U.S. patent number 3,893,768 [Application Number 05/408,273] was granted by the patent office on 1975-07-08 for zeeman modulated spectral source.
This patent grant is currently assigned to Canadian Patents & Development Limited. Invention is credited to Roger Stephens.
United States Patent |
3,893,768 |
Stephens |
July 8, 1975 |
ZEEMAN MODULATED SPECTRAL SOURCE
Abstract
Zeeman splitting of spectral lines may be used as a technique
for background correction in analytical atomic spectroscopy.
Conventional spectral sources suffer two main deficiencies when
using this method in that the plasma in conventional lamps becomes
unstable and eventually extinguishes when a magnetic field is
applied, an unacceptably high magnetic field strength would be
required to produce useful Zeeman splitting. In order to alleviate
the above, lamps have been constructed in which emission of atomic
resonance lines is achieved by sputtering or the volatilisation of
sample atoms by the cathodic region of a dc discharge, followed by
the excitation and emission of those atoms within the discharge and
in which a magnetic field may be applied over the discharge region
in parallel with the plasma causing electric field, resulting in
magnetic stability.
Inventors: |
Stephens; Roger (Hubbards,
CA) |
Assignee: |
Canadian Patents & Development
Limited (Ottawa, CA)
|
Family
ID: |
23615590 |
Appl.
No.: |
05/408,273 |
Filed: |
October 23, 1973 |
Current U.S.
Class: |
313/161; 313/618;
313/163 |
Current CPC
Class: |
G01J
3/10 (20130101) |
Current International
Class: |
G01J
3/10 (20060101); G01J 3/00 (20060101); G01j
003/30 (); H01j 001/50 () |
Field of
Search: |
;356/85,87
;313/161,163,209,210,217 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: McGraw; Vincent P.
Attorney, Agent or Firm: Rymek; Edward
Claims
I claim:
1. A spectral source comprising:
first and second spaced electrodes mounted within said spectral
source, said first and second electrodes adapted to be connected
across a potential source to produce a plasma causing electric
field having substantially parallel straight lines of electric
force in a predetermined discharge region between said electrodes
and at least one of said electrodes including a material adapted to
emit radiation having predetermined spectral lines; and
means adapted to apply a magnetic field to said discharge region
with the axis of the magnetic field substantially parallel to said
lines of electric force, for producing Zeeman splitting of said
spectral lines.
2. A spectral source as claimed in claim 1 in which at least a
portion of each of said electrodes includes a plane surface; said
electrodes positioned to provide the discharge region between
substantially parallel plane surfaces.
3. A spectral source as claimed in claim 2 in which each of said
electrodes consists entirely of said predetermined radiation
emitting material.
4. A spectral source as claimed in claim 2 in which said plane
surface of each electrode is coated with said predetermined
radiation emitting material.
5. A spectral source as claimed in claim 2 in which the first
electrode includes a first predetermined radiation emitting
material and the second electrode includes a second predetermined
radiation emitting material.
6. A spectral source as claimed in claim 2 in which the plane
surface of the electrodes are positioned slightly out of parallel
to provide a maximum view of the surfaces in one direction.
7. A spectral source as claimed in claim 1 wherein:
said predetermined radiation emitting material is liquid,
said first electrode includes a rigid wire with one end in
electrical contact with said material;
said second electrode includes a second rigid wire mounted in
parallel to the first wire, to provide a discharge region between
said electrodes.
8. A spectral source as claimed in claim 1 wherein:
said predetermined radiation emitting material is an alkali or an
alkaline earth element;
said first electrode includes a first non-conducting cylinder; and
an electrically conducting rod, axially bored along a portion of
its length, positioned within said first cylinder, with said
material packed within said bore;
said second electrode includes a second non-conducting cylinder;
and a rigid electrically conducting wire positioned within said
second cylinder;
said electrodes mounted within the spectral source to provide a
line discharge region between the end of said first electrode and
the end of said second electrode.
9. A spectral source as claimed in claim 1 wherein:
said predetermined radiation emitting material is liquid;
said first electrode includes a thin rigid metal sheet with one end
in electrical contact with said material and
said second electrode includes a second rigid metal sheet mounted
in parallel to said first sheet, to provide a discharge region
between said electrodes.
Description
This invention relates to spectral sources and in particular to
novel spectral lamps which may effectively be Zeeman modulated.
Zeeman splitting of spectral lines may be used as a technique for
background correction in analytical atomic spectroscopy. The method
assumes a comparable background absorption of perturbed and
non-perturbed components of the original spectral line, whereas
atomic absorption only occurs on the unperturbed component due to
the narrow absoption profiles of atomic spectral lines. Thus the
perturbed components carry information on the noise levels of an
analytical atomic absorption signal which can be used to correct
and reduce such noise levels, correspondingly improving analytical
sensitivity.
The difficulty of applying this method at the present time lies in
the difficulty of building Zeeman modulated spectral sources. Due
to the interactions between normal plasmas and magnetic fields,
conventional hollow cathode lamps cannot be used, since the
application of the field simple extinguishes the plasma.
In addition, existing hollow cathode lamps would demand
unacceptable large magnets to give sufficiently high field
strengths to produce useful Zeeman splittings.
These problems are discussed in more detail in a paper by N. Ioli,
P. Minguzzi and F. Strumia entitled "Operation of HIgh-Intensity
Spectral Lamps in a Strong Magnetic Field" which appeared in the
Journal of the Optical Society of America, Volume 60, Number 9 --
September 1970. Thus, Zeeman modulated sources are generally built
at present using high frequency discharges. These require high
power R.F. or microwave generators, and usually very large magnets
to produce useable Zeeman splitting.
It is therefore an object of this invention to provide a novel
spectral lamp.
It is a further object of this invention to provide a spectral lamp
which may readily be Zeeman modulated.
It is yet another object of this invention to provide a spectral
lamp which may be Zeeman modulated using permanent or low power
electro-magnets.
It is further object of this invention to provide a novel spectral
lamp which is d.c. discharged.
It is yet another object of this invention to provide a novel
spectral lamp in which either of the two electrodes may be used as
the cathode.
These and other objects are generally achieved in the novel
spectral lamp by producing a plasma causing electric field having
substantially straight lines of electric force in a predetermined
discharged region between two electrodes. A magnetic field may then
be applied to the discharge region in the lamp such that the axis
of the magnetic field is in parallel to these lines, avoiding
plasma-field interactions. This results in a plasma which is stable
in the presence of the magnetic field.
The construction of the electrode assembly in the novel spectral
lamps will vary depending on the spectral lines to be produced,
though all assemblies are governed by the above basic principle.
Embodiments will be described for cathode materials with melting
points between 600.degree. and 1,200.degree.C, for materials with
low melting points, i.e. between 200.degree. and 600.degree.C, for
materials with high melting points, i.e., above 1,200.degree.C, for
liquid materials and finally for alkali and alkaline earth
materials.
In the drawings,
FIG. 1 is a partial cross-section of the novel spectral lamp with
one embodiment of the electrode assembly;
FIG. 2 is a cross-section of the electrode assembly taken along
line A--A in FIG. 1;
FIG. 3 is a view of one type of electrode used in the novel
lamp;
FIG. 4 is a view of a second type of electrode;
FIG. 5 is a view of a third type of electrode;
FIG. 6 is a cross-section of an electrode assembly including a
liquid material;
FIG. 7 is a cross-section of an electrode assembly including alkali
or alkaline earth materials, and
FIG. 8 is a cross-section of the electrode assembly taken along
line B--B in FIG. 7.
As shown in FIGS. 1 and 2, the spectral lamp 1 includes a
conventional glass envelope 2 with a quartz window 3 sealed in the
front end and a vacuum take-off and seal tube 4 located at the
other end. The novelty of the present spectral lamp rests with the
electrode assembly 5.
The electrode assembly includes two electrodes 6 which are mounted
substantially in parallel to one another. The assembly is sealed in
place at the back end of the envelope such that the tube may be
evacuated through tube 4 and filled with a rare gas such as argon
or neon at a pressure usually between 5 and 50 torr. The electrodes
are thus substantially perpendicular to the envelope windows so
that when an appropriate voltage is applied between the electrodes,
an electric field having substantially straight lines of electric
force is created, causing a discharge between the electrodes which
emits a radiation beam with predetermined spectral lines through
the quartz window 3. A d.c. source is preferred, however a R.F. or
a microwave generator may also be used as potential sources.
The outer case of the electrodes assembly 5 may be made entirely of
materials such as soft iron so as to transmit a magnetic field
through the assembly as effectively as possible. However only walls
7 need be made of soft iron since the poles M of the magnet used in
Zeeman splitting will be located adjacent these walls. For Zeeman
splitting, either a permanent magnet or an electromagnet may be
used.
Finally a reflective surface 8 may be mounted at the end of the
electrode assembly 5, or as shown in FIG. 1, it may form the end
wall 8 of the assembly. The surface will reflect radiation emitted
in this direction towards the front window 3.
As in all spectral line sources, the spectral lines produced
depends on the materials used in the construction of the cathode.
As the different materials have different melting temperatures, the
electrode assembly will vary to take this into account and have
been divided into five categories.
Category 1 includes materials having a melting point between
600.degree.C and 1,200.degree.C such as silver, copper and
magnesium. This embodiment includes electrodes 6 as shown in FIG.
3.
Electrode 6 may consist of a plane strip having a thickness t from
0.001 inches to 0.01 inches, though only the section in the lower
portion 6' immediately adjacent the discharge region need be flat.
This section may also be necked, as shown, to raise the cathode
temperature. The upper portion 6" may be necessary in some
instances for very high power operation and will act both as a
cooling fin and as an electrode connector. However, normally 6" is
not necessary and may consist of two terminal leads. Two similarly
constructed electrodes 6 are mounted within the electrode assembly
5 as shown in FIGS. 1 and 2. An asbestos/glass combination may be
used for thermal and electrical insulation.
The electrodes are mounted substantially in parallel using spacers
9 consisting of glass. However, for optimum operation, the
electrodes themselves should be in physical contact with only a
good thermal insulator such as asbestos to avoid overheating the
glass insulators 9 (causing them to crack) or the epoxy seals
between the soft iron outer case and the glass envelope (causing
vacuum failure). Thus asbestos spacers 10 are located between the
glass spacers 9 and the electrodes 6. In addition, asbestos strips
10' are located between the electrodes 6 and the outer soft iron
wall 7 of the electrode assembly.
In order to permit a maximum view of the cathode surface in the
forward direction, a slight ridge such as a fold 11 in the asbestos
material 10 (FIG. 1) or a ridge in the electrode (not shown) may be
inserted at the front of each electrode. This forces the electrode
faces slightly out of parallel.
The glass and metal portions of the electrode assembly may be
sealed using an epoxy resin, or a single casing construction may be
used such as an all metal jacket.
Finally the faces of the poles M, used to provide a desired
magnetic field, are made to correspond to the width w and height h
(FIG. 3) of the necked portion of the electrode.
As seen in FIGS. 1 and 2, the lamp described is symmetric having
identical electrode construction. The electrodes are therefore
interchangeable, and, if made from different materials, will
provide for dual element operation of selecting the appropriate
lamp polarity.
Category 2 includes materials having a melting point between
200.degree.C and 600.degree.C such as lead, cadmium and zinc. The
electrode assembly is similar to that described above except for
the electrode structure which is shown in FIG. 4. The electrode 6
is made from a good heat conductor such as brass. The low melting
point material 12 is deposited over an area of the lower portion 6'
of the electrode. This area again corresponds to the area of the
faces of the magnet poles M. The lower portion 6' may, in addition,
be extented downward and connected to heat sinks on the exterior of
the electrode assembly. This is particularly useful if the material
concerned has a low wavelength resonance line, requiring high
excitation energy and a correspondingly high energy cathode
discharge.
The parallel electrodes may be spaced as described with regard to
category 1, and dual element operating lamps may be constructed
using the above electrodes because of the symmetry of the lamp.
Category 3 includes materials having a melting point above
1,200.degree.C such as iron, cobalt and nickel.
The cathode for these materials should have as high a temperature
as possible during operation and therefore as shown in FIG. 5, the
electrode 6 is not extended outside the electrode assembly. The
electrode material 13 is electrically connected to a rigid wire 14,
such as tungsten, having a diameter of from 0.001 inch and 0.01
inch. The wire 14 minimises heat loss and also provides electrical
contact. The electrode material should be as thin as possible
consistent with mechanical stability. However metals such as
chromium or manganese, whose mechanical characteristics do not
permit them to be readily formed into thin sheets or foil, can be
deposited on a base having a high melting point. Finally the
electrodes 6 are mounted in parallel with spacers as in FIG. 1. The
asbestos insulator 10' may be cut away at the centre. Once again,
because of the symmetry of the two electrode lamp, dual element
operating lamps may be constructed.
Category 4 includes liquid elements such as mercury. The electrodes
for such a material are shown in FIG. 6. The lamp includes a quartz
jacket 15 having a pool of the liquid material 16. Two electrodes
17, 18 made of refractory wire such as tungsten are sealed within
quartz capillaries 19. These capillaries provide for a discharge
only in the desired region. These electrodes are then sealed within
the quartz jacket 15 in parallel to each other and with one
electrode in electrical contact with the liquid material 16. The
quartz jacket may have partial sleeves of soft iron, aligned such
that the poles of a magnet may be applied to the lamp, maintaining
the magnetic and electric fields in parallel. The lamp may also
include a reflective surface on the inside or outside of the quartz
jacket 15 to direct the radiation.
As an alternative, thin metal sheet in parallel may be used as
electrodes in place of the wires, to improve lamp intensity and
stability. The cathode 17 which is dipped in the liquid material
16, vaporises the liquid into the discharge region between the
electrodes providing the predetermined radiation.
Category 5 includes the alkali and alkaline earth elements.
Electrodes for some of these elements may be made in the same
fashion as in category 2, FIG. 4, where suitable support materials
exist, however generally an electrode assembly as shown in FIGS. 7
and 8 will be used. The electrode assembly 5 includes an outer
casing which may have at least two walls 7 made of soft iron so as
to transmit a magnetic field as effectively as possible. The
cathode is formed by packing the cathode material 22 into the end
of a bored metal rod 21, such as copper, which provides mechanical
support. The bore having a diameter of approximately 1/60 inch. The
rod 21 is therefore in intimate contact with the element 22 and
acts as a thermal heat sink as well as an electrical contact
terminal. A pyrex or ceramic tube 20 is fitted over the entire
length of the rod 21 such as to prevent discharge from any part of
the rod except the end where the cathode material 22 is exposed.
The cathode is mounted within the assembly 5. The anode consists of
a refractory wire 24, such as tungsten covered by a second pyrex or
ceramic tube 23 which also prevents undesired discharge. The end of
the wire is bent so as to have a face with a width equal to the
diameter of element 22, as shown on FIG. 8. The anode is mounted
within the assembly 5, such that a line discharge of width equal to
the diameter of element 22 is effected between the electrodes. The
electrodes are also aligned such that the line discharge is
perpendicular to walls 7.
In all the lamps described, emission of atomic reasonance lines is
achieved by sputtering or volatisation of sample atoms by the
cathodic region of a discharge, followed by excitation and emission
of those atoms within the discharge. Magnetic stability is achieved
in all cases by arranging the axis of the applied magnet field to
be in parallel with electric field causing the plasma, over the
discharge region. This eliminates net plasma-field
interactions.
The lamps are normally `run in` for a period of up to about 5
hours. This consists of initial high current operation under argon
or neon for 2 or 3 minutes, followed by evacuation and re-filling.
The cycle is repeating at gradually reduced lamp currents and
increasing running times until a stable output is obtained. This
`conditions` the cathode, and the lamp is then sealed. For the
lamps which are symmetric, i.e., two identical electrodes, either
electrode may act as cathode for dual operation and therefore each
electrode should be conditioned separately while it is acting as
cathode. Finally, with very volatile elements some anodic
sputtering may occur, leading to the emission of a mixture of lines
from both the anode and the cathode.
* * * * *