U.S. patent number 3,897,262 [Application Number 05/418,330] was granted by the patent office on 1975-07-29 for syrup and method of manufacturing same.
This patent grant is currently assigned to General Foods Corporation. Invention is credited to Paul O. Carlson.
United States Patent |
3,897,262 |
Carlson |
July 29, 1975 |
Syrup and method of manufacturing same
Abstract
A sucrose-based syrup is increased in viscosity to provide a
preferred pourability and non-absorptive characteristic on pancakes
and like porous comestibles to which it is applied by a method
which employs a semi-refined sugar syrup which is filtered through
a diatomaceous earth media and mixed with CMC-thickened softened
water operative to compensate for presence of ash and other
flocculents in the semi-refined sugar syrup.
Inventors: |
Carlson; Paul O. (Hickory
Corners, MI) |
Assignee: |
General Foods Corporation
(White Plains, NY)
|
Family
ID: |
23657663 |
Appl.
No.: |
05/418,330 |
Filed: |
November 23, 1973 |
Current U.S.
Class: |
127/55; 127/29;
426/658 |
Current CPC
Class: |
A23L
29/30 (20160801); C13B 20/123 (20130101) |
Current International
Class: |
A23L
1/09 (20060101); C13D 3/00 (20060101); C13D
3/12 (20060101); C13d 003/12 (); C13f 001/00 ();
C13f 003/00 () |
Field of
Search: |
;127/29,55
;426/213,380,162 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
batdorf, J., et al., Sodium Carboxymethylcellulose, in Industrial
Gums; Polysaccharides and Their Derivatives, ed. by R. L. Whistler,
2nd Ed., N.Y., Academic Press, Sept. 26, 1973, Ch. 31, p. 716-719
TP978W5..
|
Primary Examiner: Wolk; Morris O.
Assistant Examiner: Phillips; Roger F.
Attorney, Agent or Firm: Struzzi; Bruno P. Sullivan; Thomas
V. Quillinan; Michael J.
Claims
What is claimed is:
1. Process for preparing a table syrup which employs semi-refined
sugar syrup as its principal constituent, said syrup being
thickened with CMC, said process comprising preparing a
concentrated, pasteurized, semi-refined sucrose syrup having a Brix
of at least 68.degree., said syrup containing naturally occurring
colloidal substances, filtering said syrup through a diatomaceous
earth filter media to remove colloidally suspended mineral and
organic residue contained therein, separately preparing a CMC
solution from softened water having less than 5 parts per million
calcium or magnesium, admixing the latter solution with the
concentrated syrup to dilute the concentrate and produce an
ultimate syrup having a CMC level of 0.15- 0.25% by weight, and
packaging the diluted syrup in a transparent container.
2. The process according to claim 1 wherein the ultimately prepared
syrup has a Brix below 68.degree..
3. A process according to claim 1 wherein the CMC has an average of
0.9 carboxymethyl groups substituted per anhydroglucose unit.
Description
BACKGROUND OF THE INVENTION
Many users prefer a table syrup which is thickened to an extent
such that the syrup remains on the pancake or like baked
preparation, be it chemically- or yeast-leavened, and is less
absorbed thereby to provide an improved organoleptic acceptance
from standpoints of both taste and appearance; sodium
carboxymethylcellulose (CMC) has been added to table syrup
preparations for such purposes. This addition renders more obvious
the presence of discrete "floc" in some sugar preparations after
extended shelf storage, particularly those which are less refined,
thereby reducing syrup clarity. Although the practice of employing
CMC to thicken a variety of table syrups and like topping
compositions has been employed previously, the ability to provide
an economical and reliably produced clear syrup containing CMC
remains significantly dependent upon the absence in the syrup of
such flocculents as ash, organic substances, and other matter which
may contribute to a reduction in clarity.
STATEMENT OF THE INVENTION
Accordingly, it is among the principal objects of the invention to
provide a table syrup process which is less dependent upon degree
of purification or refinement of a given syrup and is less prone to
the manifestations of a floc appearance in thickened syrup
preparations which employ CMC.
In accordance with the present invention, a process is provided
which meets these objects by employing a diatomaceous earth filter
aid to partially clarify a concentrated pasteurized semi-refined
sucrose syrup containing naturally occurring colloidal substances
and combining this filtered syrup with a softened water containing
the CMC in amounts operative to reduce Brix and increase viscosity
of the filtered syrup to the intended viscosity preparatory to
bottling.
DETAILED DESCRIPTION OF THE INVENTION
In accordance with its more specific aspects, a semi-refined syrup
having an ash level exceeding that of granulated sugar of commerce
and typically having an ash content of about 0.30 and a
polarization (dry basis) of 97.50.degree. is admixed with corn
syrup, maple syrup, flavor and color. The prepared syrup is at an
elevated Brix of at least 68.degree. and preferably
71.degree.-72.degree.. The syrup is subjected to a pasteurization
temperature, say, to a temperature of 180.degree.F and at least
160.degree.F and then is passed through a diatomaceous earth filter
medium; this medium will typically be employed in a leaf-type
pressure filter known in the art and will be continually developed
and restored to maximal efficiency by building a substrate
operative to remove impurities in the syrup. In this respect a
preferred practice will employ regenerating levels of diatomaceous
earth in the syrup solution which as it is introduced to the filter
will continue to build filtration substrate and operatively result
in partial removal of colloidally suspended mineral and organic
residue.
Separately of the syrup solution, a CMC solution is prepared at
ambient or only slightly elevated temperatures employing a softened
water which will have any chemical preservatives that may be
employed in the finished table syrup present and into which CMC
will be dispersed, say, at a level between 1-5% by weight
preferably 2.75% by weight to provide a viscolizing diluent
solution. It has been found essential in this respect to employ
water of such softened condition as minimizes the flocculation
tendencies of the semi-refined sugar syrup described hereinabove.
The softened water will be characterized by the following
criteria:
Parts per Million Maximum (By Weight)
______________________________________ Calcium and/or magnesium 5
______________________________________
The softened CMC solution, once prepared, will be heated to a
pasteurizing temperature of at least 160.degree.F upon admixture
with the filtered concentrate sugar syrup solution and will be
blended at a proportion operative to reduce Brix below 68.degree.
and typically to a preferred range of 65.degree.-67.degree., a most
preferred being about 66.5.degree. and produce viscosity in the
range of 600-1100 cps; the blend will thereafter be repasteurized
preparatory to bottling and packing, all in accordance with
procedures well known to those skilled in the art.
The following is a typical syrup formulation and range for
practicing the formulation of a syrup solution in accordance with
the invention:
Range of Ingredients wt.% Preferred Level
______________________________________ Semi-refined Liqid Sugar
Syrup (67.5.degree. Brix) 58 * Corn Syrup (42 DE, 43.degree. Baume)
30 ** Soft Water (as specified 8.7 herein) Maple Sugar Syrup
(67.50.degree. Brix) 3.0 1-5*** CMC(Sodium 0.20 0.15-0.75
carboxymethylcellulose) Sodium Benzoate 0.05 Sorbic Acid 0.03
Caramel Color 0.02 ______________________________________ *The
range of liquid sugar syrup as a percent of the finished product
can vary depending upon formulary preference. **The level of corn
syrup employed as such may similarly vary depending upon formulary
preference. ***The level of maple syrup forms no part of this
invention and may be employed as cost and quality of the finished
product is required.
In the foregoing formulation the preferred form of CMC will be one
having a high degree of substitution of carboxymethyl groups on the
cellulose ester polymer chain, the degree of substitution being
inversely related to the degree of stringiness. Moreover, when the
degree of substitution is less than optimal, the syrup as thickened
will be found to have a non-smooth texture imparted thereto whereas
at a high order of substitution the syrup will have a smooth
mouthfeel and less stringy. Accordingly, in accordance with its
most preferred and specific aspects, the syrup will employ a CMC
wherein the degree of substitution is 0.9 carboxymethyl groups
substituted per anhydroglucose unit; a medium type viscosity (800
to 3100 cps in a 2% solution by weight at 25.degree.C LVF
Brookfield 30 rmp No. 3 Spindle) is preferred.
As thus described the invention will be adaptable to a variety of
syrup manufacturers using less than refined sugar syrups.
Accordingly, the invention is to be interpreted with regard to the
accompanying claims for construction thereof.
* * * * *