U.S. patent number 3,895,474 [Application Number 05/416,484] was granted by the patent office on 1975-07-22 for process for preparing pre-moistened antimicrobial towels.
This patent grant is currently assigned to Pfizer Inc.. Invention is credited to Stuart M. Bauer.
United States Patent |
3,895,474 |
Bauer |
* July 22, 1975 |
Process for preparing pre-moistened antimicrobial towels
Abstract
A process for the preparation of pre-moistened antimicrobial
towels is disclosed.
Inventors: |
Bauer; Stuart M. (Succasunna,
NJ) |
Assignee: |
Pfizer Inc. (New York,
NY)
|
[*] Notice: |
The portion of the term of this patent
subsequent to January 22, 1991 has been disclaimed. |
Family
ID: |
26974830 |
Appl.
No.: |
05/416,484 |
Filed: |
November 16, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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305859 |
Nov 13, 1972 |
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Current U.S.
Class: |
53/429; 53/431;
53/474; 53/471 |
Current CPC
Class: |
A61F
13/00991 (20130101) |
Current International
Class: |
A61F
13/00 (20060101); B65B 063/04 () |
Field of
Search: |
;53/21FC,21FW,36 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: McGehee; Travis S.
Attorney, Agent or Firm: Murphy; Francis X. Knuth; Charles
J. Spiegel; Allen J.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of my copending
application Ser. No. 305,859, Pat No. 3,786,615, filed Nov. 13,
1972.
Claims
What is claimed is:
1. A process for preparing pre-moistened antimicrobial towels which
comprises the steps of coating paper or fabric sheet in strip form
with a solution of antimicrobial agent in a volatile vehicle;
permitting at least a portion of said vehicle to evaporate;
longitudinally folding said coated sheet; transversely perforating
said coated sheet into separable towel segments; transversely
folding said perforated sheet; arranging said folded and perforated
sheet in stack form in a moisture-impervious container; moistening
said stack with aqueous liquid; and enclosing said moistened stack
with a moisture-impervious cover seal on said container.
2. The process of claim 1 wherein said coating is effected by
gravure printing.
3. The process of claim 1 wherein said antimicrobial agent is a
quaternary ammonium compound.
4. The process of claim 3 wherein said quaternary ammonium compound
is benzalkonium chloride.
5. The process of claim 1 wherein said sheet is paper.
6. The process of claim 1 wherein said sheet is non-woven hemp.
Description
BACKGROUND OF THE INVENTION
This invention relates to a novel process for preparing
pre-moistened antimicrobial towels useful for sanitary purposes,
e.g., in hemorrhoidal conditions, feminine hygiene, first aid,
diaper change cleanups and similar uses.
Previously, packages of pre-moistened towels were prepared by
placing a stack of towels into a container, saturating the towels
with a solution containing an antimicrobial agent, placing a cover
on the container and heat sealing a top on the container to
completely seal the package. However, this method is subject to
chromatographic effects whereby the antimicrobial agent may tend to
concentrate in portions of the stack without being uniformly
dispersed through the stack and the individual towels.
SUMMARY OF THE INVENTION
It has now been found that pre-moistened antimicrobial towels can
be made by a process which comprises the steps of coating paper or
fabric sheet in strip form with a solution of antimicrobial agent
in a volatile vehicle; permitting at least a portion of said
vehicle to evaporate; longitudinally folding said coated sheet;
transversely perforating said coated sheet into separable towel
segments; transversely folding said perforated sheet; arranging
said folded and perforated sheet in stack form in a
moisture-impervious container; moistening said stack with aqueous
liquid; and enclosing said moistened stack with a
moisture-impervious cover seal on said container.
Such a process produces a moistened towel in which the
antimicrobial agent is uniformly dispersed on each towel, thereby
protecting the product from spoilage and providing a uniform
concentration of antimicrobial agent for the intended use.
BRIEF DESCRIPTION OF THE DRAWING
The invention will be better understood by reference to the
appended drawings, wherein FIG. 1 is a schematic view in section of
an apparatus for carrying out the coating step of the invention,
and FIG. 2 is a side elevation in partial section of a portion of
the apparatus of FIG. 1.
DETAILED DESCRIPTION OF THE INVENTION
As shown in FIG. 1, a strip of paper or fabric 2 is drawn past
pressure roll 4 in rolling contact with cylinder 6. Cylinder 6 is
preferably a precision engraved applicator suitable for gravure
printing. Roll 4 and cylinder 6 are rotated in the directions
indicated by the arrows by a drive source not shown. Cylinder 6 is
partially immersed in antimicrobial solution 8 contained in
reservoir 10, and excess solution is removed by doctor blade 12.
The etched or incised surface of cylinder 6 is thereby moistened or
saturated with the antimicrobial solution, and brought into contact
with the material to be coated as it travels through the nip
created by roll 4 and cylinder 6. The speed at which the material
passes through the rollers is not critical and may be set at any
predetermined speed desired.
Roll 4 suitably has a resilient surface, e.g., of rubber, whereby
strip 2 of paper or other sheet material is pressed into intimate
contact with the antimicrobial solution carried by the surface of
cylinder 6.
Cylinder 6 is suitably a conventional gravure roll, e.g., having a
diameter of about 9 inches and a width of about 54 inches. As best
seen in FIG. 2, the surface of cylinder 6 is etched or engraved
with a uniform pattern 14 (shown greatly magnified), e.g., a series
of cells or wells, each in the form of an inverted truncated right
rectangular pyramid to hold the antimicrobial solution. This
pattern, and in particular the size and spacing of the individual
cells, determines the quantity of solution transferred to strip 2
in the coating application. Preferred patterns are those having
about 200- 220 cells per lineal inch, each cell having a depth of
up to about 0.0012 inch, which, in conjunction with a 25% by weight
solution of antimicrobial agent, will transfer on the order of 0.1
mg. of said agent per square inch of surface to be coated.
Concentrations of 4 to 50% by weight will successfully deposit up
to 0.2 mg. of agent per square inch.
The towels are for example made from paper or non-woven hemp
material having a substantial wet strength such as Dexter paper,
Grade X 2067 or N 2660, available from The Dexter Corp. of Windsor
Locks, Connecticut. Woven or non-woven cloth made of rayon, nylon
or cotton, alone or in combination, may also be used.
Preferred antimicrobial compounds are the quaternary ammonium
compounds, e.g., benzalkonium chloride, an alkyl-substituted
dimethylbenzyl-ammonium chloride wherein the alkyl substituents
each contain 8 to 18 carbon atoms. Other well-known antimicrobial
agents, such as cetyl pyridinium chloride, chlorhexidine, or propyl
or methyl paraben, can be substituted wholly or partially for the
benzalkonium chloride. The optimum amount of antimicrobial agent
will vary with the particular agent being used and the end use of
the product. However, in the case of quaternary ammonium compounds,
a concentration of 0.1-0.2 mg. per square inch of the towelling is
generally used. Optional ingredients, such as local anesthetics,
vasoconstrictors, astringents, etc., may also be applied at this
step, if desired. The volatile vehicle is usually water, a
water-ethanol or a water-isopropanol mixture, which air dries by
spontaneous evaporation. It is not necessarily essential to effect
complete evaporation of the vehicle to the "bone-dry" state. The
degree of evaporation required will be dictated by the ability to
further process the towelling material without tearing in the
subsequent folding and perforating operations.
After drying, the treated towelling material is longitudinally
folded, transversely perforated, and transversely folded, e.g., by
means of a conventional zig-zag folding machine capable of
producing a transverse shear-cut perforation leaving bonds between
the individual sheets, longitudinally folding into a "wing-fold",
and transversely folding into a zig-zag fold. In a preferred
embodiment, the perforating is effected at the site of every other
transverse fold.
The expression "perforating" as employed herein and in the appended
claims is to be understood to include the introduction into the
strip material of a line of transverse slits defined by residual
fiber bonds, or alternatively the introduction of a transverse row
of holes.
The zig-zag folding affords the opportunity of packaging the towels
in stack form. The stacks are placed in moisture-impervious
containers, such as shallow polystyrene trays, and moistened with
an aqueous liquid, which may for example be water, water-ethanol or
water-isopropanol, optionally containing auxiliary agents, odorants
or the like, if desired. The containers are than fitted with a
moisture-impervious cover seal, e.g., a replaceable lid suitably
trapped within a foil-backed paper cover sealed to an outwardly
extending lip on the tray.
* * * * *