U.S. patent number 3,891,089 [Application Number 05/276,941] was granted by the patent office on 1975-06-24 for peelable heat seals for packages.
This patent grant is currently assigned to Rexham Corporation. Invention is credited to Charles C. Goodwin, James H. Grimm, David L. Rounsaville.
United States Patent |
3,891,089 |
Goodwin , et al. |
June 24, 1975 |
Peelable heat seals for packages
Abstract
Methods and compositions are disclosed for providing a sealed
non-leaking, non-contaminating flexible package for articles to be
subsequently used, with the package being comprised of at least one
uncoated layer of paper and one layer of a material other than
paper, and with the seal for the package being readily peelable,
substantially in the absence of any destruction of the matrix of
the layers previously joined by the seal. The above is achieved by
heat sealing said paper layer to a film of ethylene-vinyl acetate
copolymer, having a content of vinyl acetate within the range of
between about 9 and 28%. The ethylene-vinyl acetate copolymer film
may be a self-sustaining film layer or may be laminated to one or
more different backing or supporting layers prior to heat sealing
to the paper.
Inventors: |
Goodwin; Charles C. (Broadway,
NJ), Rounsaville; David L. (Milford, NJ), Grimm; James
H. (Milford, NJ) |
Assignee: |
Rexham Corporation (New York,
NY)
|
Family
ID: |
23058729 |
Appl.
No.: |
05/276,941 |
Filed: |
August 1, 1972 |
Current U.S.
Class: |
206/439; 428/192;
428/514; 428/220; 428/520 |
Current CPC
Class: |
B65D
65/38 (20130101); Y10T 428/31906 (20150401); Y10T
428/31928 (20150401); Y10T 428/24777 (20150115) |
Current International
Class: |
B65D
65/38 (20060101); B65d 081/20 () |
Field of
Search: |
;161/250,251,270,406,216,247,252,147 ;260/78.5B,78.5BB,78.5UA,87.3
;206/63.2R,46SG,46ST,438,439 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: Dixon, Jr.; William R.
Attorney, Agent or Firm: Mandeville and Schweitzer
Claims
What is claimed is:
1. A readily openable flexible package for use in containing
objects which may be sterilized after sealing of the package,
comprised of two layers in facing contact sealed only along a
continuous peripheral seal to form said package, said seal being
readily rupturable in the absence of destruction of the matrix of
said layers, the combination consisting essentially of a first
layer of paper and a second layer of ethylene-vinyl acetate
copolymer film having a vinyl acetate content within the range of
between about 9 and 28%, said first and second layers being heat
sealed together in facing contact to form an object containing
pocket.
2. A flexible package as described in claim 1, in which said first
layer is selected from the group consisting of standard
sterilizable kraft paper, wet strength strongly-bonded sterilizable
kraft paper, glassine, parchment, pouch paper, food grade
cardboard, Red Wallet mailing paper, and Laundry Tag waterproof
paper.
3. A flexible package as recited in claim 1, in which said second
layer is a laminate comprised of said copolymer film laminated on
the side opposite said first layer to a backing layer comprised of
a member selected from the group consisting of paper, foil,
polyolefins, polyesters, polyvinyl chloride,
chlorotrifluoroethylene, cellulose acetate and mixtures
thereof.
4. A flexible package as recited in claim 1, in which said first
layer is a laminate comprised of said paper bonded on the side
opposite said second layer to a layer of a material selected from
the group consisting of foil, paper, polyolefin films and mixtures
thereof.
5. A flexible package as recited in claim 1, in which said
copolymer film layer has a thickness within the range of between
about 0.5 and 5 mils.
6. A flexible package as recited in claim 3, in which said
copolymer film has a thickness within the range of between about
0.33 - 2 mils.
Description
Generally speaking, this invention is directed to the preparation
of packages from plies of materials normally used in packaging
various articles for commerce. More particularly, this invention
relates to methods and compositions for the preparation of such
packages in which one of the facing layers utilized for sealing the
contents of the package is an uncoated paper and the other layer is
ethylene-vinyl acetate copolymer, with the two layers heat sealed
together in a manner whereby the contents of the package are
effectively maintained in a non-leaking and non-contaminating
environment until such time when the articles are to be used. The
seal is readily peelable when the package is to be opened without
substantial destruction of the matrix of the paper and/or the
copolymer film joined together by the seal.
With the ever increasing use of light, flexible packaging for a
variety of items used in commerce, there is a corresponding concern
with the ability to package such items rapidly in a manner whereby
they are effectively sealed against failure of the seal and loss
and/or contamination of the articles, simultaneously with making
the packages readily openable by the user without the package
having to be totally destroyed in order for the user to gain access
to the contents of the package. This is particularly important in
such instances where the contents of the package are to be used in
emergency situations, where access must be gained rapidly. Even in
those instances where the contents of the package are not to be
used in such emergency situations, consumers demand that articles
which are to be dispensed in such packages are readily available to
them without unnecessary pulling or tugging in order to open the
package.
In many instances, it is appropriate and desirable to utilize paper
as one of the layers of such flexible packages, not only because it
is relatively inexpensive for mass production techniques, but also
for specialized applications in which the relative porosity of the
paper, as compared with a variety of different resin products
utilized for such flexible packaging, is desirable for certain
sterilization techniques for sterilizing the contents of the
package after the package has been sealed.
In those instances when sterilization of the contents is important,
the seals joining the various plies of the package together must be
taken into consideration because the environment of the
sterilization procedures may destroy the sealing effect of the seal
prior to the time when the contents of the package are to be
utilized. A number of different materials have been proposed for
use in the plies of such flexible packages in order to provide
appropriate leak-proof seals, including flexible packages of plies
of two different plastic films and/or laminations heat sealed
together. Certain difficulties arise, however, with the use of
resin thermoplastics for the entire flexible package in that the
thermoplastics are not always porous enough for the utilization of
such sterilizing gases as ethylene oxide or propylene oxide, which
are particularly appropriate for use in sterilizing surgical
instruments or bandages, etc.. Such contents must be maintained in
their sterilized condition up to the time when the packages are
opened and the contents are to be utilized. Even in those instances
where certain of the thermoplastics are desirably porous for such
applications, their cost makes them less than desirable for mass
production purposes.
In order to overcome this difficulty, flexible packages have been
proposed utilizing as one of the plies therefor, paper, which is
sufficiently porous for the sterilizing gases to pass through to
the contents of the package after the package is sealed. However,
certain problems may arise with the utilization of paper, in that
effective seals cannot always be achieved between the paper and the
resin ply heat sealed to it. Certain proposals have been made for
overcoming this difficulty, including coating the paper with a clay
type material which is itself permeable to the sterilizing gases.
However, this procedure involves an extra treatment of the paper
ply utilized in the package, thus again increasing the cost of such
packages for mass production uses. Furthermore, particularly in
such instances as the use of articles in a surgical environment, it
is important that the package be readily openable be peeling the
seal without ripping or destroying the paper matrix because the
small fibers ripped or pulled from the surface of the paper ply
will contaminate the contents of the package, thus reducing the
effectiveness of the previously sterilized contents for such
uses.
As will be understood, papers of the type discussed herein must
provide an effective seal with the resin ply to which it is sealed,
so that the seal does not fail prior to use even though the
contents of the package may be relatively heavy and cumbersome and
have a tendency to jolt in shipment against the seal and break it,
thus exposing the contents to contamination and/or loss. Thus, the
problem arises in the use of paper plies for flexible packages to
provide an effective seal between that paper ply and the resin ply
to which it is joined, while at the same time making the seal
readily peelable so that the user of the contents can rapidly gain
access to the contents. This must be achieved in a manner whereby
the matrix of the paper ply is not damaged to the extent where the
individual fibers thereof may contaminate the environment in which
the package is opened. Simultaneously, such packages must be
inexpensive enough to compete in mass production applications with
more rigid packaging structures.
By contrast, and quite unexpectedly, it has now been found in
accordance with this invention that by utilizing in a flexible
package, one ply of conventional packaging papers and heat sealing
it to a second ply, the facing surface of which is ethylene-vinyl
acetate copolymer, effective seals are achieved between the paper
matrix and the copolymer (EVA). Such seals are effectively
leak-proof and are simultaneously peelable by the user at the time
when the contents are to be used, substantially in the absence of
any destruction of the paper matrix. There is no tearing or
destruction of the two layers which were previously sealed. With
such an arrangement, therefore, the user may gain access to the
package without the nuisance of having to rip apart the package and
in those instances where it is important, no loose fibers are torn
from the paper matrix which would ordinarily contaminate a surgical
environment. Furthermore, with the invention herein, effective heat
sealed packages can be achieved over a wide range of sealing
temperatures and other operating conditions for sealing, even on
conventional relatively old sealing equipment.
With the foregoing and additional objects in view, this invention
will now be described in more detail and other objects and
advantages will be apparent from the following description and the
appended claims.
Before describing this invention in more detail, it may be well to
note that this invention has been found applicable to the use of a
wide variety of papers, including standard sterilizable kraft
paper, wet strength strongly bonded sterilizable kraft paper,
glassine, parchment, a food grade cardboard, Red Wallet type
mailing paper, conventional pouch paper and Laundry Tag type
waterproof paper. Furthermore, in order to reduce the amount of EVA
copolymer utilized, the copolymer film may be first laminated to a
supporting backing layer in a conventional manner, with such
backing layer being selected depending upon the contents to be
sealed in the package and the appearance thereof, including
additional layers of paper, foil, polyolefin films, such as
polypropylene and polyethylene, polyvinyl chloride,
chlorotrifluoroethylene and cellulose acetate. The EVA copolymer
film may be first formed and then subsequently adhesively adhered
to the backing layer, it may be coextruded with a second resin film
backing layer or it may be extrusion coated onto the backing
layer.
For example, satisfactory results have been achieved in accordance
herewith, and under satisfactorily and economically attractive
conditions on commercial scale operations by first preselecting a
backing substrate, such as a bleached or unbleached kraft paper or
polypropylene film, and then extrusion coating the backing with a
film of EVA, having a vinyl acetate content within the range of
between about 9-28%, thereafter heat sealing the EVA film in
conventional manner at temperatures within the range of between
about 150.degree.-500.degree.F. to a paper ply for a period of time
to heat seal the EVA copolymer film to the paper. This results in
an effective leak-proof seal which is readily peelable subsequently
when the contents of the sealed package are to be removed,
substantially in the absence of any fiber tear or fiber pick of the
paper ply.
In this connection, it should be understood that the vinyl acetate
content of the EVA copolymer will be selected depending upon such
conditions as the type of contents to be sealed in the package, the
bulkiness or weight thereof and the degree of seal desired. For
example, a heat seal measuring 75-100 gms per inch will be
effective for such contents as a bandage but a much higher range
of, for example, 350-450 gms. per inch might be necessary for a
heavier object, such as a surgeon's scalpel.
By the use of the term "heat sealing" herein, it is meant that two
surfaces are to be joined by utilizing a combination of heat and
pressure. It is sufficient for purposes of this invention to
include any of the techniques normally used in elevating the
temperature at the joining interface, whether the techniques
involve driving heat through the full thickness of one or both
webs, from one or more outside sources.
Heat sealing may be carried out by conventional sealers such as the
Sentinel sealer or a Bartelt sealer, in which the jaws thereof are
configured to provide the appropriate configuration of seal between
the plies being joined together. Generally, that portion of the
seal of the package to be initially opened (the top) will be
curved, chevron shaped or similarly configured so as to provide an
easily grasped starting point for opening the package. By contrast,
the opposite end of the package (the bottom) will be squared off or
be in the form of a more gradual curve, all in well known
manner.
It is obvious that in preparing the seals, in accordance herewith,
the temperature used may vary depending upon the pressure and the
dwell times, as well as the vinyl acetate content of the EVA
copolymer being used and the particular paper ply being sealed to
the copolymer film. There is, of course, an infinite number of
different combinations of temperature, dwell times and pressure,
depending upon the various combinations which can be selected, as
noted above. Thus, for example, to obtain the same seal strength at
20 lbs. per square inch (psi) with a 0.25 second dwell time as
would be obtained at 40 psi with a 0.50 second dwell time, it would
be necessary to increase the sealing temperature by perhaps
25.degree.-50.degree..
In addition, the effectiveness of the various seals, in accordance
herewith, are measured in gms. per inch. Various samples were
prepared at 25.degree.F. or 50.degree.F. intervals with a fixed
pressure of 40 lbs. psi and generally with a fixed dwell time
normally of about 0.50 second, unless otherwise noted below. Each
test specimen was evaluated in an Amthor tensile testing machine
with one leg of the specimen in a fixed jaw of the machine, with
the other leg in a moveable jaw. These jaws are separated at a
constant rate, normally about 12 inches per minute and the force
required to cause the seal to peel apart or to rupture is recorded
in grams per inch of seal width.
As noted above, the EVA copolymer film may be a self-supporting
film. However, it is preferred, in accordance herewith, to use a
backing support. The backing support may be a bleached or
unbleached kraft paper, also. Examples of other backing materials
include foil, a polypropylene, saran-coated polypropylene film,
polyvinyl chloride, chlorotrifluoroethylene, cellulose acetate or
polyethylene terephthalate.
A preferred cycle of operation, in accordance herewith, for
formulating the peelable seals of this invention between a paper
ply and a film of EVA copolymer includes first preselecting a
backing film for the EVA copolymer, preferably one mil uncoated
polypropylene, and thereafter extrusion coating a film of EVA
copolymer on the backing film. The thickness of the EVA copolymer
film will generally be in the range of between about 0.5 mil - 5
mils. As noted above, thicknesses in the upper part of this range
would be a self-sustaining EVA copolymer film. Preferably, however,
the EVA copolymer film will range in thickness between 0.33 mil - 2
mils.
Thereafter, the paper ply will be selected depending on a number of
factors, including the porosity desired for subsequent gas
sterilization, for example, the smoothness of the paper surface and
the quality of the paper which ultimately will depend upon the use
for which the package is being formulated. Preferably, the paper
ply will be comprised of 100% bleached wet strength Southern Kraft,
having a minimum basis weight of 33.2 lbs., 24 .times. 36/500,
having a porosity of 125, regular Gurley-Sec., a minimum density of
8.3 lbs. per mil and a smoothness of 275/295 Sheffield, F/W.
Thereafter, the EVA copolymer is heat sealed to the paper ply
utilizing conventional sealer apparatus, as noted above, at a
temperature within the range of 150.degree.-500.degree.F., and
preferably 200.degree.-300.degree.F. at a pressure within the range
of between about 10 psi and 60 psi, for a period of time necessary
to bring about appropriate sealing between the EVA copolymer ply
and the paper ply, and preferably within the range of between about
0.03 - 0.7 seconds. In this connection, it should be understood
that commercial machines will vary with pressure, time and
temperature and these conditions will be selected depending upon
the percent of vinyl acetate content in the EVA copolymer being
utilized, as well as the particular type of paper being utilized to
seal to the EVA copolymer. Typically, with a Sentinel sealer, for
example, when sealing at temperatures within the range of
225.degree.-325.degree.F., the time utilized will be within the
range of between about 0.4 - 0.7 seconds, while if the temperature
utilized is in a higher range of, for example,
300.degree.-425.degree.F., the time involved will be within the
range of between about 0.25 - 0.50 seconds.
It should be noted, further, that it is within the purview of this
invention that the backing layer for the EVA copolymer film may be
a laminate, including such materials as unbleached kraft laminated
to a polyethylene film, which is in turn laminated to a foil.
Generally, selections for the backing materials, if more than one
is to be utilized, will depend upon the function of the final
package, its desired appearance, and the weight and/or bulkiness of
the item being packaged. Furthermore, the paper ply which is sealed
to the EVA copolymer may also be comprised of a laminate of a
variety of materials, so long as the particular papers noted above
to be sealed with the EVA copolymer film face that film during the
sealing procedures.
As purely illustrative of the results achieved, in accordance
herewith, utilizing a variety of different paper plies, one may
note the results in Table I below, in which relatively poor grade
paper plies were utilized for sealing to EVA copolymer films,
including a food grade cardboard, "Red Wallet" type mailing paper
and "Laundry Tag" type waterproof paper. It should be understood
that each of these poor grade papers are comprised of relatively
loose fiber type papers. Nevertheless, appropriate peelable seals
were achieved utilizing a variety of different sealing
temperatures.
More specifically, the specimens were sealed in a Sentinel sealer,
which was set at 46 psi, with the actual pressure being 40 psi. The
dwell time in each case was 0.3 seconds and the EVA copolymer
utilized was U.E. 643, a product of U.S. Industries containing 18%
vinyl acetate with a melt index of 9. It is to be understood,
however, that these examples are being presented with the
understanding that they are to have no limiting character on the
broad disclosure of the invention as generally set forth herein,
and as directed to men skilled in the art.
TABLE I
__________________________________________________________________________
Food Grade "Red Wallet" Type "Laundry Tag" Type Example* Temp.
.degree.F. Cardboard Mailing Paper Waterproof Paper
__________________________________________________________________________
1 175.degree. very tight peel tight peel-very soft tight peel
(130-175 gms.) peel (180-200 gms.) (55-75 gms.) 2 200.degree. very
tight peel tight peel-very soft tight peel (140-180 gms) peel
(200-220 gms.) (90-120 gms.) 3 225.degree. very tight peel tight
peel-soft peel tight peel (140-225 gms.) (230-310 gms.) (120-150
gms.) 4 250.degree. very tight peel tight peel-soft peel tight
peel-some (170-280 gms.) 240-290 gms.) fiber tear (210-230 gms.) 5
275.degree. very tight peel tight peel-soft peel tight peel-some
(180-275 gms.) fiber tear fiber tear (250-380 gms.) (250-300 gms.)
6 300.degree. very tight peel tight peel-soft peel tight peel-soft
some fiber tear fiber tear peel (320-340 gms.) (180-240 gms.)
(250-380 gms.)
__________________________________________________________________________
*Average of Ten Specimens
As can be seen from Table I, even at relatively low sealing
temperatures of 175.degree.F., a very tight peel was obtained with
the food grade cardboard, as well as with the Red Wallet mailing
paper. Furthermore, with the food grade cardboard there was no
fiber tear until a temperature range of 300.degree. was reached,
even with this very poor grade of paper. Also, as can be noted in
Example 3, a tight peel was achieved at 225.degree.F. with the
Laundry Tag type waterproof paper without any fiber tear, even with
this extremely rough surfaced paper.
Further, as illustrative of the enhanced results achieved in
accordance herewith, one may note the comparative results of the
tests noted below in Table II, in which the paper ply utilized was
KR-35YJ, a 35 lb., 24 .times. 36/500 white, machine finish paper of
the Riegel Products Corporation, manufactured from 100% bleached
Southern Kraft, having no internal additives other than a melamine
wet strength additive and the addition of HCL during formulation to
control the PH to within the range of 4.5 - 5. The wet strength
additive was added at the rate of 2.25% based on the fiber content
of the paper. The EVA copolymers used in the first 3 examples were
products of U.S. Industries, containing varying percentages of
vinyl acetate, and with varying melt indexes, as noted. The fourth
example was an EVA copolymer product of Union Carbide Company. A
Sentinel sealer was used again with a 0.3 second dwell time and an
actual pressure of 40 psi. The values shown are in gms./inch Amthor
bond.
TABLE II
__________________________________________________________________________
% of Peel Strengths Ranges at Various Temperatures in gms/inch Ex-
EVA Co- Vinyl Melt ample* polymer Acetate Index 200.degree.F
225.degree.F 250.degree.F 275.degree.F 300.degree.F
__________________________________________________________________________
1 UE-633 18% 20 50-120 300-350 350-450 400-500 450-550 fiber fiber
pick tear 2 UE-635 9% 9 20-30 110-130 150-160 260-280 220-300 3
UE-643 18% 9 200-300 300-400 350-450 400-500 430 fiber fiber pick
pick 4 DQDA-3131 20% 30 60-80 110-140 160-180 180-210 200-220
__________________________________________________________________________
*Average of Ten Specimens
As can be seen from Table II, a variety of different peel strengths
can be achieved in accordance herewith, at varying sealing
temperatures, utilizing the same dwell time and pressure, as well
as the same paper, by merely selecting different percentages of
vinyl acetate content in the EVA copolymer. Obviously, the
selection will be made depending upon the final use to which the
sealed package is to be utilized and the weight and bulkiness
characteristics of the material to be packaged. For example, in
Example 1 with an 18% vinyl acetate content, peel strengths can
vary between 50 and 450 gms. with no fiber pick, let alone fiber
tear. If some fiber pick is satisfactory for the particular use to
which the package is being made, (that is, non-sterilizable
conditions), seals can be obtained at 275.degree.F. and with a peel
strength up to 500 gms. Again, in Example 2 with a 9% vinyl acetate
content, peel strengths range from 20 to 300 gms. at varying
sealing temperatures.
As further illustrative of the results achieved herein, one may
note Table III below, in which various effective ranges of seal
strengths are noted which were achieved at different temperature
intervals for paper - EVA copolymer bonds using EVA copolymer films
having three different percentage contents of vinyl acetate. In
each incidence, the paper used for heat sealing to the EVA
copolymer was the same as that used in Table II above. The EVA
copolymer films were produced from U.S. Industries EVA copolymers
designated UE-633, UE-646 and UE-635. The readings are an average
of ten specimens in grams/inch Amthor bond. A platen-type sealer
was used in this case and the pressure was 60 psi and the dwell
time was 0.5 seconds. T designates the top of the package, S the
side seal of the package and B the bottom seal. In this instance,
the configuration of the seal was a modified chevron-shaped top
with straight sides and bottom. The UE-633 EVA copolymer film was
extruded onto a backing of polypropylene film, the UE-646 EVA
copolymer film was extruded onto a backing of unbleached Kraft
paper, and the UE-635 EVA copolymer film was extruded onto a
backing of unbleached Kraft paper. In each instance, the thickness
of the EVA copolymer films was about 1.5 mils.
TABLE III ______________________________________ 18% Vinyl 28%
Vinyl 9% Vinyl Ex- Temp. Acetate Acetate Acetate ample* .degree.F
UE-633 UE-646 UE-635 ______________________________________ 1
175.degree. very slight tick T 260-300 No Seal B 290-350 S 210-585
2 200.degree. T 10-20 T 530- No Seal B 10-20 B 500-600 S 26.5-53.3
S 535-795 3 225.degree. T 180-200 T 650 Slight Tick B 150-160 B 800
S 210-265 S 795-135 4 250.degree. T 280-300 T 270-280 B 240-250 B
220-240 S 320-425 S 265-320 5 275.degree. T 210-220 T 350-370 B
240-250 B 350-360 S 290-345 S 425-505 6 300.degree. T 230-240 T
540-550 B 250-260 B 480-500 S 290-370 S 742-850 7 350.degree. T
260-270 T 460-470 B 360-370 B 670-675 S 370-450 S 900-1010 8
400.degree. T 290-300 T 580-585 B 340-350 B 510-520 S 400-475 S
795-900 Slight Fiber tear ______________________________________
*Average of ten specimens
As can be seen, a wide variety of peel strengths can be achieved
with a wide range of sealing temperatures, depending upon materials
being used, items being packaged and so forth. For example, in
example 1 at a sealing temperature of 175.degree.F. very strong
seals were achieved with a vinyl acetate percentage of 28%, while
none was achieved for the 9%, and only slight ticking or adherence
at 18%. By the same token, good seals were achieved with 9% and 18%
content at a sealing temperature of 275.degree.F. but a peelable
seal was not achieved at 28% content of vinyl acetate. In many
instances, the choice of backing layer will be determinative of the
ranges at any particular level of vinyl acetate content and more
substantial backing layers such as polypropylene film will be
chosen for higher peel strength ranges rather than a second paper
backing for the EVA film.
Table IV below shows the results achieved under the same conditions
with the same materials as in Table III above, except that the
pressure was 40 psi and the dwell time was 0.3 seconds.
TABLE IV ______________________________________ 18% Vinyl 28% Vinyl
9% Vinyl Ex- Temp. Acetate Acetate Acetate ample* .degree.F UE-633
UE-646 UE-635 ______________________________________ 1 175.degree.
No Seal Slight Tick No Seal 2 200.degree. Very Slight T 440-450 No
Seal Tick B 490-500 S 695-740 3 225.degree. T 25-40 T 500-510
Slight Tick B 30-50 B 580-600 S 53-60 S 1065-1600 4 250.degree. T
90-100 T 700 T 20-25 B 120-130 B 700 B 30-40 S 160-185 S No reading
S 26.5-60 obtainable 5 275.degree. T 130-140 T 600 T 210-220 B
130-140 B 610-620 B 190-200 S 160-210 S 1385 S 185-210 6
300.degree. T 170-180 T 660 T 250-260 B 160-170 B 650 B 280-300 S
160-210 S No reading S 210-265 obtainable 7 350.degree. T 200-210 T
740 T 340-350 B 210-220 B 830 B 330-340 S 210-265 S 2125 S 320-420
8 400.degree. T 240-250 T 780 T 460-465 B 270-290 B 830 B 470-480 S
320-400 S 2080 S 740-850 ______________________________________
*Average of Ten Specimens
As can be seen from Table IV, decreases in temperature and dwell
times decreases the seal strength at given temperatures and vinyl
acetate levels.
Table V below gives further results using the same three EVA
copolymer films on the same backing materials bonded to the same
paper as in Tables III and IV above. In these examples, however, a
Sentinel sealer was used and comparisons were made for each example
at different pressures and dwell times as noted in the table.
TABLE V
__________________________________________________________________________
18% Vinyl 28% Vinyl 18% Vinyl Ex- Temp. Acetate Acetate Acetate
ample* .degree.F. Conditions UE-633 UE-646 UE-635
__________________________________________________________________________
1 175.degree. .5 sec 40 psi 9-14 90-120 No Seal 2 175.degree. .5
sec 60 psi 15-22 330-360 No Seal 3 175.degree. .3 sec 40 psi 9-10
40-60 No Seal 4 175.degree. .3 sec 60 psi 4-7 50-70 No Seal 5
200.degree. .5 sec 40 psi 90-100 480 Slight Tick 6 200.degree. .5
sec 60 psi 100-120 540 Slight Tick 7 220.degree. .3 sec 40 psi
70-80 450 No Seal 8 200.degree. .3 sec 60 psi 50-60 500 No Seal 9
225.degree. .5 sec 40 psi 130-150 580 100-120 10 225.degree. .5 sec
60 psi 150-170 550 200-220 11 225.degree. .3 sec 40 psi 80-90
520-530 10-15 12 225.degree. .3 sec 60 psi 120-140 No Reading 40-80
13 250.degree. .5 sec 40 psi 120-140 FT 200-250 14 250.degree. .5
sec 60 psi 140-170 FT 250-270 15 250.degree. .3 sec 40 psi 80-90 FT
120-150 16 250.degree. .3 sec 60 psi 110-150 600 120-150 17
275.degree. .5 sec 40 psi 190-230 FT 260-320 18 275.degree. .5 sec
60 psi 200-230 FT 290-360 19 275.degree. .3 sec 40 psi 110-130 FT
80-120 20 275.degree. .3 sec 60 psi 150-170 FT 180-210 21
300.degree. .5 sec 40 psi 170-190 FT -- 22 300.degree. .5 sec 60
psi 220-250 FT -- 23 300.degree. .3 sec 40 psi 160-190 FT -- 24
300.degree. .3 sec 60 psi 190-220 FT -- 25 350.degree. .5 sec 40
psi 220-250 FT -- 26 350.degree. .5 sec 60 psi 280-310 FT -- 27
350.degree. .3 sec 40 psi 180-200 FT -- 28 350.degree. .3 sec 60
psi 180-220 FT -- 29 400.degree. .5 sec 40 psi 270-350 FT 800-870
30 400.degree. .5 sec 60 psi 350-390 FT 550-650 31 400.degree. .3
sec 40 psi 190-220 FT 280-320 32 400.degree. .3 sec 60 psi 230-260
FT 300-350
__________________________________________________________________________
*Average of Ten Specimens FT-Fiber Tear
In addition, packages were produced, in accordance with this
invention, under commercial conditions on a Rotowrap machine. The
size of the packages were 2 inches .times. 103/4 inches and 35
packages were produced per minute. The paper used for the paper ply
was the same as that described in Table II above. UE-633 EVA
copolymer film having a vinyl acetate content of 18% was extruded
to a thickness of 1.5 mil on a backing of 100 gauge Hercules
polypropylene film (B502 1 mil uncoated). The side seals were made
at 340.degree.F., a dwell time of about 0.04 second, and the top
and bottom seals were made at 270.degree.-290.degree.F. Bond
strengths within the range of between about 300-400 gms/inch were
achieved for the side seals and 400-480 gms/inch for the top and
bottom seals.
In a futher run under commercial conditions, a Packmaster rotary
type Model No. 50 sealer was used. The paper used again was the
same as that described in Table II above. UE-633 EVA copolymer film
having a vinyl acetate content of 18% was extruded to a thickness
of 1.5 mils on a backing of 50 gauge Mylar, a polyethylene
terephthalate film supplied by du Pont. The packages produced were
4.25 inches machine direction and 6 inches crossweb direction and
46 packages per minute were produced. The temperature range was
275.degree.F.-300.degree.F. at 13-20 psi with a dwell time of about
0.08 seconds. The average seal strengths achieved in gms/inch were
410-445 for the top seal, 275-355 for the side seals and 300-320
for the bottom seals on the Amthor tester.
Accordingly, and as will be apparent from the foregoing, there are
provided in accordance herewith, methods and compositions for
achieving peelable seals for flexible packages over a wide range of
operating conditions while simultaneously achieving seals which
substantially eliminate fiber fuzz and/or loose fiber pick, thus
making the invention herein particularly appropriate for those uses
in which fiber contamination of the contents of packages is a
factor. Furthermore, because one of the plies of the packages or
pouches produced in accordance herewith is a porous paper, the
packages can be readily sterilized by the application of
sterilizing gases after sealing of the contents in the package.
Furthermore, because of the wide range of operating conditions
which may be utilized and the wide selection of materials which can
be utilized, old sealing equipment may be used without the expense
of undergoing alteration in that equipment prior to the use of the
invention herein. Moreover, because the plies being sealed may be
in turn laminated to other substrates, the packages and/or pouches
produced, in accordance herewith, provide a wide selection of
appearances for the final package. In addition, the materials
utilized for the packages of the invention herein are within a
range of cost of less than half the price of some materials
utilized for previous sterilizable peelable type heat sealed
packages providing comparable performance, thus making the
compositions and formulations in accordance herewith, highly
advantageous commercially. Even in those instances where cost
advantages of materials used are not achieved over some prior art
materials, the increased performance in accordance with this
invention makes the use of this invention competitive over those
cheaper materials.
While the methods and compositions herein disclosed form preferred
embodiments of this invention, this invention is not limited to
those specific methods and compositions, and changes can be made
therein without departing from the scope of this invention, which
is defined in the appended claims.
* * * * *