DM 880 " Yes Octylphenoxypolyethoxy "
Yes ethanol TERGITOL 15S3 " Yes TERGITOL 15S5 " Yes TERGITOL 15S7 "
Yes TERGITOL 15S9 " Yes TERGITOL 15S12 " Yes TERGITOL 15S15 " No
PLURONIC L-62DAP " Yes PLURONIC L-35 " Yes PLURONIC L-44 " Yes
PLURONIC L-64 " Yes PLURONIC F-87 " Yes PLURONIC F-88 " Yes
PLURONIC F-108 No good Yes PLURONIC F-127 Good Yes PLURONIC P-75 "
Yes PLURONIC P-103 " Yes ______________________________________
TABLE II ______________________________________ MOLECULAR % POLY
SURFACTANT WEIGHT %POLY(ETHYLENEOXY)GROUP
______________________________________ Pluronic L-62DAP 1750 20
Pluronic L-35 950 30 Pluronic L-44 1200 40 Pluronic L-64 1750 40
Pluronic F-87 2250 70 Pluronic F-88 2250 80 Pluronic F-108 3250 80
Pluronic F-127 4000 70 Pluronic P-75 2050 50 Pluronic P-103 3250 30
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