U.S. patent number 3,893,905 [Application Number 05/399,561] was granted by the patent office on 1975-07-08 for fluid catalytic cracking process with improved propylene recovery.
This patent grant is currently assigned to Universal Oil Products Company. Invention is credited to Robert F. Anderson, Ellsworth R. Fenske.
United States Patent |
3,893,905 |
Fenske , et al. |
July 8, 1975 |
Fluid catalytic cracking process with improved propylene
recovery
Abstract
In a fluid catalytic cracking process, a method of condensing
fractionation zone overhead vapors and separating resultant liquid
and vapor phases to improve recovery of a propylene rich product. A
differential condenser is employed to withdraw condensed liquid
from vapor, as the liquid condenses, in order to limit mixing of
the phases. This reduces the amount of propylene passing in the
liquid phase to gas concentration facilities, and thereby increases
the quantity of propylene recovered.
Inventors: |
Fenske; Ellsworth R. (Palatine,
IL), Anderson; Robert F. (La Grange Park, IL) |
Assignee: |
Universal Oil Products Company
(Des Plaines, IL)
|
Family
ID: |
23580015 |
Appl.
No.: |
05/399,561 |
Filed: |
September 21, 1973 |
Current U.S.
Class: |
585/653; 585/700;
203/87; 208/113; 208/103; 208/120.01 |
Current CPC
Class: |
C10G
11/18 (20130101) |
Current International
Class: |
C10G
11/18 (20060101); C10G 11/00 (20060101); B01j
009/20 (); C07c 011/06 (); C01b 033/28 () |
Field of
Search: |
;208/113,103
;260/677A,683R ;203/87 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Schmitkons; G. E.
Attorney, Agent or Firm: Hoatson, Jr.; James R. Erickson;
Robert W. Page, II; William H.
Claims
We claim as our invention:
1. In a fluid catalytic cracking process wherein (i) a hydrocarbon
feed contacts cracking catalyst at cracking conditions in a
reaction zone, (ii) reaction products are withdrawn from the
reaction zone and introduced into a fractionation zone, (iii)
overhead vapors from the fractionation zone are passed to a
condenser, and (iv) effluent from the condenser passes in separate
conduits to gas concentration facilities, the improvement which
comprises: condensing said overhead vapors in a differential
condenser and in said differential condenser separating the
overhead vapor into a gaseous phase containing propylene and a
liquid phase comprising hydrocarbon molecules having 4 or more
carbon atoms, said separation being effected by withdrawing liquid
phase upon condensation to form gaseous and liquid phases
containing a non-equilibrium distribution of propylene.
2. The improvement of claim 1 further characterized in that said
differential condenser is maintained at a pressure within the range
of about atmospheric to 40 psig.
3. The improvement of claim 1 further characterized in that the
temperature of said liquid phase withdrawn from said differential
condenser is maintained in the range of about 80.degree.F to
120.degree.F.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The field of art to which this invention pertains is hydrocarbon
processing. Specifically, this invention relates to a fluid
catalytic cracking process (FCC) in which the recovery of propylene
product is improved.
2. Prior Art
The advent of high activity zeolitic catalysts has had a marked
effect on operating pressures in FCC units. To maintain the high
activity and favorable yield distribution characteristics of
zeolitic catalysts, it is necessary to maintain low coke levels.
This has been achieved in old and new units by increasing the
operating pressure. Higher pressure is conducive to more efficient
coke burning in the regenerator and thereby lower coke on catalyst.
However, this recent increase in operating pressure has accentuated
the traditional problem of imperfect recovery of propylene from
reaction products.
In FCC units, propylene is intended to leave the FCC factionator
overhead receiver in the vapor phase, from which it is recovered in
downstream gas concentration facilities. Part of the propylene
leaving the overhead receiver in the liquid phase is lost to a
by-product stream (fuel gas). By virtue of the mixing which takes
place between liquid and vapor phases in conventional overhead
condensing and receiving steps, the liquid phase leaving the
receiver carries with it a considerable amount of propylene which
is later lost. Increased loss is experienced when the unit
operating pressures are increased in view of the fact that the
liquid-vapor equilibrium at higher pressures favors more propylene
in the liquid phase.
The present invention reduces the amount of propylene lost in FCC
units operating either at lower or higher pressures. In the
embodiments of this invention a differential condenser increases
the quantity of propylene in the vapor phase stream introduced to
gas concentration facilities so that more propylene is recovered as
a valuable product.
OBJECTS AND EMBODIMENTS
It is an object of the present invention to provide an improvement
to the FCC process whereby recovery of propylene is improved. It is
a further object of this invention to increase the value of FCC
process products.
In one embodiment our invention affords, in a fluid catalytic
cracking process wherein (i) a hydrocarbon feed contacts cracking
catalyst at cracking conditions in a reaction zone, (ii) reaction
products are withdrawn from the reaction zone and introduced into a
fractionation zone, (iii) overhead vapors from the fractionation
zone are passed to a condenser, (iv) effluent from the condenser
passes in separate conduits to gas concentration facilities, the
improvement which comprises; introducing said overhead vapors into
a differential condenser and therein separating resultant liquid
and vapor phases.
BRIEF SUMMARY OF THE INVENTION
Our invention involves an improvement in the recovery of propylene
products from a fluid catalytic cracking process. Condensation of
FCC fractionation zone overhead vapors, and separation of resultant
liquid and vapor phases, is accomplished through the use of a
differential condenser, rather than the combination of the
conventional condenser and overhead receiver. Condensing liquid is
removed from the differential condenser as it condenses, while a
level of condensed liquid is maintained therein. Conventional
operating conditions are employed in the differential
condenser.
BRIEF DESCRIPTION OF THE DRAWING
The attached drawing illustrates a particular embodiment of the
present invention. Only such details are included as are necessary
for a clear understanding of our invention, and no intention is
thereby made to unduly limit its scope. Unnecessary items such as
certain process streams, valves, pumps, instrumentation and other
equipment have been omitted for the sake of simplicity.
FIG. 1 is a schematic representation of an FCC process utilizing
the differential condensing technique of our invention.
FIG. 2 shows the conventional FCC process steps which are replaced
by the differential condensing step of our invention.
In FIG. 1, hydrocarbon feed entering the FCC reaction zone 7 via
line 1 contacts catalyst at reaction conditions. Reaction products
plus unconverted feed, if any, pass out of the reaction zone via
line 2 and into the FCC fractionation zone 8. In the fractionation
zone, gasoline and lighter materials are separated from the mixture
of reaction products and unconverted feed and are passed as
overhead vapors to differential condenser 9 via line 3. Overhead
vapors are differentially condensed in differential condenser 9,
and resultant liquid and vapor phases are separated in this same
step. Vapor leaves differential condenser 9 via line 4, passing
therethrough to the compression section of the downstream gas
concentration zone. Liquid from differential condenser 9 leaves via
line 5 and passes to the adsorption section of the downstream gas
concentration zone.
Referring now to FIG. 2, steps of the FCC process are shown which
are replaced by the technique of our invention. Condenser 10 and
overhead receiver 11 are replaced by differential condenser 9.
Without our invention, overhead vapors from the FCC fractionation
zone 8 pass via line 3' to condenser 10. Mixed liquid and vapor
phases leave condenser 10 via line 6 and enter overhead receiver 11
where the phases are separated. Vapor from overhead receiver 11
passes via line 4' to the gas concentration zone. Liquid from
overhead receiver 11 passes to the gas concentration zone via line
5'.
DETAILED DESCRIPTION OF THE INVENTION
Propylene is a valuable FCC unit product primarily because of its
use as a raw material in the production of polypropylene, polymer
gasoline (the gasoline produced in a polymerization process unit,)
alkylate gasoline and isopropyl alchohol. Some of the propylene
produced in the reaction zone of an FCC unit is not recovered in
the propylene product stream. It is the primary object of the
present invention to improve recovery of propylene, thereby
increasing the value of FCC unit products. Those versed in the art
are familiar with conventional FCC flow schemes in which reaction
products pass from the reaction zone to a fractionation zone where
a fraction comprising gasoline and lighter materials (including
propylene) is separated from heavier reaction products and
unreacted feed. Gasoline and lighter materials leave the
fractionation zone as overhead vapors of a fractionator, and they
pass to a condenser and then to an accumulator called an overhead
receiver. Here the vapor and liquid phases are separated and pass
in separate conduits to different sections of the gas concentration
facilities where product and byproduct separations take place. As a
result of the configuration of gas concentration facilities, the
distribution of propylene in the aforementioned vapor and liquid
phases is critical to propylene recovery.
Vapor from the overhead receiver passes through two stages of
absorption in series. In the first stage propylene is absorbed and
sent with the absorber oil to the fractionation section of gas
concentration where the propylene is recovered as a valuable
product. propylene-bearing effluent vapor from the first stage is
sent to the second stage. In the second stage more propylene is
absorbed and returned to the FCC fractionation zone. The balance of
the propylene exits the second stage in the by-product stream
called fuel gas, thereby assuming a much lower value. Liquid from
the overhead receiver enters the first absorption stage near the
effluent vapor outlet. This entry point is only a few absorption
trays below the absorber oil inlet, so that propylene stripped from
this liquid by counter-current vapors within the absorber has
little chance to be absorbed by absorber oil in the first stage.
The result is that propylene entering with the vapor phase from the
overhead receiver traverses both absorption stages which together
may contain 48 or more absorption trays, whereas propylene entering
with the liquid phase traverses only the second absorption stage
and a few trays of the first absorption stage for a total of about
22 to 28 trays. This means that propylene absorption and resultant
recovery as a valuable product can be improved by causing more
propylene to leave the overhead receiver in the vapor phase and
less in the liquid phase.
Loss of propylene due to its leaving the overhead receiver in the
liquid phase has recently been made worse by certain FCC processing
practices. The recent development of zeolitic catalysts has
revitalized innovation in operating techniques. These new catalysts
are capable of higher activity and more attractive yield
distribution provided that carbon produced in the reaction zone is
not allowed to accumulate on the catalyst beyond certain levels.
Since raising the operating pressure of an FCC unit results in more
efficient carbon removal in the catalyst regenerator section of the
reaction zone, the trend has been to increase operating pressure.
The preferred pressure range in the past has been from about 10 to
25 psig in regenerators. Pressures in the range of 30 to 40 psig
are now quite common. Raising operating pressure results in higher
pressure in the fractionation zone, condenser and overhead
receiver, and this contributes to lower recovery of propylene.
Increased pressure in the condenser and overhead receiver changes
the vapor-liquid equilibrium and results in more propylene leaving
the receiver in the liquid phase. This presents a situation
particularly suited to use of the present invention.
Conventional condensing and overhead receiving steps are
characterized by extensive mixing of the liquid and vapor phases
during and after condensation takes place. This mixing allows
liquid and vapor to substantially reach equilibrium with respect to
the distribution of propylene in the two phases. Hence, the liquid
phase will be substantially saturated with propylene. The present
invention provides the technique of differential condensing rather
than conventional condensing and overhead receiving. Differential
condensing, a technique wherein the path of vapor and condensed
liquid are differentiated within the condensing means, provides
greater enrichment of the vapor phase with respect to
propylene.
The term enrichment relates to the increase in concentration of
propylene in the vapor phase as overhead vapor passes from the
fractionation zone to the gas concentration zone. Enrichment takes
place as nonpropylene components condense or are dissolved in the
liquid phase and disappear from the vapor phase. Enrichment is
thwarted to some extent when vapor phase propylene mixes thoroughly
with the liquid phase and is dissolved therein. Our invention
effects improved enrichment.
Differential condensing reduces contact between liquid and vapor
phases during and after condensation. One embodiment of the
differential condensing step of the present invention might be a
shell and tube heat exchanger with a receptable for holding liquid.
Coolant passes through the tubes. Baffles in the shell of the heat
exchanger are open at their lower extremity such that liquid can
flow freely from one end to the other in the shell side. The
exchanger is mounted inclined from the horizontal such that gravity
flow of liquid in the shell side is effected. The aforementioned
receptacle is mounted on the bottom of the lower end of the shell
to receive liquid as it exits the shell and to provide a liquid
level. Overhead vapors enter the top of the shell at the end of
higher elevation. Condensed liquid flows along the bottom of the
shell and exits the shell at the lower or outlet end, passing into
a receptacle. This allows condensed liquid to be withdrawn from the
differential condenser as it condenses, thereby avoiding further
contact between liquid and vapor. At the top of the outlet end
(lower end) of the shell, a conduit is provided for withdrawal of
vapors. Such an arrangement provides for condensation and
separation of liquid and vapor phases without undue contact between
the phases. An example will serve to show resulting improvement of
enrichment over conventional condensing and overhead receiving
steps.
For the purpose of giving an example, enrichment will be expressed
numerically as the ratio of propylene in the vapor going to gas
concentration to propylene in the liquid going to gas
concentration. Values of C.sub.3 .sup.= in liquid and C.sub.3
.sup.= in vapor as shown in the following table are mole fractions.
As shown below the use of a differential condensing step in place
of condensing and overhead receiving steps results in increase in
enrichment from 8.6 to 10.8, a 25% increase.
______________________________________ Pressure, *C.sub.3 .sup.= in
C.sub.3 .sup.= in E** psig vapor liquid
______________________________________ With Differ- ential
Condensing 24 17.3 1.6 10.8 With Con- densing and Overhead
Receiving 24 17.1 2.0 8.6 ______________________________________
*C.sub.3 .sup.= signifies propylene E** signifies enrichment, as
defined above.
The differential condenser is operated at the same conditions as
the condenser and overhead receiver that it replaces. These
conditions include the range of temperature of condensed liquid of
about 80.degree.F to 120.degree.F and the range of pressure of
about atmospheric to 40 psig.
* * * * *