U.S. patent number 3,896,010 [Application Number 05/297,851] was granted by the patent office on 1975-07-22 for process and apparatus for the coating of an electrically conductive fibrous strand.
This patent grant is currently assigned to Maschinenfabrik Augsburg-Nurnberg Aktiengesellschaft. Invention is credited to Jochen Vetter.
United States Patent |
3,896,010 |
Vetter |
July 22, 1975 |
Process and apparatus for the coating of an electrically conductive
fibrous strand
Abstract
An apparatus and process for coating and treatment of an
electrically conductive fiber strand made of a multiplicity of
individual filaments of a quasi indefinite length, said process
comprising electrically connecting the fiber strand to a voltage
source to act as a cathode, passing the strand through an
anode-equipped whirl chamber, and opening up the strand by
subjecting the strand to a continuously or discontinuously supplied
jet of fluid electrolyte to thereby uniformly treat the filaments
throughout the strand to said electrolyte. The jet of electrolyte
is arranged with a sinusoidal line in the axial direction of the
strand and annularly to the strand in a direction counter to the
direction of the twist in the strand.
Inventors: |
Vetter; Jochen (Karlsfeld,
DT) |
Assignee: |
Maschinenfabrik Augsburg-Nurnberg
Aktiengesellschaft (DT)
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Family
ID: |
5822537 |
Appl.
No.: |
05/297,851 |
Filed: |
October 16, 1972 |
Foreign Application Priority Data
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Oct 16, 1971 [DT] |
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2151618 |
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Current U.S.
Class: |
205/138; 204/206;
205/159 |
Current CPC
Class: |
C25D
7/0607 (20130101) |
Current International
Class: |
C25D
7/06 (20060101); C23b 005/58 () |
Field of
Search: |
;204/27,28,206,207,209 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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2,013,936 |
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Oct 1970 |
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DT |
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1,208,959 |
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Oct 1970 |
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GB |
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Primary Examiner: Mack; John H.
Assistant Examiner: Solomon; W. I.
Attorney, Agent or Firm: Craig & Antonelli
Claims
What is claimed is:
1. A process for the coating and treatment of an electrically
conductive fiber strand made of a multiplicity of individual
filaments of a quasi infinite length, said filaments in said fiber
strand being twisted together, which comprises the steps of:
electrically connecting the fiiber strand to a voltage source to
act as a cathode,
passing the strand through an anode-equipped whirl chamber,
supplying fluid electrolyte to said whirl chamber from a storage
tank containing a reservoir of said fluid electrolyte, said whirl
chamber being separated from said storage tank such that said whirl
chamber is substantially free of the fluid electrolyte reservoir,
and
subjecting the strand to at least one jet of said fluid electrolyte
to open up the strand such that the filaments throughout the strand
are uniformly treated exclusively with said electrolyte jet, said
at least one jet of fluid electrolyte being suppliled annularly to
the strand, wherein each jet of electrolyte is arranged with a
sinusoidal line in the axial direction of the strand and annularly
to the strand in a direction counter to the direction of the twist
in said strand.
2. The process according to claim 1, in which the fiber strand is
electroplated in the whirl chamber by conveying the strand over and
into contact with a roll connected as the cathode of said voltage
source.
3. The process according to claim 1, in which the jet of
electrolyte is directed perpendicular to the axis of said
strand.
4. The process according to claim 1 in which a plurality of jets of
a liquid electrolyte are directed against said strand.
5. The process according to claim 1 in which the fiber strand is
made of carbon and the electrolyte contains metal ions in
solution.
6. An apparatus for treating a continuous fiber strand of a
multiplicity of electrically conductive filaments, said apparatus
comprising
a storage tank for storing a reservoir of fluid electrolyte,
a whirl chamber of an electrically nonconductive material, said
chamber having a passage and an annular space defined by an outer
and an inner wall means, an anode within said space, a fluid
electrolyte feed means terminating in said space, said chamber
being separated from said storage tank such that said passage is
substantially free of the fluid electrolyte reservoir in said
storage tank,
means for passing an electrically conductive strand through said
passage,
means for supplying said fluid electrolyte from said storage tank
to said fluid electrolyte feed means, and
nozzle means for directing at least one jet of electrolyte onto
said strand, said nozzle means being arranged so that the strand is
opened up by the electrolyte to allow exclusive treatment of the
filaments within said strand by said jet of electrolyte, wherein
said nozzle means includes a plurality of individual nozzles, each
of said individual nozzles extending in a sinusoidal line in the
longitudinal direction and annularly with respect to the
strand.
7. The apparatus according to claim 6, in which the nozzle means
are radially oriented slots extending through said inner wall
means, each of said slots being disposed to extend essentially in
the longitudinal direction and being uniformly distributed along
the periphery of said strand.
8. The apparatus of claim 6, in which a roll is provided which is
connected with the cathode of the current source for placing the
fiber strand to be electroplated in the whirl chamber.
9. The apparatus of claim 6 in which said plurality of nozzle means
are radially positioned around said passage.
10. The apparatus of claim 9 in which the nozzles are spaced
equidistant from each other and are substantially identical to each
other.
11. The apparatus of claim 6 in which the nozzles are spaced
equidistant from each other.
Description
This invention relates to a process and an apparatus for
electrocoating of an electrically conductive fibrous strand made up
of thin filaments.
The continuous electroplating of electrically conductive fiber
strands and/or bundles having a large number of thin individual
filaments (approximately 10,000) causes difficulties, as is known,
since the outer filaments of the bundle electrically shield the
filaments disposed in the core, i.e. center of the bundle--in
accordance with the effect of a Faraday cage. In order to
electroplate these fiber bundles, attempts have been made
heretofore to untwist the fiber groups or bundles so that the
individual filaments or threads are disposed approximately
side-by-side in the electrolytic bath (R. V. Sara: "Fabrication and
Properties of Graphite-Fiber, Nickel-Matrix Composites," 14th
National Symposium, November 1968, Union Carbide Corp., Carbon
Products Division). Various deficiencies were encountered in this
process, such as, for example, mechanical damage to the individual
filaments, a local depletion of discharge-capable ions of the
electrolyte, as well as a nonuniform metallic deposition on the
periphery of the individual filaments.
It is an object of this invention to provide a process, as well as
an apparatus for conducting the process, for the coating and/or
treatment of a thin, electrically conductive fibrous strand or
bundle of a quasi infinite length, (i.e. a continuous or endless
strand) wherein the above-described disadvantages are substantially
avoided. Advantageously, metal from the electrolyte is deposited in
a maximally dense and uniform manner on all individual filaments
(e.g. carbon filaments) in the fiber bundle, without necessitating
a mechanical treatment (untwisting) and a damaging of the
individual filaments. The process furthermore is suitable for being
conducted in one operating step in a maximally simple apparatus to
thereby ensure a substantial automation.
According to the invention, the desired objective is attained by
electrically connecting the fiber strand as a cathode and pulling
the strand through an anode-equipped whirl chamber in such a manner
that it is fanned out by at least one continuously or
discontinuously supplied jet of fluid electrolyte that impinges on
the periphery of the strand. Furthermore, according to the
invention, the fiber strand electroplated in the whirl chamber is
conveyed so that it comes subsequently into contact with a roll
also electrically connected as the cathode.
The fiber strand serving as a cathode thus travels through the
whirl chamber into which an electrolytic fluid, especially liquid,
is sprayed. This liquid is sprayed radially inwardly into the fiber
strand so that the strand is fanned out approximately across the
length of the whirl chamber. Since the liquid electrolyte jet, due
to its passage past the anode, is simultaneously a
current-conductive element or means, a deposition of metal takes
place at the points in the strand reached by the jet. The
electrolyte advantageously also reaches the filaments in the core
of the fiber strand, without any interspersed shielding due to
external filaments. The fanning out of the fibrous strand by the
turbulence of at least one liquid electrolyte jet ensures a
statistically uniform, optimum deposition of metal or other
conductive material on the strand. The feeding of fresh electrolyte
furthermore prevents any local depletion of discharge-capable ions.
A special advantage of the process of this invention is, moreover,
seen in that any desired electrolyte fluid can be employed (for
example an alkaline or acidic Cu electrolyte; nickel sulfamate,
etc.). Exemplary of the metal-containing electrolytes suitable for
the purposes of this invention are alkaline tin electrolyte and
silver-cyanide electrolyte.
In accordance with the invention, the apparatus for conducting the
process of this invention resides essentially in that the whirl
chamber, consisting of an electrically nonconductive material e.g.
polyvinyl chloride (PVC), exhibits an annular space defined on the
inside by a bushing or inner wall means; this space accommodates an
annular anode, and the liquid electrolyte feed inlet terminates in
this space.
In order to achieve a satisfactory turbulence of the jet (i.e.
stream spray or the like) of fluid electrolyte, it is suggested
according to a further feature of this invention, to dispose in the
jacket of the bushing radially oriented nozzles or orifices
extending essentially in the longitudinal direction so that they
are uniformly distributed along the periphery or the fiber
strand.
In order to place the fiber strand to be electroplated in the whirl
chamber under current, a roll is provided which is connected with
the cathode of an electrical current source over which roll the
electroplated fiber strand is passed.
The nozzles, through which the electrolytic fluid exits from the
annular space to the fiber strand, can be of a circular or
slot-like shape; however, their configuration must ensure that an
appropriate amount of turbulence required for fanning out the fiber
strand is positively provided. An additional advantage can be
obtained, if required, by moving the nozzles, as well as feeding
the electrolyte in a pulsating manner.
The use of the apparatus of this invention is not limited merely to
the electroplating of fiber strands; rather, it is also possible to
utilize the apparatus for electrolytic etching or scouring of fiber
strands or otherwise treating the strands with a fluid
electrolyte.
The process and apparatus of the invention will be further
understood from the following detailed description and the
accompanying drawing wherein:
FIG. 1 shows the apparatus of the invention in an elevational view;
and
FIG. 2 shows a whirl chamber of the invention.
The fiber strand 2, consisting of about 10,000 individual carbon
filaments, passes from a take-off reel 1 approximately in the axial
direction through the passage provided in whirl chamber 3 and over
a guide roll 4 to a windup reel 5. In the annular space 6 of the
whirl chamber 3, described in greater detail in FIG. 2, a
ring-shaped anode 7 is arranged which is connected with an
electrical current source 9 via an electrical line 8 provided with
an ammeter A; the voltage of this current source is measured by a
voltmeter V. Furthermore, a feed line 10 leads into the annular
space 6, by means of which the liquid electrolyte E (e.g. nickel
sulfamate solution) is conveyed by a pump 11 from a storage tank 12
through the nozzles 13 against the fiber strand 2. The excess
electrolytic liquid dripping off from the fiber strand drips into
the storage tank. After the fiber strand 2 has been coated in the
whirl chamber 3, it is conducted via the roll 4, connected to the
cathode of the current source 9 by way of an electrical line 14. By
the contact of the fiber strand with this roll, the objective is
achieved that the fiber strand becomes effective to serve as a
cathode. The electroplated fiber strand is finally, after a drying
step (by drier means not shown), wound up on the windup reel 5 in
the direction of the arrow.
The whirl chamber 3 (FIG. 2) comprises essentially two circular
housing sections 15 and 16, connected with each other and made of
an electrically nonconductive material, e.g. PVC, teflon (PTFE), or
glass; these sections form the annular space 6. The housing section
15 has a disk portion and a bushing portion 15a defining a wall
extending from the bore of the disk portion disposed along the axis
A'. The wall of this bushing has six nozzles 13 uniformly
distributed along the circumference; each of these nozzles extends
approximately in accordance with a sinusoidal line in an axial
parallel manner (axis A'). The length of these nozzles, projected
onto the axis A', corresponds approximately to the height of the
anode 7. However, the nozzles can be of any desired configuration;
for example, it is possible to arrange bores or slots of any
desired shape, but the nozzles must ensure that the fiber strand
moving in the axis A' is uniformly exposed along its entire
periphery to the turbulent jets of electrolyte and is thereby
fanned out.
The annular anode 7, as well as the wall portion of the second
housing section 16 are seated on the disk portion of the housing
section 15. The contact surfaces of the two housing sections 15 and
16 are provided with gaskets 17 and 18 which thus seal the annular
space 6 appropriately. Furthermore, bores 10' and 19 are provided
in the housing section 16 for the feed line 10 of the liquid
electrolyte as well as for the anode line 8. The bores 20 are
intended for the screws that are used to assemble the housing.
Within the scope of this invention, still further embodiments of
the whirl chamber, especially the nozzles, are possible, by means
of which the effect of a fanning out of the fiber strand with the
aid of the electrolyte jet or jets is attained. Thus, it would be
possible, for example, to make the nozzles movable, their cross
section variable, or to make the annular anode adjustable with
regard to the periphery of the strand during operation.
The process of this invention will be further understood from the
following examples.
EXAMPLE 1
In an apparatus as illustrated in FIGS. 1 and 2 a strand of carbon
filaments (10,000) having a denier of 1 gram per meter and of a
twist of 6 turns per meter under a tension of 2 pounds is passed at
a speed of 1/4 feet per minute through a whirl chamber having six
nozzles through which nickel sulfamate is supplied as an
electrolyte. The electrolyte is injected via the nozzles (each
having a discharge opening with a length of 1 inch and a width of
.02 inch) at a rate of 5 liters per minute and under a pressure of
1000 mm water column. The high velocity jets of electrolyte
impinging on the strand cause the strand to open or fan out so that
the center filaments are uniformly coated with the electrolyte. A
voltage of 5 volts and a current of 2 amperes are used to effect
the required electroplating of the nickel metal.
EXAMPLE 2
Additional strands of the following electroconductive filaments are
treated with various electrolytes by following the procedure set
forth in Example 1.
______________________________________ Number of Type of Strand
Filaments Kind of Electrolyte
______________________________________ Maraging Steel Wires 2,000
Silver Cyanide Maraging Steel Wires 2,000 Cobaltous Cyanide
______________________________________
In each case the filaments within the center are observed to have
the same degree of treatment as the filaments on the outer
periphery.
From the above examples it is apparent that the process of this
invention is suitable for electrotreating a wide variety of
conductive strands with electrolytes.
It will be understood that the process of this invention as
applicable to coating various conductive strands including those of
carbon fibers, and metallic wires such as maraging steel wires.
These fiber strands are usually in a twisted condition.
Furthermore, it will also be appreciated that many different
metal-containing electrolytes may be used for treating the fiber
strand. Among the suitable electrolytes are nickel sulfamate,
silver cyanide and like electrolytes which contain metal ions of
cobalt, chromium, zinc, cadmium, tin, lead, gold, platinum, iron,
indium, antimony, arsenic, manganese, rhenium, selenium, tellurium,
and bismuth.
While the novel principles of the invention have been described, it
will be understood that various omissions, modifications and
changes in these principles may be made by one skilled in the art
without departing from the spirit and scope of the invention.
* * * * *