U.S. patent number 3,895,367 [Application Number 05/437,351] was granted by the patent office on 1975-07-15 for gas indicator with semiconductive gas sensor.
This patent grant is currently assigned to Frans Verlinden, Johan Willem Visser. Invention is credited to Robertus Gerardus Visser.
United States Patent |
3,895,367 |
Visser |
July 15, 1975 |
Gas indicator with semiconductive gas sensor
Abstract
A gas indicator provided with a gas sensor consisting of a
semiconductive body incorporating two spaced electrodes. The body
may be heated by means of one of the electrodes which is shaped as
a filament for this purpose. When heated, the body is activated,
whereby it obtains a high resistivity; however, this resistivity is
reduced to a low value when the body is exposed to a gas. The gas
indicator is operated by means of two bistable circuits, changing
their states, respectively, at the end of the activating time of
the body, and upon occurrence of a gas. The output signals of the
two bistable circuits actuate an alarm circuit by means of a
coincidence circuit. The filament of the gas sensor may be fed by
the output energy of an oscillator.
Inventors: |
Visser; Robertus Gerardus
(Amsterdam, NL) |
Assignee: |
Visser; Johan Willem
(Amsterdam, NL)
Verlinden; Frans (Amstelveen, Breukeleveen,
NL)
|
Family
ID: |
19819783 |
Appl.
No.: |
05/437,351 |
Filed: |
January 28, 1974 |
Foreign Application Priority Data
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Oct 10, 1973 [NL] |
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7313897 |
Nov 30, 1973 [BE] |
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138387 |
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Current U.S.
Class: |
340/634; 340/629;
340/628 |
Current CPC
Class: |
G08B
17/117 (20130101); G01N 27/122 (20130101) |
Current International
Class: |
G01N
27/12 (20060101); G08B 17/10 (20060101); G08B
17/117 (20060101); G08b 017/10 () |
Field of
Search: |
;340/237R ;23/254E |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Caldwell; John W.
Assistant Examiner: Myer; Daniel
Attorney, Agent or Firm: Waters, Schwartz & Nissen
Claims
I claim:
1. A gas indicator, comprising a semiconductive body serving as a
gas sensor adapted to be thermally activated and having in
activated condition the property that the resistivity thereof is
substantially reduced upon exposure to a gas, a first electrode
incorporated in said body and shaped as a filament for activating
the same, an alternating current source, means for connecting said
alternating current source across said first electrode, a second
electrode incorporated in said body and spaced with respect to said
first electrode, a circuit interconnecting the said electrodes and
including a direct current source, a current change occurring in
the said circuit when the resistivity of said body is reduced, a
delay circuit coupled to said direct current source and actuated
when the indicator is energized, a first trigger controlled by said
delay circuit to change state at the end of a determinable
activating time, a second trigger controlled by said current change
so as to change state when the resistivity of said body is reduced,
a coincidence gate controlled by output signals of the said
triggers occurring after their changes of state, and an alarm
circuit actuated by the output signal of said coincidence gate, the
alternating current source being an oscillator coupled to and
energized by said direct-current source.
2. A gas indicator as claimed in claim 1, further comprising means
for supplying the output voltage of said oscillator as a heating
voltage to the ends of said first electrode.
3. A gas indicator as claimed in claim 2, further comprising a
piezo-electric sound generator inserted in said alarm circuit, and
means for supplying the output voltage of said oscillator as an
energizing voltage to said sound generator.
4. A gas indicator as claimed in claim 3, wherein said coincidence
gate has a third input terminal, further comprising means for
supplying said oscillator voltage to said third input terminal.
5. A gas indicator, comprising a semiconductive body serving as a
gas sensor, adapted to be thermally activated and having, in
activated condition, the property that the resistivity thereof is
substantially reduced upon exposure to a gas, a first electrode
incorporated in said body and shaped as a filament for activating
the same, an alternating current source coupled across said first
electrode, a second electrode incorporated in said body and spaced
with respect to said first electrode, a circuit interconnecting the
said electrodes, a direct current source coupled to said
interconnecting circuit such that a current change occurs in the
same when the resistivity of said body is reduced, a delay circuit
including a first resistor and a condenser in series with said
first resistor, a first Schmitt trigger controlled by the voltage
across said condenser so as to deliver a 1-signal during the
activating time of said body and a 0-signal after expiration of
said activating time, a second inverting Schmitt trigger, an
inverter controlled by the 0-signal of said first trigger, a
nand-gate having at least two input terminals, means for supplying
the output signal of said inverter to one of the said input
terminals, a second resistor, an emitter follower having a base, an
emitter and a collector, means for supplying the output signal of
said inverter throught said second resistor to the base of said
emitter follower, means connecting one of the said electrodes with
the base of said emitter follower, means for grounding the other of
the said electrodes, means connecting the emitter of said emitter
follower with the input terminal of said second trigger, means
connecting the output terminal of said second trigger with a second
input terminal of said nand-gate with said alarm circuit, in such
manner that the emitter voltage of said emitter follower disappears
upon occurrence of a gas after expiration of the activating time of
said body, whereby said second trigger delivers a 1-signal, and
said hand-gate is operated to deliver a 0-signal for actuating said
alarm circuit.
6. A gas indicator as claimed in claim 5, wherein said inverter is
an inverting Schmitt trigger.
7. A gas indicator as claimed in claim 5, further comprising a
second inverter connected with the output terminal of said
nand-gate, a second nand-gate having at least two input terminals,
means for supplying the output signal of said second inverter to
one of the input terminals of said second nand-gate, an oscillator,
means for supplying the output voltage of said oscillator to
another input terminal of said second nand-gate, a loudspeaker, and
means connecting said loudspeaker with the output terminal of said
second nand-gate.
8. A gas indicator as claimed in claim 7, further comprising a
relay having a coil and at least one back contact, means for
supplying the output signal of said second inverter to one of the
ends of said coil, means connecting the other end of said coil with
the 1-voltage, and means for removing the dangerous condition due
to the presence of a gas, such as an exhauster, actuated by said
back contact when said relay is de-energized.
Description
BACKGROUND OF THE INVENTION
The invention relates to a gas indicator provided with a gas sensor
consisting of a body of a semiconductive material incorporating two
spaced electrodes of which one is constructed as a filament for
heating the body, which is activated by the heating and thereby
obtains the property that the electric resistivity is considerably
reduced when the body is exposed to a gas, the current path between
the electrodes of the sensor being inserted in a circuit containing
a current source, so that the decrease of the resistivity gives
rise to a current change whereby an alarm circuit is actuated.
A known sensor of the above-mentioned kind consists of an N-type
metal oxide, such as tin oxide, zinc oxide, or ferric sesquioxide,
and is sensitive, inter alia, to hydrogen, carbon monoxide,
methane, propane, volatile oils, acetylene, smoke, and carbon
containing air.
In a gas sensor of the above-mentioned kind, the resistance
occurring between the electrodes is small when the semiconductive
body is at room temperature. When the body is heated by means of
the filament, the resistance between the electrodes obtains
gradually a very high value. After about one minute, a final
condition is reached in which the sensor has a maximum activity.
When the semiconductive body is now exposed to a gas, such as
carbon monoxide, hydrogen, hydrocarbons, or the like, the
resistance between the electrodes is considerably reduced, whereby
the alarm circuit may be actuated. During the heating time of about
one minute, the operation of the alarm circuit must be
inhibited.
BRIEF SUMMARY OF THE INVENTION
It is a main object of the invention to provide a simple and
effective circuit arrangement for a gas indicator of the
above-mentioned kind.
Another object of the invention is to provide a gas indicator of
the above-mentioned kind adapted to be constructed as a portable
apparatus.
According to the invention, a gas indicator is constructed in such
manner that the operation of the alarm circuit is inhibited during
the activating time by a delay circuit controlling a first bistable
circuit changing its state at the end of the activating time, and
the current flowing through the semiconductive body in the presence
of a gas to which the sensor is sensitive causes a change of state
of a second bistable circuit, the output signals of the two
bistable circuits occurring after their changes of state being
supplied to a coincidence circuit actuating the alarm circuit when
both output signals are present.
In some cases, it is desirable to construct the gas indicator
according to the invention as a portable apparatus, which may be
carried along by persons working, for instance, in a mine, s ship
hold or a sewer, so that they are warned upon the occurrence of
harmful gases. A portable apparatus of this kind may also be
arranged in a motor car to warn the passengers upon the occurrence
of carbon monoxide.
Such a portable apparatus would, of course, have to be fed by a
battery, which ought to have a voltage of at least 6 volts, and
preferably of 12 volts in order to obtain a sufficient energy for
the alarm circuit. However, this leads to some difficulties in
connection with the feeding of the filament which is laid out for a
voltage of one volt at a current of one ampere. The required
current of one ampere can only be furnished during a short time by
a battery having a reasonable weight, and a series resistor must be
used to reduce the battery voltage to the voltage of one volt
required for the filament, whereby a considerable energy is
lost.
This difficulty may be removed by using, as a current source, a
D.C. source also feeding an oscillator of which the output energy
feeds the filament. The use of an oscillator for feeding the
filament leads to an important additional advantage. If the
oscillator frequency is suitably chosen, it is possible to insert a
piezo-electric sound generator fed by the oscillator in the alarm
circuit, so that a very strong acoustic alarm is obtained by simple
means. For this purpose, the oscillator voltage may be supplied to
a third input terminal of the coincidence circuit.
In a particularly effective embodiment of the invention, adapted to
be fed from the A.C. mains, a voltage is supplied, when the
indicator is switched on, to the series circuit of a resistor and a
condenser, the first bistable circuit being constructed as a
Schmitt trigger controlled by the voltage across the condenser, so
that the first bistable circuit delivers a 1-signal during the
activating time and a 0-signal after termination of the activating
time, said 0-signal being inverted and the 1-signal obtained by
this inversion being simultaneously supplied to one of the input
terminals of a nand-gate, and through a series resistor to the base
of an emitter follower; furthermore, the current path between the
electrodes of the sensor is connected between the base of said
emitter follower and ground, and the emitter voltage of said
emitter follower is supplied to the second bistable circuit, which
is constructed as an inverting Schmitt trigger and of which the
output signal is supplied to the second input terminal of said
nand-gate, in such manner that the emitter voltage of said emitter
follower disappears upon occurrence of a gas after termination of
the activating time, whereby the second bistable circuit delivers a
1-signal and the nand-gate is operated to deliver a 0-signal which
actuates the alarm circuit.
The above-mentioned inversion of the 0-signal of the first bistable
circuit may be performed by a third bistable circuit constructed as
an inverting Schmitt trigger. Preferably, the 0-signal of the said
nand-gate is supplied, after inversion, to an input terminal of a
second nand-gate, of which the other input terminal is controlled
by an oscillator, and of which the output signal feeds a
loudspeaker. Furthermore, it is recommendable to supply the
inverted 0-signal of the first-mentioned nand-gate to one of the
ends of a relay coil of which the other end is connected with the
1-voltage, so that the relay is de-energized and actuates, by means
of a back contact, means for removing the dangerous condition, such
as an exhauster.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention is further explained by reference to the drawings,
showing two embodiments, and in which:
FIG. 1 shows a gas indicator according to the invention which is
fed by a D.C. current source, so that it may be constructed as a
portable apparatus; and
FIG. 2 shows a gas indicator according to the invention which may
be fed from A.C. mains.
DETAILED DESCRIPTION
The circuit arrangement shown in FIG. 1 is fed by a D.C. source
having a voltage of 12 volts, and connected with the terminals 1
and 2. The gas sensor proper consists of a semiconductive body 3,
incorporating two electrodes 4 and 5. The electrode 4 has a helical
shape and serves as a filament for activating the sensor. The
electrode 5 may, in principle, have any desired shape; however, it
is generally also shaped as a helix, so that each of the electrodes
4 and 5 may be used as a filament, as desired.
An oscillator 6 operating, for instance, at a frequency of the
order of 800 cycles per second, is connected with the terminals 1
and 2. The output energy of the oscillator is supplied to the
filament 4 through a transformer 7.
The filament 4 is also connected with the positive terminal 1 of
the D.C. source, so that the entire voltage of this source is
available for controlling the alarm circuit.
During the activating time, the alarm circuit is blocked. Use is
made, for this purpose, of a delay circuit provided with a
condenser 8, which is charged by the D.C. source through an
adjustable resistor 9. After 1 minute, the voltage across condenser
8 has obtained such a value that a unijunction transistor 10 is
rendered conductive. A voltage impulse is thereby generated across
a resistor 11, and supplied through a resistor 12 to the 1-input
terminal of a bistable circuit 13. The voltage occurring at the
1-output terminal of the circuit 13 is supplied to one of the input
terminals of an and-gate 14. The 0-input terminal of the circuit 13
is connected with the terminal 1 through the series connection of a
resistor 15 and a condenser 16, so that the circuit 13 is always
brought into its 0-condition when the indicator is connected with
the D.C. source.
The electrode 5 of the sensor is connected with a resistor 17, and
with the input terminal of a Schmitt trigger 18. When the
resistance of the semiconductive body is reduced by the presence of
a gas, a current flows through resistor 17, whereby the trigger 18
changes its state. The output terminal of the trigger 18 is
connected with a second input terminal of the and-gate 14.
The oscillator voltage is supplied through a conductor 19 to the
third input terminal of the and-gate 14. The output circuit of the
and-gate 14 contains a piezo-electric sound generator 20 tuned to
the oscillator frequency.
It will be clear that the oscillator voltage is transmitted to the
piezo-electric sound generator if two conditions are satisfied,
namely that the activating time has expired so that the bistable
circuit 13 is in its 1-condition, and that the resistance between
the electrodes 4 and 5 has a low value, so that the Schmitt trigger
18 has changed its state. Thus, an alarm is given when the said
conditions are satisfied.
The transformer 7 may form a part of the frequency determining
circuit of the oscillator 6, and may be provided with a third
winding for feed-back purposes.
In the gas indicator shown in FIG. 2, the inhibition of the alarm
circuit during the activating time is also obtained by means of a
delay circuit comprising a condenser 8 and a resistor 9; this delay
circuit is connected with a D.C. voltage when the indicator is
switched on. The voltage across condenser 8 controls a Schmitt
trigger consisting of two transistors 21 and 22 having a common
emitter resistor; the collector of each transistor is connected
through a resistor with the base of the other one. When the
indicator is switched on, the condenser 8 is not yet charged, so
that transistor 22 is cut off. Thus, the collector of this
transistor carries a positive voltage, which may be considered as a
1-signal, and which is supplied to the output line 23 of the
trigger. At the end of the required activating time, the voltage
across condenser 8 has increased to such a value that the trigger
21, 22 changes its state, so that a 0-signal appears in line
23.
The 0-signal in line 23 is converted into a 1-signal by means of an
inverting Schmitt trigger 24; this 1-signal is supplied to one of
the input terminals of a nand-gate 25, and through an adjustable
series resistor 26 to the base of an emitter follower 27. The base
of transistor 27 is also connected with the electrode 5 of the
sensor 3; the filament 4 is fed with an A.C. voltage of 1 volt at a
current of one ampere, derived from the A.C. mains by means of a
transformer. The activated sensor has a high resistance, so that
the base voltage of transistor 27 is not influenced by the sensor.
In this case, the emitter of transistor 27 carries a 1-signal,
which is supplied to an inverting Schmitt trigger 28, so that this
trigger delivers a 0-signal. This 0-signal is supplied to the
second input terminal of the nand-gate 25, and through two
inverting amplifiers 29 and 30 to a green indicating lamp 31, so
that this lamp is ignited to indicate that no gas is present.
Upon occurrence of a gas to which the sensor is sensitive, the base
of transistor 27 is grounded through a small resistance, so that
the emitter delivers a 0-signal which is converted into a 1-signal
by the trigger 28. The green lamp 31 is now extinguished, and both
input terminals of the nand-gate 25 carry 1-signals, so that the
gate is operated and delivers a 0-signal, which is converted into a
1-signal by an inverting amplifier 32. This 1-signal is supplied to
one of the ends of a relay coil 33, of which the other end is
connected with the 1-voltage, so that the relay is de-energized. A
back contact of the relay actuates means for removing the dangerous
condition, such as an exhauster. Through an inverting amplifier 34,
a red indicating lamp 35 is ignited, indicating a dangerous
condition.
The 1-signal at the output terminal of amplifier 32 is also
supplied to one of the input terminals of a nand-gate 36, of which
the other input terminal is connected with an oscillator 37. The
oscillator signal is now supplied through amplifiers 38 and 39 to a
loudspeaker 40, whereby an acoustic alarm is obtained.
The above-described circuit arrangement may be composed of
integrated circuits, in such manner that the triggers 24 and 28 are
incorporated in a first integrated circuit, the amplifiers 29, 30,
32, 34, 38 and 39 in a second integrated circuit, and the gates 25
and 26, together with the oscillator 37, in a third integrated
circuit. It will be understood that the assembly of the circuit
arrangement is rendered very simple in this manner.
The D.C. voltage for feeding the various parts of the circuit
arrangement may, for instance, amount to 5 volts, and is derived
from the A.C. mains voltage by transformation and
rectification.
Instead of the delay circuit 8, 9, thermal devices may be used for
the inhibition of the alarm circuit during the activating time, for
instance a bimetal switch or a resistance with a negative
temperature coefficient. In this case, the thermal device is
gradually heated after the gas indicator has been switched on, so
that it may bring about a change-over after expiration of the
desired activating time.
* * * * *