U.S. patent number 3,889,270 [Application Number 05/378,014] was granted by the patent office on 1975-06-10 for ink jet recording material.
This patent grant is currently assigned to Agfa-Gevaert Aktiengesellschaft. Invention is credited to Klaus Hoffmann, Hans-Dieter Konig, Rudolf Meyer.
United States Patent |
3,889,270 |
Hoffmann , et al. |
June 10, 1975 |
Ink jet recording material
Abstract
Ink jet images are produced by spraying the recording substrate
with a fine jet of a coloured liquid which is mudulated according
to the image. The new type of recording material consists of a
transparent or opaque substrate and an image receiving layer is
formed by a molecular disperse or colloidal disperse substance. It
is important that the image receiving layer should be wetted by the
coloured liquid and that, after spraying, the coloured liquid
should penetrate the layer to a depth of at least several microns.
Ink jet images of high quality can be obtained with such a
recording material.
Inventors: |
Hoffmann; Klaus (Leverkusen,
DT), Konig; Hans-Dieter (Leverkusen, DT),
Meyer; Rudolf (Leverkusen, DT) |
Assignee: |
Agfa-Gevaert Aktiengesellschaft
(Leverkusen-Bayerwerk, DT)
|
Family
ID: |
5850711 |
Appl.
No.: |
05/378,014 |
Filed: |
July 10, 1973 |
Foreign Application Priority Data
|
|
|
|
|
Jul 15, 1972 [DT] |
|
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2234823 |
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Current U.S.
Class: |
347/105; 347/101;
427/457 |
Current CPC
Class: |
B44D
3/18 (20130101); B41M 5/52 (20130101); B41M
5/5218 (20130101); B41M 5/5254 (20130101); B41M
5/5236 (20130101) |
Current International
Class: |
B44D
3/18 (20060101); B41M 5/52 (20060101); B41M
5/50 (20060101); B41M 5/00 (20060101); G01d
015/18 (); G01d 015/20 () |
Field of
Search: |
;346/1,75,135
;117/155UA,156,157,37LE,93.4NC |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sofocleous; Michael
Attorney, Agent or Firm: Connolly and Hutz
Claims
What we claim is:
1. In a process for information recording comprising producing a
fine jet of colored liquid, directing the jet of colored liquid
onto a recording medium, modulating the density of the applied jet
by an electric field in accordance with the information to be
recorded, the improvement comprising the recording medium
consisting of a support with an image-receiving layer, wherein the
image-receiving layer is a molecular or colloidal disperse
substance, which is wetted by the colored liquid and into which the
colored liquid penetrates to a depth in the order of a few
microns.
2. A process according to claim 1 wherein the image receiving layer
comprises a protein, a polysaccharide, cellulose, a cellulose
derivative, a polyvinyl alcohol, a copolymer of vinyl alcohols or a
hydrophilic silica gel.
3. A process according to claim 2 wherein the image receiving layer
comprises gelatin, albumen or casein.
4. A process according to claim 1 wherein a white toner is added to
the image receiving layer.
5. A process according to claim 1 wherein the image receiving layer
is treated with a substance which produces a directional reflection
in the optically visible wave-length range.
6. A process according to claim 5 wherein the image receiving layer
is cast on a polyolefine layer.
7. A process according to claim 5 wherein a layer of polyolefine is
cast on the image receiving layer after the recording has been
made.
8. A process according to claim 5 wherein a glossy surface is
imparted to the image receiving layer by heating in a glazing press
or by calendering.
Description
This invention relates to a recording material for ink-jet images
which are produced by spraying a fine jet of a coloured liquid
which is modulated according to the image. The recording material
basically comprises a transparent or opaque substrate and an image
receiving layer on this substrate.
A recording technique has recently become known by the term ink-jet
process, in which technique a very fine jet of coloured liquid
sprayed from a capillary tube is modulated in density according to
the image by an electric field. The jet of coloured liquid from the
capillary impinges on the substrate at a high velocity
(approximately 20 m/sec). The ink jet process has been described,
for example, in German Auslegeschrift DT-AS No. 1,271,754 and in
British Patent Specification No. 1,123,587.
It has now been found that the quality of the image depends to a
large extent on the properties of the recording material. The
materials used for recording substrates have previously been paper
or synthetic resin materials resembling paper in consistency or
transparent foils, depending on whether the image to be produced is
a transparency or an image viewed by reflected light.
The practice has already been adopted of improving the quality of
the images viewed by reflected light by adding white or tinted
pigments to the paper. In the case of paper which has not been
coated, however, it is observed that the droplets of coloured
liquid break on the surface of the paper or the ink solution
spreads out so that the quality of the image is deleteriously
affected as regards its resolution and visual density and the
colours are matt and dull. If for the production of colour images,
several different dye solutions are sprayed simultaneously or at
short intervals onto the substrate, there is the added risk that
the solutions will not dry or be absorbed by the surface
sufficiently rapidly but will intermingle. In that case, cloudy
irregularities are observed, especially in the case of large
coloured or black areas. In addition, the colours sprayed on
uncoated surfaces are generally not smudge-proof.
The substrates used for the production of transparencies by the
ink-jet process are generally transparent foils (e.g. Cellite or
polyester) but these foils generally have the disadvantage that
their surfaces repel dye solutions, and the ink droplets coalesce
to larger drops on the surface. Continuous colour surfaces are
therefore not obtained.
It is an object of this invention to find an improved recording
material for reflection copies and for transparencies. The
individual properties in which improvement is required are:
1. The power of resolution should be increased.
2. The dye solution should not run after it has been sprayed on the
surface and it should be fixed as quickly as possible on, or also
in, the image receptor layer.
3. The smudge resistance should be increased.
4. A gloss effect is desired in order to achieve high visual
density of reflection and high colour brilliance in reflection
copies.
5. Uniform optical densities should be achieved in
transparencies.
In a recording material which comprises a transparent or opaque
substrate and an image receiving layer on this substrate, these
conditions are substantially fulfilled if the image receiving layer
comprises, according to the invention, of a moleculae disperse or
colloidal disperse substance which is wetted by the coloured liquid
and into which the sprayed coloured liquid preferably penetrates to
a depth of at least several microns.
The image receiving layer preferably consists of a protein,
polysaccharide, cellulose or cellulose derivative, polyvinyl
alcohol or a copolymer of vinyl alcohols. Image receiving layers of
gelatine, albumen or casein are found to be particularly suitable.
Very good results have also been obtained with an image receiving
layer consisting of a hydrophilic silica gel.
For reflection copies, it is advantageous to add dyes and/or white
toners to the image receiving layer to increase the degree of
whiteness.
For reflection copies, the recording material may be further
improved by treating the image receiving layer with substances
which produce a directional reflection in the optically visible
wavelength range. Such a gloss effect can advantageously be
produced by casting the image receiving layer on a layer of a
polyolefine such as polyethylene or a polypropylene. An alternative
method of producing a glass effect consists of pouring a layer of
polyolefin or polypropylene on the image receiving layer after the
recording has been made. A glossy surface on the image receiving
layer can also be produced by heating in a glazing press or by
calendering.
The new recording material fulfils the above mentioned requirements
very satisfactorily and in particular the resolution and brilliance
can be substantially increased.
To test the image quality of the recording material, an ink
(aqueous solution of a cyan, magenta or yellow dye) which has a
viscosity of 1.2 cp at room temperature is sprayed at a pressure of
40 excess atmospheres through a glass capillary which has an
opening of 7 .mu.m. The scanning velocity, i.e. the relative
velocity between the recording substrate and the ink-jet, is 5
m/sec. With scan line densities of 10 lines per mm, viewing
densities on reflection copies of between 1.0 and 1.3 are obtained
in the case of a single colour. Reflection copies of very high
quality were obtained under these conditions in the following image
receiving layers:
EXAMPLE 1
A suitably pigmented paper (e.g. the photographic raw paper
weighing 90 g/m.sup.2 manufactured by Schoeller, Burg Gretesch) was
coated with a gelatine layer with the addition of AGEPON as wetting
agent and chrome alum as hardener. The layer had a thickness of 10
.mu.m when dry. The dye penetrated the layer to a depth of about 4
.mu.m, as shown by a thin layer section under the microscope. The
depth of penetration of the dye could be adjusted by varying the
quantity of hardener added. In the case of the reflection copies,
it was seen under the microscope that the track of a single scan
line had a width of less than 50 .mu.m whereas in uncoated paper
this track spread to a width of about 100 .mu.m. When the ink was
sprayed under the conditions defined above, viewing densities
obtained on reflection copies were 1.1 for a single colour as
compared with 0.7 in the case of an uncoated paper surface.
EXAMPLE 2
The pigmented paper was coated with a 5 .mu.m thick layer of
silicic acid sol (K100, Farbenfabriken Bayer) with the addition of
AGEPON as wetting agent. The depth of penetration of the dye
solution was approximately equal to the thickness of the layer. The
viewing density under reflected light was about 1.2 for one
colour.
EXAMPLE 3
Gelatine and barium sulphate (ratio: 1:10) were mixed with water to
form a spread coating suspension (temperature 50.degree. to
60.degree.C). Hardener (chrome alum) were added to this supsension
and in addition white toner and pigment dyes were added to adjust
the suspension to the optimum degree of whiteness. The suspension
was then applied to the raw paper to produce a layer which has a
thickness of 10 .mu.m when dry. The dye penetrated the layer to a
depth of about 6 .mu.m. The viewing densities under reflected light
were in the region of 1.1.
EXAMPLE 4
The pigmented paper was first covered with a coating of
polyethylene as gloss layer. Over this, a layer of gelatine was
cast as described in Example 1. Brilliant colours were obtained and
the viewing density was increased to 1.3.
EXAMPLE 5
An image was produced by spraying on a material which had been
prepared as described in Example 2. This image was then coated with
a layer of clear lacquer. Viewing densities of 1.3 were obtained
for each colour under reflected light and at the same time the
lightfastness and smudge resistance of the image were
increased.
EXAMPLE 6
Before application of the ink-jet image, the layer prepared
according to Example 3 was passed over a calendering press in which
the rollers were heated to about 80.degree.C. A glazing effect was
thereby obtained and the viewing densities under reflected light
were increased to 1.3 as in Example 3.
* * * * *